JP6407475B2 - 半導体装置および半導体装置を生産する方法 - Google Patents
半導体装置および半導体装置を生産する方法 Download PDFInfo
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- 239000004065 semiconductor Substances 0.000 title claims description 148
- 238000004519 manufacturing process Methods 0.000 title claims description 20
- 150000004767 nitrides Chemical class 0.000 claims description 208
- 239000013078 crystal Substances 0.000 claims description 199
- 230000017525 heat dissipation Effects 0.000 claims description 174
- 239000010432 diamond Substances 0.000 claims description 131
- 229910003460 diamond Inorganic materials 0.000 claims description 124
- 239000002131 composite material Substances 0.000 claims description 67
- 229910021417 amorphous silicon Inorganic materials 0.000 claims description 50
- 230000005764 inhibitory process Effects 0.000 claims description 44
- PMHQVHHXPFUNSP-UHFFFAOYSA-M copper(1+);methylsulfanylmethane;bromide Chemical compound Br[Cu].CSC PMHQVHHXPFUNSP-UHFFFAOYSA-M 0.000 claims description 29
- 230000002401 inhibitory effect Effects 0.000 claims description 26
- 229910021419 crystalline silicon Inorganic materials 0.000 claims description 17
- 239000011800 void material Substances 0.000 claims description 14
- 238000005229 chemical vapour deposition Methods 0.000 claims description 13
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 8
- 229910052799 carbon Inorganic materials 0.000 claims description 8
- 230000005855 radiation Effects 0.000 claims description 5
- 230000001678 irradiating effect Effects 0.000 claims 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 74
- 229910052710 silicon Inorganic materials 0.000 description 74
- 239000010703 silicon Substances 0.000 description 74
- JMASRVWKEDWRBT-UHFFFAOYSA-N Gallium nitride Chemical compound [Ga]#N JMASRVWKEDWRBT-UHFFFAOYSA-N 0.000 description 73
- 229910002601 GaN Inorganic materials 0.000 description 72
- 238000000034 method Methods 0.000 description 24
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- 238000005336 cracking Methods 0.000 description 19
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- 238000010586 diagram Methods 0.000 description 9
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- 238000004544 sputter deposition Methods 0.000 description 4
- JNDMLEXHDPKVFC-UHFFFAOYSA-N aluminum;oxygen(2-);yttrium(3+) Chemical compound [O-2].[O-2].[O-2].[Al+3].[Y+3] JNDMLEXHDPKVFC-UHFFFAOYSA-N 0.000 description 3
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- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 3
- 229910019901 yttrium aluminum garnet Inorganic materials 0.000 description 3
- PIGFYZPCRLYGLF-UHFFFAOYSA-N Aluminum nitride Chemical compound [Al]#N PIGFYZPCRLYGLF-UHFFFAOYSA-N 0.000 description 2
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- 239000002245 particle Substances 0.000 description 2
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 2
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- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- RNQKDQAVIXDKAG-UHFFFAOYSA-N aluminum gallium Chemical compound [Al].[Ga] RNQKDQAVIXDKAG-UHFFFAOYSA-N 0.000 description 1
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- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 229910003465 moissanite Inorganic materials 0.000 description 1
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- 230000006911 nucleation Effects 0.000 description 1
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- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
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Description
1.1 半導体デバイスにおける結晶窒化物層の割れの原因
表1は、ダイヤモンド、窒化ガリウム(GaN)、窒化アルミニウム(AlN)およびシリコン(Si)の各々について、線膨張率および熱伝導率を示す。
図1は、実施の形態1の半導体デバイスを示す模式図である。図1は、断面図である。
結晶窒化物層1022の一方の主面1052の領域1092は、シリコン層1024に覆われず、積層体1014の一方の主面1102を構成する。領域1092には、GaNバッファ層1036が露出する。主面1052の領域(被覆領域)1094は、シリコン層1024に覆われる。
図4は、実施の形態1の半導体デバイスを生産する方法を示すフローチャートである。図5,6,7および8の各々は、実施の形態1の半導体デバイスの仕掛品を示す模式図である。図5,6,7および8の各々は、断面図である。
図9,10,11および12は、実施の形態1の半導体デバイスに備えられる結晶窒化物層の上に形成される非晶質部分のサブ部分、ダイヤモンド等を示す。図9,10,11および12の各々は、模式図であり、断面図である。
上記の説明によれば、実施の形態1は、半導体装置1000に関する下記の発明1から7までを含み、半導体装置1000を生産する方法に関する下記の発明8および9を含む。
2.1 実施の形態1との相違
図13は、実施の形態2の半導体デバイスを示す模式図である。図13は、断面図である。図2および3の各々は、実施の形態2の半導体デバイスに備えられる非晶質部分および空隙の平面配置を示す図でもある。図4は、実施の形態2の半導体デバイスを生産する方法を示すフローチャートでもある。
上記の説明によれば、実施の形態2は、半導体装置2000に関する発明1から7までを含み、半導体装置2000を生産する方法に関する発明8および9を含む。
3.1 実施の形態1との相違
図14は、実施の形態3の半導体デバイスを示す模式図である。図14は、断面図である。図2および3の各々は、実施の形態3の半導体デバイスに備えられる非晶質部分および空隙の平面配置を示す図でもある。図4は、実施の形態3の半導体デバイスを生産する方法を示すフローチャートでもある。
上記の説明によれば、実施の形態3は、半導体装置3000に関する下記の発明1から5までを含み、半導体装置3000を生産する方法に関する下記の発明6および7を含む。
4.1 実施の形態3との相違
図15は、実施の形態4の半導体デバイスを示す断面図である。図2および3の各々は、実施の形態4の半導体デバイスに備えられる非晶質部分および空隙の平面配置を示す図でもある。図16は、実施の形態4の半導体デバイスを生産する方法を示すフローチャートである。
上記の説明によれば、実施の形態4は、半導体装置4000に関する下記の発明1から5までを含み、半導体装置4000を生産する方法に関する下記の発明6および7を含む。
Claims (14)
- 結晶窒化物層(1022,2022,3022,4022)および複合層(1024,2024,3024,4024)を備え、前記複合層(1024,2024,3024,4024)が表面におけるダイヤモンド成長を阻害しない非阻害部分(1042,2042,3042,4042)および表面におけるダイヤモンド成長を阻害する阻害部分(1044,2044,3044,4044)を備え、前記非阻害部分(1042,2042,3042,4042)が露出する第1の領域(1122,2122,3332,4332)および前記阻害部分(1044,2044,3044,4044)が露出する第2の領域(1124,2124,3312,4312)を有する積層体主面(1102,2102,3102,4102)を有する積層体(1014,2014,3014,4014)と、
ダイヤモンドからなり、前記積層体主面(1102,2102,3102,4102)に対向し、前記第1の領域(1122,2122,3332,4332)に密着し、前記第2の領域(1124,2124,3312,4312)から空隙(1072,2072,3072,4072)により分離された放熱層(1016,2016,3016,4016)と、
を備える半導体装置(1000,2000,3000,4000)。 - 前記非阻害部分(1042,2042,3042,4042)は、非晶質シリコンからなる
請求項1の半導体装置(1000,2000,3000,4000)。 - 前記阻害部分(1044,2044,3044,4044)は、結晶質シリコン、窒化アルミニウムまたはダイヤモンド状炭素からなる
請求項1または2の半導体装置(1000,2000,3000,4000)。 - 前記第1の領域(1122,2122,3332,4332)は、互いに分離された複数のサブ領域(1152,1154,1156,1158,1160,1162,1196,1198)を備え、
前記放熱層(1016,2016,3016,4016)は、前記複数のサブ領域(1152,1154,1156,1158,1160,1162,1196,1198)の各々に密着する
請求項1から3までのいずれかの半導体装置(1000,2000,3000,4000)。 - 前記空隙(1072)は、第1の空隙(1072)であり、
前記積層体主面(1102)は、前記結晶窒化物層(1022)が露出する第3の領域(1092)をさらに有し、
前記放熱層(1016)は、前記第3の領域(1092)から第2の空隙(1074)により分離される
請求項1から4までのいずれかの半導体装置(1000)。 - 前記結晶窒化物層(1022)は、前記放熱層(1016)に向けられる結晶窒化物層主面(1052)を有し、
前記結晶窒化物層主面(1052)は、前記第3の領域(1092)および前記複合層(1024)に覆われる被覆領域(1094)を有し、
前記複合層(1024)は、前記放熱層(1016)に向けられる複合層主面(1062)を有し、
前記複合層主面(1062)は、前記第1の領域(1122)および前記第2の領域(1124)を有する
請求項5の半導体装置(1000)。 - 前記結晶窒化物層(2022,3022,4022)は、前記積層体主面(2102,3102,4102)に露出しない
請求項1から4までのいずれかの半導体装置(2000,3000,4000)。 - 前記結晶窒化物層(2022,3022,4022)は、前記放熱層(2016,3016,4016)に向けられる結晶窒化物層主面(2052,3052,4052)を有し、
前記複合層(2024,3024,4024)は、前記放熱層(2016,3016,4016)に向けられる複合層主面(2062,3062,4062)を有し、前記結晶窒化物層主面(2052,3052,4052)の全体を覆い、
前記複合層主面(2062,3062,4062)は、前記第1の領域(2122,3332,4332)および前記第2の領域(2124,3312,4312)を有する
請求項7の半導体装置(2000,3000,4000)。 - 前記結晶窒化物層(1022,2022)は、前記放熱層(1016,2016)に向けられる結晶窒化物層主面(1052,2052)を有し、
前記非阻害部分(1042,2042)および前記阻害部分(1044,2044)は、前記結晶窒化物層主面(1052,2052)の上の互いに異なる領域に形成される
請求項1から8までいずれかの半導体装置(1000,2000)。 - 前記結晶窒化物層(3022,4022)は、前記放熱層(3016,4016)に向けられる結晶窒化物層主面(3052,4052)を有し、
前記阻害部分(3044,4044)は、前記放熱層(3016,4016)に向けられる阻害層主面(3302,4302)を有し前記結晶窒化物層主面(3052,4052)を覆う阻害層(3044,4044)であり、
前記阻害層主面(3302,4302)は、前記第2の領域(3312,4312)および前記非阻害部分(3042,4042)に覆われる被覆領域(3314,4314)を有し、
前記非阻害部分(3042,4042)は、前記放熱層(3016,4016)に向けられる非阻害層主面(3322,4322)を有する非阻害層(3042,4042)であり、
非阻害層主面(3322,4322)は、前記第1の領域(3332,4332)を有する
請求項1から8までいずれかの半導体装置(3000,4000)。 - a) 結晶窒化物層主面(1052,2052,3052,4052)を有する結晶窒化物層(1022,2022,3022,4022)を準備する工程(S101,S401)と、
b) 表面におけるダイヤモンド成長を阻害しない非阻害部分(1042,2042,3042,4042)および表面におけるダイヤモンド成長を阻害する阻害部分(1044,2044,3044,4044)を備える複合層(1024,2024,3024,4024)により前記結晶窒化物層主面(1052,2052,3052,4052)を覆い、前記結晶窒化物層(1022,2022,3022,4022)および前記複合層(1024,2024,3024,4024)を備え前記非阻害部分(1042,2042,3042,4042)が露出する第1の領域(1122,2122,3332,4332)および前記阻害部分(1044,2044,3044,4044)が露出する第2の領域(1124,2124,3312,4312)を有する積層体主面(1102,2102,3102,4102)を有する積層体(1014,2014,3014,4014)を得る工程(S102,S402)と、
c) 化学気相成長法により前記第1の領域(1122,2122,3332,4332)の上に多結晶ダイヤモンドを堆積し、多結晶ダイヤモンドからなり前記積層体主面(1102,2102,3102,4102)に対向し前記第1の領域(1122,2122,3332,4332)に密着し前記第2の領域(1124,2124,3312,4312)から空隙(1072,2072,3072,4072)により分離された放熱層(1016,2016,3016,4016)を形成する工程(S103,S403)と、
を備える半導体装置(1000,2000,3000,4000)を生産する方法。 - 前記非阻害部分(1042)は、非晶質シリコンからなり、
前記阻害部分(1044)は、結晶質シリコンからなり、
前記空隙(1072)は、第1の空隙(1072)であり、
工程b)は、
第1の部分(1244)、第2の部分(1246)および第3の部分(1248)を備える非晶質シリコン層(1242)により前記結晶窒化物層主面(1052)を覆い、
前記第2の部分(1246)に第1の強度を有するレーザービーム(1252)を照射し前記第3の部分(1248)に前記第1の強度より強い第2の強度を有するレーザービーム(1254)を照射することにより、前記第1の部分(1244)を前記非阻害部分(1042)とし、前記第2の部分(1246)を前記阻害部分(1044)に変化させ、前記第3の部分(1248)を除去し、前記結晶窒化物層(1022)が露出する第3の領域(1092)を前記積層体主面(1102)が有するようにし、
工程c)は、前記放熱層(1016)が前記第3の領域(1092)から第2の空隙(1074)により分離されるように前記放熱層(1016)を形成する
請求項11の半導体装置(1000)を生産する方法。 - 前記非阻害部分(2042)は、非晶質シリコンからなり、
前記阻害部分(2044)は、結晶質シリコンからなり、
工程b)は、
第1の部分および第2の部分を備える非晶質シリコン層により前記結晶窒化物層主面(2052)の全体を覆い、
前記第2の部分にレーザービームを照射することにより、前記第1の部分を前記非阻害部分(2042)とし、前記第2の部分を前記阻害部分(2044)に変化させる
請求項11の半導体装置(2000)を生産する方法。 - 前記阻害部分(3044,4044)は、阻害層主面(3302,4302)を有する阻害層(3044,4044)であり、
阻害層主面(3302,4302)は、被覆領域(3314,4314)および非被覆領域(3312,4312)を有し、
前記非阻害部分(3042,4042)は、非阻害層主面(3322,4322)を有する非阻害層(3042,4042)であり、
工程b)は、
前記阻害部分(3044,4044)により前記結晶窒化物層主面(3052,4052)を覆い、
前記非阻害部分(3042,4042)により前記被覆領域(3314,4314)を覆い、前記非阻害層主面(3322,4322)を前記第1の領域(3332,4332)にし、前記非被覆領域(3312,4312)を前記第2の領域(3312,4312)にする
請求項11の半導体装置(3000,4000)を生産する方法。
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