JP6262261B2 - Ｓｉ−Ｍｇ−Ａｌゾル、それにコアシェル微細球をドープさせた複合塗膜液及びその作製適用 - Google Patents
Ｓｉ−Ｍｇ−Ａｌゾル、それにコアシェル微細球をドープさせた複合塗膜液及びその作製適用 Download PDFInfo
- Publication number
- JP6262261B2 JP6262261B2 JP2016002185A JP2016002185A JP6262261B2 JP 6262261 B2 JP6262261 B2 JP 6262261B2 JP 2016002185 A JP2016002185 A JP 2016002185A JP 2016002185 A JP2016002185 A JP 2016002185A JP 6262261 B2 JP6262261 B2 JP 6262261B2
- Authority
- JP
- Japan
- Prior art keywords
- sol
- hydroxyl group
- aluminum
- composite coating
- magnesium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000011248 coating agent Substances 0.000 title claims description 102
- 238000000576 coating method Methods 0.000 title claims description 101
- 229910003023 Mg-Al Inorganic materials 0.000 title claims description 72
- 239000007788 liquid Substances 0.000 title claims description 53
- 239000002131 composite material Substances 0.000 title claims description 37
- 238000004519 manufacturing process Methods 0.000 title claims description 35
- 239000011258 core-shell material Substances 0.000 title claims description 32
- 239000004005 microsphere Substances 0.000 title claims description 21
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 86
- 239000011521 glass Substances 0.000 claims description 72
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 66
- 239000002904 solvent Substances 0.000 claims description 49
- 239000000243 solution Substances 0.000 claims description 42
- 239000007822 coupling agent Substances 0.000 claims description 41
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical group OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 36
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 35
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims description 32
- 159000000003 magnesium salts Chemical class 0.000 claims description 32
- 239000003054 catalyst Substances 0.000 claims description 31
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 30
- 239000003431 cross linking reagent Substances 0.000 claims description 30
- 238000000034 method Methods 0.000 claims description 29
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 24
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims description 22
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 20
- 238000001816 cooling Methods 0.000 claims description 20
- 230000032683 aging Effects 0.000 claims description 19
- -1 trialkyl trichloride Chemical compound 0.000 claims description 17
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 16
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 16
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 16
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 15
- 239000011259 mixed solution Substances 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 14
- 239000007787 solid Substances 0.000 claims description 14
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 12
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 12
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 10
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims description 10
- 239000002994 raw material Substances 0.000 claims description 9
- LEEANUDEDHYDTG-UHFFFAOYSA-N 1,2-dimethoxypropane Chemical compound COCC(C)OC LEEANUDEDHYDTG-UHFFFAOYSA-N 0.000 claims description 8
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 claims description 8
- FMVOPJLFZGSYOS-UHFFFAOYSA-N 2-[2-(2-ethoxypropoxy)propoxy]propan-1-ol Chemical compound CCOC(C)COC(C)COC(C)CO FMVOPJLFZGSYOS-UHFFFAOYSA-N 0.000 claims description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 8
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 8
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 8
- 235000011187 glycerol Nutrition 0.000 claims description 8
- YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 claims description 8
- CUDYYMUUJHLCGZ-UHFFFAOYSA-N 2-(2-methoxypropoxy)propan-1-ol Chemical compound COC(C)COC(C)CO CUDYYMUUJHLCGZ-UHFFFAOYSA-N 0.000 claims description 7
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 claims description 7
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 7
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 7
- 230000002378 acidificating effect Effects 0.000 claims description 7
- 150000002148 esters Chemical class 0.000 claims description 7
- 229910017604 nitric acid Inorganic materials 0.000 claims description 7
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 6
- 230000008569 process Effects 0.000 claims description 6
- BNGXYYYYKUGPPF-UHFFFAOYSA-M (3-methylphenyl)methyl-triphenylphosphanium;chloride Chemical compound [Cl-].CC1=CC=CC(C[P+](C=2C=CC=CC=2)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 BNGXYYYYKUGPPF-UHFFFAOYSA-M 0.000 claims description 5
- LCZVSXRMYJUNFX-UHFFFAOYSA-N 2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol Chemical compound CC(O)COC(C)COC(C)CO LCZVSXRMYJUNFX-UHFFFAOYSA-N 0.000 claims description 5
- MJWPFSQVORELDX-UHFFFAOYSA-K aluminium formate Chemical compound [Al+3].[O-]C=O.[O-]C=O.[O-]C=O MJWPFSQVORELDX-UHFFFAOYSA-K 0.000 claims description 5
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 claims description 5
- UEGPKNKPLBYCNK-UHFFFAOYSA-L magnesium acetate Chemical compound [Mg+2].CC([O-])=O.CC([O-])=O UEGPKNKPLBYCNK-UHFFFAOYSA-L 0.000 claims description 5
- 239000011654 magnesium acetate Substances 0.000 claims description 5
- 229940069446 magnesium acetate Drugs 0.000 claims description 5
- 235000011285 magnesium acetate Nutrition 0.000 claims description 5
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims description 5
- 239000001095 magnesium carbonate Substances 0.000 claims description 5
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims description 5
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 5
- QIJRBQDGQLSRLG-UHFFFAOYSA-N magnesium;pentane-2,4-dione Chemical compound [Mg].CC(=O)CC(C)=O QIJRBQDGQLSRLG-UHFFFAOYSA-N 0.000 claims description 5
- 230000003287 optical effect Effects 0.000 claims description 5
- 235000006408 oxalic acid Nutrition 0.000 claims description 5
- ZNOCGWVLWPVKAO-UHFFFAOYSA-N trimethoxy(phenyl)silane Chemical compound CO[Si](OC)(OC)C1=CC=CC=C1 ZNOCGWVLWPVKAO-UHFFFAOYSA-N 0.000 claims description 5
- HDYRYUINDGQKMC-UHFFFAOYSA-M acetyloxyaluminum;dihydrate Chemical compound O.O.CC(=O)O[Al] HDYRYUINDGQKMC-UHFFFAOYSA-M 0.000 claims description 4
- SMZOGRDCAXLAAR-UHFFFAOYSA-N aluminium isopropoxide Chemical compound [Al+3].CC(C)[O-].CC(C)[O-].CC(C)[O-] SMZOGRDCAXLAAR-UHFFFAOYSA-N 0.000 claims description 4
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 4
- 229940009827 aluminum acetate Drugs 0.000 claims description 4
- DMGNPLVEZUUCBT-UHFFFAOYSA-K aluminum;propanoate Chemical compound [Al+3].CCC([O-])=O.CCC([O-])=O.CCC([O-])=O DMGNPLVEZUUCBT-UHFFFAOYSA-K 0.000 claims description 4
- AHUXYBVKTIBBJW-UHFFFAOYSA-N dimethoxy(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](OC)(OC)C1=CC=CC=C1 AHUXYBVKTIBBJW-UHFFFAOYSA-N 0.000 claims description 4
- YYLGKUPAFFKGRQ-UHFFFAOYSA-N dimethyldiethoxysilane Chemical compound CCO[Si](C)(C)OCC YYLGKUPAFFKGRQ-UHFFFAOYSA-N 0.000 claims description 4
- 229960001708 magnesium carbonate Drugs 0.000 claims description 4
- 235000014380 magnesium carbonate Nutrition 0.000 claims description 4
- 229960002337 magnesium chloride Drugs 0.000 claims description 4
- 235000011147 magnesium chloride Nutrition 0.000 claims description 4
- GVALZJMUIHGIMD-UHFFFAOYSA-H magnesium phosphate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O GVALZJMUIHGIMD-UHFFFAOYSA-H 0.000 claims description 4
- 239000004137 magnesium phosphate Substances 0.000 claims description 4
- 229960002261 magnesium phosphate Drugs 0.000 claims description 4
- 229910000157 magnesium phosphate Inorganic materials 0.000 claims description 4
- 235000010994 magnesium phosphates Nutrition 0.000 claims description 4
- 239000000391 magnesium silicate Substances 0.000 claims description 4
- 229910052919 magnesium silicate Inorganic materials 0.000 claims description 4
- 235000019792 magnesium silicate Nutrition 0.000 claims description 4
- 229960002366 magnesium silicate Drugs 0.000 claims description 4
- ZADYMNAVLSWLEQ-UHFFFAOYSA-N magnesium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[Mg+2].[Si+4] ZADYMNAVLSWLEQ-UHFFFAOYSA-N 0.000 claims description 4
- LFQCEHFDDXELDD-UHFFFAOYSA-N tetramethyl orthosilicate Chemical compound CO[Si](OC)(OC)OC LFQCEHFDDXELDD-UHFFFAOYSA-N 0.000 claims description 4
- JCVQKRGIASEUKR-UHFFFAOYSA-N triethoxy(phenyl)silane Chemical compound CCO[Si](OCC)(OCC)C1=CC=CC=C1 JCVQKRGIASEUKR-UHFFFAOYSA-N 0.000 claims description 4
- 238000003756 stirring Methods 0.000 description 55
- 238000002834 transmittance Methods 0.000 description 41
- 238000012360 testing method Methods 0.000 description 40
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 25
- 238000005259 measurement Methods 0.000 description 20
- 239000011257 shell material Substances 0.000 description 16
- 239000008367 deionised water Substances 0.000 description 12
- 229910021641 deionized water Inorganic materials 0.000 description 12
- 238000002360 preparation method Methods 0.000 description 11
- 239000002253 acid Substances 0.000 description 10
- 239000003795 chemical substances by application Substances 0.000 description 10
- 239000002245 particle Substances 0.000 description 10
- 239000006117 anti-reflective coating Substances 0.000 description 9
- 230000008859 change Effects 0.000 description 8
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 7
- 230000005540 biological transmission Effects 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- 239000000463 material Substances 0.000 description 5
- 239000012528 membrane Substances 0.000 description 5
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 5
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 5
- 230000003595 spectral effect Effects 0.000 description 5
- 239000000758 substrate Substances 0.000 description 5
- 238000003786 synthesis reaction Methods 0.000 description 5
- 102100038784 Carbohydrate sulfotransferase 4 Human genes 0.000 description 4
- 101710158423 Carbohydrate sulfotransferase 4 Proteins 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 230000035699 permeability Effects 0.000 description 4
- 238000005057 refrigeration Methods 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- WAEVWDZKMBQDEJ-UHFFFAOYSA-N 2-[2-(2-methoxypropoxy)propoxy]propan-1-ol Chemical compound COC(C)COC(C)COC(C)CO WAEVWDZKMBQDEJ-UHFFFAOYSA-N 0.000 description 3
- 239000003377 acid catalyst Substances 0.000 description 3
- 238000004364 calculation method Methods 0.000 description 3
- SDGKUVSVPIIUCF-UHFFFAOYSA-N 2,6-dimethylpiperidine Chemical compound CC1CCCC(C)N1 SDGKUVSVPIIUCF-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 238000012512 characterization method Methods 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 238000005188 flotation Methods 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 238000010248 power generation Methods 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 238000003980 solgel method Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- COPFMLHTUMFXGR-OSZYEJKESA-N (Z)-19-methyl-1-[(Z)-octadec-9-enoxy]icos-9-ene Chemical group C(C)(C)CCCCCCCC\C=C/CCCCCCCCOCCCCCCCC\C=C/CCCCCCCC COPFMLHTUMFXGR-OSZYEJKESA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- UWIULCYKVGIOPW-UHFFFAOYSA-N Glycolone Natural products CCOC1=C(CC=CC)C(=O)N(C)c2c(O)cccc12 UWIULCYKVGIOPW-UHFFFAOYSA-N 0.000 description 1
- 229910018011 MK-II Inorganic materials 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- HUAJMGSKVSZNCK-UHFFFAOYSA-K [Cl-].[Cl-].[Cl-].[Al+3].[Al+3].[Al+3] Chemical compound [Cl-].[Cl-].[Cl-].[Al+3].[Al+3].[Al+3] HUAJMGSKVSZNCK-UHFFFAOYSA-K 0.000 description 1
- 239000002318 adhesion promoter Substances 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- WADSLQQIOJIXTB-UHFFFAOYSA-L dichloroalumane Chemical compound Cl[AlH]Cl WADSLQQIOJIXTB-UHFFFAOYSA-L 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 125000005822 ethenylethoxy group Chemical group [H]\[#6]([H])=[#6](\[H])C([H])([H])C([H])([H])[#8]-* 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000007888 film coating Substances 0.000 description 1
- 238000009501 film coating Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 238000012643 polycondensation polymerization Methods 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- 239000008279 sol Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 238000013268 sustained release Methods 0.000 description 1
- 239000012730 sustained-release form Substances 0.000 description 1
- 238000005496 tempering Methods 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
- Surface Treatment Of Glass (AREA)
- Silicon Compounds (AREA)
- Surface Treatment Of Optical Elements (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510312827.0 | 2015-06-09 | ||
| CN201510312827.0A CN104927416B (zh) | 2015-06-09 | 2015-06-09 | 硅镁铝溶胶和掺杂核壳二氧化硅微球镀膜液及制备应用 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2017001934A JP2017001934A (ja) | 2017-01-05 |
| JP6262261B2 true JP6262261B2 (ja) | 2018-01-17 |
Family
ID=54114853
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2016002185A Active JP6262261B2 (ja) | 2015-06-09 | 2016-01-08 | Ｓｉ−Ｍｇ−Ａｌゾル、それにコアシェル微細球をドープさせた複合塗膜液及びその作製適用 |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JP6262261B2 (zh) |
| CN (1) | CN104927416B (zh) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105964195B (zh) * | 2016-05-06 | 2019-01-11 | 东莞南玻太阳能玻璃有限公司 | 纳米核壳二氧化硅微球及增透减反复合镀膜液制备应用 |
| JP7048616B2 (ja) * | 2017-07-26 | 2022-04-05 | 富士フイルム株式会社 | インク組成物及びその製造方法、並びに画像形成方法 |
| CN109852157B (zh) * | 2018-11-29 | 2021-06-18 | 东莞南玻太阳能玻璃有限公司 | 一种高硬度ar镀膜液及其制备方法 |
| CN110189655B (zh) * | 2019-05-27 | 2021-10-08 | 深圳市致竑光电有限公司 | 一种发光玻璃模组 |
| CN110724430B (zh) * | 2019-09-05 | 2021-10-26 | 深圳市安品有机硅材料有限公司 | 一种水性复合涂层材料及其制备方法和应用 |
| CN114573244B (zh) * | 2022-03-23 | 2023-11-17 | 东莞南玻太阳能玻璃有限公司 | 一种硅铝溶胶及其制备方法和应用 |
| CN115403050B (zh) * | 2022-08-17 | 2024-04-12 | 浙江博来纳润电子材料有限公司 | 一种高纯有机铝改性酸性硅溶胶及其制备方法和应用 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102004027842A1 (de) * | 2004-06-08 | 2006-01-12 | Institut für Neue Materialien Gemeinnützige GmbH | Abrieb- und kratzfeste Beschichtungen mit niedriger Brechzahl auf einem Substrat |
| JP2011175252A (ja) * | 2010-02-01 | 2011-09-08 | Central Glass Co Ltd | 親水性低反射部材 |
| CN101880154B (zh) * | 2010-06-25 | 2013-01-09 | 沈阳大学 | 高频片式电感用纳米堇青石基陶瓷介质材料的制备方法 |
| CN102531406B (zh) * | 2012-01-17 | 2015-03-25 | 信义玻璃工程（东莞）有限公司 | 减反射镀膜溶液、其制备方法和光伏玻璃及其制备方法 |
| CN102702966B (zh) * | 2012-05-24 | 2014-08-06 | 长兴化学材料(珠海)有限公司 | 减反射组合物及其制造方法与用途 |
| CN104101918B (zh) * | 2013-04-03 | 2017-03-01 | 法国圣戈班玻璃公司 | 一种光学增透膜及其制备方法和光学组件 |
-
2015
- 2015-06-09 CN CN201510312827.0A patent/CN104927416B/zh active Active
-
2016
- 2016-01-08 JP JP2016002185A patent/JP6262261B2/ja active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN104927416A (zh) | 2015-09-23 |
| CN104927416B (zh) | 2017-08-29 |
| JP2017001934A (ja) | 2017-01-05 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP6262261B2 (ja) | Ｓｉ−Ｍｇ−Ａｌゾル、それにコアシェル微細球をドープさせた複合塗膜液及びその作製適用 | |
| CN109321050B (zh) | 一种耐候涂液、耐候性汽车玻璃及其制造方法 | |
| CN108300286B (zh) | 掺锆二氧化硅聚合物溶胶及其增透减反镀膜液的制备应用 | |
| CN105439457B (zh) | 链状或网状硅溶胶及超亲水自清洁增透镀膜液及制备应用 | |
| CN103305036B (zh) | 一种含poss减反射膜镀膜液及其制备方法与应用 | |
| CN105964195A (zh) | 纳米核壳二氧化硅微球及增透减反复合镀膜液制备应用 | |
| US20150056438A1 (en) | Hollow Silica Particles, Method of Manufacturing the Same, Composition Including the Same and Sheet with Inner Cavities | |
| TWI480345B (zh) | 塗料及其製備方法及塗料所形成之薄膜 | |
| CN102849962A (zh) | 一种二氧化硅超疏水薄膜的制备方法及一种超疏水材料 | |
| TWI633162B (zh) | 塗料組合物、其製備方法及其用途 | |
| CN102408765B (zh) | 一种紫外线和电子束固化隔热涂料 | |
| CN103408947A (zh) | 一种可双重固化的高性能led封装材料及其制备方法 | |
| CN103459139A (zh) | 功能性物品、运输机械用物品、建筑用物品及涂布用组合物 | |
| CN103596669B (zh) | 杂化封装材料制造方法 | |
| JP6233136B2 (ja) | 膜形成用液組成物 | |
| KR20190100231A (ko) | 블랙 매트릭스용 조성물, 블랙 매트릭스, 및 블랙 매트릭스의 제조 방법 | |
| JP2009108155A (ja) | 繊維状中空シリカ微粒子分散液、繊維状中空シリカ微粒子ならびに該微粒子を含有する反射防止被膜形成用組成物および反射防止被膜付基材 | |
| CN102964983A (zh) | 一种硅杂化复合涂覆电子胶及其制备方法 | |
| JP2012216814A (ja) | 薄膜太陽電池向け透明導電膜用組成物および透明導電膜 | |
| CN110386761B (zh) | 一种具有高透光率的超疏水减反射涂层的制备方法 | |
| CN103360800B (zh) | 高漂浮型水性铝银浆及其制备方法 | |
| TWI480344B (zh) | 白色塗料組合物及包含其所形成之塗層的裝置 | |
| JP6451424B2 (ja) | 高耐久性低屈折率膜 | |
| JP2013043791A (ja) | 変性中空シリカ微粒子 | |
| JP6123432B2 (ja) | 低屈折率膜形成用組成物の製造方法及び低屈折率膜の形成方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20170307 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20170607 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20171205 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20171213 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 6262261 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |