JP6258976B2 - イオン交換プロセスに適合した装飾用多孔性無機層を表面に有する強化ガラス物品 - Google Patents
イオン交換プロセスに適合した装飾用多孔性無機層を表面に有する強化ガラス物品 Download PDFInfo
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- JP6258976B2 JP6258976B2 JP2015559034A JP2015559034A JP6258976B2 JP 6258976 B2 JP6258976 B2 JP 6258976B2 JP 2015559034 A JP2015559034 A JP 2015559034A JP 2015559034 A JP2015559034 A JP 2015559034A JP 6258976 B2 JP6258976 B2 JP 6258976B2
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- 239000005341 toughened glass Substances 0.000 title claims description 28
- 238000005342 ion exchange Methods 0.000 title description 26
- 239000011521 glass Substances 0.000 claims description 100
- 239000000758 substrate Substances 0.000 claims description 44
- 239000002245 particle Substances 0.000 claims description 21
- 230000009477 glass transition Effects 0.000 claims description 11
- 239000000843 powder Substances 0.000 claims description 8
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 2
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 2
- 238000000034 method Methods 0.000 description 23
- 239000000049 pigment Substances 0.000 description 18
- 239000000203 mixture Substances 0.000 description 17
- 230000008569 process Effects 0.000 description 17
- 238000005034 decoration Methods 0.000 description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 8
- 239000011734 sodium Substances 0.000 description 8
- 150000002500 ions Chemical group 0.000 description 7
- 238000007650 screen-printing Methods 0.000 description 6
- 238000003426 chemical strengthening reaction Methods 0.000 description 5
- 239000005400 gorilla glass Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 241000282575 Gorilla Species 0.000 description 4
- 238000005452 bending Methods 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 239000011230 binding agent Substances 0.000 description 4
- 238000000151 deposition Methods 0.000 description 4
- 238000000227 grinding Methods 0.000 description 4
- 239000000377 silicon dioxide Substances 0.000 description 4
- 239000006060 molten glass Substances 0.000 description 3
- 239000010665 pine oil Substances 0.000 description 3
- 238000005728 strengthening Methods 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- JGDFBJMWFLXCLJ-UHFFFAOYSA-N copper chromite Chemical compound [Cu]=O.[Cu]=O.O=[Cr]O[Cr]=O JGDFBJMWFLXCLJ-UHFFFAOYSA-N 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000007679 ring-on-ring test Methods 0.000 description 2
- 238000007873 sieving Methods 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 229910001415 sodium ion Inorganic materials 0.000 description 2
- 229910052596 spinel Inorganic materials 0.000 description 2
- 239000011029 spinel Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 239000005407 aluminoborosilicate glass Substances 0.000 description 1
- 239000005354 aluminosilicate glass Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 238000005352 clarification Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000004031 devitrification Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000005357 flat glass Substances 0.000 description 1
- 238000007496 glass forming Methods 0.000 description 1
- 229910001416 lithium ion Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229910001414 potassium ion Inorganic materials 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 239000006254 rheological additive Substances 0.000 description 1
- 239000005361 soda-lime glass Substances 0.000 description 1
- 238000007619 statistical method Methods 0.000 description 1
- 239000006058 strengthened glass Substances 0.000 description 1
- 238000005496 tempering Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C21/00—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface
- C03C21/001—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface in liquid phase, e.g. molten salts, solutions
- C03C21/002—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface in liquid phase, e.g. molten salts, solutions to perform ion-exchange between alkali ions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
- C03C17/007—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character containing a dispersed phase, e.g. particles, fibres or flakes, in a continuous phase
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/02—Surface treatment of glass, not in the form of fibres or filaments, by coating with glass
- C03C17/04—Surface treatment of glass, not in the form of fibres or filaments, by coating with glass by fritting glass powder
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/12—Silica-free oxide glass compositions
- C03C3/16—Silica-free oxide glass compositions containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/12—Silica-free oxide glass compositions
- C03C3/16—Silica-free oxide glass compositions containing phosphorus
- C03C3/17—Silica-free oxide glass compositions containing phosphorus containing aluminium or beryllium
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/12—Silica-free oxide glass compositions
- C03C3/16—Silica-free oxide glass compositions containing phosphorus
- C03C3/21—Silica-free oxide glass compositions containing phosphorus containing titanium, zirconium, vanadium, tungsten or molybdenum
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
- C03C4/18—Compositions for glass with special properties for ion-sensitive glass
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
- C03C8/08—Frit compositions, i.e. in a powdered or comminuted form containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2204/00—Glasses, glazes or enamels with special properties
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2207/00—Compositions specially applicable for the manufacture of vitreous enamels
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/21—Oxides
- C03C2217/23—Mixtures
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/40—Coatings comprising at least one inhomogeneous layer
- C03C2217/425—Coatings comprising at least one inhomogeneous layer consisting of a porous layer
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/70—Properties of coatings
- C03C2217/72—Decorative coatings
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Composite Materials (AREA)
- Glass Compositions (AREA)
- Surface Treatment Of Glass (AREA)
Description
表2及び3において提供される以下の実施例(実施例1〜16)は、≧450℃のガラス転移温度(Tg)、≦650℃のガラス軟化温度(Ts)、及びガラス基材に対して10X10−7/℃以内の熱膨張係数(CTE)を有する、本開示の1つ又は複数の実施形態による例示的な無機結晶化ガラスフリットである。表4は、実施例3、7及び16に関する具体的な特性を列挙している。
下の表5は、本発明の一部ではないフリットの組成物の複数の比較例を列挙している。比較例1、2及び3は高すぎる、即ち650℃超の軟化点(Ts)を有する。あるいは、比較例4、6及び9は、高すぎる、即ち110X10−7/℃を優に超えるCTE値を有する。これは、硬化後の装飾された層のCTEとGorillaガラスのCTEとの大きな不一致をもたらした。これらの試料は全て、硬化後に損傷した。比較例5を用いると、極めて悪い品質の層が得られた。スクリーン印刷後の基材上のペーストの湿潤性は極めて低く、硬化後の装飾用層の粗度は極めて高かった。比較例7から溶融物は得られず、比較例8では極めて急速な失透が起こった。よってこれら2つの組成物は加工できなかった。比較例10に関して、硬化の前の装飾用層の極めて低い安定性が観察された。具体的には、層の色が灰色からピンク色に急速に変化した。
実施例6の組成物を利用して、下の表6は、粒子サイズが硬化後の装飾用多孔性無機層の多孔性に対して有する影響を、総粒子数の50%(d50)及び90%(d90)における粒子サイズとの関連において示す。層の多孔性レベルを、装飾の上面に堆積された水により視覚制御する。装飾内部での水の拡散に直接的に結び付く、0〜5の等級内の多孔性の定性的値は、以下のように定義される‐0は多孔性がないことを意味し、5は極めて高い多孔性を意味する。
下の表8は、イオン交換され、機械的耐性に関して特徴づけられた、異なる多孔性レベルを有する複数の装飾された試料を示す。表8に示した通り、ROR(リングオンリング)曲げ強度値は、装飾用多孔性無機層の多孔性に関連している。更に、多孔性の高い装飾用ガラスフリット層に関して400MPaより高いROR値が得られ、そのうちの全てはGorillaガラス上での良好な付着性を有していた。これらのROR値は、摩耗していない試料のリングオンリング測定及び後続のワイブル分析を利用することにより得られた。
10 ガラス基材
20 装飾用多孔性無機層
30 圧縮応力層
Claims (5)
- 強化ガラス物品であって、
前記強化ガラス物品は:
ガラス基材;及び
前記ガラス基材の表面の少なくとも一部に結合された少なくとも1つの装飾用多孔性無機層であって、ここで前記装飾用多孔性無機層は≧450℃のガラス転移温度(Tg)、≦650℃のガラス軟化温度(Ts)を有し、ここで前記ガラス基材と前記装飾用多孔性無機層との間の熱膨張係数の差は、少なくとも室温から前記ガラス転移温度の温度範囲内において10X10−7/℃以内である、装飾用多孔性無機層
を備え、
前記ガラス基材は、少なくとも室温から前記ガラス転移温度の温度範囲内において、60X10 −7 /℃〜110X10 −7 /℃の範囲の熱膨張係数を有し、
前記強化ガラス物品は、前記ガラス基材中において、該ガラス基材の前記表面から≧30μmの層深さDOLを有する圧縮応力層を備えている、強化ガラス物品。 - 前記装飾用多孔性無機層はフリット粉末を含む層であり、前記フリット粉末は、(d50)≦15μmのメジアン粒径を画定し、又は50μm以下の粒径を画定し、又は少なくとも90%の粒子が(d90)≦40μmの直径を有する粒径を画定し、又は125μm以下の粒径を画定する、請求項1に記載の強化ガラス物品。
- 前記装飾用多孔性無機層は:
0〜10mol%のAl2O3;
0〜10mol%のCoO;
5〜25mol%のNa2O;
0〜15mol%のK2O;
0〜10mol%のV2O5;
0〜8mol%のTiO2;
0〜15mol%のZnO;
0〜10mol%のCaO;
20〜40mol%のFe2O3;及び
少なくとも50mol%のP2O5
を含む、請求項1に記載の強化ガラス物品。 - 前記装飾用多孔性無機層は、8〜25mol%のR2Oを含み、ここでR2OはNa2O、K2O、又はその両方であり、
前記装飾用多孔性無機層は、50〜60mol%のP2O5を含み、
Na2O/Fe2O3のmol%による比は、0.2〜1である、請求項3に記載の強化ガラス物品。 - 前記ガラス軟化温度Tsは500〜650℃である、請求項1に記載の強化ガラス物品。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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US201361769518P | 2013-02-26 | 2013-02-26 | |
US61/769,518 | 2013-02-26 | ||
PCT/US2014/017911 WO2014133932A1 (en) | 2013-02-26 | 2014-02-24 | Decorative porous inorganic layer compatible with ion exchange processes |
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US (2) | US11554986B2 (ja) |
EP (1) | EP2961705B1 (ja) |
JP (2) | JP6258976B2 (ja) |
KR (1) | KR20160021747A (ja) |
CN (1) | CN105143128B (ja) |
WO (1) | WO2014133932A1 (ja) |
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CN105705330B (zh) * | 2013-08-29 | 2019-06-04 | 康宁股份有限公司 | 薄玻璃层压结构 |
WO2017106085A1 (en) * | 2015-12-16 | 2017-06-22 | Corning Incorporated | Decorative non-porous layers for ion-exchangeable glass substrates |
WO2017147854A1 (zh) * | 2016-03-03 | 2017-09-08 | 深圳市东丽华科技有限公司 | 一种玻璃用涂料 |
KR102558050B1 (ko) * | 2016-08-05 | 2023-07-21 | 엘지전자 주식회사 | 3차원 형상 글래스 제조방법 |
CO2017013094A1 (es) | 2017-09-30 | 2018-03-28 | Agp America Sa | Artículo de vidrio con frita de vidrio y método de formación de fritas de vidrio |
US11970421B2 (en) * | 2018-12-21 | 2024-04-30 | Corning Incorporated | Strengthened 3D printed surface features and methods of making the same |
US11427498B2 (en) | 2019-03-06 | 2022-08-30 | Owens-Brockway Glass Container Inc. | Three-dimensional printing of a porous matrix on a container |
JP7377282B2 (ja) * | 2019-04-16 | 2023-11-09 | コーニング インコーポレイテッド | イオン交換および自動車用ガラスのための細孔充填装飾層 |
JP2023553170A (ja) | 2020-12-10 | 2023-12-20 | コーニング インコーポレイテッド | 車両のフロントガラス用の特有の破壊挙動を備えたガラス |
WO2023107300A1 (en) | 2021-12-06 | 2023-06-15 | Corning Incorporated | Chemically durable borosilicate glass compositions for storing pharmaceutical compositions and articles formed therefrom |
WO2023172447A1 (en) | 2022-03-09 | 2023-09-14 | Corning Incorporated | Boroaluminosilicate glass composition having high fusion flow rate and advantaged pair shaping temperature |
WO2023224799A1 (en) | 2022-05-18 | 2023-11-23 | Corning Incorporated | Decorative enamel for automotive glasses and associated methods |
WO2023244750A1 (en) | 2022-06-15 | 2023-12-21 | Corning Incorporated | Solar devices with borosilicate glass and methods of the same |
WO2023244747A1 (en) | 2022-06-15 | 2023-12-21 | Corning Incorporated | IGUs AND WINDOWS HAVING BOROSILICATE GLASS AND METHODS OF THE SAME |
WO2024112425A1 (en) | 2022-11-22 | 2024-05-30 | Corning Incorporated | Glass articles and methods of making the same |
WO2024118750A1 (en) | 2022-11-29 | 2024-06-06 | Corning Incorporated | Decorative enamel for automotive glasses and associated methods |
Family Cites Families (57)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3721594A (en) * | 1969-07-01 | 1973-03-20 | Ppg Industries Inc | Applying electroconductive heating circuits to glass |
US3723080A (en) | 1971-02-12 | 1973-03-27 | Corning Glass Works | Ion-exchange strengthened electrically-heated glass |
US3773489A (en) * | 1971-03-16 | 1973-11-20 | Corning Glass Works | Chemically strengthened glass |
US4080694A (en) | 1974-07-17 | 1978-03-28 | Uniroyal, Inc. | Method for separating and winding pre-treated tire cord |
GB2079119A (en) | 1980-06-17 | 1982-01-13 | Bfg Glassgroup | Vitreous cooking hob |
JPS58151476A (ja) | 1982-02-28 | 1983-09-08 | Matsushita Electric Works Ltd | ほうろう製品の製法 |
JPS61151043A (ja) | 1984-12-22 | 1986-07-09 | Matsushita Electric Works Ltd | ガラス製品の強化方法 |
JPH0735270B2 (ja) * | 1987-03-24 | 1995-04-19 | 日本板硝子株式会社 | ガラスのイオン交換処理方法 |
US5215563A (en) * | 1990-05-04 | 1993-06-01 | Alfred University | Process for preparing a durable glass composition |
DE4109710C1 (ja) | 1991-03-23 | 1992-02-27 | Vegla Vereinigte Glaswerke Gmbh, 5100 Aachen, De | |
US5298329A (en) | 1992-04-28 | 1994-03-29 | Martin Marietta Energy Systems, Inc. | Alkali-lead-iron phosphate glass and associated method |
DE4316575C1 (de) | 1993-05-18 | 1994-07-07 | Ver Glaswerke Gmbh | Verfahren zur Herstellung einer gebogenen Verbundglasscheibe, insbesondere Autoglasscheibe |
US5451180A (en) | 1994-01-03 | 1995-09-19 | Thinkway Trading Corporation | Toy with a movable figure |
JP3858292B2 (ja) * | 1995-11-02 | 2006-12-13 | 日本電気硝子株式会社 | 低膨張結晶化ガラス装飾用組成物および装飾低膨張結晶化ガラス板 |
US6624104B2 (en) | 1998-04-27 | 2003-09-23 | Ferro Glass & Color Corporation | High durability low temperature lead-free glass and enamel compositions with low boron content |
DE19843419A1 (de) * | 1998-09-22 | 2000-03-23 | Patent Treuhand Ges Fuer Elektrische Gluehlampen Mbh | Entladungslampe mit dielektrisch behinderten Elektroden |
DE19939737A1 (de) * | 1999-08-21 | 2001-02-22 | Dmc2 Degussa Metals Catalysts | Verfahren zur Herstellung schwarzer recyclingfähiger Glasemails, Glasfarbe hierfür und damit emaillierte Glassubstrate |
US6733850B1 (en) | 1999-10-22 | 2004-05-11 | Nippon Sheet Glass Co., Ltd. | Glass panel and production method therefor |
SG99350A1 (en) | 2000-02-17 | 2003-10-27 | Hoya Corp | Glass for cathode-ray tube, strengthened glass, method for the production thereof and use thereof |
JP2002234754A (ja) * | 2001-02-02 | 2002-08-23 | Nippon Sheet Glass Co Ltd | 強化された機能性膜被覆ガラス物品の製造方法 |
US6742360B2 (en) | 2001-02-26 | 2004-06-01 | Sony Corporation | Frit coating method, a frit coating apparatus, a sealing apparatus, and a sealing method for a flat-type cathode-ray tube |
JP2003095699A (ja) | 2001-09-19 | 2003-04-03 | Ishizuka Glass Co Ltd | 印刷部を有する強化ガラス製品の製法 |
US7179512B2 (en) | 2002-05-14 | 2007-02-20 | Fujitsu Limited | Liquid crystal display and manufacturing method of same |
GB0219583D0 (en) | 2002-08-22 | 2002-10-02 | Johnson Matthey Plc | Ceramic ink |
US6998776B2 (en) | 2003-04-16 | 2006-02-14 | Corning Incorporated | Glass package that is hermetically sealed with a frit and method of fabrication |
DE102004026433A1 (de) * | 2004-05-29 | 2005-12-22 | Schott Ag | Nanoglaspulver und deren Verwendung |
US7435695B2 (en) * | 2004-12-09 | 2008-10-14 | B.G. Negev Technologies And Applications Ltd. | Lead-free phosphate glasses |
US20060154085A1 (en) | 2005-01-12 | 2006-07-13 | Visteon Global Technologies, Inc. | Multilayered article having decorative frit layer for vehicle windshield and method for making same |
DE102005018246A1 (de) | 2005-04-19 | 2006-10-26 | Schott Ag | Glas- oder Glaskeramik-Artikel mit dekorativer Beschichtung |
GB0512077D0 (en) | 2005-06-14 | 2005-07-20 | Pilkington Plc | Glazing |
JP5178204B2 (ja) | 2005-12-06 | 2013-04-10 | コーニング インコーポレイテッド | フリットで密封されたガラスパッケージおよびその製造方法 |
US7439201B2 (en) | 2006-08-29 | 2008-10-21 | Corning Incorporation | Lead-free frits for plasma displays and other glass devices utilizing glass sealing materials |
FR2908406B1 (fr) | 2006-11-14 | 2012-08-24 | Saint Gobain | Couche poreuse, son procede de fabrication et ses applications. |
US8444967B2 (en) | 2010-07-09 | 2013-05-21 | Master Supplements, Inc. | Treatment including prebiotic composition for use with probiotics |
US7560401B2 (en) | 2007-04-20 | 2009-07-14 | Johnson Matthey Public Limited Company | Frits and obscuration enamels for automotive applications |
JP5743125B2 (ja) | 2007-09-27 | 2015-07-01 | 日本電気硝子株式会社 | 強化ガラス及び強化ガラス基板 |
US8500933B2 (en) | 2007-12-14 | 2013-08-06 | Guardian Industries Corp. | Localized heating of edge seals for a vacuum insulating glass unit, and/or unitized oven for accomplishing the same |
JP5552743B2 (ja) | 2008-03-28 | 2014-07-16 | 旭硝子株式会社 | フリット |
US7992411B2 (en) | 2008-05-30 | 2011-08-09 | Corning Incorporated | Method for sintering a frit to a glass plate |
US20100095705A1 (en) | 2008-10-20 | 2010-04-22 | Burkhalter Robert S | Method for forming a dry glass-based frit |
JP2010120823A (ja) | 2008-11-21 | 2010-06-03 | Tokyo Univ Of Science | 着色ガラス複合体およびその製造方法 |
JP2010235408A (ja) * | 2009-03-31 | 2010-10-21 | Central Glass Co Ltd | 封着用無鉛着色ガラス |
JP5678410B2 (ja) | 2009-03-31 | 2015-03-04 | セントラル硝子株式会社 | 無鉛低融点ガラス |
US8440479B2 (en) | 2009-05-28 | 2013-05-14 | Corning Incorporated | Method for forming an organic light emitting diode device |
CN104891806B (zh) * | 2009-06-19 | 2017-09-08 | 费罗公司 | 瓷釉组合物和红色颜料组合物的制备方法 |
US8802581B2 (en) | 2009-08-21 | 2014-08-12 | Corning Incorporated | Zircon compatible glasses for down draw |
JP5433372B2 (ja) * | 2009-10-20 | 2014-03-05 | フクビ化学工業株式会社 | 反射防止強化ガラスの製造方法 |
CN102092940A (zh) | 2009-12-11 | 2011-06-15 | 肖特公开股份有限公司 | 用于触摸屏的铝硅酸盐玻璃 |
US20110183118A1 (en) * | 2010-01-28 | 2011-07-28 | Lisa Ann Lamberson | Glass frit coatings for impact resistance |
CN101885582B (zh) | 2010-06-11 | 2012-02-08 | 济南大学 | 四元磷酸铁锂玻璃及其制备方法 |
US9822580B2 (en) | 2011-02-22 | 2017-11-21 | Guardian Glass, LLC | Localized heating techniques incorporating tunable infrared element(s) for vacuum insulating glass units, and/or apparatuses for same |
US8802203B2 (en) | 2011-02-22 | 2014-08-12 | Guardian Industries Corp. | Vanadium-based frit materials, and/or methods of making the same |
US8772189B2 (en) * | 2011-05-04 | 2014-07-08 | Ferro Corporation | Glass frit compositions for enamels |
EP2794500A4 (en) | 2012-04-24 | 2015-09-02 | Ferro Corp | HEAVY-METAL-FREE GLASSEMAIL WITH INTERCHANGEABLE IONS |
US9346708B2 (en) * | 2012-05-04 | 2016-05-24 | Corning Incorporated | Strengthened glass substrates with glass frits and methods for making the same |
US8591278B1 (en) * | 2012-09-20 | 2013-11-26 | E. I. Du Pont De Nemours And Company | Method of manufacturing PDP bus electrode |
US10297787B2 (en) * | 2014-04-21 | 2019-05-21 | Corning Incorporated | Laser welding of high thermal expansion glasses and glass-ceramics |
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US20230183129A1 (en) | 2023-06-15 |
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US11554986B2 (en) | 2023-01-17 |
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