JP6225387B2 - 水性樹脂組成物、コーティング剤及び物品 - Google Patents
水性樹脂組成物、コーティング剤及び物品 Download PDFInfo
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- JP6225387B2 JP6225387B2 JP2016544490A JP2016544490A JP6225387B2 JP 6225387 B2 JP6225387 B2 JP 6225387B2 JP 2016544490 A JP2016544490 A JP 2016544490A JP 2016544490 A JP2016544490 A JP 2016544490A JP 6225387 B2 JP6225387 B2 JP 6225387B2
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- 239000011734 sodium Substances 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 1
- 239000001593 sorbitan monooleate Substances 0.000 description 1
- 235000011069 sorbitan monooleate Nutrition 0.000 description 1
- 229940035049 sorbitan monooleate Drugs 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229960004793 sucrose Drugs 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 238000012719 thermal polymerization Methods 0.000 description 1
- WJCNZQLZVWNLKY-UHFFFAOYSA-N thiabendazole Chemical compound S1C=NC(C=2NC3=CC=CC=C3N=2)=C1 WJCNZQLZVWNLKY-UHFFFAOYSA-N 0.000 description 1
- JOUDBUYBGJYFFP-FOCLMDBBSA-N thioindigo Chemical compound S\1C2=CC=CC=C2C(=O)C/1=C1/C(=O)C2=CC=CC=C2S1 JOUDBUYBGJYFFP-FOCLMDBBSA-N 0.000 description 1
- YRHRIQCWCFGUEQ-UHFFFAOYSA-N thioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3SC2=C1 YRHRIQCWCFGUEQ-UHFFFAOYSA-N 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 229940043810 zinc pyrithione Drugs 0.000 description 1
- PICXIOQBANWBIZ-UHFFFAOYSA-N zinc;1-oxidopyridine-2-thione Chemical compound [Zn+2].[O-]N1C=CC=CC1=S.[O-]N1C=CC=CC1=S PICXIOQBANWBIZ-UHFFFAOYSA-N 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/67—Unsaturated compounds having active hydrogen
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
- C08L75/14—Polyurethanes having carbon-to-carbon unsaturated bonds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polyurethanes Or Polyureas (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Description
加熱装置、攪拌機、温度計及び還流冷却管を備えた2リットル4つ口フラスコに、メチルエチルケトン89.9質量部、ポリカーボネートポリオール(1,6−ヘキサンジオールと1,5−ペンタンジオールとジエチルカーボネートとを反応させて得られるポリカーボネートポリオール、数平均分子量2000)90質量部、2,2−ジメチロールプロピオン酸12.2質量部、1,6−ヘキサンジオール11.8質量部、ペンタエリスリトールジアクリレート(一般式(1)中のR1は、炭素原子数3のもので、重合性不飽和基を有する原子団を2つ有するものである。)20.1質量部、メチルヒドロキノン0.004質量部、及び、2,6−tert−ブチル−p−クレゾール0.04質量部を仕込み、撹拌しながら50℃に調整した。
加熱装置、攪拌機、温度計及び還流冷却管を備えた2リットル4つ口フラスコに、メチルエチルケトン49.9質量部、ポリカーボネートポリオール(1,6−ヘキサンジオールと1,5−ペンタンジオールとジエチルカーボネートとを反応させて得られるポリカーボネートポリオール、数平均分子量2000)50質量部、2,2−ジメチロールプロピオン酸6.8質量部、1,6−ヘキサンジオール6.6質量部、ペンタエリスリトールジアクリレート(一般式(1)中のR1は、炭素原子数3のもので、重合性不飽和基を有する原子団を2つ有するものである。)11.2質量部、メチルヒドロキノン0.0022質量部、及び、2,6−tert−ブチル−p−クレゾール0.022質量部を仕込み、撹拌しながら50℃に調整した。
加熱装置、攪拌機、温度計及び還流冷却管を備えた2リットル4つ口フラスコに、1,4−ビス(3−アクリロイロキシ−2−ヒドロキシプロポキシ)ブタン(一般式(2)中のR1及びR3は炭素原子数2のもので、重合性不飽和基を有する原子団を1つ有するものであり、R2は炭素原子数4のものである。)35.6質量部、メチルヒドロキノン0.007質量部、及び、2,6−tert−ブチル−p−クレゾール0.07質量部を仕込み、攪拌しながら50℃で調整した。
温度計、窒素ガス導入管、攪拌器を備えた窒素置換された容器中で、1,6−ヘキサンジオールとネオペンチルグリコールとアジピン酸とを反応させて得られるポリエステルポリオール(数平均分子量2,000)100質量部と、1,6−ヘキサンジオール10.6質量部と、2,2−ジメチロールプロピオン酸13.4質量部と、ジシクロヘキシルメタンジイソシアネート106.3質量部とを、メチルエチルケトン98質量部に混合し、前記反応容器中の温度80℃の条件下で反応させることによって、末端にイソシアネート基を有するウレタンプレポリマーの有機溶剤溶液を得た。
温度計、窒素ガス導入管、攪拌器を備えた窒素置換された容器中で、1,6−ヘキサンジオールとネオペンチルグリコールとアジピン酸とを反応させて得られるポリエステルポリオール(数平均分子量2,000)100質量部と、1,6−ヘキサンジオール21.2質量部と、2,2−ジメチロールプロピオン酸13.9質量部と、ジシクロヘキシルメタンジイソシアネート106.3質量部とを、メチルエチルケトン93.8質量部に混合し、前記反応容器中の温度80℃の条件下で反応させることによって、末端にイソシアネート基を有するウレタンプレポリマーの有機溶剤溶液を得た。
攪拌機、還流冷却管、窒素導入管、温度計、単量体混合物滴下用滴下漏斗、重合触媒滴下用滴下漏斗を備えた反応容器に脱イオン水200質量部、ポリオキシエチレン−1−(アリルオキシメチル)アルキル硫酸エステルアンモニウム塩(第一工業製薬株式会社製「アクアロンKH−10」、固形分100質量%)1.5質量部を入れ、窒素を吹き込みながら80℃まで昇温した。
攪拌機、還流冷却管、窒素導入管、温度計、単量体混合物滴下用滴下漏斗、重合触媒滴下用滴下漏斗を備えた反応容器に脱イオン水200質量部、ポリオキシエチレン−1−(アリルオキシメチル)アルキル硫酸エステルアンモニウム塩(第一工業製薬株式会社製「アクアロンKH−10」、固形分100質量%)1.5質量部を入れ、窒素を吹き込みながら80℃まで昇温した。
攪拌機、還流冷却管、窒素導入管、温度計、単量体混合物滴下用滴下漏斗、重合触媒滴下用滴下漏斗を備えた反応容器に脱イオン水200質量部、ポリオキシエチレン−1−(アリルオキシメチル)アルキル硫酸エステルアンモニウム塩(第一工業製薬株式会社製「アクアロンKH−10」、固形分100質量%)1.5質量部を入れ、窒素を吹き込みながら80℃まで昇温した。
攪拌機を備えた容器に、合成例1の不揮発分33質量%ウレタン樹脂(1)水分散体151.5質量部(ウレタン樹脂(1)として50質量部)、合成例6の不揮発分30質量%アクリル樹脂(1)水分散体166.7質量部(アクリル樹脂(1)として50質量部)、光重合開始剤(BASFジャパン株式会社製「イルガキュア 500」;1−ヒドロキシ−シクロヘキシル−フェニル−ケトンとベンゾフェノンの混合物)4質量部、およびイオン交換水を不揮発分が30質量%となるように加えて、10分間攪拌し、水性樹脂組成物(1)を得た。
攪拌機を備えた容器に、合成例1の不揮発分33質量%ウレタン樹脂(1)水分散体242.4質量部(ウレタン樹脂(1)として80質量部)、合成例6の不揮発分30質量%アクリル樹脂(1)水分散体66.7質量部(アクリル樹脂(1)として20質量部)、光重合開始剤(BASFジャパン株式会社製「イルガキュア 500」)4質量部、およびイオン交換水を不揮発分が30質量%となるように加えて、10分間攪拌し、水性樹脂組成物(2)を得た。
攪拌機を備えた容器に、合成例1の不揮発分33質量%ウレタン樹脂(1)水分散体60.6質量部(ウレタン樹脂(1)として20質量部)、合成例6の不揮発分30質量%アクリル樹脂(1)水分散体266.7質量部(アクリル樹脂(1)として80質量部)、光重合開始剤(BASFジャパン株式会社製「イルガキュア 500」)4質量部、およびイオン交換水を不揮発分が30質量%となるように加えて、10分間攪拌し、水性樹脂組成物(3)を得た。
攪拌機を備えた容器に、合成例1の不揮発分33質量%ウレタン樹脂(1)水分散体151.5質量部(ウレタン樹脂(1)として50質量部)、合成例7の不揮発分30質量%アクリル樹脂(2)水分散体166.7質量部(アクリル樹脂(2)として50質量部)、光重合開始剤(BASFジャパン株式会社製「イルガキュア 500」)4質量部、およびイオン交換水を不揮発分が30質量%となるように加えて、10分間攪拌し、水性樹脂組成物(4)を得た。
攪拌機を備えた容器に、合成例1の不揮発分33質量%ウレタン樹脂(1)水分散体151.5質量部(ウレタン樹脂(1)として50質量部)、合成例8の不揮発分30質量%アクリル樹脂(3)水分散体166.7質量部(アクリル樹脂(3)として50質量部)、光重合開始剤(BASFジャパン株式会社製「イルガキュア 500」)4質量部、およびイオン交換水を不揮発分が30質量%となるように加えて、10分間攪拌し、水性樹脂組成物(5)を得た。
攪拌機を備えた容器に、合成例2の不揮発分33質量%ウレタン樹脂(2)水分散体151.5質量部(ウレタン樹脂(2)として50質量部)、合成例6の不揮発分30質量%アクリル樹脂(1)水分散体166.7質量部(アクリル樹脂(1)として50質量部)、光重合開始剤(BASFジャパン株式会社製「イルガキュア 500」)4質量部、およびイオン交換水を不揮発分が30質量%となるように加えて、10分間攪拌し、水性樹脂組成物(6)を得た。
攪拌機を備えた容器に、合成例2の不揮発分33質量%ウレタン樹脂(2)水分散体151.5質量部(ウレタン樹脂(2)として50質量部)、合成例8の不揮発分30質量%アクリル樹脂(3)水分散体166.7質量部(アクリル樹脂(3)として50質量部)、光重合開始剤(BASFジャパン株式会社製「イルガキュア 500」)4質量部、およびイオン交換水を不揮発分が30質量%となるように加えて、10分間攪拌し、水性樹脂組成物(7)を得た。
攪拌機を備えた容器に、合成例3の不揮発分33質量%ウレタン樹脂(3)水分散体151.5質量部(ウレタン樹脂(3)として50質量部)、合成例6の不揮発分30質量%アクリル樹脂(1)水分散体166.7質量部(アクリル樹脂(1)として50質量部)、光重合開始剤(BASFジャパン株式会社製「イルガキュア 500」)4質量部、およびイオン交換水を不揮発分が30質量%となるように加えて、10分間攪拌し、水性樹脂組成物(8)を得た。
攪拌機を備えた容器に、合成例3の不揮発分33質量%ウレタン樹脂(3)水分散体151.5質量部(ウレタン樹脂(3)として50質量部)、合成例8の不揮発分30質量%アクリル樹脂(3)水分散体166.7質量部(アクリル樹脂(3)として50質量部)、光重合開始剤(BASFジャパン株式会社製「イルガキュア 500」)4質量部、およびイオン交換水を不揮発分が30質量%となるように加えて、10分間攪拌し、水性樹脂組成物(9)を得た。
攪拌機を備えた容器に、合成例1の不揮発分33質量%ウレタン樹脂(1)水分散体287.9質量部(ウレタン樹脂(1)として95質量部)、合成例7の不揮発分30質量%アクリル樹脂(2)水分散体16.7質量部(アクリル樹脂(2)として5質量部)、光重合開始剤(BASFジャパン株式会社製「イルガキュア 500」)4質量部、およびイオン交換水を不揮発分が30質量%となるように加えて、10分間攪拌し、水性樹脂組成物(10)を得た。
攪拌機を備えた容器に、合成例1の不揮発分33質量%ウレタン樹脂(1)水分散体27.3質量部(ウレタン樹脂(1)として9質量部)、合成例7の不揮発分30質量%アクリル樹脂(2)水分散体303.3質量部(アクリル樹脂(2)として91質量部)、光重合開始剤(BASFジャパン株式会社製「イルガキュア 500」)4質量部、およびイオン交換水を不揮発分が30質量%となるように加えて、10分間攪拌し、水性樹脂組成物(11)を得た。
攪拌機を備えた容器に、合成例4の不揮発分33質量%ウレタン樹脂(4)水分散体303質量部(ウレタン樹脂(4)として100質量部)、光重合開始剤(BASFジャパン株式会社製「イルガキュア 500」)4質量部、およびイオン交換水を不揮発分が30質量%となるように加えて、10分間攪拌し、水性樹脂組成物(C1)を得た。
攪拌機を備えた容器に、合成例5の不揮発分33質量%ウレタン樹脂(5)水分散体303質量部(ウレタン樹脂(5)として100質量部)、光重合開始剤(BASFジャパン株式会社製「イルガキュア 500」)4質量部、およびイオン交換水を不揮発分が30質量%となるように加えて、10分間攪拌し、水性樹脂組成物(C2)を得た。
攪拌機を備えた容器に、合成例6の不揮発分30質量%アクリル樹脂(1)水分散体333質量部(アクリル樹脂(1)として100質量部)、光重合開始剤(BASFジャパン株式会社製「イルガキュア 500」)4質量部、およびイオン交換水を不揮発分が30質量%となるように加えて、10分間攪拌し、水性樹脂組成物(C3)を得た。
攪拌機を備えた容器に、合成例7の不揮発分30質量%アクリル樹脂(2)水分散体333質量部(アクリル樹脂(2)として100質量部)、光重合開始剤(BASFジャパン株式会社製「イルガキュア 500」)4質量部、およびイオン交換水を不揮発分が30質量%となるように加えて、10分間攪拌し、水性樹脂組成物(C4)を得た。
攪拌機を備えた容器に、合成例4の不揮発分33質量%ウレタン樹脂(4)水分散体151.5質量部(ウレタン樹脂(4)として50質量部)、合成例6の不揮発分30質量%アクリル樹脂(1)水分散体166.7質量部(アクリル樹脂(1)として50質量部)、光重合開始剤(BASFジャパン株式会社製「イルガキュア 500」)4質量部、およびイオン交換水を不揮発分が30質量%となるように加えて、10分間攪拌し、水性樹脂組成物(C5)を得た。
攪拌機を備えた容器に、合成例4の不揮発分33質量%ウレタン樹脂(4)水分散体151.5質量部(ウレタン樹脂(4)として50質量部)、合成例7の不揮発分30質量%アクリル樹脂(2)水分散体166.7質量部(アクリル樹脂(2)として50質量部)、光重合開始剤(BASFジャパン株式会社製「イルガキュア 500」)4質量部、およびイオン交換水を不揮発分が30質量%となるように加えて、10分間攪拌し、水性樹脂組成物(C6)を得た。
攪拌機を備えた容器に、合成例5の不揮発分33質量%ウレタン樹脂(5)水分散体151.5質量部(ウレタン樹脂(5)として50質量部)、合成例6の不揮発分30質量%アクリル樹脂(1)水分散体166.7質量部(アクリル樹脂(1)として50質量部)、光重合開始剤(BASFジャパン株式会社製「イルガキュア 500」)4質量部、およびイオン交換水を不揮発分が30質量%となるように加えて、10分間攪拌し、水性樹脂組成物(C7)を得た。
攪拌機を備えた容器に、合成例5の不揮発分33質量%ウレタン樹脂(5)水分散体151.5質量部(ウレタン樹脂(5)として50質量部)、合成例7の不揮発分30質量%アクリル樹脂(2)水分散体166.7質量部(アクリル樹脂(2)として50質量部)、光重合開始剤(BASFジャパン株式会社製「イルガキュア 500」)4質量部、およびイオン交換水を不揮発分が30質量%となるように加えて、10分間攪拌し、水性樹脂組成物(C8)を得た。
実施例、参考例及び比較例で得た各水性樹脂組成物を、塗膜の膜厚が50μmとなるように、それぞれ離型フィルムの表面に塗布した。前記塗布物を25℃の環境下で24時間乾燥した後、高圧水銀灯(株式会社GSユアサ製)を用いて、0.5J/cm2の紫外線を1パス照射し、前記離型フィルムを除去することによって、前記水性樹脂組成物からなる試験フィルム(縦40mm、横5mm)を作製した。
○:引張試験前の試験フィルムの長さに対して、引張試験後の試験フィルムの長さが50%以上100%未満伸長した。
○△:引張試験前の試験フィルムの長さに対して、引張試験後の試験フィルムの長さが30%以上50%未満の範囲で伸長した。
△:引張試験前の試験フィルムの長さに対して、引張試験後の試験フィルムの長さが10%以上30%未満の範囲で伸長した。
×:引張試験前の試験フィルムの長さに対して、引張試験後の試験フィルムの長さが10%未満の範囲で伸長した。
実施例、参考例及び比較例で得た各水性樹脂組成物を、塗膜の膜厚が2μmとなるように、それぞれ金属板(未処理鋼板、厚さ0.8mm)の表面に塗布した。前記塗布物を100℃で30秒間乾燥した後、高圧水銀灯(株式会社GSユアサ製)を用いて、0.5J/cm2の紫外線を1パス照射し、前記離型フィルムを除去することによって、前記金属板の表面に塗膜が積層した物品を得た。
△:塗膜の屈曲部位で、塗膜の若干のクラック、または、白いスジ状のシワが見られた。
×:塗膜の屈曲部位の全体で、塗膜の著しいクラックが見られた。
実施例、参考例及び比較例で得た各複合樹脂を、塗膜の膜厚が15μmとなるように、それぞれガラス基材の表面に塗布した。前記塗布物を140℃で5分間乾燥した後、高圧水銀灯(株式会社GSユアサ製)を用いて、0.5J/cm2の紫外線を1パス照射することによって、前記ガラス基材の表面に塗膜が積層した物品を得た。
前記塗膜をデューパネル光ウェザーメーター〔スガ試験機株式会社製、光照射時:30W/m2、70℃、湿潤時:湿度90%以上、50℃、光照射/湿潤サイクル=8時間/4時間〕を用いて1000時間の曝露試験を行った後、該試験板の表面の塗膜の外観を下記評価基準に従って目視で評価した。
△:塗膜表面のごく一部に若干のクラックおよび黄変の発生がみられる。
×:塗膜表面全体にクラックおよび黄変の発生がみられる。
Claims (4)
- 下記一般式(2)で示される2つ以上の重合性不飽和基を有するオキシアルキレンジオール(a1−2)、及び親水性基を有するポリオールを含有するポリオール(a1)と、ポリイソシアネート(a2)との反応物である重合性不飽和基を有するウレタン樹脂(A)、水性樹脂(B)及び水性媒体(C)を含有する水性樹脂組成物であって、
前記ウレタン樹脂(A)と前記水性樹脂(B)の質量割合[(A)/(B)]が93/7〜10/90であり、
前記水性樹脂(B)が、アクリル樹脂であり、
前記アクリル樹脂が、(メタ)アクリロイル基を有する単量体を必須成分として、(メタ)アクリル酸エステル、カルボキシル基を有する重合性単量体、水酸基を有する重合性単量体、アミド基を有する重合性単量体、ビニルエステル化合物、ビニルエーテル化合物、ビニルニトリル化合物、複素環式ビニル単量体、イソプレン、ブタジエン、及びエチレンからなる群より選ばれる1種以上の重合性単量体を重合して得られたものであることを特徴とする水性樹脂組成物。
- 前記(メタ)アクリル酸エステルの含有量が、前記重合性単量体混合物全量中に45〜99質量%の範囲である請求項1記載の水性樹脂組成物。
- 請求項1または2記載の水性樹脂組成物を含有することを特徴とするコーティング剤。
- 請求項3記載のコーティング剤の塗膜を有することを特徴とする物品。
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