JP6094842B2 - ゲルポリマー電解質及びこれを含むリチウム二次電池 - Google Patents
ゲルポリマー電解質及びこれを含むリチウム二次電池 Download PDFInfo
- Publication number
- JP6094842B2 JP6094842B2 JP2015545400A JP2015545400A JP6094842B2 JP 6094842 B2 JP6094842 B2 JP 6094842B2 JP 2015545400 A JP2015545400 A JP 2015545400A JP 2015545400 A JP2015545400 A JP 2015545400A JP 6094842 B2 JP6094842 B2 JP 6094842B2
- Authority
- JP
- Japan
- Prior art keywords
- positive electrode
- gel polymer
- polymer electrolyte
- secondary battery
- salt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000005518 polymer electrolyte Substances 0.000 title claims description 60
- 229910052744 lithium Inorganic materials 0.000 title claims description 13
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title description 12
- -1 lithium bis (fluorosulfonyl) imide imide salt Chemical class 0.000 claims description 43
- 230000001681 protective effect Effects 0.000 claims description 38
- 239000000203 mixture Substances 0.000 claims description 36
- 239000003792 electrolyte Substances 0.000 claims description 27
- 238000005260 corrosion Methods 0.000 claims description 25
- 230000007797 corrosion Effects 0.000 claims description 25
- 239000000178 monomer Substances 0.000 claims description 22
- 150000003839 salts Chemical class 0.000 claims description 18
- 239000007774 positive electrode material Substances 0.000 claims description 14
- 239000004743 Polypropylene Substances 0.000 claims description 10
- 239000011248 coating agent Substances 0.000 claims description 10
- 238000000576 coating method Methods 0.000 claims description 10
- 229920001155 polypropylene Polymers 0.000 claims description 10
- 239000003112 inhibitor Substances 0.000 claims description 8
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 8
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 8
- 229910003002 lithium salt Inorganic materials 0.000 claims description 7
- 159000000002 lithium salts Chemical class 0.000 claims description 7
- 239000011734 sodium Substances 0.000 claims description 7
- 239000004642 Polyimide Substances 0.000 claims description 6
- 229920001721 polyimide Polymers 0.000 claims description 6
- 239000003505 polymerization initiator Substances 0.000 claims description 6
- 239000002904 solvent Substances 0.000 claims description 6
- 229910013870 LiPF 6 Inorganic materials 0.000 claims description 5
- 229920001577 copolymer Polymers 0.000 claims description 5
- HCLJOFJIQIJXHS-UHFFFAOYSA-N 2-[2-[2-(2-prop-2-enoyloxyethoxy)ethoxy]ethoxy]ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOCCOCCOC(=O)C=C HCLJOFJIQIJXHS-UHFFFAOYSA-N 0.000 claims description 4
- AEPWOCLBLLCOGZ-UHFFFAOYSA-N 2-cyanoethyl prop-2-enoate Chemical group C=CC(=O)OCCC#N AEPWOCLBLLCOGZ-UHFFFAOYSA-N 0.000 claims description 4
- OECTYKWYRCHAKR-UHFFFAOYSA-N 4-vinylcyclohexene dioxide Chemical compound C1OC1C1CC2OC2CC1 OECTYKWYRCHAKR-UHFFFAOYSA-N 0.000 claims description 4
- 239000002202 Polyethylene glycol Substances 0.000 claims description 4
- XRMBQHTWUBGQDN-UHFFFAOYSA-N [2-[2,2-bis(prop-2-enoyloxymethyl)butoxymethyl]-2-(prop-2-enoyloxymethyl)butyl] prop-2-enoate Chemical compound C=CC(=O)OCC(COC(=O)C=C)(CC)COCC(CC)(COC(=O)C=C)COC(=O)C=C XRMBQHTWUBGQDN-UHFFFAOYSA-N 0.000 claims description 4
- 125000000524 functional group Chemical group 0.000 claims description 4
- GEPDYQSQVLXLEU-AATRIKPKSA-N methyl (e)-3-dimethoxyphosphoryloxybut-2-enoate Chemical compound COC(=O)\C=C(/C)OP(=O)(OC)OC GEPDYQSQVLXLEU-AATRIKPKSA-N 0.000 claims description 4
- 229920001223 polyethylene glycol Polymers 0.000 claims description 4
- 230000000379 polymerizing effect Effects 0.000 claims description 4
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 claims description 3
- QJMMCGKXBZVAEI-UHFFFAOYSA-N tris(trimethylsilyl) phosphate Chemical compound C[Si](C)(C)OP(=O)(O[Si](C)(C)C)O[Si](C)(C)C QJMMCGKXBZVAEI-UHFFFAOYSA-N 0.000 claims description 3
- MYWOJODOMFBVCB-UHFFFAOYSA-N 1,2,6-trimethylphenanthrene Chemical compound CC1=CC=C2C3=CC(C)=CC=C3C=CC2=C1C MYWOJODOMFBVCB-UHFFFAOYSA-N 0.000 claims description 2
- LFKLPJRVSHJZPL-UHFFFAOYSA-N 1,2:7,8-diepoxyoctane Chemical compound C1OC1CCCCC1CO1 LFKLPJRVSHJZPL-UHFFFAOYSA-N 0.000 claims description 2
- ZPFAVCIQZKRBGF-UHFFFAOYSA-N 1,3,2-dioxathiolane 2,2-dioxide Chemical compound O=S1(=O)OCCO1 ZPFAVCIQZKRBGF-UHFFFAOYSA-N 0.000 claims description 2
- WDXYVJKNSMILOQ-UHFFFAOYSA-N 1,3,2-dioxathiolane 2-oxide Chemical compound O=S1OCCO1 WDXYVJKNSMILOQ-UHFFFAOYSA-N 0.000 claims description 2
- FSSPGSAQUIYDCN-UHFFFAOYSA-N 1,3-Propane sultone Chemical compound O=S1(=O)CCCO1 FSSPGSAQUIYDCN-UHFFFAOYSA-N 0.000 claims description 2
- UWFRVQVNYNPBEF-UHFFFAOYSA-N 1-(2,4-dimethylphenyl)propan-1-one Chemical compound CCC(=O)C1=CC=C(C)C=C1C UWFRVQVNYNPBEF-UHFFFAOYSA-N 0.000 claims description 2
- VFFFESPCCPXZOQ-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)propane-1,3-diol;oxirane Chemical compound C1CO1.OCC(CO)(CO)CO VFFFESPCCPXZOQ-UHFFFAOYSA-N 0.000 claims description 2
- QCCMSMFTYZDAID-UHFFFAOYSA-N 2,8-dimethylnona-2,7-dienedioic acid Chemical compound OC(=O)C(C)=CCCCC=C(C)C(O)=O QCCMSMFTYZDAID-UHFFFAOYSA-N 0.000 claims description 2
- PRAMZQXXPOLCIY-UHFFFAOYSA-N 2-(2-methylprop-2-enoyloxy)ethanesulfonic acid Chemical compound CC(=C)C(=O)OCCS(O)(=O)=O PRAMZQXXPOLCIY-UHFFFAOYSA-N 0.000 claims description 2
- ZSZRUEAFVQITHH-UHFFFAOYSA-N 2-(2-methylprop-2-enoyloxy)ethyl 2-(trimethylazaniumyl)ethyl phosphate Chemical compound CC(=C)C(=O)OCCOP([O-])(=O)OCC[N+](C)(C)C ZSZRUEAFVQITHH-UHFFFAOYSA-N 0.000 claims description 2
- YSUQLAYJZDEMOT-UHFFFAOYSA-N 2-(butoxymethyl)oxirane Chemical compound CCCCOCC1CO1 YSUQLAYJZDEMOT-UHFFFAOYSA-N 0.000 claims description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 2
- SYEWHONLFGZGLK-UHFFFAOYSA-N 2-[1,3-bis(oxiran-2-ylmethoxy)propan-2-yloxymethyl]oxirane Chemical compound C1OC1COCC(OCC1OC1)COCC1CO1 SYEWHONLFGZGLK-UHFFFAOYSA-N 0.000 claims description 2
- HTJFSXYVAKSPNF-UHFFFAOYSA-N 2-[2-(oxiran-2-yl)ethyl]oxirane Chemical compound C1OC1CCC1CO1 HTJFSXYVAKSPNF-UHFFFAOYSA-N 0.000 claims description 2
- AOBIOSPNXBMOAT-UHFFFAOYSA-N 2-[2-(oxiran-2-ylmethoxy)ethoxymethyl]oxirane Chemical compound C1OC1COCCOCC1CO1 AOBIOSPNXBMOAT-UHFFFAOYSA-N 0.000 claims description 2
- FDSUVTROAWLVJA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol;prop-2-enoic acid Chemical compound OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OCC(CO)(CO)COCC(CO)(CO)CO FDSUVTROAWLVJA-UHFFFAOYSA-N 0.000 claims description 2
- NXBXJOWBDCQIHF-UHFFFAOYSA-N 2-[hydroxy-[2-(2-methylprop-2-enoyloxy)ethoxy]phosphoryl]oxyethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOP(O)(=O)OCCOC(=O)C(C)=C NXBXJOWBDCQIHF-UHFFFAOYSA-N 0.000 claims description 2
- ULFGMWXPMBPUSJ-UHFFFAOYSA-N 2-diethoxyphosphoryloxyethyl 2-methylprop-2-enoate Chemical compound CCOP(=O)(OCC)OCCOC(=O)C(C)=C ULFGMWXPMBPUSJ-UHFFFAOYSA-N 0.000 claims description 2
- SEILKFZTLVMHRR-UHFFFAOYSA-N 2-phosphonooxyethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOP(O)(O)=O SEILKFZTLVMHRR-UHFFFAOYSA-N 0.000 claims description 2
- UDXXYUDJOHIIDZ-UHFFFAOYSA-N 2-phosphonooxyethyl prop-2-enoate Chemical compound OP(O)(=O)OCCOC(=O)C=C UDXXYUDJOHIIDZ-UHFFFAOYSA-N 0.000 claims description 2
- NCNNNERURUGJAB-UHFFFAOYSA-N 3-[2,2-bis(3-prop-2-enoyloxypropoxymethyl)butoxy]propyl prop-2-enoate Chemical compound C=CC(=O)OCCCOCC(CC)(COCCCOC(=O)C=C)COCCCOC(=O)C=C NCNNNERURUGJAB-UHFFFAOYSA-N 0.000 claims description 2
- BCAIDFOKQCVACE-UHFFFAOYSA-N 3-[dimethyl-[2-(2-methylprop-2-enoyloxy)ethyl]azaniumyl]propane-1-sulfonate Chemical compound CC(=C)C(=O)OCC[N+](C)(C)CCCS([O-])(=O)=O BCAIDFOKQCVACE-UHFFFAOYSA-N 0.000 claims description 2
- FHQQSCLABUBWQR-UHFFFAOYSA-N 4-methylsulfonyloxybutyl prop-2-enoate Chemical compound CS(=O)(=O)OCCCCOC(=O)C=C FHQQSCLABUBWQR-UHFFFAOYSA-N 0.000 claims description 2
- JHWGFJBTMHEZME-UHFFFAOYSA-N 4-prop-2-enoyloxybutyl prop-2-enoate Chemical compound C=CC(=O)OCCCCOC(=O)C=C JHWGFJBTMHEZME-UHFFFAOYSA-N 0.000 claims description 2
- FIHBHSQYSYVZQE-UHFFFAOYSA-N 6-prop-2-enoyloxyhexyl prop-2-enoate Chemical compound C=CC(=O)OCCCCCCOC(=O)C=C FIHBHSQYSYVZQE-UHFFFAOYSA-N 0.000 claims description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 2
- XXXSILNSXNPGKG-ZHACJKMWSA-N Crotoxyphos Chemical compound COP(=O)(OC)O\C(C)=C\C(=O)OC(C)C1=CC=CC=C1 XXXSILNSXNPGKG-ZHACJKMWSA-N 0.000 claims description 2
- 229910013063 LiBF 4 Inorganic materials 0.000 claims description 2
- 229910012851 LiCoO 2 Inorganic materials 0.000 claims description 2
- 239000004734 Polyphenylene sulfide Substances 0.000 claims description 2
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 claims description 2
- MPIAGWXWVAHQBB-UHFFFAOYSA-N [3-prop-2-enoyloxy-2-[[3-prop-2-enoyloxy-2,2-bis(prop-2-enoyloxymethyl)propoxy]methyl]-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(COC(=O)C=C)(COC(=O)C=C)COCC(COC(=O)C=C)(COC(=O)C=C)COC(=O)C=C MPIAGWXWVAHQBB-UHFFFAOYSA-N 0.000 claims description 2
- 239000000654 additive Substances 0.000 claims description 2
- 230000000996 additive effect Effects 0.000 claims description 2
- XFUOBHWPTSIEOV-UHFFFAOYSA-N bis(oxiran-2-ylmethyl) cyclohexane-1,2-dicarboxylate Chemical compound C1CCCC(C(=O)OCC2OC2)C1C(=O)OCC1CO1 XFUOBHWPTSIEOV-UHFFFAOYSA-N 0.000 claims description 2
- GTBGXKPAKVYEKJ-UHFFFAOYSA-N decyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCOC(=O)C(C)=C GTBGXKPAKVYEKJ-UHFFFAOYSA-N 0.000 claims description 2
- 125000004386 diacrylate group Chemical group 0.000 claims description 2
- 239000003822 epoxy resin Substances 0.000 claims description 2
- 125000002573 ethenylidene group Chemical group [*]=C=C([H])[H] 0.000 claims description 2
- 239000004744 fabric Substances 0.000 claims description 2
- 239000011521 glass Substances 0.000 claims description 2
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 claims description 2
- 229920006122 polyamide resin Polymers 0.000 claims description 2
- 229920000647 polyepoxide Polymers 0.000 claims description 2
- 229920000728 polyester Polymers 0.000 claims description 2
- 229920000069 polyphenylene sulfide Polymers 0.000 claims description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 2
- VNLMVEHAAAAZPP-UHFFFAOYSA-N tris(triethylsilyl) phosphate Chemical compound CC[Si](CC)(CC)OP(=O)(O[Si](CC)(CC)CC)O[Si](CC)(CC)CC VNLMVEHAAAAZPP-UHFFFAOYSA-N 0.000 claims description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 2
- AMXOYNBUYSYVKV-UHFFFAOYSA-M lithium bromide Chemical compound [Li+].[Br-] AMXOYNBUYSYVKV-UHFFFAOYSA-M 0.000 claims 2
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 claims 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims 1
- DNXHEGUUPJUMQT-CBZIJGRNSA-N Estrone Chemical compound OC1=CC=C2[C@H]3CC[C@](C)(C(CC4)=O)[C@@H]4[C@@H]3CCC2=C1 DNXHEGUUPJUMQT-CBZIJGRNSA-N 0.000 claims 1
- 229910010238 LiAlCl 4 Inorganic materials 0.000 claims 1
- 229910010090 LiAlO 4 Inorganic materials 0.000 claims 1
- 229910015015 LiAsF 6 Inorganic materials 0.000 claims 1
- 229910015044 LiB Inorganic materials 0.000 claims 1
- 229910013684 LiClO 4 Inorganic materials 0.000 claims 1
- 229910012513 LiSbF 6 Inorganic materials 0.000 claims 1
- BEKPOUATRPPTLV-UHFFFAOYSA-N [Li].BCl Chemical compound [Li].BCl BEKPOUATRPPTLV-UHFFFAOYSA-N 0.000 claims 1
- 125000005639 glycero group Chemical group 0.000 claims 1
- HSZCZNFXUDYRKD-UHFFFAOYSA-M lithium iodide Inorganic materials [Li+].[I-] HSZCZNFXUDYRKD-UHFFFAOYSA-M 0.000 claims 1
- BHVTUPMWGCXDPW-UHFFFAOYSA-N lithium;phenoxyboronic acid Chemical compound [Li].OB(O)OC1=CC=CC=C1 BHVTUPMWGCXDPW-UHFFFAOYSA-N 0.000 claims 1
- OPUAWDUYWRUIIL-UHFFFAOYSA-L methanedisulfonate Chemical compound [O-]S(=O)(=O)CS([O-])(=O)=O OPUAWDUYWRUIIL-UHFFFAOYSA-L 0.000 claims 1
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 claims 1
- 239000010408 film Substances 0.000 description 35
- VDVLPSWVDYJFRW-UHFFFAOYSA-N lithium;bis(fluorosulfonyl)azanide Chemical compound [Li+].FS(=O)(=O)[N-]S(F)(=O)=O VDVLPSWVDYJFRW-UHFFFAOYSA-N 0.000 description 17
- 229910052782 aluminium Inorganic materials 0.000 description 11
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 11
- 238000004519 manufacturing process Methods 0.000 description 11
- 239000000126 substance Substances 0.000 description 10
- 229920000642 polymer Polymers 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 7
- 229910003473 lithium bis(trifluoromethanesulfonyl)imide Inorganic materials 0.000 description 7
- QSZMZKBZAYQGRS-UHFFFAOYSA-N lithium;bis(trifluoromethylsulfonyl)azanide Chemical compound [Li+].FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F QSZMZKBZAYQGRS-UHFFFAOYSA-N 0.000 description 7
- 239000008151 electrolyte solution Substances 0.000 description 6
- 239000011572 manganese Substances 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- 239000007773 negative electrode material Substances 0.000 description 5
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 4
- 239000005977 Ethylene Substances 0.000 description 4
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 4
- 238000007599 discharging Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 150000003949 imides Chemical class 0.000 description 4
- 239000011149 active material Substances 0.000 description 3
- 125000002947 alkylene group Chemical group 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000006229 carbon black Substances 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 230000005764 inhibitory process Effects 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical group [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical group O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 2
- 229910013716 LiNi Inorganic materials 0.000 description 2
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
- 125000000732 arylene group Chemical group 0.000 description 2
- 230000000903 blocking effect Effects 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000006258 conductive agent Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000011267 electrode slurry Substances 0.000 description 2
- JBTWLSYIZRCDFO-UHFFFAOYSA-N ethyl methyl carbonate Chemical compound CCOC(=O)OC JBTWLSYIZRCDFO-UHFFFAOYSA-N 0.000 description 2
- 239000011244 liquid electrolyte Substances 0.000 description 2
- 229910001416 lithium ion Inorganic materials 0.000 description 2
- 229910021450 lithium metal oxide Inorganic materials 0.000 description 2
- ACFSQHQYDZIPRL-UHFFFAOYSA-N lithium;bis(1,1,2,2,2-pentafluoroethylsulfonyl)azanide Chemical compound [Li+].FC(F)(F)C(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)C(F)(F)F ACFSQHQYDZIPRL-UHFFFAOYSA-N 0.000 description 2
- 239000011255 nonaqueous electrolyte Substances 0.000 description 2
- 239000004745 nonwoven fabric Substances 0.000 description 2
- 229920006254 polymer film Polymers 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 239000010409 thin film Substances 0.000 description 2
- GWAOOGWHPITOEY-UHFFFAOYSA-N 1,5,2,4-dioxadithiane 2,2,4,4-tetraoxide Chemical compound O=S1(=O)CS(=O)(=O)OCO1 GWAOOGWHPITOEY-UHFFFAOYSA-N 0.000 description 1
- HAZWONBCJXKAMF-UHFFFAOYSA-N 2-[1-[1,3-bis[2-(oxiran-2-ylmethoxy)propoxy]propan-2-yloxy]propan-2-yloxymethyl]oxirane Chemical compound C1OC1COC(C)COCC(OCC(C)OCC1OC1)COCC(C)OCC1CO1 HAZWONBCJXKAMF-UHFFFAOYSA-N 0.000 description 1
- MTPIZGPBYCHTGQ-UHFFFAOYSA-N 2-[2,2-bis(2-prop-2-enoyloxyethoxymethyl)butoxy]ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCC(CC)(COCCOC(=O)C=C)COCCOC(=O)C=C MTPIZGPBYCHTGQ-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 125000000882 C2-C6 alkenyl group Chemical group 0.000 description 1
- 229910013733 LiCo Inorganic materials 0.000 description 1
- 229910015644 LiMn 2 - z Ni Inorganic materials 0.000 description 1
- 229910015643 LiMn 2 O 4 Inorganic materials 0.000 description 1
- 229910015676 LiMn 2-z Co Inorganic materials 0.000 description 1
- 229910014689 LiMnO Inorganic materials 0.000 description 1
- 229910013290 LiNiO 2 Inorganic materials 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- VIEVWNYBKMKQIH-UHFFFAOYSA-N [Co]=O.[Mn].[Li] Chemical compound [Co]=O.[Mn].[Li] VIEVWNYBKMKQIH-UHFFFAOYSA-N 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229910003481 amorphous carbon Inorganic materials 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229910002102 lithium manganese oxide Inorganic materials 0.000 description 1
- FRMOHNDAXZZWQI-UHFFFAOYSA-N lithium manganese(2+) nickel(2+) oxygen(2-) Chemical compound [O-2].[Mn+2].[Ni+2].[Li+] FRMOHNDAXZZWQI-UHFFFAOYSA-N 0.000 description 1
- VGYDTVNNDKLMHX-UHFFFAOYSA-N lithium;manganese;nickel;oxocobalt Chemical compound [Li].[Mn].[Ni].[Co]=O VGYDTVNNDKLMHX-UHFFFAOYSA-N 0.000 description 1
- VLXXBCXTUVRROQ-UHFFFAOYSA-N lithium;oxido-oxo-(oxomanganiooxy)manganese Chemical compound [Li+].[O-][Mn](=O)O[Mn]=O VLXXBCXTUVRROQ-UHFFFAOYSA-N 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229910000403 monosodium phosphate Inorganic materials 0.000 description 1
- 235000019799 monosodium phosphate Nutrition 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 125000005010 perfluoroalkyl group Chemical group 0.000 description 1
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 229920001384 propylene homopolymer Polymers 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 229910052596 spinel Inorganic materials 0.000 description 1
- 239000011029 spinel Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L sulfate group Chemical group S(=O)(=O)([O-])[O-] QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 229910000314 transition metal oxide Inorganic materials 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0565—Polymeric materials, e.g. gel-type or solid-type
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G79/00—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule
- C08G79/02—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule a linkage containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/66—Selection of materials
- H01M4/665—Composites
- H01M4/667—Composites in the form of layers, e.g. coatings
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/571—Methods or arrangements for affording protection against corrosion; Selection of materials therefor
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
- H01M10/0567—Liquid materials characterised by the additives
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2220/00—Batteries for particular applications
- H01M2220/30—Batteries in portable systems, e.g. mobile phone, laptop
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0065—Solid electrolytes
- H01M2300/0082—Organic polymers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0085—Immobilising or gelification of electrolyte
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0088—Composites
- H01M2300/0091—Composites in the form of mixtures
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- General Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Physics & Mathematics (AREA)
- Dispersion Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Composite Materials (AREA)
- Secondary Cells (AREA)
- Connection Of Batteries Or Terminals (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR20130129439 | 2013-10-29 | ||
KR10-2013-0129439 | 2013-10-29 | ||
PCT/KR2014/010170 WO2015065004A1 (ko) | 2013-10-29 | 2014-10-28 | 겔 폴리머 전해질 및 이를 포함하는 리튬 이차전지 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2015537352A JP2015537352A (ja) | 2015-12-24 |
JP6094842B2 true JP6094842B2 (ja) | 2017-03-15 |
Family
ID=53004528
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2015545400A Active JP6094842B2 (ja) | 2013-10-29 | 2014-10-28 | ゲルポリマー電解質及びこれを含むリチウム二次電池 |
Country Status (8)
Country | Link |
---|---|
US (1) | US11121404B2 (pl) |
EP (1) | EP3043405B1 (pl) |
JP (1) | JP6094842B2 (pl) |
KR (2) | KR20150050412A (pl) |
CN (1) | CN104885289B (pl) |
PL (1) | PL3043405T3 (pl) |
TW (1) | TWI553941B (pl) |
WO (1) | WO2015065004A1 (pl) |
Families Citing this family (40)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3206248B1 (en) | 2014-10-31 | 2021-03-24 | LG Chem, Ltd. | Lithium sulfur battery and method for producing same |
WO2017061424A1 (ja) * | 2015-10-05 | 2017-04-13 | リンテック株式会社 | 正極、二次電池、及び二次電池の使用方法 |
KR102016510B1 (ko) * | 2016-03-30 | 2019-09-02 | 주식회사 엘지화학 | 겔 폴리머 전해질용 조성물 및 겔 폴리머 전해질 |
US10326166B2 (en) * | 2016-08-15 | 2019-06-18 | GM Global Technology Operations LLC | Gel electrolytes and precursors thereof |
CN106532115A (zh) * | 2016-11-25 | 2017-03-22 | 张家港市国泰华荣化工新材料有限公司 | 一种凝胶电解质及锂硫二次电池 |
WO2018097259A1 (ja) * | 2016-11-28 | 2018-05-31 | トヨタ自動車株式会社 | リチウムイオン二次電池用電解液、その製造方法、及びリチウムイオン二次電池 |
US20200028212A1 (en) | 2017-03-15 | 2020-01-23 | Envision Aesc Energy Devices Ltd. | Lithium ion secondary battery |
KR102081773B1 (ko) * | 2017-04-14 | 2020-02-26 | 주식회사 엘지화학 | 고분자 고체 전해질 및 이를 포함하는 리튬 이차전지 |
CN108933286B (zh) * | 2017-05-26 | 2020-11-06 | 北京师范大学 | 一种含有环状醚类化合物的可凝胶化体系及其制备方法和应用 |
CN108933275B (zh) * | 2017-05-26 | 2020-11-13 | 北京师范大学 | 一种用于锂硫电池的可凝胶化体系及其制备方法和应用 |
KR102662511B1 (ko) | 2017-05-26 | 2024-04-30 | 베이징사범대학교 | 에테르계 화합물을 포함하는 겔화 가능 시스템 및 이의 제조 방법 및 응용 |
JP6983548B2 (ja) * | 2017-06-27 | 2021-12-17 | 株式会社日本触媒 | 電解質組成物及び電池 |
CN110770959B (zh) | 2017-06-27 | 2023-08-25 | 株式会社日本触媒 | 电解质组合物、电解质膜、电极、电池和电解质组合物的评价方法 |
KR102256487B1 (ko) * | 2017-07-06 | 2021-05-27 | 주식회사 엘지에너지솔루션 | 이차전지용 고분자 전해질 및 이를 포함하는 리튬 이차전지 |
WO2019070513A1 (en) * | 2017-10-04 | 2019-04-11 | Trustees Of Tufts College | ELECTROLYTIC COMPOSITES IN THE FORM OF GEL |
CN111742436A (zh) * | 2018-02-27 | 2020-10-02 | 松下知识产权经营株式会社 | 非水电解质二次电池 |
JP7352900B2 (ja) * | 2018-02-27 | 2023-09-29 | パナソニックIpマネジメント株式会社 | 非水電解質二次電池 |
KR102259744B1 (ko) | 2018-03-06 | 2021-06-02 | 주식회사 엘지에너지솔루션 | 비수 전해액 및 이를 포함하는 리튬 이차 전지 |
CN208000939U (zh) * | 2018-04-11 | 2018-10-23 | 宁德新能源科技有限公司 | 电池和设备 |
CN112470318A (zh) | 2018-07-31 | 2021-03-09 | 株式会社日本触媒 | 电解质组合物、电解质膜及电解质膜的制造方法 |
EP3826085B1 (en) * | 2018-08-29 | 2023-03-01 | Youilet Co., Ltd. | Secondary battery electrode production system |
KR102465820B1 (ko) | 2018-09-10 | 2022-11-11 | 주식회사 엘지에너지솔루션 | 리튬 이차전지용 열경화성 전해질 조성물, 이로부터 제조된 젤 폴리머 전해질 및 이를 포함하는 리튬 이차전지 |
WO2020055122A1 (ko) | 2018-09-10 | 2020-03-19 | 주식회사 엘지화학 | 리튬 이차전지용 열경화성 전해질 조성물, 이로부터 제조된 젤 폴리머 전해질 및 이를 포함하는 리튬 이차전지 |
KR102128041B1 (ko) * | 2018-09-13 | 2020-06-29 | 주식회사 그리너지 | 고체 고분자 전해질, 이를 포함하는 전극 구조체 및 전기화학소자, 그리고 고체 고분자 전해질 막의 제조방법 |
CN109494400A (zh) * | 2018-10-17 | 2019-03-19 | 浙江大学 | 双氟磺酰亚胺锂/1,3-二氧五环锂电池凝胶电解液及其制备方法和电池 |
US20220013875A1 (en) * | 2018-10-23 | 2022-01-13 | Panasonic Intellectual Property Management Co., Ltd. | Battery and protective tape for batteries |
US10511059B1 (en) * | 2018-11-15 | 2019-12-17 | ZAF Energy Systems, Incorporated | Alkaline pouch cell with coated terminals |
WO2020102907A1 (fr) * | 2018-11-21 | 2020-05-28 | HYDRO-QUéBEC | Compositions polymériques comprenant au moins deux sels de lithium et leur utilisation dans des cellules électrochimiques |
CN109560323B (zh) * | 2018-11-26 | 2021-01-19 | 宁德新能源科技有限公司 | 一种凝胶聚合物电解质及包含其的电化学装置 |
KR102268183B1 (ko) * | 2018-12-21 | 2021-06-22 | 주식회사 엘지화학 | 고분자 전해질 및 이의 제조방법 |
CN109888385B (zh) * | 2019-01-25 | 2020-11-06 | 厦门大学 | 一种锂金属二次电池用电解液及锂金属二次电池 |
CN110380118A (zh) * | 2019-07-18 | 2019-10-25 | 华中科技大学 | 一种具有阻燃功能的聚合物电解质及其制备与应用 |
JP2021134251A (ja) * | 2020-02-25 | 2021-09-13 | 株式会社リコー | 液体組成物、電極の製造方法及び電気化学素子の製造方法 |
WO2021187965A1 (ko) * | 2020-03-19 | 2021-09-23 | 주식회사 엘지에너지솔루션 | 전도성의 부식 방지층이 탭 상에 형성되어 있는 양극 집전체, 이를 포함하는 양극, 및 리튬 이차전지 |
CN111430792B (zh) * | 2020-04-01 | 2020-10-13 | 深圳市奥能动力科技有限公司 | 复合凝胶固态电解质、制备方法及全固态锂离子电池 |
CN114695953A (zh) * | 2020-12-28 | 2022-07-01 | 荣盛盟固利新能源科技有限公司 | 一种高电压高安全型聚酰亚胺凝胶聚合物电解质及其制备方法和应用以及锂离子电池 |
US11949109B2 (en) * | 2021-03-12 | 2024-04-02 | Honeycomb Battery Company | Flame-resistant electrodes lithium containing quasi-solid or solid-state electrolytes and manufacturing method |
KR20230014654A (ko) * | 2021-07-21 | 2023-01-30 | 주식회사 천보 | 알루미늄 부식방지제 및 비스(플루오로설포닐)이미드 알칼리금속염을 포함하는 전해액 조성물 |
EP4309228A2 (en) | 2021-09-27 | 2024-01-24 | QuantumScape Battery, Inc. | Electrochemical stack and method of assembly thereof |
EP4270579A3 (en) * | 2022-04-27 | 2024-04-03 | Industrial Technology Research Institute | Electrolyte composition, quasi-solid electrolyte and lithium-ion battery employing the same |
Family Cites Families (37)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1764387B1 (de) * | 1968-05-29 | 1971-04-15 | Metalloxyd Gmbh | Elektrische scheibenspule mit einer wicklung aus metall band und verfahren zu deren herstellung |
WO1995026056A1 (fr) * | 1994-03-21 | 1995-09-28 | Centre National De La Recherche Scientifique | Materiau a conduction ionique presentant de bonnes proprietes anti-corrosion |
JP2004047487A (ja) | 1995-01-25 | 2004-02-12 | Ricoh Co Ltd | リチウム二次電池用負極および該負極を用いたリチウム二次電池 |
US6013393A (en) * | 1995-05-09 | 2000-01-11 | Ricoh Company, Ltd. | Ionic conductive polymer gel and lithium-ion battery using the same |
JP3617197B2 (ja) | 1996-06-15 | 2005-02-02 | ソニー株式会社 | 難燃性ゲル電解質及びそれを用いた電池 |
DE69734339T2 (de) * | 1996-08-07 | 2006-06-01 | Mitsui Chemicals, Inc. | Ionenleitender gelierter Polymerelektrolyt und diesen Elektrolyt enthaltende Feststoffbatterie |
US6203942B1 (en) * | 1998-10-22 | 2001-03-20 | Wilson Greatbatch Ltd. | Phosphate additives for nonaqueous electrolyte rechargeable electrochemical cells |
DE60034838D1 (de) * | 1999-03-16 | 2007-06-28 | Sumitomo Chemical Co | Nichtwässriger Elektrolyt und Lithium-Sekundärbatterie unter Verwendung desselben |
JP4439610B2 (ja) * | 1999-04-07 | 2010-03-24 | アオイ電子株式会社 | 高分子ゲル電解質及びそれを用いたリチウム二次電池 |
JP2001093574A (ja) | 1999-09-22 | 2001-04-06 | Sanyo Electric Co Ltd | ゲル状高分子電解質二次電池 |
WO2001093363A2 (en) * | 2000-05-26 | 2001-12-06 | Covalent Associates, Inc. | Non-flammable electrolytes |
KR100449757B1 (ko) * | 2001-11-23 | 2004-09-22 | 삼성에스디아이 주식회사 | 전지부와 이를 채용한 이차전지 |
US7300933B2 (en) * | 2002-05-07 | 2007-11-27 | Neurosearch A/S | Diazabicyclic biaryl derivatives |
US7709157B2 (en) * | 2002-10-23 | 2010-05-04 | Panasonic Corporation | Non-aqueous electrolyte secondary battery and electrolyte for the same |
CA2418257A1 (fr) * | 2003-01-30 | 2004-07-30 | Hydro-Quebec | Composition electrolytique et electrolyte, generateurs les contenant et operant sans formation de dendrite lors du cyclage |
JP2005183249A (ja) * | 2003-12-22 | 2005-07-07 | Japan Carlit Co Ltd:The | ゲル状電解質及びその製造方法 |
US9508973B2 (en) * | 2004-05-25 | 2016-11-29 | Samsung Sdi Co., Ltd. | Secondary battery |
CN1303719C (zh) * | 2004-12-22 | 2007-03-07 | 华南理工大学 | 一种凝胶聚合物电解质的制备方法 |
CN101103070B (zh) * | 2005-01-14 | 2010-08-25 | 三井化学株式会社 | 聚乙烯醇缩醛树脂清漆、胶凝剂、非水电解液和电化学元件 |
JP4940617B2 (ja) * | 2005-10-06 | 2012-05-30 | 株式会社Gsユアサ | 非水電解質二次電池 |
JP5032773B2 (ja) * | 2006-02-03 | 2012-09-26 | 第一工業製薬株式会社 | イオン性液体を用いたリチウム二次電池 |
KR100744835B1 (ko) | 2006-07-26 | 2007-08-01 | 한국화학연구원 | 고분자 전해질용 포스페이트계 아크릴레이트 가교제와,이를 함유하는 고분자 전해질 조성물 |
JP2009070606A (ja) | 2007-09-11 | 2009-04-02 | Dai Ichi Kogyo Seiyaku Co Ltd | リチウムポリマー電池 |
JP2009277413A (ja) | 2008-05-13 | 2009-11-26 | Dai Ichi Kogyo Seiyaku Co Ltd | リチウムポリマー電池 |
WO2009142251A1 (ja) * | 2008-05-19 | 2009-11-26 | 日本電気株式会社 | 二次電池 |
CN101436653B (zh) * | 2008-12-15 | 2012-08-29 | 厦门宝龙工业股份有限公司 | 锂电池极耳的制作工艺 |
JP2011001254A (ja) | 2009-05-21 | 2011-01-06 | Toyota Motor Corp | 窒化Li−Ti複合酸化物の製造方法、窒化Li−Ti複合酸化物およびリチウム電池 |
JP5480376B2 (ja) * | 2009-06-24 | 2014-04-23 | トヨタ モーター エンジニアリング アンド マニュファクチャリング ノース アメリカ,インコーポレイティド | 高電圧電解質 |
CN201503887U (zh) * | 2009-09-24 | 2010-06-09 | 陈性保 | 一种锂离子聚合物电池 |
CN101702449B (zh) | 2009-11-03 | 2011-08-17 | 中国科学院化学研究所 | 一种锂离子电池凝胶电解液及其制备方法 |
WO2012035935A1 (ja) | 2010-09-17 | 2012-03-22 | 株式会社村田製作所 | 誘電体セラミック、積層セラミックコンデンサ、及びこれらの製造方法 |
US9263731B2 (en) | 2010-11-12 | 2016-02-16 | A123 Systems Llc | High performance lithium or lithium ion cell |
JP6065367B2 (ja) | 2011-06-07 | 2017-01-25 | ソニー株式会社 | 非水電解質電池、電池パック、電子機器、電動車両、蓄電装置および電力システム |
US9130246B2 (en) * | 2012-01-11 | 2015-09-08 | Samsung Sdi Co., Ltd. | Rechargeable lithium battery having lithium difluorophosphate and a sultone-based compound |
JP2013152825A (ja) | 2012-01-24 | 2013-08-08 | Sony Corp | 電池ならびに電池パック、電子機器、電動車両、蓄電装置および電力システム |
CN103165938B (zh) * | 2013-02-28 | 2015-07-08 | 上海交通大学 | 亲水性聚四氟乙烯微孔膜支撑的交联凝胶聚合物电解质膜 |
US9755213B2 (en) * | 2013-03-11 | 2017-09-05 | Lg Chem, Ltd. | Cathode including insulation layer on cathode tab and secondary battery including the cathode |
-
2014
- 2014-10-28 PL PL14825079T patent/PL3043405T3/pl unknown
- 2014-10-28 WO PCT/KR2014/010170 patent/WO2015065004A1/ko active Application Filing
- 2014-10-28 KR KR1020140147072A patent/KR20150050412A/ko active Search and Examination
- 2014-10-28 TW TW103137250A patent/TWI553941B/zh active
- 2014-10-28 JP JP2015545400A patent/JP6094842B2/ja active Active
- 2014-10-28 US US14/413,755 patent/US11121404B2/en active Active
- 2014-10-28 CN CN201480002099.7A patent/CN104885289B/zh active Active
- 2014-10-28 EP EP14825079.8A patent/EP3043405B1/en active Active
-
2017
- 2017-03-10 KR KR1020170030762A patent/KR101840593B1/ko active IP Right Grant
Also Published As
Publication number | Publication date |
---|---|
KR20170032260A (ko) | 2017-03-22 |
US11121404B2 (en) | 2021-09-14 |
EP3043405A4 (en) | 2016-12-28 |
PL3043405T3 (pl) | 2020-05-18 |
CN104885289B (zh) | 2018-10-09 |
JP2015537352A (ja) | 2015-12-24 |
EP3043405B1 (en) | 2020-01-22 |
TWI553941B (zh) | 2016-10-11 |
CN104885289A (zh) | 2015-09-02 |
KR20150050412A (ko) | 2015-05-08 |
KR101840593B1 (ko) | 2018-03-20 |
EP3043405A1 (en) | 2016-07-13 |
US20160028110A1 (en) | 2016-01-28 |
WO2015065004A1 (ko) | 2015-05-07 |
TW201539833A (zh) | 2015-10-16 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP6094842B2 (ja) | ゲルポリマー電解質及びこれを含むリチウム二次電池 | |
KR102452329B1 (ko) | 리튬 이차전지용 비수전해액 및 이를 포함하는 리튬 이차전지 | |
KR101537142B1 (ko) | 전해액 첨가제, 상기 첨가제를 포함하는 비수성 전해액 및 리튬 이차 전지 | |
KR101639858B1 (ko) | 리튬 이차 전지용 전해액 첨가제, 상기 전해액 첨가제를 포함하는 비수성 전해액 및 리튬 이차 전지 | |
TWI537277B (zh) | 非水性電解質溶液及含有彼之鋰二次電池 | |
CA2717503C (en) | Method for preparing an electrochemical cell having a gel electrolyte | |
TWI580097B (zh) | 非水性液態電解質及含彼之鋰二次電池 | |
US10333142B2 (en) | Secondary battery including silicon-based compound | |
US10454137B2 (en) | Non-aqueous electrolyte solution and lithium secondary battery comprising the same | |
JP7176821B2 (ja) | リチウム二次電池用非水電解液添加剤、これを含むリチウム二次電池用非水電解液及びリチウム二次電池 | |
JP2022551058A (ja) | リチウム二次電池用非水電解液及びそれを含むリチウム二次電池 | |
JP7250401B2 (ja) | リチウム二次電池用非水電解質及びこれを含むリチウム二次電池 | |
JP5614431B2 (ja) | リチウムイオン二次電池用非水電解液及びリチウムイオン二次電池 | |
KR20160036807A (ko) | 비수성 전해액 및 이를 포함하는 리튬 이차 전지 | |
JP7408223B2 (ja) | 二次電池用電解液添加剤、それを含むリチウム二次電池用非水電解液およびリチウム二次電池 | |
CN103828118B (zh) | 用于锂二次电池的电解质和包含所述电解质的锂二次电池 | |
JP2024517278A (ja) | 非水電解質用添加剤、それを含む非水電解質、およびリチウム二次電池 | |
JP7442660B2 (ja) | ゲルポリマー電解質二次電池の製造方法、及びそれによって製造されたゲルポリマー電解質二次電池 | |
CN103828117A (zh) | 用于锂二次电池的电解质和包含所述电解质的锂二次电池 | |
JP7278657B2 (ja) | 非水電解液及びこれを含むリチウム二次電池 | |
JP7515960B2 (ja) | 非水電解液およびそれを含むリチウム二次電池 | |
JP7408226B2 (ja) | リチウム二次電池用非水電解液及びこれを含むリチウム二次電池 | |
JP2024514218A (ja) | ゲルポリマー電解質およびこれを含むリチウム二次電池 | |
JP2024524976A (ja) | リチウム二次電池 | |
KR20230141621A (ko) | 리튬 이차전지용 비수성 전해액 및 이를 포함하는 리튬 이차전지 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20160209 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20160427 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20160906 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20161111 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20170117 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20170201 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 6094842 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
S111 | Request for change of ownership or part of ownership |
Free format text: JAPANESE INTERMEDIATE CODE: R313111 |
|
R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |