JP6093907B2 - 粘着性組成物、粘着剤および粘着シート - Google Patents
粘着性組成物、粘着剤および粘着シート Download PDFInfo
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- JP6093907B2 JP6093907B2 JP2016509857A JP2016509857A JP6093907B2 JP 6093907 B2 JP6093907 B2 JP 6093907B2 JP 2016509857 A JP2016509857 A JP 2016509857A JP 2016509857 A JP2016509857 A JP 2016509857A JP 6093907 B2 JP6093907 B2 JP 6093907B2
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- Prior art keywords
- pressure
- sensitive adhesive
- meth
- acrylic acid
- adhesive
- Prior art date
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- 239000000853 adhesive Substances 0.000 title claims description 77
- 230000001070 adhesive effect Effects 0.000 title claims description 77
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- 229920000642 polymer Polymers 0.000 claims description 72
- 239000000178 monomer Substances 0.000 claims description 71
- 239000010410 layer Substances 0.000 claims description 62
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 59
- -1 2-ethylhexyl Chemical group 0.000 claims description 30
- 239000012790 adhesive layer Substances 0.000 claims description 30
- 239000003431 cross linking reagent Substances 0.000 claims description 28
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 27
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 27
- 229910052751 metal Inorganic materials 0.000 claims description 27
- 239000002184 metal Substances 0.000 claims description 27
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 23
- 239000012964 benzotriazole Substances 0.000 claims description 21
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 21
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 15
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- HOWXFKMMBYLEOM-UHFFFAOYSA-N 4-(1-methylcyclohexa-2,4-dien-1-yl)-2h-triazole Chemical compound C=1NN=NC=1C1(C)CC=CC=C1 HOWXFKMMBYLEOM-UHFFFAOYSA-N 0.000 claims description 5
- OKQVTLCUHATGDD-UHFFFAOYSA-N n-(benzotriazol-1-ylmethyl)-2-ethyl-n-(2-ethylhexyl)hexan-1-amine Chemical compound C1=CC=C2N(CN(CC(CC)CCCC)CC(CC)CCCC)N=NC2=C1 OKQVTLCUHATGDD-UHFFFAOYSA-N 0.000 claims description 5
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- 125000004202 aminomethyl group Chemical group [H]N([H])C([H])([H])* 0.000 claims description 2
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- DHTAIMJOUCYGOL-UHFFFAOYSA-N 2-ethyl-n-(2-ethylhexyl)-n-[(4-methylbenzotriazol-1-yl)methyl]hexan-1-amine Chemical compound C1=CC=C2N(CN(CC(CC)CCCC)CC(CC)CCCC)N=NC2=C1C DHTAIMJOUCYGOL-UHFFFAOYSA-N 0.000 description 3
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- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 3
- PSGCQDPCAWOCSH-UHFFFAOYSA-N (4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl) prop-2-enoate Chemical compound C1CC2(C)C(OC(=O)C=C)CC1C2(C)C PSGCQDPCAWOCSH-UHFFFAOYSA-N 0.000 description 2
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 2
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- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
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- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
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- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
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- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/10—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
- C09J2301/12—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
- C09J2301/124—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present on both sides of the carrier, e.g. double-sided adhesive tape
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Landscapes
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Description
〔粘着性組成物〕
本実施形態に係る粘着性組成物(以下「粘着性組成物P」という。)は、金属部材と接触して使用される粘着剤を構成するための粘着性組成物である。金属部材としては、好ましくは静電容量方式のタッチパネルにおける電極としての銅メッシュが例示されるが、これに限定されるものではない。
(メタ)アクリル酸エステル重合体(A)が、当該重合体を構成するモノマー単位として含有する水酸基含有モノマーとしては、例えば、(メタ)アクリル酸2−ヒドロキシエチル、(メタ)アクリル酸2−ヒドロキシプロピル、(メタ)アクリル酸3−ヒドロキシプロピル、(メタ)アクリル酸2−ヒドロキシブチル、(メタ)アクリル酸3−ヒドロキシブチル、(メタ)アクリル酸4−ヒドロキシブチルなどの(メタ)アクリル酸ヒドロキシアルキルエステル等が挙げられる。中でも、得られる(メタ)アクリル酸エステル重合体(A)における水酸基の架橋剤(C)との反応性および他の単量体との共重合性の点から(メタ)アクリル酸2−ヒドロキシエチルが好ましい。これらは単独で用いてもよいし、2種以上を組み合わせて用いてもよい。
ベンゾトリアゾール系防錆剤(B)としては、例えば、1H−ベンゾトリアゾール、1H−トリルトリアゾール、1−[N,N−ビス(2−エチルヘキシル)アミノメチル]ベンゾトリアゾール、1−[N,N−ビス(2−エチルヘキシル)アミノメチル]メチルベンゾトリアゾール、カルボキシベンゾトリアゾール、2、2’−[[(メチル−1H−ベンゾトリアゾール−1−イル)メチル]イミノ]ビスエタノール等が挙げられる。中でも、1H−ベンゾトリアゾール、1H−トリルトリアゾール、1−[N,N−ビス(2−エチルヘキシル)アミノメチル]ベンゾトリアゾールおよび1−[N,N−ビス(2−エチルヘキシル)アミノメチル]メチルベンゾトリアゾールが好ましい。これらによれば、接触する金属部材の腐食を特に効果的に抑制することができる。上記のベンゾトリアゾール系防錆剤(B)は、単独で用いてもよいし、2種以上を組み合わせて用いてもよい。
粘着性組成物Pは、架橋剤(C)を含有することが好ましい。粘着性組成物Pは、架橋剤(C)を含有することで、(メタ)アクリル酸エステル共重合体(A)を架橋して三次元網目構造を形成し、得られる粘着剤の凝集力を向上させる。
粘着性組成物Pには、所望により、アクリル系粘着剤に通常使用されている各種添加剤、例えばシランカップリング剤、帯電防止剤、粘着付与剤、酸化防止剤、紫外線吸収剤、光安定剤、軟化剤、充填剤、屈折率調整剤などを添加することができる。
粘着性組成物Pは、(メタ)アクリル酸エステル重合体(A)を製造し、得られた(メタ)アクリル酸エステル重合体(A)と、ベンゾトリアゾール系防錆剤(B)とを混合するとともに、所望により、架橋剤(C)および添加剤を加えることで製造することができる。
本実施形態に係る粘着剤は、粘着性組成物Pを架橋してなるものである。粘着性組成物Pの架橋は、加熱処理により行うことができる。なお、この加熱処理は、粘着性組成物Pの希釈溶剤等を揮発させる際の乾燥処理で兼ねることもできる。
図1に示すように、本実施形態に係る粘着シート1は、2枚の剥離シート12a,12bと、それら2枚の剥離シート12a,12bの剥離面と接するように当該2枚の剥離シート12a,12bに挟持された粘着剤層11とから構成される。ただし、粘着シート1において剥離シート12a,12bは必須の構成要素ではなく、粘着シート1の使用時に剥離・除去されるものである。なお、本明細書における剥離シートの剥離面とは、剥離シートにおいて剥離性を有する面をいい、剥離処理を施した面および剥離処理を施さなくても剥離性を示す面のいずれをも含むものである。
粘着剤層11は、前述した粘着性組成物Pを架橋してなる粘着剤から構成される。粘着剤層11の厚さ(JIS K7130に準じて測定した値)は、10〜300μmであることが好ましく、特に25〜250μmであることが好ましく、さらには50〜100μmであることが好ましい。粘着剤層11の厚さが10μm以上であることにより、優れた粘着力が十分に発揮され、粘着剤層11の厚さが300μm以下であることにより、加工性が良好になる。また、粘着剤層11の厚さが25〜100μmであると、光学用途、特にタッチパネル用途として好適なものとなる。なお、粘着剤層11は単層で形成してもよいし、複数層を積層して形成することもできる。
剥離シート12a,12bとしては、特に限定されることはなく、公知のプラスチックフィルムを用いることができる。例えば、ポリエチレンフィルム、ポリプロピレンフィルム、ポリブテンフィルム、ポリブタジエンフィルム、ポリメチルペンテンフィルム、ポリ塩化ビニルフィルム、塩化ビニル共重合体フィルム、ポリエチレンテレフタレートフィルム、ポリエチレンナフタレートフィルム、ポリブチレンテレフタレートフィルム、ポリウレタンフィルム、エチレン酢酸ビニルフィルム、アイオノマー樹脂フィルム、エチレン・(メタ)アクリル酸共重合体フィルム、エチレン・(メタ)アクリル酸エステル共重合体フィルム、ポリスチレンフィルム、ポリカーボネートフィルム、ポリイミドフィルム、フッ素樹脂フィルム等が用いられる。また、これらの架橋フィルムも用いられる。さらに、これらの積層フィルムであってもよい。
粘着シート1の一製造例としては、一方の剥離シート12a(または12b)の剥離面に、上記粘着性組成物Pの塗布液を塗布し、加熱処理を行って粘着性組成物Pを架橋し、塗布層を形成した後、その塗布層に他方の剥離シート12b(または12a)の剥離面を重ね合わせる。養生期間が必要な場合は養生期間をおくことにより、養生期間が不要な場合はそのまま、上記塗布層が粘着剤層11となる。これにより、上記粘着シート1が得られる。加熱処理および養生の条件については、前述した通りである。
本実施形態における粘着剤層11は、ヘイズ値(JIS K7136:2000に準じて測定した値)が、1.0%以下であることが好ましく、特に0.8%以下であることが好ましく、さらには0.6%以下であることが好ましい。ヘイズ値が1.0%以下であると、透明性が非常に高く、光学用途として好適なものとなる。なお、粘着剤層11のヘイズ値は、後述する耐湿熱白化性の評価試験後においても上記範囲内にあることが特に好ましい。
上記粘着シート1を使用することにより、例えば、図2に示す静電容量方式のタッチパネル2を製造することができる。タッチパネル2は、表示体モジュール3と、その上に粘着剤層4を介して積層された第1のフィルムセンサー5aと、その上に粘着剤層11を介して積層された第2のフィルムセンサー5bと、その上に粘着剤層11を介して積層されたカバー材6とを備えて構成される。
粘着シート1として、第1の粘着シート1および第2の粘着シート1を用意する。第1の粘着シート1から一方の剥離シート12aを剥離し、露出した粘着剤層11(第1の粘着剤層11)を、第2のフィルムセンサー5bの電極52と接するように、当該第2のフィルムセンサー5bと貼合する。また、第2の粘着シート1から一方の剥離シート12aを剥離し、露出した粘着剤層11(第2の粘着剤層)を、第1のフィルムセンサー5aの電極52と接するように、当該第1のフィルムセンサー5aと貼合する。
1.(メタ)アクリル酸エステル共重合体の調製
アクリル酸2−エチルヘキシル60質量部、メタクリル酸メチル20質量部およびアクリル酸2−ヒドロキシエチル20質量部を共重合させて、(メタ)アクリル酸エステル重合体(A)を調製した。この(メタ)アクリル酸エステル重合体(A)の分子量を後述する方法で測定したところ、重量平均分子量(Mw)60万であった。
上記工程(1)で得られた(メタ)アクリル酸エステル重合体(A)100質量部(固形分換算値;以下同じ)と、ベンゾトリアゾール系防錆剤(B)としての1H−ベンゾトリアゾール(城北化学工業社製,製品名「BT−120」)0.3質量部と、架橋剤(C)としてのトリメチロールプロパン変性トリレンジイソシアネート(日本ポリウレタン社製,製品名「コロネートL」)0.15質量部と、シランカップリング剤としての3−グリシドキシプロピルトリメトキシシラン(信越化学工業社製,製品名「KBM−403」)0.2質量部とを混合し、十分に撹拌して、メチルエチルケトンで希釈することにより、固形分濃度25質量%の粘着性組成物の塗布溶液を得た。
[(メタ)アクリル酸エステル重合体(A)]
2EHA:アクリル酸2−エチルヘキシル
MMA:メタクリル酸メチル
HEA:アクリル酸2−ヒドロキシエチル
BA:アクリル酸n−ブチル
[ベンゾトリアゾール系防錆剤(B)]
防錆剤B1:1H−ベンゾトリアゾール(城北化学工業社製,製品名「BT−120」)
防錆剤B2:1H−トリルトリアゾール(シプロ化成社製,製品名「SEETEC TT−R」)
防錆剤B3:1−[N,N−ビス(2−エチルヘキシル)アミノメチル]ベンゾトリアゾール(城北化学工業社製,製品名「BT−LX」)
防錆剤B4:1−[N,N−ビス(2−エチルヘキシル)アミノメチル]メチルベンゾトリアゾール(城北化学工業社製,製品名「TT−LX」)
得られた粘着性組成物の塗布溶液を、ポリエチレンテレフタレートフィルムの片面をシリコーン系剥離剤で剥離処理した重剥離型剥離シート(リンテック社製,製品名「SP−PET382150」,厚さ:38μm)の剥離処理面に、乾燥後の厚さが50μmになるようにナイフコーターで塗布したのち、90℃で1分間加熱処理して塗布層を形成した。
(メタ)アクリル酸エステル重合体(A)を構成する各モノマーの種類および割合、(メタ)アクリル酸エステル重合体(A)の重量平均分子量(Mw)、ならびにベンゾトリアゾール系防錆剤(B)の種類を表1に示すように変更する以外、実施例1と同様にして粘着シートを製造した。
<測定条件>
・GPC測定装置:東ソー社製,HLC−8020
・GPCカラム(以下の順に通過):東ソー社製
TSK guard column HXL−H
TSK gel GMHXL(×2)
TSK gel G2000HXL
・測定溶媒:テトラヒドロフラン
・測定温度:40℃
実施例および比較例で得られた粘着シートの粘着剤層を、70mm×70mmサイズの無アルカリガラス(厚さ:1mm)2枚で挟み、その積層体を50℃、0.5MPaの条件で30分間オートクレーブ処理し、これをサンプルとした。
○:ヘイズ値が1.0%以下であった
×:ヘイズ値が1.0%超であった
(1)銅メッシュ積層フィルムの作製
ポリエチレンテレフタレート(PET)フィルム(東洋紡績社製,製品名「PET100A4100」,厚さ:100μm)と、片面を黒化処理した銅箔(古河サーキットフォイル社製,製品名「BW−S」,厚さ:10μm)と、ポリウレタン系接着剤(武田薬品工業社製,タケラックA310/タケネートA10/酢酸エチル=12/1/21(質量比))とを用意した。
実施例および比較例で得られた粘着シートから軽剥離型剥離シートを剥離し、露出した粘着剤層を、上記銅メッシュ積層フィルムの銅メッシュ側に貼付した。その後、粘着剤層から重剥離型剥離シートを剥離し、露出した粘着剤層に対して、PETフィルム(東洋紡績社製,製品名「PET A4100」,厚さ:100μm)を貼付し、PETフィルム/接着剤層/銅メッシュ/粘着剤層/PETフィルムからなる積層体を得て、これをサンプルとした。
○:銅メッシュに腐食がなかった
×:銅メッシュに腐食があった
厚さ50μmのポリエチレンテレフタレートフィルムの片面に、実施例および比較例と同様にして厚さ100μmの粘着剤層を形成し、その粘着剤層に、厚さ50μmのポリエチレンテレフタレートフィルムを貼合した後、50mm×50mmに裁断した。得られた積層体について、インピーダンスアナライザ(日本ヒューレット・パッカード社製,「HP−4194A」)を使用して静電容量(C1)を測定した。また、上記厚さ50μmのポリエチレンテレフタレートフィルムを2枚重ねて50mm×50mmに裁断し、同様にして静電容量(C2)を測定した。そして、C1からC2を差し引いて、粘着剤の静電容量(C3)を算出した。この静電容量C3に基づき、下記の式から粘着剤の誘電率εsを算出した。結果を表1に示す。
εs:粘着剤の誘電率
ε0:真空の誘電率(8.854×10−12)
C3:粘着剤の静電容量
S:粘着剤層の面積
d:粘着剤層の厚さ
11…粘着剤層
12a,12b…剥離シート
2…タッチパネル
3…表示体モジュール
4…粘着剤層
5a…第1のフィルムセンサー
5b…第2のフィルムセンサー
51…基材フィルム
52…電極
6…カバー材
7…印刷層
Claims (6)
- 金属部材と接触して使用される粘着剤を構成するための粘着性組成物であって、
重量平均分子量が30万以上であり、重合体を構成するモノマー単位として、(メタ)アクリル酸2−エチルヘキシルを30質量%以上含有し、水酸基を有するモノマーを15質量%超25質量%以下含有し、ホモポリマーとしてのガラス転移温度が70℃以上のハードモノマーを15質量%以上含有し、カルボキシル基を有するモノマーを含有しない(メタ)アクリル酸エステル重合体(A)と、
ベンゾトリアゾール系防錆剤(B)と、
イソシアネート系架橋剤と、
溶剤と
を含有することを特徴とする粘着性組成物。 - 前記ベンゾトリアゾール系防錆剤(B)として、1H−ベンゾトリアゾール、1H−トリルトリアゾール、1−[N,N−ビス(2−エチルヘキシル)アミノメチル]ベンゾトリアゾールおよび1−[N,N−ビス(2−エチルヘキシル)アミノメチル]メチルベンゾトリアゾールからなる群から選ばれる少なくとも1種を含有することを特徴とする請求項1に記載の粘着性組成物。
- 請求項1または2に記載の粘着性組成物を架橋してなる粘着剤。
- 1.0MHzにおける誘電率が2.0〜8.0であることを特徴とする請求項3に記載の粘着剤。
- 2枚の剥離シートと、
前記2枚の剥離シートの剥離面と接するように前記剥離シートに挟持された粘着剤層とを備え、
前記粘着剤層が、請求項3または4に記載の粘着剤からなる
ことを特徴とする粘着シート。 - 前記粘着剤層は、タッチパネルにおいて金属メッシュと接触するように配置されることを特徴とする請求項5に記載の粘着シート。
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JP6676429B2 (ja) * | 2016-03-23 | 2020-04-08 | リンテック株式会社 | 粘着性組成物、粘着剤、粘着シートおよび表示体 |
JP6561901B2 (ja) * | 2016-04-15 | 2019-08-21 | 信越化学工業株式会社 | 金属表面処理剤 |
JP6625927B2 (ja) * | 2016-04-18 | 2019-12-25 | 三菱製紙株式会社 | 光透過性電極積層体 |
US10800944B2 (en) * | 2016-08-10 | 2020-10-13 | Nitto Denko Corporation | Pressure-sensitive adhesive sheet |
JP6872869B2 (ja) * | 2016-08-10 | 2021-05-19 | 日東電工株式会社 | 粘着シート |
JP6962411B2 (ja) * | 2016-12-22 | 2021-11-05 | 三菱ケミカル株式会社 | アクリル系粘着剤組成物、およびそれを用いてなる粘着剤、粘着シート、ならびに粘着剤層付偏光板 |
JP6724767B2 (ja) * | 2016-12-22 | 2020-07-15 | 三菱ケミカル株式会社 | アクリル系粘着剤組成物、およびそれを用いてなる粘着剤、粘着シート、ならびに粘着剤層付偏光板 |
KR102535758B1 (ko) * | 2017-06-23 | 2023-05-23 | 미쯔비시 케미컬 주식회사 | 광경화형 점착 시트, 화상 표시 장치 구성용 적층체, 화상 표시 장치의 제조 방법 및 도전부재의 부식 억제 방법 |
JP7358041B2 (ja) * | 2018-10-12 | 2023-10-10 | 積水化学工業株式会社 | 防食用粘着剤、防食用粘着剤層及び防食用粘着テープ |
WO2021193747A1 (ja) | 2020-03-27 | 2021-09-30 | 日東電工株式会社 | 粘着剤シートの製造方法及び粘着剤シート |
Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH05163473A (ja) * | 1991-12-17 | 1993-06-29 | Sekisui Chem Co Ltd | ポリオレフィン発泡体用粘着剤組成物及び粘着加工品 |
JP2011021103A (ja) * | 2009-07-16 | 2011-02-03 | Daio Paper Corp | 難燃性粘着シート |
JP2011168684A (ja) * | 2010-02-18 | 2011-09-01 | Lintec Corp | 光学フィルター用の粘着性材料、粘着剤および粘着シート |
JP2012046681A (ja) * | 2010-08-30 | 2012-03-08 | Dainippon Printing Co Ltd | 金属貼付用粘着シート |
JP2012207055A (ja) * | 2011-03-29 | 2012-10-25 | Lintec Corp | 光学用箔状粘着剤および光学用粘着シート |
JP2012229410A (ja) * | 2011-04-11 | 2012-11-22 | Oji Holdings Corp | 両面粘着シート、剥離シート付き両面粘着シートおよび光学積層体 |
WO2012173247A1 (ja) * | 2011-06-17 | 2012-12-20 | 積水化学工業株式会社 | 透明粘着テープ、金属薄膜付フィルム積層体、カバーパネル-タッチパネルモジュール積層体、カバーパネル-ディスプレイパネルモジュール積層体、タッチパネルモジュール-ディスプレイパネルモジュール積層体、及び、画像表示装置 |
JP2013213203A (ja) * | 2012-03-09 | 2013-10-17 | Nippon Synthetic Chem Ind Co Ltd:The | アクリル系粘着剤組成物、アクリル系粘着剤、およびそれを用いてなる透明電極用粘着剤、タッチパネル及び画像表示装置 |
JP2013253160A (ja) * | 2012-06-06 | 2013-12-19 | Soken Chem & Eng Co Ltd | 導電膜用粘着シート、積層体および該積層体を有するタッチパネル |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1963186C3 (de) | 1969-12-17 | 1979-02-15 | Bayer Ag, 5090 Leverkusen | Schwefelhaltige 1,4-Dihydropyridin-33-dicarbonsäureester |
JP4818236B2 (ja) | 2007-09-18 | 2011-11-16 | 株式会社巴川製紙所 | 粘着シートおよびそれを使用した光学フィルター部材 |
JP2009227851A (ja) * | 2008-03-24 | 2009-10-08 | Dainippon Printing Co Ltd | 光学フィルタ用粘着剤組成物及び光学フィルタ |
US20130164478A1 (en) * | 2010-08-05 | 2013-06-27 | Oji Holdings Corporation | Double-faced pressure-sensitive adhesive sheet, double-faced pressure-sensitive adhesive sheet with release sheet, process for producing same, and transparent laminate |
JP5630256B2 (ja) * | 2010-12-24 | 2014-11-26 | Dic株式会社 | 紫外線硬化型粘着剤用樹脂組成物、粘着剤及び積層体 |
JP5611129B2 (ja) * | 2011-06-28 | 2014-10-22 | リンテック株式会社 | 粘着性組成物、粘着剤および粘着シート |
JP6001255B2 (ja) * | 2011-11-15 | 2016-10-05 | 日東電工株式会社 | 粘着シート |
JP6508869B2 (ja) * | 2013-02-14 | 2019-05-08 | 日東電工株式会社 | 粘着剤組成物、粘着剤層、粘着シート、光学部材、及びタッチパネル |
-
2014
- 2014-03-28 KR KR1020167029743A patent/KR20160140782A/ko not_active IP Right Cessation
- 2014-03-28 CN CN202211046246.3A patent/CN115322693A/zh active Pending
- 2014-03-28 KR KR1020217012436A patent/KR20210049194A/ko not_active IP Right Cessation
- 2014-03-28 JP JP2016509857A patent/JP6093907B2/ja active Active
- 2014-03-28 WO PCT/JP2014/059304 patent/WO2015145767A1/ja active Application Filing
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- 2014-03-28 KR KR1020227034477A patent/KR102658943B1/ko active IP Right Grant
-
2015
- 2015-03-27 TW TW104109921A patent/TWI668266B/zh active
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH05163473A (ja) * | 1991-12-17 | 1993-06-29 | Sekisui Chem Co Ltd | ポリオレフィン発泡体用粘着剤組成物及び粘着加工品 |
JP2011021103A (ja) * | 2009-07-16 | 2011-02-03 | Daio Paper Corp | 難燃性粘着シート |
JP2011168684A (ja) * | 2010-02-18 | 2011-09-01 | Lintec Corp | 光学フィルター用の粘着性材料、粘着剤および粘着シート |
JP2012046681A (ja) * | 2010-08-30 | 2012-03-08 | Dainippon Printing Co Ltd | 金属貼付用粘着シート |
JP2012207055A (ja) * | 2011-03-29 | 2012-10-25 | Lintec Corp | 光学用箔状粘着剤および光学用粘着シート |
JP2012229410A (ja) * | 2011-04-11 | 2012-11-22 | Oji Holdings Corp | 両面粘着シート、剥離シート付き両面粘着シートおよび光学積層体 |
WO2012173247A1 (ja) * | 2011-06-17 | 2012-12-20 | 積水化学工業株式会社 | 透明粘着テープ、金属薄膜付フィルム積層体、カバーパネル-タッチパネルモジュール積層体、カバーパネル-ディスプレイパネルモジュール積層体、タッチパネルモジュール-ディスプレイパネルモジュール積層体、及び、画像表示装置 |
JP2013213203A (ja) * | 2012-03-09 | 2013-10-17 | Nippon Synthetic Chem Ind Co Ltd:The | アクリル系粘着剤組成物、アクリル系粘着剤、およびそれを用いてなる透明電極用粘着剤、タッチパネル及び画像表示装置 |
JP2013253160A (ja) * | 2012-06-06 | 2013-12-19 | Soken Chem & Eng Co Ltd | 導電膜用粘着シート、積層体および該積層体を有するタッチパネル |
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CN115322693A (zh) | 2022-11-11 |
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