JP6085155B2 - アンモニア含有排水の処理装置およびアンモニア含有排水の処理方法 - Google Patents
アンモニア含有排水の処理装置およびアンモニア含有排水の処理方法 Download PDFInfo
- Publication number
- JP6085155B2 JP6085155B2 JP2012258573A JP2012258573A JP6085155B2 JP 6085155 B2 JP6085155 B2 JP 6085155B2 JP 2012258573 A JP2012258573 A JP 2012258573A JP 2012258573 A JP2012258573 A JP 2012258573A JP 6085155 B2 JP6085155 B2 JP 6085155B2
- Authority
- JP
- Japan
- Prior art keywords
- ammonia
- treatment
- water
- reverse osmosis
- osmosis membrane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 title claims description 588
- 229910021529 ammonia Inorganic materials 0.000 title claims description 291
- 238000004065 wastewater treatment Methods 0.000 title claims description 46
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 221
- 239000012528 membrane Substances 0.000 claims description 131
- 238000001223 reverse osmosis Methods 0.000 claims description 125
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 116
- 239000002351 wastewater Substances 0.000 claims description 71
- 238000000354 decomposition reaction Methods 0.000 claims description 29
- 238000000034 method Methods 0.000 claims description 27
- 239000012466 permeate Substances 0.000 claims description 27
- 102000016938 Catalase Human genes 0.000 claims description 11
- 108010053835 Catalase Proteins 0.000 claims description 11
- 102000004190 Enzymes Human genes 0.000 claims description 11
- 108090000790 Enzymes Proteins 0.000 claims description 11
- 238000011144 upstream manufacturing Methods 0.000 claims description 10
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 38
- 239000000126 substance Substances 0.000 description 29
- 239000003795 chemical substances by application Substances 0.000 description 14
- 238000001471 micro-filtration Methods 0.000 description 11
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 238000011109 contamination Methods 0.000 description 9
- 239000002270 dispersing agent Substances 0.000 description 8
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 7
- 238000010979 pH adjustment Methods 0.000 description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- 239000003513 alkali Substances 0.000 description 6
- -1 ammonium ions Chemical class 0.000 description 6
- 230000007423 decrease Effects 0.000 description 6
- 238000010586 diagram Methods 0.000 description 6
- 238000004821 distillation Methods 0.000 description 6
- 150000002500 ions Chemical class 0.000 description 6
- 239000000498 cooling water Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 229910001424 calcium ion Inorganic materials 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- 239000012498 ultrapure water Substances 0.000 description 3
- 238000011033 desalting Methods 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000005416 organic matter Substances 0.000 description 2
- 230000003204 osmotic effect Effects 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 239000013618 particulate matter Substances 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- WGTYBPLFGIVFAS-UHFFFAOYSA-M tetramethylammonium hydroxide Chemical compound [OH-].C[N+](C)(C)C WGTYBPLFGIVFAS-UHFFFAOYSA-M 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
- 241000220317 Rosa Species 0.000 description 1
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 231100000676 disease causative agent Toxicity 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000008214 highly purified water Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 229910001425 magnesium ion Inorganic materials 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
- C02F1/441—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by reverse osmosis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/02—Reverse osmosis; Hyperfiltration ; Nanofiltration
- B01D61/025—Reverse osmosis; Hyperfiltration
- B01D61/026—Reverse osmosis; Hyperfiltration comprising multiple reverse osmosis steps
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/58—Multistep processes
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/20—Treatment of water, waste water, or sewage by degassing, i.e. liberation of dissolved gases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2311/00—Details relating to membrane separation process operations and control
- B01D2311/04—Specific process operations in the feed stream; Feed pretreatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2311/00—Details relating to membrane separation process operations and control
- B01D2311/25—Recirculation, recycling or bypass, e.g. recirculation of concentrate into the feed
- B01D2311/252—Recirculation of concentrate
- B01D2311/2523—Recirculation of concentrate to feed side
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2317/00—Membrane module arrangements within a plant or an apparatus
- B01D2317/02—Elements in series
- B01D2317/025—Permeate series
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/02—Reverse osmosis; Hyperfiltration ; Nanofiltration
- B01D61/025—Reverse osmosis; Hyperfiltration
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/14—Ultrafiltration; Microfiltration
- B01D61/147—Microfiltration
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/66—Treatment of water, waste water, or sewage by neutralisation; pH adjustment
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/16—Nitrogen compounds, e.g. ammonia
Landscapes
- Engineering & Computer Science (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Organic Chemistry (AREA)
- Nanotechnology (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Physical Water Treatments (AREA)
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2012258573A JP6085155B2 (ja) | 2012-11-27 | 2012-11-27 | アンモニア含有排水の処理装置およびアンモニア含有排水の処理方法 |
| CN201380061979.7A CN104812705B (zh) | 2012-11-27 | 2013-07-19 | 含氨废水的处理装置及含氨废水的处理方法 |
| SG11201503489RA SG11201503489RA (en) | 2012-11-27 | 2013-07-19 | Device for treating ammonia-containing wastewater, and method for treating ammonia-containing wastewater |
| PCT/JP2013/069608 WO2014083887A1 (ja) | 2012-11-27 | 2013-07-19 | アンモニア含有排水の処理装置およびアンモニア含有排水の処理方法 |
| TW102135873A TWI613153B (zh) | 2012-11-27 | 2013-10-03 | 含氨廢水的處理裝置及含氨廢水的處理方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2012258573A JP6085155B2 (ja) | 2012-11-27 | 2012-11-27 | アンモニア含有排水の処理装置およびアンモニア含有排水の処理方法 |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2016244098A Division JP6368767B2 (ja) | 2016-12-16 | 2016-12-16 | アンモニア含有排水の処理装置およびアンモニア含有排水の処理方法 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2014104410A JP2014104410A (ja) | 2014-06-09 |
| JP2014104410A5 JP2014104410A5 (enrdf_load_stackoverflow) | 2015-08-27 |
| JP6085155B2 true JP6085155B2 (ja) | 2017-02-22 |
Family
ID=50827542
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2012258573A Active JP6085155B2 (ja) | 2012-11-27 | 2012-11-27 | アンモニア含有排水の処理装置およびアンモニア含有排水の処理方法 |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JP6085155B2 (enrdf_load_stackoverflow) |
| CN (1) | CN104812705B (enrdf_load_stackoverflow) |
| SG (1) | SG11201503489RA (enrdf_load_stackoverflow) |
| TW (1) | TWI613153B (enrdf_load_stackoverflow) |
| WO (1) | WO2014083887A1 (enrdf_load_stackoverflow) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2017070927A1 (en) * | 2015-10-30 | 2017-05-04 | Dow Global Technologies Llc | Membrane treatment of ammonia-containing waste water |
| JP6653626B2 (ja) * | 2016-06-07 | 2020-02-26 | オルガノ株式会社 | 水処理方法および装置、水処理装置の改造方法、並びに水処理装置改造用キット |
| JP7092530B2 (ja) * | 2018-03-23 | 2022-06-28 | 月島環境エンジニアリング株式会社 | 酸性成分及びアンモニアを含有する廃水のアンモニアストリッピング処理装置及びその方法 |
| JP6773164B2 (ja) * | 2019-03-28 | 2020-10-21 | 栗田工業株式会社 | 水処理装置及び水処理方法 |
| JP7248046B2 (ja) * | 2021-03-29 | 2023-03-29 | 栗田工業株式会社 | 逆浸透膜装置の運転方法 |
| JP7637570B2 (ja) * | 2021-06-04 | 2025-02-28 | オルガノ株式会社 | 水処理方法および水処理装置 |
| CN115417547A (zh) * | 2022-09-01 | 2022-12-02 | 宁德邦普循环科技有限公司 | 一种前驱体合成废水淡化系统 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3246011B2 (ja) * | 1992-12-03 | 2002-01-15 | 栗田工業株式会社 | 過酸化水素を含む半導体製造排水の処理方法 |
| US5766479A (en) * | 1995-08-07 | 1998-06-16 | Zenon Environmental Inc. | Production of high purity water using reverse osmosis |
| JPH10314735A (ja) * | 1997-05-14 | 1998-12-02 | Kurita Water Ind Ltd | 純水製造方法 |
| JP4066527B2 (ja) * | 1998-08-06 | 2008-03-26 | 栗田工業株式会社 | 過酸化水素とアンモニアとを含む排水の処理法 |
| JP3667597B2 (ja) * | 2000-05-12 | 2005-07-06 | 三菱住友シリコン株式会社 | 半導体製造工程から排出されるアンモニア含有排水の処理方法 |
| JP2002143850A (ja) * | 2000-11-15 | 2002-05-21 | Hitachi Zosen Corp | 排水処理装置 |
| JP2002192152A (ja) * | 2000-12-25 | 2002-07-10 | Nomura Micro Sci Co Ltd | 水処理方法および水処理装置 |
| TW200838810A (en) * | 2007-03-21 | 2008-10-01 | Powerchip Semiconductor Corp | System of wastewater disposal and method of the same |
| CN201485354U (zh) * | 2009-08-27 | 2010-05-26 | 浙江华友钴业股份有限公司 | 一种处理氨氮废水的新型装置 |
| JP2011212585A (ja) * | 2010-03-31 | 2011-10-27 | Kurita Water Ind Ltd | 有機物含有排水の処理方法及び装置 |
| TWI534096B (zh) * | 2010-05-18 | 2016-05-21 | Wastewater recovery and treatment system and its treatment method |
-
2012
- 2012-11-27 JP JP2012258573A patent/JP6085155B2/ja active Active
-
2013
- 2013-07-19 SG SG11201503489RA patent/SG11201503489RA/en unknown
- 2013-07-19 CN CN201380061979.7A patent/CN104812705B/zh not_active Expired - Fee Related
- 2013-07-19 WO PCT/JP2013/069608 patent/WO2014083887A1/ja active Application Filing
- 2013-10-03 TW TW102135873A patent/TWI613153B/zh active
Also Published As
| Publication number | Publication date |
|---|---|
| TWI613153B (zh) | 2018-02-01 |
| JP2014104410A (ja) | 2014-06-09 |
| TW201427910A (zh) | 2014-07-16 |
| WO2014083887A1 (ja) | 2014-06-05 |
| SG11201503489RA (en) | 2015-06-29 |
| CN104812705A (zh) | 2015-07-29 |
| CN104812705B (zh) | 2019-04-19 |
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