JP6047169B2 - 複合酸化物触媒及びその製造方法、並びに不飽和ニトリルの製造方法 - Google Patents

複合酸化物触媒及びその製造方法、並びに不飽和ニトリルの製造方法 Download PDF

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JP6047169B2
JP6047169B2 JP2014538399A JP2014538399A JP6047169B2 JP 6047169 B2 JP6047169 B2 JP 6047169B2 JP 2014538399 A JP2014538399 A JP 2014538399A JP 2014538399 A JP2014538399 A JP 2014538399A JP 6047169 B2 JP6047169 B2 JP 6047169B2
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catalyst
composite oxide
raw material
reaction
producing
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JPWO2014050615A1 (ja
Inventor
悠輔 石井
悠輔 石井
実 門脇
実 門脇
加藤　高明
高明 加藤
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Asahi Kasei Corp
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/30—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0045—Drying a slurry, e.g. spray drying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/04—Mixing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • B01J37/088—Decomposition of a metal salt
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
    • C07C253/26—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons containing carbon-to-carbon multiple bonds, e.g. unsaturated aldehydes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00—Carboxylic acid nitriles
    • C07C255/01—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms
    • C07C255/06—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms of an acyclic and unsaturated carbon skeleton
    • C07C255/07—Mononitriles
    • C07C255/08—Acrylonitrile; Methacrylonitrile
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0236—Drying, e.g. preparing a suspension, adding a soluble salt and drying
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
JP2014538399A 2012-09-27 2013-09-13 複合酸化物触媒及びその製造方法、並びに不飽和ニトリルの製造方法 Active JP6047169B2 (ja)

Applications Claiming Priority (3)

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JP2012214867 2012-09-27
JP2012214867 2012-09-27
PCT/JP2013/074888 WO2014050615A1 (ja) 2012-09-27 2013-09-13 複合酸化物触媒及びその製造方法、並びに不飽和ニトリルの製造方法

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JP6047169B2 true JP6047169B2 (ja) 2016-12-21

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JP2016085399A Active JP6159847B2 (ja) 2012-09-27 2016-04-21 複合酸化物触媒及びその製造方法、並びに不飽和ニトリルの製造方法

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US (1) US10343146B2 (enExample)
EP (1) EP2902105B1 (enExample)
JP (2) JP6047169B2 (enExample)
KR (1) KR101741888B1 (enExample)
CN (2) CN104661745A (enExample)
IN (1) IN2015DN01735A (enExample)
MY (1) MY169921A (enExample)
RU (1) RU2601990C1 (enExample)
TR (1) TR201905402T4 (enExample)
TW (1) TWI580470B (enExample)
WO (1) WO2014050615A1 (enExample)

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KR101506828B1 (ko) * 2010-12-27 2015-03-27 아사히 가세이 케미칼즈 가부시키가이샤 복합 산화물 촉매 및 그 제조 방법
EP3127608A4 (en) * 2014-03-31 2017-07-05 Asahi Kasei Kabushiki Kaisha Method for producing oxide catalyst and method for producing unsaturated nitrile
US9950313B2 (en) 2015-03-31 2018-04-24 Asahi Kasei Kabushiki Kaisha Method for producing oxide catalyst, and method for producing unsaturated nitrile
EP3120926A1 (de) * 2015-07-20 2017-01-25 Evonik Degussa GmbH Verfahren zur herstellung von mischoxidkatalysatoren
MY188595A (en) * 2016-08-02 2021-12-22 Asahi Chemical Ind Method for producing oxide catalyst and method for producing unsaturated nitrile
CN109562356B (zh) * 2016-08-12 2022-03-08 旭化成株式会社 氧化物催化剂的制造方法、以及不饱和腈和不饱和酸的制造方法
CN106311219B (zh) * 2016-09-08 2018-11-09 江苏大学 一种碳掺杂二氧化硅复合材料的制备方法及其应用
JP6764939B2 (ja) * 2016-09-13 2020-10-07 旭化成株式会社 酸化物触媒の製造方法、及び不飽和ニトリルの製造方法
TWI668204B (zh) * 2017-06-09 2019-08-11 日商旭化成股份有限公司 Method for producing unsaturated nitrile
US10894762B2 (en) * 2017-07-03 2021-01-19 Asahi Kasei Kabushiki Kaisha Process for producing unsaturated nitrile
TWI655967B (zh) * 2017-11-22 2019-04-11 國立清華大學 還原態觸媒的製備方法、其製備之還原態觸媒、其用途以及合成氣的製造方法
US12357969B2 (en) 2019-06-06 2025-07-15 Asahi Kasei Kabushiki Kaisha Oxide catalyst and method for producing unsaturated nitrile
KR20220116326A (ko) * 2020-01-31 2022-08-22 아사히 가세이 가부시키가이샤 촉매 제조용 조성물, 촉매 제조용 조성물의 제조 방법, 및 산화물 촉매를 제조하는 제조 방법
CN117323999A (zh) * 2022-06-24 2024-01-02 中国石油化工股份有限公司 丙烯腈催化剂及其制备方法和应用

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JP5041514B2 (ja) 2006-01-19 2012-10-03 旭化成ケミカルズ株式会社 不飽和酸または不飽和ニトリル製造用酸化物触媒およびその製造方法並びに不飽和酸または不飽和ニトリルの製造方法
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JP5694727B2 (ja) * 2010-10-04 2015-04-01 旭化成ケミカルズ株式会社 不飽和酸又は不飽和ニトリルの製造方法
KR101506828B1 (ko) * 2010-12-27 2015-03-27 아사히 가세이 케미칼즈 가부시키가이샤 복합 산화물 촉매 및 그 제조 방법
CN103402976B (zh) * 2011-03-02 2016-03-30 旭化成化学株式会社 不饱和腈的制造方法

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TW201420184A (zh) 2014-06-01
CN104661745A (zh) 2015-05-27
RU2601990C1 (ru) 2016-11-10
TR201905402T4 (tr) 2019-05-21
EP2902105A1 (en) 2015-08-05
EP2902105A4 (en) 2016-02-17
EP2902105B1 (en) 2019-03-20
CN110026183A (zh) 2019-07-19
TWI580470B (zh) 2017-05-01
JPWO2014050615A1 (ja) 2016-08-22
US20150231604A1 (en) 2015-08-20
US10343146B2 (en) 2019-07-09
KR101741888B1 (ko) 2017-05-30
MY169921A (en) 2019-06-17
JP2016215187A (ja) 2016-12-22
WO2014050615A1 (ja) 2014-04-03
JP6159847B2 (ja) 2017-07-05
KR20150011830A (ko) 2015-02-02
IN2015DN01735A (enExample) 2015-05-29

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