CN104661745A - 复合氧化物催化剂及其制造方法、和不饱和腈的制造方法 - Google Patents

复合氧化物催化剂及其制造方法、和不饱和腈的制造方法 Download PDF

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Publication number
CN104661745A
CN104661745A CN201380049253.1A CN201380049253A CN104661745A CN 104661745 A CN104661745 A CN 104661745A CN 201380049253 A CN201380049253 A CN 201380049253A CN 104661745 A CN104661745 A CN 104661745A
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China
Prior art keywords
composite oxide
raw material
roasting
catalyst
oxide catalyst
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Pending
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CN201380049253.1A
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English (en)
Chinese (zh)
Inventor
石井悠辅
门胁实
加藤高明
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Asahi Kasei Corp
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Asahi Kasei Chemicals Corp
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Priority to CN201910231920.7A priority Critical patent/CN110026183A/zh
Publication of CN104661745A publication Critical patent/CN104661745A/zh
Pending legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/30—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0045—Drying a slurry, e.g. spray drying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/04—Mixing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • B01J37/088—Decomposition of a metal salt
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
    • C07C253/26—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons containing carbon-to-carbon multiple bonds, e.g. unsaturated aldehydes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00—Carboxylic acid nitriles
    • C07C255/01—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms
    • C07C255/06—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms of an acyclic and unsaturated carbon skeleton
    • C07C255/07—Mononitriles
    • C07C255/08—Acrylonitrile; Methacrylonitrile
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0236—Drying, e.g. preparing a suspension, adding a soluble salt and drying
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
CN201380049253.1A 2012-09-27 2013-09-13 复合氧化物催化剂及其制造方法、和不饱和腈的制造方法 Pending CN104661745A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910231920.7A CN110026183A (zh) 2012-09-27 2013-09-13 复合氧化物催化剂的制造方法和不饱和腈的制造方法

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2012-214867 2012-09-27
JP2012214867 2012-09-27
PCT/JP2013/074888 WO2014050615A1 (ja) 2012-09-27 2013-09-13 複合酸化物触媒及びその製造方法、並びに不飽和ニトリルの製造方法

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CN201910231920.7A Pending CN110026183A (zh) 2012-09-27 2013-09-13 复合氧化物催化剂的制造方法和不饱和腈的制造方法

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US (1) US10343146B2 (enExample)
EP (1) EP2902105B1 (enExample)
JP (2) JP6047169B2 (enExample)
KR (1) KR101741888B1 (enExample)
CN (2) CN104661745A (enExample)
IN (1) IN2015DN01735A (enExample)
MY (1) MY169921A (enExample)
RU (1) RU2601990C1 (enExample)
TR (1) TR201905402T4 (enExample)
TW (1) TWI580470B (enExample)
WO (1) WO2014050615A1 (enExample)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107530682A (zh) * 2015-03-31 2018-01-02 旭化成株式会社 氧化物催化剂的制造方法和不饱和腈的制造方法
CN107847922A (zh) * 2015-07-20 2018-03-27 赢创德固赛有限公司 制备含有钼和铋的混合氧化物催化剂的方法
CN109195704A (zh) * 2016-08-02 2019-01-11 旭化成株式会社 氧化物催化剂的制造方法及不饱和腈的制造方法
TWI655967B (zh) * 2017-11-22 2019-04-11 國立清華大學 還原態觸媒的製備方法、其製備之還原態觸媒、其用途以及合成氣的製造方法
CN112423879A (zh) * 2019-06-06 2021-02-26 旭化成株式会社 氧化物催化剂及不饱和腈的制造方法
RU2793851C1 (ru) * 2019-06-06 2023-04-07 Асахи Касеи Кабусики Кайся Оксидный катализатор и способ получения ненасыщенных нитрилов
CN117323999A (zh) * 2022-06-24 2024-01-02 中国石油化工股份有限公司 丙烯腈催化剂及其制备方法和应用

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US9855546B2 (en) * 2010-12-27 2018-01-02 Asahi Kasei Chemicals Corporation Composite oxide catalyst and method for producing the same
JP6105809B2 (ja) * 2014-03-31 2017-03-29 旭化成株式会社 酸化物触媒の製造方法、及び不飽和ニトリルの製造方法
CN109562356B (zh) * 2016-08-12 2022-03-08 旭化成株式会社 氧化物催化剂的制造方法、以及不饱和腈和不饱和酸的制造方法
CN106311219B (zh) * 2016-09-08 2018-11-09 江苏大学 一种碳掺杂二氧化硅复合材料的制备方法及其应用
KR102368347B1 (ko) 2016-09-13 2022-03-02 아사히 가세이 가부시키가이샤 산화물 촉매의 제조 방법, 및 불포화 니트릴의 제조 방법
US10640458B2 (en) * 2017-06-09 2020-05-05 Asahi Kasei Kabushiki Kaisha Process for producing unsaturated nitrile
WO2019008924A1 (ja) * 2017-07-03 2019-01-10 旭化成株式会社 不飽和ニトリルの製造方法
US20230057028A1 (en) * 2020-01-31 2023-02-23 Asahi Kasei Kabushiki Kaisha Composition for catalyst production, method for producing composition for catalyst production, and production method for producing oxide catalyst

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JP2002219362A (ja) * 2001-01-24 2002-08-06 Asahi Kasei Corp 低比重シリカ担持触媒
JP2003320248A (ja) * 2002-04-25 2003-11-11 Asahi Kasei Corp 酸化用触媒の調製方法とその触媒を用いたニトリルの製法
CN1723083A (zh) * 2002-12-02 2006-01-18 标准石油公司 用于制造丙烯腈的Rb、Ce、Cr、Ni、Fe、Bi及Mo的混合氧化物催化剂
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JP2002219362A (ja) * 2001-01-24 2002-08-06 Asahi Kasei Corp 低比重シリカ担持触媒
JP2003320248A (ja) * 2002-04-25 2003-11-11 Asahi Kasei Corp 酸化用触媒の調製方法とその触媒を用いたニトリルの製法
CN1723083A (zh) * 2002-12-02 2006-01-18 标准石油公司 用于制造丙烯腈的Rb、Ce、Cr、Ni、Fe、Bi及Mo的混合氧化物催化剂
WO2012090979A1 (ja) * 2010-12-27 2012-07-05 旭化成ケミカルズ株式会社 複合酸化物触媒及びその製造方法

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107530682A (zh) * 2015-03-31 2018-01-02 旭化成株式会社 氧化物催化剂的制造方法和不饱和腈的制造方法
CN107847922A (zh) * 2015-07-20 2018-03-27 赢创德固赛有限公司 制备含有钼和铋的混合氧化物催化剂的方法
US11007506B2 (en) 2015-07-20 2021-05-18 Evonik Operations Gmbh Method for preparing mixed metal oxide catalysts containing molybdenum and bismuth
CN109195704A (zh) * 2016-08-02 2019-01-11 旭化成株式会社 氧化物催化剂的制造方法及不饱和腈的制造方法
TWI655967B (zh) * 2017-11-22 2019-04-11 國立清華大學 還原態觸媒的製備方法、其製備之還原態觸媒、其用途以及合成氣的製造方法
CN112423879A (zh) * 2019-06-06 2021-02-26 旭化成株式会社 氧化物催化剂及不饱和腈的制造方法
RU2793851C1 (ru) * 2019-06-06 2023-04-07 Асахи Касеи Кабусики Кайся Оксидный катализатор и способ получения ненасыщенных нитрилов
CN112423879B (zh) * 2019-06-06 2023-06-16 旭化成株式会社 氧化物催化剂及不饱和腈的制造方法
US12357969B2 (en) 2019-06-06 2025-07-15 Asahi Kasei Kabushiki Kaisha Oxide catalyst and method for producing unsaturated nitrile
CN117323999A (zh) * 2022-06-24 2024-01-02 中国石油化工股份有限公司 丙烯腈催化剂及其制备方法和应用

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EP2902105A4 (en) 2016-02-17
TWI580470B (zh) 2017-05-01
JPWO2014050615A1 (ja) 2016-08-22
US20150231604A1 (en) 2015-08-20
IN2015DN01735A (enExample) 2015-05-29
JP6047169B2 (ja) 2016-12-21
JP2016215187A (ja) 2016-12-22
EP2902105B1 (en) 2019-03-20
MY169921A (en) 2019-06-17
TW201420184A (zh) 2014-06-01
KR20150011830A (ko) 2015-02-02
CN110026183A (zh) 2019-07-19
EP2902105A1 (en) 2015-08-05
JP6159847B2 (ja) 2017-07-05
US10343146B2 (en) 2019-07-09
WO2014050615A1 (ja) 2014-04-03
TR201905402T4 (tr) 2019-05-21
RU2601990C1 (ru) 2016-11-10
KR101741888B1 (ko) 2017-05-30

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Application publication date: 20150527