JP6046167B2 - 染料を含有する洗濯ケア組成物 - Google Patents
染料を含有する洗濯ケア組成物 Download PDFInfo
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- JP6046167B2 JP6046167B2 JP2014557622A JP2014557622A JP6046167B2 JP 6046167 B2 JP6046167 B2 JP 6046167B2 JP 2014557622 A JP2014557622 A JP 2014557622A JP 2014557622 A JP2014557622 A JP 2014557622A JP 6046167 B2 JP6046167 B2 JP 6046167B2
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- dye
- alkyl
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- 239000000203 mixture Substances 0.000 title claims description 328
- 239000000975 dye Substances 0.000 title description 153
- 125000000217 alkyl group Chemical group 0.000 claims description 76
- 229910052739 hydrogen Inorganic materials 0.000 claims description 72
- 229910052799 carbon Inorganic materials 0.000 claims description 49
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 34
- 229910052727 yttrium Inorganic materials 0.000 claims description 32
- 125000003118 aryl group Chemical group 0.000 claims description 31
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 29
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 claims description 25
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- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 10
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- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
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- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 description 1
- 229910052913 potassium silicate Inorganic materials 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 150000003141 primary amines Chemical group 0.000 description 1
- 239000011164 primary particle Substances 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 150000003219 pyrazolines Chemical class 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
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- 239000000985 reactive dye Substances 0.000 description 1
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- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 description 1
- 238000007142 ring opening reaction Methods 0.000 description 1
- 229930007790 rose oxide Natural products 0.000 description 1
- 238000002390 rotary evaporation Methods 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
- 150000003335 secondary amines Chemical group 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 239000004208 shellac Substances 0.000 description 1
- ZLGIYFNHBLSMPS-ATJNOEHPSA-N shellac Chemical compound OCCCCCC(O)C(O)CCCCCCCC(O)=O.C1C23[C@H](C(O)=O)CCC2[C@](C)(CO)[C@@H]1C(C(O)=O)=C[C@@H]3O ZLGIYFNHBLSMPS-ATJNOEHPSA-N 0.000 description 1
- 229940113147 shellac Drugs 0.000 description 1
- 235000013874 shellac Nutrition 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 150000003377 silicon compounds Chemical class 0.000 description 1
- 239000013514 silicone foam Substances 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 239000004945 silicone rubber Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 229940100890 silver compound Drugs 0.000 description 1
- 150000003379 silver compounds Chemical class 0.000 description 1
- 229910021647 smectite Inorganic materials 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- QSKQNALVHFTOQX-UHFFFAOYSA-M sodium nonanoyloxybenzenesulfonate Chemical compound [Na+].CCCCCCCCC(=O)OC1=CC=CC=C1S([O-])(=O)=O QSKQNALVHFTOQX-UHFFFAOYSA-M 0.000 description 1
- 229960001922 sodium perborate Drugs 0.000 description 1
- 229940045872 sodium percarbonate Drugs 0.000 description 1
- AXMCIYLNKNGNOT-UHFFFAOYSA-M sodium;3-[[4-[(4-dimethylazaniumylidenecyclohexa-2,5-dien-1-ylidene)-[4-[ethyl-[(3-sulfonatophenyl)methyl]amino]phenyl]methyl]-n-ethylanilino]methyl]benzenesulfonate Chemical compound [Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](C)C)C=2C=CC(=CC=2)N(CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 AXMCIYLNKNGNOT-UHFFFAOYSA-M 0.000 description 1
- RWVGQQGBQSJDQV-UHFFFAOYSA-M sodium;3-[[4-[(e)-[4-(4-ethoxyanilino)phenyl]-[4-[ethyl-[(3-sulfonatophenyl)methyl]azaniumylidene]-2-methylcyclohexa-2,5-dien-1-ylidene]methyl]-n-ethyl-3-methylanilino]methyl]benzenesulfonate Chemical compound [Na+].C1=CC(OCC)=CC=C1NC1=CC=C(C(=C2C(=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C)C=2C(=CC(=CC=2)N(CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C)C=C1 RWVGQQGBQSJDQV-UHFFFAOYSA-M 0.000 description 1
- IXNUVCLIRYUKFB-UHFFFAOYSA-M sodium;3-[[4-[[4-(diethylamino)-2-methylphenyl]-[4-[ethyl-[(3-sulfonatophenyl)methyl]azaniumylidene]cyclohexa-2,5-dien-1-ylidene]methyl]-n-ethylanilino]methyl]benzenesulfonate Chemical compound [Na+].CC1=CC(N(CC)CC)=CC=C1C(C=1C=CC(=CC=1)N(CC)CC=1C=C(C=CC=1)S([O-])(=O)=O)=C(C=C1)C=CC1=[N+](CC)CC1=CC=CC(S([O-])(=O)=O)=C1 IXNUVCLIRYUKFB-UHFFFAOYSA-M 0.000 description 1
- NTOOJLUHUFUGQI-UHFFFAOYSA-M sodium;4-(4-acetamidoanilino)-1-amino-9,10-dioxoanthracene-2-sulfonate Chemical compound [Na+].C1=CC(NC(=O)C)=CC=C1NC1=CC(S([O-])(=O)=O)=C(N)C2=C1C(=O)C1=CC=CC=C1C2=O NTOOJLUHUFUGQI-UHFFFAOYSA-M 0.000 description 1
- WQZNLMYQHGWSHK-UHFFFAOYSA-M sodium;5-[[4-(dimethylamino)phenyl]-(4-dimethylazaniumylidenecyclohexa-2,5-dien-1-ylidene)methyl]-4-ethoxy-2-(4-methyl-2-sulfonatoanilino)benzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C=1C=C(C(=C2C=CC(C=C2)=[N+](C)C)C=2C=CC(=CC=2)N(C)C)C(OCC)=CC=1NC1=CC=C(C)C=C1S([O-])(=O)=O WQZNLMYQHGWSHK-UHFFFAOYSA-M 0.000 description 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- LJFWQNJLLOFIJK-UHFFFAOYSA-N solvent violet 13 Chemical compound C1=CC(C)=CC=C1NC1=CC=C(O)C2=C1C(=O)C1=CC=CC=C1C2=O LJFWQNJLLOFIJK-UHFFFAOYSA-N 0.000 description 1
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- 235000021286 stilbenes Nutrition 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 150000003890 succinate salts Chemical class 0.000 description 1
- RINCXYDBBGOEEQ-UHFFFAOYSA-N succinic anhydride Chemical compound O=C1CCC(=O)O1 RINCXYDBBGOEEQ-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-O sulfonium group Chemical group [SH3+] RWSOTUBLDIXVET-UHFFFAOYSA-O 0.000 description 1
- 239000002426 superphosphate Substances 0.000 description 1
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- 108010038851 tannase Proteins 0.000 description 1
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- 125000005207 tetraalkylammonium group Chemical group 0.000 description 1
- 150000004685 tetrahydrates Chemical class 0.000 description 1
- 238000003856 thermoforming Methods 0.000 description 1
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- JADVWWSKYZXRGX-UHFFFAOYSA-M thioflavine T Chemical compound [Cl-].C1=CC(N(C)C)=CC=C1C1=[N+](C)C2=CC=C(C)C=C2S1 JADVWWSKYZXRGX-UHFFFAOYSA-M 0.000 description 1
- 150000003573 thiols Chemical group 0.000 description 1
- GLQWRXYOTXRDNH-UHFFFAOYSA-N thiophen-2-amine Chemical compound NC1=CC=CS1 GLQWRXYOTXRDNH-UHFFFAOYSA-N 0.000 description 1
- 229960000790 thymol Drugs 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- ILJSQTXMGCGYMG-UHFFFAOYSA-N triacetic acid Chemical compound CC(=O)CC(=O)CC(O)=O ILJSQTXMGCGYMG-UHFFFAOYSA-N 0.000 description 1
- 150000003626 triacylglycerols Chemical class 0.000 description 1
- 125000005208 trialkylammonium group Chemical group 0.000 description 1
- QQOWHRYOXYEMTL-UHFFFAOYSA-N triazin-4-amine Chemical class N=C1C=CN=NN1 QQOWHRYOXYEMTL-UHFFFAOYSA-N 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- AAAQKTZKLRYKHR-UHFFFAOYSA-N triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 description 1
- 239000012588 trypsin Substances 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 235000013799 ultramarine blue Nutrition 0.000 description 1
- YKSGNOMLAIJTLT-UHFFFAOYSA-N violanthrone Chemical compound C12=C3C4=CC=C2C2=CC=CC=C2C(=O)C1=CC=C3C1=CC=C2C(=O)C3=CC=CC=C3C3=CC=C4C1=C32 YKSGNOMLAIJTLT-UHFFFAOYSA-N 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
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- 229940088594 vitamin Drugs 0.000 description 1
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- 239000000080 wetting agent Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 210000000707 wrist Anatomy 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
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- 239000011701 zinc Substances 0.000 description 1
- GAWWVVGZMLGEIW-GNNYBVKZSA-L zinc ricinoleate Chemical compound [Zn+2].CCCCCC[C@@H](O)C\C=C/CCCCCCCC([O-])=O.CCCCCC[C@@H](O)C\C=C/CCCCCCCC([O-])=O GAWWVVGZMLGEIW-GNNYBVKZSA-L 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B29/00—Monoazo dyes prepared by diazotising and coupling
- C09B29/34—Monoazo dyes prepared by diazotising and coupling from other coupling components
- C09B29/36—Monoazo dyes prepared by diazotising and coupling from other coupling components from heterocyclic compounds
- C09B29/3682—Monoazo dyes prepared by diazotising and coupling from other coupling components from heterocyclic compounds containing only sulfur as heteroatom
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B29/00—Monoazo dyes prepared by diazotising and coupling
- C09B29/06—Monoazo dyes prepared by diazotising and coupling from coupling components containing amino as the only directing group
- C09B29/08—Amino benzenes
- C09B29/0801—Amino benzenes containing acid groups, e.g. COOH, SO3H, PO3H2, OSO3H, OPO3H2; SO2NHSO2R or salts thereof, R being hydrocarbonyls
- C09B29/0802—Amino benzenes containing acid groups, e.g. COOH, SO3H, PO3H2, OSO3H, OPO3H2; SO2NHSO2R or salts thereof, R being hydrocarbonyls containing COOH
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B29/00—Monoazo dyes prepared by diazotising and coupling
- C09B29/0025—Monoazo dyes prepared by diazotising and coupling from diazotized amino heterocyclic compounds
- C09B29/0059—Monoazo dyes prepared by diazotising and coupling from diazotized amino heterocyclic compounds the heterocyclic ring containing only sulfur as heteroatom
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B69/00—Dyes not provided for by a single group of this subclass
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Detergent Compositions (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
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| US201261597925P | 2012-02-13 | 2012-02-13 | |
| US61/597,925 | 2012-02-13 | ||
| US13/615,765 US20140371435A9 (en) | 2011-06-03 | 2012-09-14 | Laundry Care Compositions Containing Thiophene Azo Dyes |
| US13/615,765 | 2012-09-14 | ||
| PCT/US2012/056794 WO2013006871A2 (en) | 2012-02-13 | 2012-09-24 | Laundry care compositions containing dyes |
Publications (2)
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|---|---|
| JP2015513576A JP2015513576A (ja) | 2015-05-14 |
| JP6046167B2 true JP6046167B2 (ja) | 2016-12-14 |
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| JP (1) | JP6046167B2 (forum.php) |
| CN (1) | CN104105787B (forum.php) |
| BR (1) | BR112014019549A8 (forum.php) |
| CA (1) | CA2861099C (forum.php) |
| IN (1) | IN2014DN05968A (forum.php) |
| MX (1) | MX2014009036A (forum.php) |
| WO (1) | WO2013006871A2 (forum.php) |
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| FR2680619B1 (fr) * | 1991-08-21 | 1993-12-24 | Sgs Thomson Microelectronics Sa | Predicteur d'image. |
| US8715368B2 (en) | 2010-11-12 | 2014-05-06 | The Procter & Gamble Company | Thiophene azo dyes and laundry care compositions containing the same |
| US9163146B2 (en) * | 2011-06-03 | 2015-10-20 | Milliken & Company | Thiophene azo carboxylate dyes and laundry care compositions containing the same |
| US8888865B2 (en) | 2011-06-03 | 2014-11-18 | The Procter & Gamble Company | Thiophene azo carboxylate dyes and laundry care compositions containing the same |
| CA2867361C (en) * | 2012-03-19 | 2017-07-25 | Milliken & Company | Carboxylate dyes |
| EP2698195B1 (en) * | 2012-08-15 | 2019-04-17 | The Procter & Gamble Company | Process for making a crystalline structurant |
| US9404071B2 (en) * | 2012-12-06 | 2016-08-02 | The Procter & Gamble Company | Use of composition to reduce weeping and migration through a water soluble film |
| BR112015012915A2 (pt) * | 2012-12-06 | 2017-07-11 | Procter & Gamble | saco de contenção solúvel compreendendo corante tonalizante |
| HUE035718T2 (hu) * | 2013-01-21 | 2018-08-28 | Procter & Gamble | Mosogatószer |
| EP2813564A1 (en) * | 2013-06-14 | 2014-12-17 | Unilever PLC | Laundry formulation comprising a dye |
| WO2015041814A1 (en) * | 2013-09-18 | 2015-03-26 | The Procter & Gamble Company | Laundry care composition comprising carboxylate dye |
| US9834682B2 (en) | 2013-09-18 | 2017-12-05 | Milliken & Company | Laundry care composition comprising carboxylate dye |
| MX2016003538A (es) * | 2013-09-18 | 2016-06-28 | Procter & Gamble | Composiciones para el cuidado de la ropa que contienen colorantes azoicos de tiofeno y carboxilato. |
| CN105555935A (zh) * | 2013-09-18 | 2016-05-04 | 宝洁公司 | 包含羧化物染料的衣物洗涤护理组合物 |
| US20150080560A1 (en) * | 2013-09-18 | 2015-03-19 | Milliken & Company | Laundry Care Compositions Containing Dyes |
| CN105555936A (zh) * | 2013-09-18 | 2016-05-04 | 宝洁公司 | 包含羧化物染料的衣物洗涤护理组合物 |
| CA2920497A1 (en) * | 2013-09-18 | 2015-03-26 | The Procter & Gamble Company | Laundry care composition comprising carboxylate dye |
| EP2862919A1 (en) * | 2013-10-17 | 2015-04-22 | The Procter and Gamble Company | Composition comprising shading dye |
| EP2862920A1 (en) * | 2013-10-17 | 2015-04-22 | The Procter and Gamble Company | Laundry treatment composition comprising a shading dye and chelant |
| EP2862921A1 (en) * | 2013-10-17 | 2015-04-22 | The Procter and Gamble Company | Liquid laundry composition comprising an alkoxylated polymer and a shading dye |
| EP2913388A1 (en) * | 2014-02-28 | 2015-09-02 | The Procter and Gamble Company | Detergent |
| BR112016020848B1 (pt) * | 2014-03-17 | 2022-02-15 | Unilever Ip Holdings B.V. | Método doméstico de tratamento de tecido |
| CN118452207A (zh) | 2014-12-08 | 2024-08-09 | 金诺斯公司 | 用于颜料消毒的添加剂组合物及其方法 |
| TR201819130T4 (tr) * | 2015-02-03 | 2019-01-21 | Basf Se | Sulu Formülasyonlar, Bunların Üretimi Ve Kullanımı |
| EP3098295A1 (en) * | 2015-05-29 | 2016-11-30 | The Procter and Gamble Company | Process for making a single or multi-compartment pouch |
| US20170015948A1 (en) * | 2015-07-16 | 2017-01-19 | The Procter & Gamble Company | Cleaning compositions containing a cyclic amine and a silicone |
| US20170015949A1 (en) * | 2015-07-16 | 2017-01-19 | The Procter & Gamble Company | Cleaning compositions containing a cyclic amine and an encapsulated perfume |
| US20170015951A1 (en) * | 2015-07-16 | 2017-01-19 | The Procter & Gamble Company | Cleaning compositions containing a cyclic amine and a fabric shading agent and/or a brightener |
| JP6681404B2 (ja) * | 2015-09-03 | 2020-04-15 | ライオン株式会社 | 衣料用液体洗浄剤 |
| US10155868B2 (en) * | 2015-10-13 | 2018-12-18 | Milliken & Company | Whitening agents for cellulosic substrates |
| US10344251B2 (en) | 2016-02-12 | 2019-07-09 | Kinnos, Inc. | Compositions and methods for use in surface decontamination |
| CA3069176C (en) | 2017-07-27 | 2022-05-03 | The Procter & Gamble Company | Method and system for reducing auto-dosing fluctuation of an automatic cleaning machine |
| EP3697957A4 (en) * | 2017-10-20 | 2021-08-04 | Everyone's Earth Inc. | BLEACHING COMPOSITIONS FOR FABRIC CONTAINING CELLULOSE |
| JP7149732B2 (ja) * | 2018-05-18 | 2022-10-07 | 理想科学工業株式会社 | インクジェット捺染用前処理液、捺染物の製造方法及びインクジェット捺染用インクセット |
| US11344492B2 (en) * | 2020-09-14 | 2022-05-31 | Milliken & Company | Oxidative hair cream composition containing polymeric colorant |
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| US2826551A (en) | 1954-01-04 | 1958-03-11 | Simoniz Co | Nontangling shampoo |
| NL211637A (forum.php) | 1955-10-27 | |||
| GB849433A (en) | 1957-08-22 | 1960-09-28 | Raymond Woolston | Hair washing preparations |
| BE680847A (forum.php) | 1963-05-27 | 1966-11-14 | ||
| NL136759C (forum.php) | 1966-02-16 | |||
| US3646015A (en) | 1969-07-31 | 1972-02-29 | Procter & Gamble | Optical brightener compounds and detergent and bleach compositions containing same |
| LU60943A1 (forum.php) | 1970-05-20 | 1972-02-23 | ||
| US3958581A (en) | 1972-05-17 | 1976-05-25 | L'oreal | Cosmetic composition containing a cationic polymer and divalent metal salt for strengthening the hair |
| GB1407997A (en) | 1972-08-01 | 1975-10-01 | Procter & Gamble | Controlled sudsing detergent compositions |
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-
2012
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- 2012-09-24 BR BR112014019549A patent/BR112014019549A8/pt not_active Application Discontinuation
- 2012-09-24 EP EP12773163.6A patent/EP2814934B1/en active Active
- 2012-09-24 MX MX2014009036A patent/MX2014009036A/es unknown
- 2012-09-24 WO PCT/US2012/056794 patent/WO2013006871A2/en active Application Filing
- 2012-09-24 IN IN5968DEN2014 patent/IN2014DN05968A/en unknown
- 2012-09-24 JP JP2014557622A patent/JP6046167B2/ja active Active
- 2012-09-24 CA CA2861099A patent/CA2861099C/en active Active
- 2012-09-24 CN CN201280069567.3A patent/CN104105787B/zh active Active
Also Published As
| Publication number | Publication date |
|---|---|
| WO2013006871A3 (en) | 2013-03-14 |
| WO2013006871A2 (en) | 2013-01-10 |
| EP2814934B1 (en) | 2024-11-06 |
| IN2014DN05968A (forum.php) | 2015-06-26 |
| US20140371435A9 (en) | 2014-12-18 |
| CA2861099C (en) | 2019-04-23 |
| CA2861099A1 (en) | 2013-01-10 |
| BR112014019549A2 (forum.php) | 2017-06-20 |
| BR112014019549A8 (pt) | 2017-07-11 |
| CN104105787A (zh) | 2014-10-15 |
| CN104105787B (zh) | 2018-05-22 |
| JP2015513576A (ja) | 2015-05-14 |
| US20130245242A1 (en) | 2013-09-19 |
| MX2014009036A (es) | 2014-10-14 |
| EP2814934A2 (en) | 2014-12-24 |
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| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |