JP6001455B2 - ナノ構造触媒及び分散した触媒副層を有する燃料電池電極 - Google Patents
ナノ構造触媒及び分散した触媒副層を有する燃料電池電極 Download PDFInfo
- Publication number
- JP6001455B2 JP6001455B2 JP2012546197A JP2012546197A JP6001455B2 JP 6001455 B2 JP6001455 B2 JP 6001455B2 JP 2012546197 A JP2012546197 A JP 2012546197A JP 2012546197 A JP2012546197 A JP 2012546197A JP 6001455 B2 JP6001455 B2 JP 6001455B2
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- nstf
- sublayer
- layer
- typically
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000003054 catalyst Substances 0.000 title claims description 114
- 239000000446 fuel Substances 0.000 title claims description 30
- 239000000463 material Substances 0.000 claims description 42
- 239000012528 membrane Substances 0.000 claims description 38
- 239000005518 polymer electrolyte Substances 0.000 claims description 28
- 239000002245 particle Substances 0.000 claims description 22
- 239000010409 thin film Substances 0.000 claims description 20
- 210000000170 cell membrane Anatomy 0.000 claims description 10
- 239000010410 layer Substances 0.000 description 85
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 28
- 210000004027 cell Anatomy 0.000 description 23
- 102100025532 Male-enhanced antigen 1 Human genes 0.000 description 14
- 239000011572 manganese Substances 0.000 description 14
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 12
- 238000000034 method Methods 0.000 description 12
- 229910052697 platinum Inorganic materials 0.000 description 12
- 229910052751 metal Inorganic materials 0.000 description 11
- 239000002184 metal Substances 0.000 description 11
- 229920000642 polymer Polymers 0.000 description 11
- 229910052799 carbon Inorganic materials 0.000 description 10
- 229910052748 manganese Inorganic materials 0.000 description 9
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 8
- 239000010408 film Substances 0.000 description 8
- 239000011229 interlayer Substances 0.000 description 8
- 239000006185 dispersion Substances 0.000 description 7
- 239000007789 gas Substances 0.000 description 7
- 239000002253 acid Substances 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- 229920000554 ionomer Polymers 0.000 description 6
- 230000008569 process Effects 0.000 description 6
- 229910052723 transition metal Inorganic materials 0.000 description 6
- 150000002739 metals Chemical class 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 5
- 150000003624 transition metals Chemical class 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical group C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 238000011084 recovery Methods 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- -1 transition metal salt Chemical class 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- 239000004809 Teflon Substances 0.000 description 3
- 229920006362 Teflon® Polymers 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 125000000524 functional group Chemical group 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 150000005846 sugar alcohols Polymers 0.000 description 3
- 229920000049 Carbon (fiber) Polymers 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- 229910052684 Cerium Inorganic materials 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 238000000429 assembly Methods 0.000 description 2
- 230000000712 assembly Effects 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000004917 carbon fiber Substances 0.000 description 2
- 239000002041 carbon nanotube Substances 0.000 description 2
- 229910021393 carbon nanotube Inorganic materials 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 239000010411 electrocatalyst Substances 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 238000011068 loading method Methods 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 239000002086 nanomaterial Substances 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 description 2
- 229910052707 ruthenium Inorganic materials 0.000 description 2
- 125000001424 substituent group Chemical group 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- 210000003771 C cell Anatomy 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 150000000703 Cerium Chemical class 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 229920003935 Flemion® Polymers 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- WLLGXSLBOPFWQV-UHFFFAOYSA-N MGK 264 Chemical compound C1=CC2CC1C1C2C(=O)N(CC(CC)CCCC)C1=O WLLGXSLBOPFWQV-UHFFFAOYSA-N 0.000 description 1
- WAEMQWOKJMHJLA-UHFFFAOYSA-N Manganese(2+) Chemical compound [Mn+2] WAEMQWOKJMHJLA-UHFFFAOYSA-N 0.000 description 1
- 102100034256 Mucin-1 Human genes 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- 229920000557 Nafion® Polymers 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 239000004696 Poly ether ether ketone Substances 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 238000003491 array Methods 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 125000002843 carboxylic acid group Chemical group 0.000 description 1
- 238000005341 cation exchange Methods 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000013626 chemical specie Substances 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 125000004093 cyano group Chemical group *C#N 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000003487 electrochemical reaction Methods 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 235000012209 glucono delta-lactone Nutrition 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 125000001475 halogen functional group Chemical group 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 125000005462 imide group Chemical group 0.000 description 1
- 239000011872 intimate mixture Substances 0.000 description 1
- 238000001755 magnetron sputter deposition Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000002663 nebulization Methods 0.000 description 1
- 239000006199 nebulizer Substances 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 238000002047 photoemission electron microscopy Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920001483 poly(ethyl methacrylate) polymer Polymers 0.000 description 1
- 229920001467 poly(styrenesulfonates) Polymers 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
- 229920002530 polyetherether ketone Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000007784 solid electrolyte Substances 0.000 description 1
- 238000002336 sorption--desorption measurement Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000000859 sublimation Methods 0.000 description 1
- 230000008022 sublimation Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 238000001771 vacuum deposition Methods 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/8647—Inert electrodes with catalytic activity, e.g. for fuel cells consisting of more than one material, e.g. consisting of composites
- H01M4/8657—Inert electrodes with catalytic activity, e.g. for fuel cells consisting of more than one material, e.g. consisting of composites layered
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
- H01M4/8803—Supports for the deposition of the catalytic active composition
- H01M4/881—Electrolytic membranes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
- H01M4/8803—Supports for the deposition of the catalytic active composition
- H01M4/8814—Temporary supports, e.g. decal
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M2008/1095—Fuel cells with polymeric electrolytes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
- H01M4/8825—Methods for deposition of the catalytic active composition
- H01M4/8828—Coating with slurry or ink
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
- H01M4/8825—Methods for deposition of the catalytic active composition
- H01M4/8867—Vapour deposition
- H01M4/8871—Sputtering
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/92—Metals of platinum group
- H01M4/921—Alloys or mixtures with metallic elements
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Composite Materials (AREA)
- Inert Electrodes (AREA)
- Catalysts (AREA)
- Fuel Cell (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US28888209P | 2009-12-22 | 2009-12-22 | |
| US61/288,882 | 2009-12-22 | ||
| PCT/US2010/061798 WO2011087842A1 (en) | 2009-12-22 | 2010-12-22 | Fuel cell electrode with nanostructured catalyst and dispersed catalyst sublayer |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2016122499A Division JP2016192411A (ja) | 2009-12-22 | 2016-06-21 | ナノ構造触媒及び分散した触媒副層を有する燃料電池電極 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2013515350A JP2013515350A (ja) | 2013-05-02 |
| JP2013515350A5 JP2013515350A5 (https=) | 2014-01-16 |
| JP6001455B2 true JP6001455B2 (ja) | 2016-10-05 |
Family
ID=43755126
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2012546197A Active JP6001455B2 (ja) | 2009-12-22 | 2010-12-22 | ナノ構造触媒及び分散した触媒副層を有する燃料電池電極 |
| JP2016122499A Pending JP2016192411A (ja) | 2009-12-22 | 2016-06-21 | ナノ構造触媒及び分散した触媒副層を有する燃料電池電極 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2016122499A Pending JP2016192411A (ja) | 2009-12-22 | 2016-06-21 | ナノ構造触媒及び分散した触媒副層を有する燃料電池電極 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US9570756B2 (https=) |
| EP (1) | EP2517290B1 (https=) |
| JP (2) | JP6001455B2 (https=) |
| CN (1) | CN102668201B (https=) |
| WO (1) | WO2011087842A1 (https=) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2774203B8 (en) | 2011-11-04 | 2016-06-01 | Greenerity GmbH | Method for the preparation of catalyst-coated membranes |
| CN103849885B (zh) * | 2012-12-06 | 2016-12-21 | 清华大学 | 阴极催化剂,阴极材料及其制备方法及反应器 |
| EP3083039A2 (en) * | 2013-12-18 | 2016-10-26 | King Abdullah University Of Science And Technology | Methods of making supported ni/pt bimetallic nanoparticles and ni/pt multilayer core-shell structures and their uses for co2 reforming |
| US9468909B2 (en) * | 2014-06-27 | 2016-10-18 | Ford Global Technologies, Llc | Metal oxide stabilized platinum-based ORR catalyst |
| CN108075139B (zh) * | 2016-11-18 | 2020-11-10 | 中国科学院大连化学物理研究所 | 基于金属氧化物纳米带的有序化膜电极及其制备和应用 |
| JP6809897B2 (ja) * | 2016-12-20 | 2021-01-06 | スリーエム イノベイティブ プロパティズ カンパニー | 膜電極接合体及び固体高分子形燃料電池 |
| JP6966475B2 (ja) * | 2016-12-20 | 2021-11-17 | 京セラ株式会社 | セル、セルスタック装置、モジュールおよびモジュール収納装置 |
| EP3607114A1 (en) * | 2017-04-03 | 2020-02-12 | 3M Innovative Properties Company | Water electrolyzers |
| WO2018185616A1 (en) | 2017-04-03 | 2018-10-11 | 3M Innovative Properties Company | Water electrolyzers |
| EP3635806B1 (en) * | 2017-06-05 | 2021-10-06 | 3M Innovative Properties Company | Electrode catalyst-containing dispersion compositions and articles therefrom |
| KR102335927B1 (ko) * | 2019-02-08 | 2021-12-06 | 한국전력공사 | 막-전극 집합체 제조방법 |
| EP4395930A4 (en) * | 2021-09-03 | 2026-04-22 | Blue O Tech Inc | HDV-READY ELECTROCHEMICAL ELECTRODES WITH NEW COMPOSITION, STRUCTURE, AND MANUFACTURING PROCESS |
Family Cites Families (40)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4340276A (en) * | 1978-11-01 | 1982-07-20 | Minnesota Mining And Manufacturing Company | Method of producing a microstructured surface and the article produced thereby |
| US4568598A (en) * | 1984-10-30 | 1986-02-04 | Minnesota Mining And Manufacturing Company | Article with reduced friction polymer sheet support |
| US4812352A (en) | 1986-08-25 | 1989-03-14 | Minnesota Mining And Manufacturing Company | Article having surface layer of uniformly oriented, crystalline, organic microstructures |
| US5039561A (en) | 1986-08-25 | 1991-08-13 | Minnesota Mining And Manufacturing Company | Method for preparing an article having surface layer of uniformly oriented, crystalline, organic microstructures |
| US5176786A (en) | 1988-07-13 | 1993-01-05 | Minnesota Mining And Manufacturing Company | Organic thin film controlled molecular epitaxy |
| US5336558A (en) | 1991-06-24 | 1994-08-09 | Minnesota Mining And Manufacturing Company | Composite article comprising oriented microstructures |
| US5338430A (en) * | 1992-12-23 | 1994-08-16 | Minnesota Mining And Manufacturing Company | Nanostructured electrode membranes |
| US5728485A (en) * | 1995-03-15 | 1998-03-17 | Tanaka Kikinzoku Kogyo K.K. | Electrode for polymer electrolyte electrochemical cell and process of preparing same |
| US5879828A (en) | 1997-10-10 | 1999-03-09 | Minnesota Mining And Manufacturing Company | Membrane electrode assembly |
| US5879827A (en) * | 1997-10-10 | 1999-03-09 | Minnesota Mining And Manufacturing Company | Catalyst for membrane electrode assembly and method of making |
| US7098163B2 (en) * | 1998-08-27 | 2006-08-29 | Cabot Corporation | Method of producing membrane electrode assemblies for use in proton exchange membrane and direct methanol fuel cells |
| US6287717B1 (en) * | 1998-11-13 | 2001-09-11 | Gore Enterprise Holdings, Inc. | Fuel cell membrane electrode assemblies with improved power outputs |
| US6238534B1 (en) | 1999-05-14 | 2001-05-29 | 3M Innovative Properties Company | Hybrid membrane electrode assembly |
| US6482763B2 (en) | 1999-12-29 | 2002-11-19 | 3M Innovative Properties Company | Suboxide fuel cell catalyst for enhanced reformate tolerance |
| CA2407202C (en) * | 2001-10-11 | 2009-11-03 | Honda Giken Kogyo Kabushiki Kaisha | Electrode for polymer electrolyte fuel cell |
| DE10159476A1 (de) * | 2001-12-04 | 2003-07-17 | Omg Ag & Co Kg | Verfahren zur Herstellung von Membran-Elektrodeneinheiten für Brennstoffzellen |
| US20030190517A1 (en) | 2002-04-08 | 2003-10-09 | John Elter | Fuel cell |
| US6946362B2 (en) * | 2002-09-06 | 2005-09-20 | Hewlett-Packard Development Company, L.P. | Method and apparatus for forming high surface area material films and membranes |
| US20040116742A1 (en) * | 2002-12-17 | 2004-06-17 | 3M Innovative Properties Company | Selective reaction of hexafluoropropylene oxide with perfluoroacyl fluorides |
| US6624328B1 (en) * | 2002-12-17 | 2003-09-23 | 3M Innovative Properties Company | Preparation of perfluorinated vinyl ethers having a sulfonyl fluoride end-group |
| US7348088B2 (en) * | 2002-12-19 | 2008-03-25 | 3M Innovative Properties Company | Polymer electrolyte membrane |
| US7419741B2 (en) | 2003-09-29 | 2008-09-02 | 3M Innovative Properties Company | Fuel cell cathode catalyst |
| JP4482352B2 (ja) * | 2004-03-11 | 2010-06-16 | 本田技研工業株式会社 | 固体高分子型燃料電池 |
| JP4031463B2 (ja) * | 2004-04-26 | 2008-01-09 | 株式会社東芝 | 液体燃料型固体高分子燃料電池用アノード電極、液体燃料型固体高分子燃料電池用膜電極複合体及び液体燃料型固体高分子燃料電池 |
| CA2505653A1 (en) * | 2004-04-28 | 2005-10-28 | National Research Council Of Canada | Composite catalyst layer, electrode and passive mixing flow field for compressionless fuel cells |
| KR101030046B1 (ko) | 2004-06-30 | 2011-04-20 | 삼성에스디아이 주식회사 | 막-전극 접합체 및 이를 포함하는 연료전지 |
| US8101317B2 (en) * | 2004-09-20 | 2012-01-24 | 3M Innovative Properties Company | Durable fuel cell having polymer electrolyte membrane comprising manganese oxide |
| US7572534B2 (en) * | 2004-09-20 | 2009-08-11 | 3M Innovative Properties Company | Fuel cell membrane electrode assembly |
| WO2006062947A2 (en) * | 2004-12-09 | 2006-06-15 | Nanosys, Inc. | Nanowire-based membrane electrode assemblies for fuel cells |
| US20080020923A1 (en) * | 2005-09-13 | 2008-01-24 | Debe Mark K | Multilayered nanostructured films |
| US7622217B2 (en) * | 2005-10-12 | 2009-11-24 | 3M Innovative Properties Company | Fuel cell nanocatalyst |
| US20070082814A1 (en) | 2005-10-12 | 2007-04-12 | 3M Innovative Properties Company | Ternary nanocatalyst and method of making |
| TW200723580A (en) * | 2005-12-12 | 2007-06-16 | Antig Tech Co Ltd | Membrane electrode assembly structure of fuel cell and method of manufacturing the same |
| CN100468836C (zh) | 2005-12-14 | 2009-03-11 | 胜光科技股份有限公司 | 燃料电池的膜电极组及其制造方法 |
| JP4957047B2 (ja) | 2006-03-31 | 2012-06-20 | 大日本印刷株式会社 | 燃料電池用触媒層−電解質膜積層体 |
| KR100738062B1 (ko) * | 2006-05-16 | 2007-07-10 | 삼성에스디아이 주식회사 | 막 전극 접합체 및 이를 이용한 연료전지 |
| WO2008153113A1 (en) * | 2007-06-12 | 2008-12-18 | Canon Kabushiki Kaisha | Method of manufacturing membrane electrode assembly, method of manufacturing fuel cell, membrane electrode assembly, and fuel cell |
| KR100908720B1 (ko) * | 2007-09-14 | 2009-07-22 | 삼성에스디아이 주식회사 | 연료 전지용 막-전극 어셈블리, 및 이를 포함하는 연료전지 시스템 |
| JP4456148B2 (ja) * | 2007-11-27 | 2010-04-28 | アイシン精機株式会社 | 燃料電池用膜電極接合体、燃料電池および燃料電池システム |
| JP5196988B2 (ja) | 2007-12-21 | 2013-05-15 | スリーエム イノベイティブ プロパティズ カンパニー | インク組成物、その製造方法、そのインク組成物を用いて形成した電極触媒層及びこれらの用途 |
-
2010
- 2010-12-22 CN CN201080059082.7A patent/CN102668201B/zh not_active Expired - Fee Related
- 2010-12-22 US US12/976,168 patent/US9570756B2/en active Active
- 2010-12-22 WO PCT/US2010/061798 patent/WO2011087842A1/en not_active Ceased
- 2010-12-22 EP EP10803542.9A patent/EP2517290B1/en not_active Not-in-force
- 2010-12-22 JP JP2012546197A patent/JP6001455B2/ja active Active
-
2016
- 2016-06-21 JP JP2016122499A patent/JP2016192411A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| EP2517290A1 (en) | 2012-10-31 |
| CN102668201B (zh) | 2015-05-20 |
| JP2013515350A (ja) | 2013-05-02 |
| CN102668201A (zh) | 2012-09-12 |
| US9570756B2 (en) | 2017-02-14 |
| JP2016192411A (ja) | 2016-11-10 |
| EP2517290B1 (en) | 2018-08-29 |
| WO2011087842A1 (en) | 2011-07-21 |
| US20110151353A1 (en) | 2011-06-23 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP6001455B2 (ja) | ナノ構造触媒及び分散した触媒副層を有する燃料電池電極 | |
| JP5161097B2 (ja) | 燃料電池用ナノ触媒 | |
| JP5249036B2 (ja) | 三元素のナノ触媒及び製造方法 | |
| JP5580312B2 (ja) | 電圧反転耐性を有する燃料電池用ナノ触媒 | |
| JP6126130B2 (ja) | 電気化学電池電極 | |
| CN101953012B (zh) | 具有组合添加剂的耐久性燃料电池膜电极组件 | |
| KR20060131733A (ko) | 연료 전지 캐소드 촉매 | |
| JP5676696B2 (ja) | 耐久性のあるポリマー電解質薄膜を製造する方法 | |
| CN110088960B (zh) | 膜电极组件和固体聚合物燃料电池 | |
| JP5265926B2 (ja) | 燃料電池触媒 | |
| CN101057360B (zh) | 预处理的燃料电池膜电极组件 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20131119 |
|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20131119 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20140716 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20140722 |
|
| A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20141111 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20160621 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20160901 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 6001455 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |