JP5945552B2 - 太陽電池モジュール用バックシート及び太陽電池モジュール - Google Patents
太陽電池モジュール用バックシート及び太陽電池モジュール Download PDFInfo
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- JP5945552B2 JP5945552B2 JP2013553276A JP2013553276A JP5945552B2 JP 5945552 B2 JP5945552 B2 JP 5945552B2 JP 2013553276 A JP2013553276 A JP 2013553276A JP 2013553276 A JP2013553276 A JP 2013553276A JP 5945552 B2 JP5945552 B2 JP 5945552B2
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Description
図1の太陽電池モジュール用バックシート1(以下、バックシート1ということがある)は、互いに色相の異なる明度L*45以上の三種以上の色料を含み明度L*が40以下の着色層2と、この着色層2が積層される基材シート3とを備えている。また、当該バックシート1は、基材シート3の裏面側に積層されるガスバリア層6と、このガスバリア層6の裏面側に積層される裏面側基材シート7とを備えている。
上記着色層2は、基材シート3の表面側に積層されており、顔料(色料)が含有される樹脂層から形成されている。
上記基材シート3は、表面側から見て白色を呈しており、合成樹脂を材料とする基材フィルム4と、この基材フィルム4の表面側に積層される白色層5とを有している。
上記基材フィルム4に用いられる合成樹脂としては、特に限定されるものではなく、例えばポリエチレン系樹脂、ポリプロピレン系樹脂、環状ポリオレフィン系樹脂、ポリスチレン系樹脂、アクリロニトリル−スチレン共重合体(AS樹脂)、アクリロニトリル−ブタジエン−スチレン共重合体(ABS樹脂)、ポリ塩化ビニル系樹脂、フッ素系樹脂、ポリ(メタ)アクリル系樹脂、ポリカーボネート系樹脂、ポリエステル系樹脂、ポリアミド系樹脂、ポリイミド系樹脂、ポリアミドイミド系樹脂、ポリアリールフタレート系樹脂、シリコーン系樹脂、ポリスルホン系樹脂、ポリフェニレンスルフィド系樹脂、ポリエーテルスルホン系樹脂、ポリウレタン系樹脂、アセタール系樹脂、セルロース系樹脂等が挙げられる。上記樹脂の中でも、高い耐熱性、強度、耐候性、耐久性、水蒸気等に対するガスバリア性等を有し、白色層5の塗工条件に耐え、白色層5との密接着性に優れているポリエステル系樹脂、フッ素系樹脂及び環状ポリオレフィン系樹脂が好ましい。
上記白色層5は、基材フィルム4の表面側に積層されており、白色顔料が含有される樹脂層から形成されている。
上記ガスバリア層6は、水素ガス、酸素ガス等のガスの透過を低減する機能を有する層である。このガスバリア層6は、フィルム状あるいはシート状の基材(図示省略)と、この基材に積層された無機酸化層(図示省略)とを備えている。なお、ガスバリア層は、アルミ箔等から構成することも可能である。
裏面側基材シート7は、合成樹脂を主成分として形成されている。この耐加水分解樹脂層の主成分の合成樹脂としては、耐加水分解性及び耐熱性に優れるポリエチレンナフタレート(PEN)が用いられている。
上記のように重畳される基材シート3、ガスバリア層6及び裏面側基材シート7の各層間には接着剤層が積層されている(各図において接着層の図示は省略している)。この接着剤層によって各層が接着固定され、当該バックシート1の強度、耐久性、堅牢性等が向上し、さらに上記無機酸化物層の欠陥を封止及び保護する機能が奏される。
次に、当該バックシート1の製造方法について説明する。
次に、当該バックシート1を用いた太陽電池モジュールの製造方法を説明する。
上記透光性基板12は、最表面に積層されるものであり、(a)太陽光に対する透過性及び電気絶縁性を有すること、(b)機械的、化学的及び物理的強度、具体的には耐候性、耐熱性、耐久性、耐水性、水蒸気等に対するガスバリア性、耐風圧性、耐薬品性、堅牢性に優れること、(c)表面硬度が高く、かつ表面の汚れ、ゴミ等の蓄積を防止する防汚性に優れることが要求される。
また、表面側の充填層を構成するシート13及び裏面側の充填層を構成するシート15は、上記加熱ラミネート時に溶融し、その後冷却されて固化することにより、透光性基板12及び当該バックシート1間における太陽電池セル14の周囲に充填されている。この充填層13及び充填層15は、透光性基板12及びバックシート1との接着性や、太陽電池セル14を保護するための耐スクラッチ性、衝撃吸収性等を有している。さらに、充填層13及び充填層15は、上記諸機能に加え、太陽光を透過する透明性を有している。
上記太陽電池セル14は、光エネルギーを電気エネルギーに変換する光起電力素子であり、充填層13及び充填層15間に配設される。複数枚の太陽電池セル14は、略同一平面内で且つ互いに若干離間して敷設され、図示していないが直列又は並列に配線されている。この太陽電池セル14としては、例えば単結晶シリコン型太陽電池素子、多結晶シリコン型太陽電池素子等の結晶シリコン太陽電子素子、シングル接合型やタンデム構造型等からなるアモルファスシリコン太陽電池素子、ガリウムヒ素(GaAs)やインジウム燐(InP)等の第3〜第5族化合物半導体太陽電子素子、カドミウムテルル(CdTe)や銅インジウムセレナイド(CuInSe2)等の第2〜第6族化合物半導体太陽電子素子等を使用することができ、それらのハイブリット素子も使用することができる。なお、複数枚の太陽電池セル14の間には、上記充填層13又は充填層15が隙間なく充填されることになる。
上記製造方法の上記加熱ラミネート工程においては、バックシート1の表面の着色層2及び充填層13,15が溶融し、これらの溶融樹脂が一体的に接合される。そして、冷却されることによって着色層2及び充填層13,15が固化して、当該太陽電池モジュール11が製造されることになる。
図3は、上記製造方法によって製造された太陽電池モジュール11を示し、透光性基板12と、充填層13と、複数枚の太陽電池セル14と、充填層15と、当該バックシート1とが表面側からこの順に積層されている。
なお、本発明は上記実施形態の構成に限定されるものではない。つまり、上記実施形態においては、着色層2が最表面に配設されるものについて説明したが、本発明はこれに限定されるものではなく、例えば上記実施形態の着色層2の表面に透明又は半透明な熱融着層を配設することも可能である。
当該バックシート1の着色層2を、基材シート3(白色層5)の表面に塗工液を塗工して形成したときの反射率を計測した。
次に、当該バックシート1の着色層2を、基材シート3(白色層5)の表面に塗工液を塗工して形成したときの反射率について、二種類の塗工方法(塗工方法A及び塗工方法B)とバックシートの表面にカーボンブラックを塗工(塗工方法C)した場合とを計測し比較した。
塗工液は、濃度27%の赤色系顔料(大日精化工業株式会社製ラミックSR915R紅)を配合比34.9%、濃度27%の青色系顔料(大日精化工業株式会社製ラミックSR739R藍)を配合比39.8%、及び濃度27%の黄色系顔料(大日精化工業株式会社製ラミックSR722R黄)を配合比25.3%で混合したもの使用した。そして、この塗工液を基材シート3の表面に塗工した。なお、塗工量は1.5g/m2とした。着色層2が視認される側から測定した明度L*は、24.17であった。
三種類の塗工液をそれぞれ基材シート3の表面に以下の割合でドット状に塗工した。
(1)濃度27%の赤色系顔料(大日精化工業株式会社製ラミックSR915R紅)を基材シート3の表面に対して80%の割合(単位面積あたり80%)で塗工。
(2)濃度27%の青色系顔料(大日精化工業株式会社製ラミックSR739R藍)を基材シート3の表面に対して80%の割合(単位面積あたり80%)で塗工。
(3)濃度27%の黄色系顔料(大日精化工業株式会社製ラミックSR722R黄)を基材シート3の表面に対して20%の割合(単位面積あたり20%)で塗工。
なお、このときの着色層2が視認される側から測定した明度L*は、39.76であった。また、外観は黒色に近いものであった。
カーボンブラックを着色顔料とした塗工液を、基材シート3の表面に塗工した。着色層2が視認される側から測定した明度L*は略0である。
2 着色層
3 基材シート
4 基材フィルム
5 白色層
6 ガスバリア層
7 裏面側基材シート
11 太陽電池モジュール
12 透光性基板
13 充填層
14 太陽電池セル
15 充填層
Claims (7)
- 互いに色相の異なる明度L*45以上の三種以上の顔料が含有される樹脂層から形成される着色層を備え、
上記着色層の明度L*が、40以下であり、
上記着色層の厚みが、1μm以上300μm以下であり、
上記着色層の顔料の配合量が、上記樹脂層の形成材料であるポリマー組成物中の基材ポリマー100質量部に対して80質量部以上であると共に、上記三種以上の顔料それぞれの顔料全体に対する割合が20質量%以上であり、
上記着色層の裏面側に着色層を透過した光線を反射する白色層を備える太陽電池モジュール用バックシート。 - 上記着色層が積層される基材シートをさらに備える請求項1に記載の太陽電池モジュール用バックシート。
- 上記基材シートが白色であり、
上記着色層が基材シートの表面側に積層される請求項2に記載の太陽電池モジュール用バックシート。 - 上記基材シートが、基材フィルムと、この基材フィルムの表面側に積層される上記白色層とを備える請求項3に記載の太陽電池モジュール用バックシート。
- 上記着色層が、平面視略格子状パターンで配設されている請求項2に記載の太陽電池モジュール用バックシート。
- 上記三種以上の顔料が、少なくとも赤色系顔料、青色系顔料及び黄色系顔料である請求項1に記載の太陽電池モジュール用バックシート。
- 透光性基板と、充填剤層と、光起電力素子としての太陽電池セルと、充填剤層と、請求項1から請求項6のいずれか1項に記載の太陽電池モジュール用バックシートとが表面側からこの順に積層されている太陽電池モジュール。
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Application Number | Priority Date | Filing Date | Title |
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JP2012005471 | 2012-01-13 | ||
JP2012005471 | 2012-01-13 | ||
PCT/JP2013/050008 WO2013105522A1 (ja) | 2012-01-13 | 2013-01-04 | 太陽電池モジュール用バックシート、太陽電池モジュール用バックシートの製造方法及び太陽電池モジュール |
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US (1) | US20150075615A1 (ja) |
EP (1) | EP2803483A4 (ja) |
JP (1) | JP5945552B2 (ja) |
CN (1) | CN104039553B (ja) |
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KR102253620B1 (ko) * | 2014-07-30 | 2021-05-18 | 엘지전자 주식회사 | 태양 전지 모듈 |
JP6851828B2 (ja) * | 2014-09-18 | 2021-03-31 | 大日本印刷株式会社 | 太陽電池モジュール用裏面保護シート |
TWI705110B (zh) * | 2014-09-30 | 2020-09-21 | 日商大日本印刷股份有限公司 | 紅外線穿透性暗色墨水及使用該墨水之紅外線穿透性薄片 |
CN105450163A (zh) * | 2014-09-30 | 2016-03-30 | 杜邦公司 | 具有防污层的太阳能电池模块 |
WO2016099994A1 (en) * | 2014-12-18 | 2016-06-23 | Dow Global Technologies Llc | Photovoltaic devices with direct bonded connector bodies |
KR20170027956A (ko) * | 2015-09-03 | 2017-03-13 | 엘지전자 주식회사 | 태양 전지 모듈 |
EP3139417A1 (en) * | 2015-09-03 | 2017-03-08 | Borealis AG | Polyethylene composition for a layer element of a photovoltaic module |
EP3703945B1 (en) * | 2017-10-30 | 2022-01-05 | Balder Energy S.L.U | Solar module |
EP3537485B1 (en) * | 2018-03-06 | 2022-10-12 | LG Electronics Inc. | Solar cell panel |
DE102018113251B4 (de) * | 2018-06-04 | 2021-12-09 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Verfahren zum Herstellen einer CdTe-Solarzelle |
JP7295583B2 (ja) * | 2019-05-15 | 2023-06-21 | エム・テクニック株式会社 | ペリレン系黒色顔料微粒子、その製造方法、それを含む黒色顔料組成物、並びに色相及び/又は彩度が制御されたペリレン系黒色顔料微粒子の製造方法 |
JP7477271B2 (ja) | 2019-08-08 | 2024-05-01 | トヨタ自動車株式会社 | 加飾された太陽電池モジュールの調製方法 |
CN112054084A (zh) * | 2020-08-21 | 2020-12-08 | 友达光电股份有限公司 | 太阳能模块 |
DE102021107199A1 (de) * | 2021-03-23 | 2022-09-29 | Hanwha Q Cells Gmbh | Rückseitenschichtstapel für ein Photovoltaikmodul und ein Verfahren zu dessen Herstellung |
CN114373819A (zh) * | 2022-01-06 | 2022-04-19 | 苏州福斯特光伏材料有限公司 | 背板及光伏组件 |
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JP2000034378A (ja) | 1998-07-16 | 2000-02-02 | Kyodo Chem Co Ltd | 塩素含有樹脂用安定化剤及び塩素含有樹脂組成物 |
JP4303951B2 (ja) * | 2002-12-17 | 2009-07-29 | 大日本印刷株式会社 | 太陽電池モジュ−ル用裏面保護シ−トおよびそれを使用した太陽電池モジュ−ル |
JP2007103813A (ja) * | 2005-10-07 | 2007-04-19 | Techno Polymer Co Ltd | 太陽電池用バックシート |
JP5140919B2 (ja) | 2005-11-01 | 2013-02-13 | 東レ株式会社 | 太陽電池用バックシートおよび太陽電池モジュール |
JP5301107B2 (ja) * | 2006-08-31 | 2013-09-25 | 恵和株式会社 | 太陽電池モジュール用バックシート及びこれを用いた太陽電池モジュール |
WO2009061956A1 (en) * | 2007-11-06 | 2009-05-14 | Ming-Liang Shiao | Photovoltaic roofing elements and roofs using them |
US20100043871A1 (en) * | 2008-04-14 | 2010-02-25 | Bp Corporation North America Inc. | Thermal Conducting Materials for Solar Panel Components |
CN102150279A (zh) * | 2008-07-11 | 2011-08-10 | 三菱树脂株式会社 | 太阳能电池背板 |
JP5215832B2 (ja) * | 2008-12-08 | 2013-06-19 | テイ・エス テック株式会社 | 自動二輪車用シート |
CN102414838B (zh) * | 2009-04-30 | 2015-05-06 | 三菱树脂株式会社 | 太阳能电池用片及太阳能电池组件 |
JP5734569B2 (ja) * | 2010-01-18 | 2015-06-17 | 富士フイルム株式会社 | 太陽電池用バックシート及びその製造方法、並びに太陽電池モジュール |
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JPWO2013105522A1 (ja) | 2015-05-11 |
EP2803483A1 (en) | 2014-11-19 |
TW201340339A (zh) | 2013-10-01 |
US20150075615A1 (en) | 2015-03-19 |
WO2013105522A1 (ja) | 2013-07-18 |
EP2803483A4 (en) | 2015-09-09 |
TWI572046B (zh) | 2017-02-21 |
CN104039553A (zh) | 2014-09-10 |
CN104039553B (zh) | 2016-12-28 |
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