JP5944894B2 - 触媒担体粒子、および触媒担体粒子の作製方法 - Google Patents

触媒担体粒子、および触媒担体粒子の作製方法 Download PDF

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JP5944894B2
JP5944894B2 JP2013515956A JP2013515956A JP5944894B2 JP 5944894 B2 JP5944894 B2 JP 5944894B2 JP 2013515956 A JP2013515956 A JP 2013515956A JP 2013515956 A JP2013515956 A JP 2013515956A JP 5944894 B2 JP5944894 B2 JP 5944894B2
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particles
catalyst
hydrogel
aging
catalyst support
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JP2013534470A (ja
JP2013534470A5 (ru
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パラグ・ラシクラル・シャー
ヤタオ・レイチェル・フー
イ・ミョンギ
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ピーキュー コーポレイション
ピーキュー コーポレイション
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/02—Carriers therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/26—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/617—500-1000 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/638—Pore volume more than 1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/036—Precipitation; Co-precipitation to form a gel or a cogel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/06—Washing
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C08F4/22—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of chromium, molybdenum or tungsten
    • C08F4/24—Oxides

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Dispersion Chemistry (AREA)
  • Silicon Compounds (AREA)
  • Polymerization Catalysts (AREA)
  • Catalysts (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
JP2013515956A 2010-06-24 2011-06-23 触媒担体粒子、および触媒担体粒子の作製方法 Active JP5944894B2 (ja)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US35812510P 2010-06-24 2010-06-24
EP10251143.3 2010-06-24
EP10251143 2010-06-24
US61/358,125 2010-06-24
PCT/GB2011/000943 WO2011161412A1 (en) 2010-06-24 2011-06-23 Catalyst supports, catalysts and their manufacture and use

Publications (3)

Publication Number Publication Date
JP2013534470A JP2013534470A (ja) 2013-09-05
JP2013534470A5 JP2013534470A5 (ru) 2014-08-07
JP5944894B2 true JP5944894B2 (ja) 2016-07-05

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JP2013515956A Active JP5944894B2 (ja) 2010-06-24 2011-06-23 触媒担体粒子、および触媒担体粒子の作製方法

Country Status (13)

Country Link
US (1) US9228029B2 (ru)
EP (1) EP2585214B1 (ru)
JP (1) JP5944894B2 (ru)
KR (1) KR101820064B1 (ru)
CN (1) CN103140284B (ru)
BR (1) BR112012032827B1 (ru)
EA (1) EA027044B1 (ru)
ES (1) ES2604109T3 (ru)
HU (1) HUE030161T2 (ru)
MX (1) MX337353B (ru)
MY (1) MY160564A (ru)
SG (2) SG186280A1 (ru)
WO (1) WO2011161412A1 (ru)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10395134B2 (en) * 2013-07-26 2019-08-27 University Of Utah Research Foundation Extraction of spectral information
WO2016141020A1 (en) 2015-03-02 2016-09-09 Equistar Chemicals, Lp Catalysts and methods of controlling long chain branching in polyolefins
BR112018011169B1 (pt) 2015-12-02 2022-03-29 Lyondell Chemical Technology, L.P. Composição de catalisador, método para sua produção e método para produção de um epóxido
KR102220684B1 (ko) 2016-11-18 2021-03-02 엑손모빌 케미칼 패턴츠 인코포레이티드 크롬 함유 촉매를 이용한 중합 방법
US10543480B2 (en) 2018-04-16 2020-01-28 Chevron Phillips Chemical Company Lp Methods of preparing a catalyst utilizing hydrated reagents
US10722874B2 (en) 2018-04-16 2020-07-28 Chevron Phillips Chemical Company Lp Methods of preparing a catalyst utilizing hydrated reagents
EP4241878A3 (en) 2018-09-24 2023-11-15 Chevron Phillips Chemical Company LP Methods for making supported chromium catalysts with increased polymerization activity
EP4110836A1 (en) * 2020-02-28 2023-01-04 Ecovyst Catalyst Technologies LLC Chromium-on-silica catalysts and methods of making the same
US11732065B2 (en) 2020-02-28 2023-08-22 Pq Corporation Chromium-on-silica catalysts and methods of making the same
CN115989275A (zh) 2020-08-25 2023-04-18 埃克森美孚化学专利公司 具有优异物理性能的高密度聚乙烯组合物

Family Cites Families (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3652214A (en) 1968-08-06 1972-03-28 Nat Petro Chemicals Co Inc Preparation of silica gels
US3652216A (en) * 1968-10-11 1972-03-28 Nat Petro Chemicals Co Inc Preparation of silica gels
US3900457A (en) * 1970-10-08 1975-08-19 Phillips Petroleum Co Olefin polymerization catalyst
US3959174A (en) 1971-08-24 1976-05-25 W. R. Grace & Co. Method of selectively producing high pore volume silica gel
NL171273C (nl) 1976-05-24 1983-03-01 Stamicarbon Werkwijze voor het polymeriseren van alkenen en werkwijze voor het bereiden van een chroomoxyde-op drager-katalysator.
US4193851A (en) * 1978-07-21 1980-03-18 Ppg Industries, Inc. Silica gels and their formation by electrolysis of silicate solutions
US4230679A (en) * 1978-12-22 1980-10-28 E. I. Du Pont De Nemours And Company Poly(silicic acid)
US4279879A (en) * 1979-10-01 1981-07-21 W. R. Grace & Co. Silica gel
US4339559A (en) * 1980-05-21 1982-07-13 Phillips Petroleum Company Polymerization using silica from single phase controlled hydrolysis of silicate ester
DE3635710A1 (de) 1986-10-21 1988-04-28 Basf Ag Verfahren zum herstellen von homo- sowie copolymerisaten des ethens durch phillips-katalyse
US5229096A (en) 1990-11-19 1993-07-20 Scm Chemicals, Inc. Silica gel
US5401596A (en) 1991-10-14 1995-03-28 Stoilov; Georgi T. Hermetically sealed dry accumulator
GB9316167D0 (en) * 1992-08-07 1993-09-22 British Petroleum Co Plc Silica product and processes
KR100192094B1 (ko) * 1993-11-20 1999-06-15 이정국 올레핀 중합용 촉매의 제조방법 및 이를 이용하여 제조한 올레핀 중합용 촉매
KR100221174B1 (ko) * 1994-06-17 1999-09-15 밀리스 제임스 알 구형 흡착 입자의 제조 방법
DE19648798C2 (de) 1996-11-26 1998-11-19 Hoechst Ag Verfahren zur Herstellung von organisch modifizierten Aerogelen durch Oberflächenmodifikation des wäßrigen Gels (ohne vorherigen Lösungsmitteltausch) und anschließender Trocknung
US6172120B1 (en) * 1997-04-09 2001-01-09 Cabot Corporation Process for producing low density gel compositions
PL339129A1 (en) 1997-09-11 2000-12-04 Bp Chem Int Ltd Method of polymerising olefins in gaseous state
JPH1192517A (ja) * 1997-09-24 1999-04-06 Nippon Polyolefin Kk ポリオレフィン製造用触媒成分およびポリオレフィン製造用触媒
US6355596B2 (en) * 1999-06-01 2002-03-12 Pq Holding, Inc. Method for preparing titanium on silica catalysts with controlled distributions
US6239243B1 (en) * 1999-06-10 2001-05-29 Dow Corning Corporation Method for preparing hydrophilic silica gels with high pore volume
US6399535B1 (en) * 1999-11-01 2002-06-04 W. R. Grace & Co.-Conn. Coordination catalyst systems employing agglomerated metal oxide/clay support-activator and method of their preparation
US7019089B2 (en) 2000-07-05 2006-03-28 Basell Polyolefine Gmbh Suspended chrome catalyst containing titanium and the use thereof for producing ethylene homopolymers and copolymers
JP2003192713A (ja) * 2001-12-27 2003-07-09 Mitsubishi Chemicals Corp オレフィン重合触媒用担体シリカゲル及びオレフィン重合触媒
GB0720983D0 (en) 2007-10-26 2007-12-05 Ineos Silicas Ltd Catalyst particles their preparation and use

Also Published As

Publication number Publication date
MX2013000032A (es) 2013-03-22
SG10201507873YA (en) 2015-10-29
EP2585214B1 (en) 2016-08-17
KR20130041138A (ko) 2013-04-24
MX337353B (es) 2016-02-29
ES2604109T3 (es) 2017-03-03
KR101820064B1 (ko) 2018-01-18
WO2011161412A1 (en) 2011-12-29
BR112012032827A2 (pt) 2016-11-08
BR112012032827B1 (pt) 2019-01-02
CN103140284B (zh) 2015-11-25
CN103140284A (zh) 2013-06-05
EA201390023A1 (ru) 2013-06-28
HUE030161T2 (en) 2017-04-28
JP2013534470A (ja) 2013-09-05
MY160564A (en) 2017-03-15
EA027044B1 (ru) 2017-06-30
SG186280A1 (en) 2013-01-30
US9228029B2 (en) 2016-01-05
EP2585214A1 (en) 2013-05-01
US20130090437A1 (en) 2013-04-11

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