JP5937812B2 - イソシアネート基変成炭素材料及びその製造方法 - Google Patents
イソシアネート基変成炭素材料及びその製造方法 Download PDFInfo
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- JP5937812B2 JP5937812B2 JP2011262157A JP2011262157A JP5937812B2 JP 5937812 B2 JP5937812 B2 JP 5937812B2 JP 2011262157 A JP2011262157 A JP 2011262157A JP 2011262157 A JP2011262157 A JP 2011262157A JP 5937812 B2 JP5937812 B2 JP 5937812B2
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- carbon material
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- 239000003575 carbonaceous material Substances 0.000 title claims description 68
- -1 Isocyanate group-modified carbon Chemical class 0.000 title claims description 43
- 239000012948 isocyanate Substances 0.000 title claims description 27
- 238000004519 manufacturing process Methods 0.000 title claims description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 84
- 229910002804 graphite Inorganic materials 0.000 claims description 64
- 239000010439 graphite Substances 0.000 claims description 64
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims description 19
- 239000002904 solvent Substances 0.000 claims description 9
- 229910021389 graphene Inorganic materials 0.000 description 13
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 11
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 238000010438 heat treatment Methods 0.000 description 9
- 239000007789 gas Substances 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 238000000197 pyrolysis Methods 0.000 description 8
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 7
- 229910017604 nitric acid Inorganic materials 0.000 description 7
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
- 150000001721 carbon Chemical class 0.000 description 6
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 6
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 6
- 150000002513 isocyanates Chemical class 0.000 description 6
- 229920005989 resin Polymers 0.000 description 6
- 239000011347 resin Substances 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 229910002651 NO3 Inorganic materials 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 5
- 230000000704 physical effect Effects 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 4
- 229910021393 carbon nanotube Inorganic materials 0.000 description 4
- 239000002041 carbon nanotube Substances 0.000 description 4
- 239000002131 composite material Substances 0.000 description 4
- 230000014759 maintenance of location Effects 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 238000005868 electrolysis reaction Methods 0.000 description 3
- 238000001819 mass spectrum Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 150000002009 diols Chemical class 0.000 description 2
- 230000005674 electromagnetic induction Effects 0.000 description 2
- 230000003014 reinforcing effect Effects 0.000 description 2
- 238000005096 rolling process Methods 0.000 description 2
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 229910021607 Silver chloride Inorganic materials 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
- 239000002134 carbon nanofiber Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- SCONTQOJTFJUQL-UHFFFAOYSA-N cyanic acid 3,5,5-trimethylcyclohex-2-en-1-one Chemical compound OC#N.OC#N.CC1=CC(=O)CC(C)(C)C1 SCONTQOJTFJUQL-UHFFFAOYSA-N 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 238000002290 gas chromatography-mass spectrometry Methods 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 238000002329 infrared spectrum Methods 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 238000011002 quantification Methods 0.000 description 1
- 239000007870 radical polymerization initiator Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 239000012763 reinforcing filler Substances 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
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- Carbon And Carbon Compounds (AREA)
Description
原料の黒鉛シートとして東洋炭素社製、品番:PF100−UHPを用意した。この黒鉛シートと同じ製法で、圧延処理時の圧延倍率を下げて密度0.7、厚み1mmの低密度黒鉛シートを用意した。
炭素材料として、薄片化黒鉛を酸化黒鉛に変更したこと以外は実施例1と同様にして、イソシアネート基変成薄片化黒鉛を得た。
Claims (2)
- ジイソシアネート化合物のイソシアネート基が、比表面積が1296m 2 /g以下の薄片化黒鉛に結合されている、イソシアネート基変成炭素材料。
- 比表面積が1296m 2 /g以下の薄片化黒鉛と、ジイソシアネート化合物とを溶媒中で加熱攪拌させる、イソシアネート基変成炭素材料の製造方法。
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
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JP2011262157A JP5937812B2 (ja) | 2011-11-30 | 2011-11-30 | イソシアネート基変成炭素材料及びその製造方法 |
PCT/JP2012/080078 WO2013080843A1 (ja) | 2011-11-30 | 2012-11-20 | 官能基変成炭素材料及びその製造方法 |
EP12852901.3A EP2786962B1 (en) | 2011-11-30 | 2012-11-20 | Functional-group-modified exfoliated graphite, and method for producing same |
CN201280029130.7A CN103608288B (zh) | 2011-11-30 | 2012-11-20 | 官能团改性碳材料及其制造方法 |
US14/008,532 US9346748B2 (en) | 2011-11-30 | 2012-11-20 | Functional-group-modified carbon material, and method for producing same |
KR1020137028198A KR20140109246A (ko) | 2011-11-30 | 2012-11-20 | 관능기 변성 탄소 재료 및 그의 제조 방법 |
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JP2011262157A JP5937812B2 (ja) | 2011-11-30 | 2011-11-30 | イソシアネート基変成炭素材料及びその製造方法 |
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JP5937812B2 true JP5937812B2 (ja) | 2016-06-22 |
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CN104661958A (zh) * | 2012-10-19 | 2015-05-27 | 积水化学工业株式会社 | 薄片化石墨衍生物的制造方法、以及薄片化石墨-树脂复合材料的制造方法 |
US9718914B2 (en) * | 2015-08-31 | 2017-08-01 | Palo Alto Research Center Incorporated | Mechanically robust linked particle networks |
CN112680076A (zh) * | 2019-10-18 | 2021-04-20 | 天津工业大学 | 一种功能化石墨烯增强水性聚氨酯防腐涂层的制备方法 |
CN110845870A (zh) * | 2019-11-08 | 2020-02-28 | 常熟理工学院 | 一种表面共价接枝改性六方氮化硼纳米片及其制备方法 |
CN111186835B (zh) * | 2020-01-13 | 2021-11-30 | 北京诺芯环境科技有限公司 | 甲苯二异氰酸酯釜残的应用及其制备石墨的方法、石墨及其应用 |
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JP2005508067A (ja) * | 2001-10-29 | 2005-03-24 | ハイピリオン カタリシス インターナショナル インコーポレイテッド | 官能化されたカーボンナノチューブを含むポリマー |
JP4049655B2 (ja) * | 2002-11-13 | 2008-02-20 | 紀夫 坪川 | 変性カーボンナノ繊維およびこれを含む樹脂組成物、塗料 |
JP4379002B2 (ja) * | 2003-05-30 | 2009-12-09 | 富士ゼロックス株式会社 | カーボンナノチューブデバイスの製造方法、並びに、カーボンナノチューブ転写体 |
JP2007169112A (ja) * | 2005-12-22 | 2007-07-05 | Tokyo Univ Of Science | 変性炭素材料及びその製造方法 |
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