JP5918362B2 - ７―アセチレンキノンメチド誘導体の合成及びそのビニル重合遅延剤としての用途 - Google Patents

７―アセチレンキノンメチド誘導体の合成及びそのビニル重合遅延剤としての用途 Download PDF

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JP5918362B2
JP5918362B2 JP2014515897A JP2014515897A JP5918362B2 JP 5918362 B2 JP5918362 B2 JP 5918362B2 JP 2014515897 A JP2014515897 A JP 2014515897A JP 2014515897 A JP2014515897 A JP 2014515897A JP 5918362 B2 JP5918362 B2 JP 5918362B2
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phenyl
group
tert
alkyl
cycloalkyl
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JP2014525898A (ja
JP2014525898A5 (enExample
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マーセル ジョナサン
マーセル ジョナサン
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ChampionX LLC
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Nalco Co LLC
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C46/00—Preparation of quinones
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/20—Use of additives, e.g. for stabilisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/511—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition involving transformation of singly bound oxygen functional groups to >C = O groups
    • C07C45/512—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition involving transformation of singly bound oxygen functional groups to >C = O groups the singly bound functional group being a free hydroxyl group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B63/00—Purification; Separation; Stabilisation; Use of additives
    • C07B63/04—Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C45/69—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by addition to carbon-to-carbon double or triple bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/04—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms
    • C07D295/08—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by singly bound oxygen or sulfur atoms
    • C07D295/096—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by singly bound oxygen or sulfur atoms with the ring nitrogen atoms and the oxygen or sulfur atoms separated by carbocyclic rings or by carbon chains interrupted by carbocyclic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/04—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms
    • C07D295/10—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by doubly bound oxygen or sulphur atoms
    • C07D295/112—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by doubly bound oxygen or sulphur atoms with the ring nitrogen atoms and the doubly bound oxygen or sulfur atoms separated by carbocyclic rings or by carbon chains interrupted by carbocyclic rings
    • C07D295/116—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by doubly bound oxygen or sulphur atoms with the ring nitrogen atoms and the doubly bound oxygen or sulfur atoms separated by carbocyclic rings or by carbon chains interrupted by carbocyclic rings with the doubly bound oxygen or sulfur atoms directly attached to a carbocyclic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C08F2/40—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation using retarding agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/005—Stabilisers against oxidation, heat, light, ozone
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K15/00—Anti-oxidant compositions; Compositions inhibiting chemical change
    • C09K15/04—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
    • C09K15/06—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K15/00—Anti-oxidant compositions; Compositions inhibiting chemical change
    • C09K15/04—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
    • C09K15/06—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing oxygen
    • C09K15/08—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing oxygen containing a phenol or quinone moiety

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Hydrogenated Pyridines (AREA)
JP2014515897A 2011-06-13 2012-06-11 ７―アセチレンキノンメチド誘導体の合成及びそのビニル重合遅延剤としての用途 Active JP5918362B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US13/158,958 US8884038B2 (en) 2011-06-13 2011-06-13 Synthesis of 7-acetyleno quinone methide derivatives and their application as vinylic polymerization retarders
US13/158,958 2011-06-13
PCT/US2012/041823 WO2012173909A2 (en) 2011-06-13 2012-06-11 Synthesis of 7-acetyleno quinone methide derivatives and their application as vinylic polymerization retarders

Publications (3)

Publication Number Publication Date
JP2014525898A JP2014525898A (ja) 2014-10-02
JP2014525898A5 JP2014525898A5 (enExample) 2015-05-14
JP5918362B2 true JP5918362B2 (ja) 2016-05-18

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JP2014515897A Active JP5918362B2 (ja) 2011-06-13 2012-06-11 ７―アセチレンキノンメチド誘導体の合成及びそのビニル重合遅延剤としての用途

Country Status (12)

Country Link
US (2) US8884038B2 (enExample)
EP (1) EP2718254B1 (enExample)
JP (1) JP5918362B2 (enExample)
KR (1) KR101951903B1 (enExample)
CN (1) CN103619797B (enExample)
BR (2) BR122019013055B1 (enExample)
CA (1) CA2835868C (enExample)
ES (1) ES2633763T3 (enExample)
MX (1) MX355215B (enExample)
SG (1) SG194960A1 (enExample)
TW (1) TWI596087B (enExample)
WO (1) WO2012173909A2 (enExample)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8901362B2 (en) * 2012-02-02 2014-12-02 General Electric Company Methods and compositions for styrene inhibition via in situ generation of quinone methides
DE102013204950A1 (de) 2013-03-20 2014-09-25 Evonik Industries Ag Verfahren und Zusammensetzung zur Inhibierung der Polymerisation von Cyclopentadienverbindungen
CN104341281A (zh) * 2014-06-29 2015-02-11 浙江大学 2,6-二叔丁基-4-(2-甲氧基苯亚甲基)-2,5-环己二烯-1-酮及其制备法
JP6503059B2 (ja) 2014-10-14 2019-04-17 エコラブ ユーエスエイ インク アクリレート／メタクリレートプロセスにおけるポリマーの汚損および凝集の低減
CA2979828C (en) 2015-03-18 2023-08-29 Ecolab Usa Inc. The use of stable lipophilic hydroxylamine compounds for inhibiting polymerization of vinyl monomers
US9957209B2 (en) 2015-03-31 2018-05-01 Ecolab Usa Inc. Use of quinone methides as antipolymerants for vinylic monomers
BR112017022431B1 (pt) 2015-04-20 2023-03-28 Ecolab Usa Inc Método para inibir polimerização durante refino, transporte ou armazenamento de uma corrente de hidrocarboneto
TWI826485B (zh) 2018-07-13 2023-12-21 美商藝康美國公司 作為乙烯系單體之防垢劑之含氧胺及醌甲基化物之組合物
CN112533902B (zh) 2018-07-13 2025-03-14 埃科莱布美国股份有限公司 抑制单体聚合的包含氮氧化物抑制剂、醌甲基化物阻滞剂和胺稳定剂的组合物
CN116553996A (zh) * 2023-07-07 2023-08-08 吉林金海化工新材料有限公司 一种阻聚剂及其应用

Family Cites Families (23)

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US2459597A (en) 1945-05-16 1949-01-18 Gulf Research Development Co Di-alkylated mono-hydroxy phenol
US3257321A (en) 1960-09-01 1966-06-21 Ethyl Corp 3, 5-dialkyl-4-hydroxybenzyl chloride
US3390198A (en) 1965-12-16 1968-06-25 Koppers Co Inc Tertiary-butyl-5-methyl catechol as polymerization inhibitor for hot styrene
US3660505A (en) 1969-08-27 1972-05-02 Exxon Research Engineering Co Hindered alkenyl phenols from quinone methide
US4003800A (en) 1976-01-02 1977-01-18 Gulf Research & Development Company Styrene purification process
US4032547A (en) 1976-02-23 1977-06-28 Gulf Research & Development Company Quinone alkide synthesis system
US4409408A (en) 1982-09-24 1983-10-11 Atlantic Richfield Company Inhibiting polymerization of vinyl aromatic monomers
US5446220A (en) 1994-08-24 1995-08-29 Betz Laboratories, Inc. Methods for inhibiting vinyl aromatic monomer polymerization
US5616774A (en) 1995-04-14 1997-04-01 Ciba-Geigy Corporation Inhibition of unsaturated monomers with 7-aryl quinone methides
US5583247A (en) 1995-04-14 1996-12-10 Ciba-Geigy Corporation 7-substituted quinone methides as inhibitors for unsaturated monomers
EP0744392A1 (en) * 1995-05-26 1996-11-27 Ciba-Geigy Ag A new one-pot process for the preparation of 7-aryl-2,6-disubstituted quinone methides
FR2746098B1 (fr) * 1996-03-14 1998-04-30 Composes propynyl biaromatiques
US6024894A (en) 1998-03-25 2000-02-15 Betzdearborn Inc. Compositions and methods for inhibiting vinyl aromatic monomer polymerization
EP1235885B1 (en) * 1999-12-03 2007-08-15 Uniroyal Chemical Company, Inc. Composition and method for inhibiting polymerization and polymer growth
JP4248875B2 (ja) 2000-10-16 2009-04-02 ケムチュア コーポレイション 重合抑制剤としての、キノンアルカイドとニトロキシル化合物の混合物
CN1282695C (zh) 2001-03-20 2006-11-01 西巴特殊化学品控股有限公司 阻燃剂组合物
US6926820B2 (en) 2002-09-20 2005-08-09 G.E. Betz, Inc. Inhibition of viscosity increase and fouling in hydrocarbon streams including unsaturation
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JP4790414B2 (ja) 2003-03-17 2011-10-12 伯東株式会社 芳香族ビニル化合物の重合抑制剤および重合抑制方法
US20080132726A1 (en) * 2006-11-30 2008-06-05 Vinod Kumar Rai Process for the production of quinone methide
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Also Published As

Publication number Publication date
JP2014525898A (ja) 2014-10-02
CN103619797B (zh) 2015-02-04
US20120313036A1 (en) 2012-12-13
WO2012173909A3 (en) 2013-03-21
KR101951903B1 (ko) 2019-02-25
MX355215B (es) 2018-04-10
CA2835868C (en) 2018-03-13
CA2835868A1 (en) 2012-12-20
MX2013013687A (es) 2014-01-08
US9447002B2 (en) 2016-09-20
BR112013031103A2 (pt) 2016-12-06
SG194960A1 (en) 2013-12-30
US20150060727A1 (en) 2015-03-05
EP2718254A4 (en) 2015-04-01
US8884038B2 (en) 2014-11-11
KR20140041729A (ko) 2014-04-04
TW201307277A (zh) 2013-02-16
EP2718254A2 (en) 2014-04-16
BR112013031103B1 (pt) 2020-04-22
EP2718254B1 (en) 2017-05-10
WO2012173909A2 (en) 2012-12-20
ES2633763T3 (es) 2017-09-25
TWI596087B (zh) 2017-08-21
CN103619797A (zh) 2014-03-05
BR122019013055B1 (pt) 2019-12-17

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