JP5850345B2 - 高速混合反応器およびその使用 - Google Patents
高速混合反応器およびその使用 Download PDFInfo
- Publication number
- JP5850345B2 JP5850345B2 JP2013546549A JP2013546549A JP5850345B2 JP 5850345 B2 JP5850345 B2 JP 5850345B2 JP 2013546549 A JP2013546549 A JP 2013546549A JP 2013546549 A JP2013546549 A JP 2013546549A JP 5850345 B2 JP5850345 B2 JP 5850345B2
- Authority
- JP
- Japan
- Prior art keywords
- feed
- reactor
- channel
- distributor
- feed distributor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000002156 mixing Methods 0.000 title claims description 75
- 238000006243 chemical reaction Methods 0.000 claims description 68
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 claims description 42
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 38
- 150000001412 amines Chemical class 0.000 claims description 38
- -1 aromatic isocyanate Chemical class 0.000 claims description 33
- 229920000768 polyamine Polymers 0.000 claims description 31
- 238000000034 method Methods 0.000 claims description 27
- 238000003756 stirring Methods 0.000 claims description 25
- 238000004519 manufacturing process Methods 0.000 claims description 23
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 claims description 20
- 150000002430 hydrocarbons Chemical group 0.000 claims description 20
- 239000007788 liquid Substances 0.000 claims description 20
- 239000012948 isocyanate Substances 0.000 claims description 17
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 claims description 16
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 14
- 229920000265 Polyparaphenylene Polymers 0.000 claims description 13
- 230000003068 static effect Effects 0.000 claims description 13
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 12
- 125000002723 alicyclic group Chemical group 0.000 claims description 12
- 125000001931 aliphatic group Chemical group 0.000 claims description 12
- MMCPOSDMTGQNKG-UHFFFAOYSA-N anilinium chloride Chemical compound Cl.NC1=CC=CC=C1 MMCPOSDMTGQNKG-UHFFFAOYSA-N 0.000 claims description 10
- 239000012295 chemical reaction liquid Substances 0.000 claims description 9
- 125000003118 aryl group Chemical group 0.000 claims description 7
- RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 claims description 6
- 239000003960 organic solvent Substances 0.000 claims description 6
- 239000008098 formaldehyde solution Substances 0.000 claims description 5
- 239000012442 inert solvent Substances 0.000 claims description 5
- 230000008707 rearrangement Effects 0.000 claims description 5
- OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 claims description 4
- VOZKAJLKRJDJLL-UHFFFAOYSA-N 2,4-diaminotoluene Chemical compound CC1=CC=C(N)C=C1N VOZKAJLKRJDJLL-UHFFFAOYSA-N 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 4
- 238000006386 neutralization reaction Methods 0.000 claims description 4
- 238000000746 purification Methods 0.000 claims description 4
- 238000005406 washing Methods 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- DMDPKUWXJUYFKO-UHFFFAOYSA-N 1,1'-biphenyl;hydrochloride Chemical compound Cl.C1=CC=CC=C1C1=CC=CC=C1 DMDPKUWXJUYFKO-UHFFFAOYSA-N 0.000 claims description 3
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 claims description 3
- GCKJRDJPEIPERM-UHFFFAOYSA-N 3,4-dimethyl-6-phenylbenzene-1,2-diamine Chemical compound NC1=C(C)C(C)=CC(C=2C=CC=CC=2)=C1N GCKJRDJPEIPERM-UHFFFAOYSA-N 0.000 claims description 3
- RNLHGQLZWXBQNY-UHFFFAOYSA-N 3-(aminomethyl)-3,5,5-trimethylcyclohexan-1-amine Chemical compound CC1(C)CC(N)CC(C)(CN)C1 RNLHGQLZWXBQNY-UHFFFAOYSA-N 0.000 claims description 3
- RXBWOHTVLPIZIQ-UHFFFAOYSA-N CC=1C(CCCC=1)(N)N Chemical compound CC=1C(CCCC=1)(N)N RXBWOHTVLPIZIQ-UHFFFAOYSA-N 0.000 claims description 3
- 125000002029 aromatic hydrocarbon group Chemical group 0.000 claims description 3
- YMHQVDAATAEZLO-UHFFFAOYSA-N cyclohexane-1,1-diamine Chemical compound NC1(N)CCCCC1 YMHQVDAATAEZLO-UHFFFAOYSA-N 0.000 claims description 3
- 238000007599 discharging Methods 0.000 claims description 3
- SYECJBOWSGTPLU-UHFFFAOYSA-N hexane-1,1-diamine Chemical compound CCCCCC(N)N SYECJBOWSGTPLU-UHFFFAOYSA-N 0.000 claims description 3
- NTNWKDHZTDQSST-UHFFFAOYSA-N naphthalene-1,2-diamine Chemical compound C1=CC=CC2=C(N)C(N)=CC=C21 NTNWKDHZTDQSST-UHFFFAOYSA-N 0.000 claims description 3
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 claims description 3
- 239000006166 lysate Substances 0.000 claims description 2
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims 1
- 229910003460 diamond Inorganic materials 0.000 claims 1
- 239000010432 diamond Substances 0.000 claims 1
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 1
- 239000012530 fluid Substances 0.000 description 23
- 239000000047 product Substances 0.000 description 18
- 150000002513 isocyanates Chemical class 0.000 description 14
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 9
- 238000013461 design Methods 0.000 description 7
- 230000001965 increasing effect Effects 0.000 description 7
- 239000002904 solvent Substances 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- 239000011541 reaction mixture Substances 0.000 description 6
- 239000000376 reactant Substances 0.000 description 5
- 239000006227 byproduct Substances 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 description 4
- 238000009826 distribution Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000007086 side reaction Methods 0.000 description 4
- PBKONEOXTCPAFI-UHFFFAOYSA-N 1,2,4-trichlorobenzene Chemical compound ClC1=CC=C(Cl)C(Cl)=C1 PBKONEOXTCPAFI-UHFFFAOYSA-N 0.000 description 3
- CKDWPUIZGOQOOM-UHFFFAOYSA-N Carbamyl chloride Chemical compound NC(Cl)=O CKDWPUIZGOQOOM-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 239000012043 crude product Substances 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000013341 scale-up Methods 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- JTPNRXUCIXHOKM-UHFFFAOYSA-N 1-chloronaphthalene Chemical compound C1=CC=C2C(Cl)=CC=CC2=C1 JTPNRXUCIXHOKM-UHFFFAOYSA-N 0.000 description 1
- 241000239290 Araneae Species 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000012824 chemical production Methods 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- 229940117389 dichlorobenzene Drugs 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000003840 hydrochlorides Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000000543 intermediate Substances 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- AXNUJYHFQHQZBE-UHFFFAOYSA-N toluenediamine group Chemical group C1(=C(C(=CC=C1)N)N)C AXNUJYHFQHQZBE-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/18—Stationary reactors having moving elements inside
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/26—Nozzle-type reactors, i.e. the distribution of the initial reactants within the reactor is effected by their introduction or injection through nozzles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
- B01F25/20—Jet mixers, i.e. mixers using high-speed fluid streams
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
- B01F27/27—Mixers with stator-rotor systems, e.g. with intermeshing teeth or cylinders or having orifices
- B01F27/272—Mixers with stator-rotor systems, e.g. with intermeshing teeth or cylinders or having orifices with means for moving the materials to be mixed axially between the surfaces of the rotor and the stator, e.g. the stator rotor system formed by conical or cylindrical surfaces
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
- B01F27/60—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a horizontal or inclined axis
- B01F27/62—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a horizontal or inclined axis comprising liquid feeding, e.g. spraying means
- B01F27/621—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a horizontal or inclined axis comprising liquid feeding, e.g. spraying means the liquid being fed through the shaft of the stirrer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
- B01F27/60—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a horizontal or inclined axis
- B01F27/625—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a horizontal or inclined axis the receptacle being divided into compartments, e.g. with porous divisions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/0006—Controlling or regulating processes
- B01J19/002—Avoiding undesirable reactions or side-effects, e.g. avoiding explosions, or improving the yield by suppressing side-reactions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/68—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton
- C07C209/78—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton from carbonyl compounds, e.g. from formaldehyde, and amines having amino groups bound to carbon atoms of six-membered aromatic rings, with formation of methylene-diarylamines
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C263/00—Preparation of derivatives of isocyanic acid
- C07C263/10—Preparation of derivatives of isocyanic acid by reaction of amines with carbonyl halides, e.g. with phosgene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G12/00—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08G12/02—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes
- C08G12/04—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds
- C08G12/06—Amines
- C08G12/08—Amines aromatic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00189—Controlling or regulating processes controlling the stirring velocity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00245—Avoiding undesirable reactions or side-effects
- B01J2219/00247—Fouling of the reactor or the process equipment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00761—Details of the reactor
- B01J2219/00763—Baffles
- B01J2219/00765—Baffles attached to the reactor wall
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Mixers Of The Rotary Stirring Type (AREA)
- Accessories For Mixers (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/CN2010/080434 WO2012088671A1 (zh) | 2010-12-29 | 2010-12-29 | 一种快速混合反应器及其应用 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2014509247A JP2014509247A (ja) | 2014-04-17 |
| JP2014509247A5 JP2014509247A5 (ko) | 2015-01-22 |
| JP5850345B2 true JP5850345B2 (ja) | 2016-02-03 |
Family
ID=46382188
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2013546549A Active JP5850345B2 (ja) | 2010-12-29 | 2010-12-29 | 高速混合反応器およびその使用 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US9138717B2 (ko) |
| EP (1) | EP2486975B1 (ko) |
| JP (1) | JP5850345B2 (ko) |
| KR (1) | KR101499758B1 (ko) |
| BR (1) | BR112012029403B1 (ko) |
| HU (1) | HUE026867T2 (ko) |
| SA (1) | SA111330016B1 (ko) |
| WO (1) | WO2012088671A1 (ko) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101577760B1 (ko) * | 2013-08-23 | 2015-12-15 | 금호석유화학 주식회사 | 고속 분사를 이용한 이종 유체의 혼합반응기 |
| KR101416760B1 (ko) * | 2014-03-25 | 2014-07-09 | 금호석유화학 주식회사 | 고속 분사를 이용한 이소시아네이트 제조용 혼합 반응기 |
| KR101452423B1 (ko) * | 2013-12-10 | 2014-10-22 | 금호석유화학 주식회사 | 고속 분사를 이용한 이종 유체의 혼합반응기 |
| JP5815087B2 (ja) | 2013-12-10 | 2015-11-17 | コリア クムホ ペトロケミカル カンパニー．， リミテッド | 高速噴射を利用した異種流体の混合反応器 |
| KR20170026487A (ko) | 2014-06-24 | 2017-03-08 | 코베스트로 도이칠란트 아게 | 디페닐메탄 시리즈의 디- 및 폴리아민의 제조 방법 |
| CN106470970B (zh) * | 2014-06-24 | 2019-11-12 | 科思创德国股份有限公司 | 用于制备二苯基甲烷系列的二胺和多胺的方法 |
| WO2015197520A1 (de) * | 2014-06-24 | 2015-12-30 | Covestro Deutschland Ag | Verfahren zur herstellung von di- und polyaminen der diphenylmethanreihe |
| CN105198099A (zh) * | 2015-10-23 | 2015-12-30 | 宜兴汉光高新石化有限公司 | 一种用于高效加氢阻垢剂生产的搅拌装置 |
| CN107597028B (zh) * | 2017-09-21 | 2020-05-08 | 万华化学（宁波）有限公司 | 一种制备异氰酸酯的反应器及方法 |
| CN108905842B (zh) * | 2018-06-25 | 2021-08-27 | 山东大学 | 罗丹明b荧光示踪剂全自动配置投放控制装置与操作方法 |
| CN109126681A (zh) * | 2018-10-16 | 2019-01-04 | 湖南行者环保科技有限公司 | 一种管道振动式物料反应装置 |
| CN109663546B (zh) * | 2019-02-21 | 2022-09-06 | 南京科技职业学院 | 一种乙酰苯胺合成专用反应器 |
| KR102025042B1 (ko) * | 2019-03-06 | 2019-09-24 | 곽동채 | 고속 순간 혼화방식 액상폴리머 용해장치 |
| EA202100032A3 (ru) * | 2020-02-21 | 2021-10-29 | Вингфлоу Аг | Реактор для производства микронизированного силикагеля |
| CN115286535B (zh) * | 2022-08-17 | 2023-10-17 | 万华化学集团股份有限公司 | 一种异氰酸酯的制备工艺以及成盐、光化反应耦合装置 |
| CN115634655A (zh) * | 2022-11-04 | 2023-01-24 | 万华化学集团股份有限公司 | 一种高剪切混合反应器及二苯基甲烷系列胺的制备方法 |
| CN116271935B (zh) * | 2023-03-16 | 2024-02-23 | 福建省德旭新材料有限公司 | 一种六氟磷酸钠制备用冷却器 |
Family Cites Families (38)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1152769A (en) * | 1912-06-12 | 1915-09-07 | Lamartine C Trent | Apparatus for treating solid-bearing solutions. |
| US2392542A (en) * | 1942-10-05 | 1946-01-08 | Phillips Petroleum Co | Apparatus for mixing fluids |
| US2402905A (en) * | 1943-09-14 | 1946-06-25 | Girdler Corp | Mixing apparatus |
| US2904407A (en) * | 1956-11-01 | 1959-09-15 | Klauder Weldon Giles Machine C | Chemical reactor |
| US3226205A (en) * | 1960-10-03 | 1965-12-28 | Phillips Petroleum Co | Reactor impeller with feed inlet along shaft |
| JPS4941029B1 (ko) * | 1970-05-28 | 1974-11-06 | ||
| JPS54162269A (en) * | 1978-06-12 | 1979-12-22 | Ihara Chemical Ind Co | Liquid rapid mixer |
| DE3116878C2 (de) * | 1981-04-28 | 1985-07-18 | Institut Biochimii I Fiziologii Mikroorganizmov Akademii Nauk Sssr | Vorrichtung zum Züchten von Mikroorganismen |
| CA1284017C (en) * | 1987-05-21 | 1991-05-14 | Hugo I. De Lasa | Riser simulator |
| DE3717057A1 (de) * | 1987-05-21 | 1988-12-01 | Bayer Ag | Verfahren zur herstellung von isocyanaten |
| DE3717058A1 (de) * | 1987-05-21 | 1988-12-08 | Bayer Ag | Mischer zum vermischen mindestens zweier fliessfaehiger stoffe, insbesondere unter durchfuehrung bzw. einleitung einer reaktion waehrend der vermischung |
| DE3744001C1 (de) | 1987-12-24 | 1989-06-08 | Bayer Ag | Verfahren zur kontinuierlichen Herstellung von Mono- oder Polyisocyanaten |
| US5620250A (en) * | 1996-03-05 | 1997-04-15 | Pro-Quip, Inc. | Jet mixer having a self-centering liquid bearing hub arrangement |
| DE19638567A1 (de) * | 1996-09-20 | 1998-03-26 | Bayer Ag | Mischer-Reaktor und Verfahren zur Durchführung von Reaktionen, insbesondere die Phosgenierung von primären Aminen |
| US5811259A (en) * | 1997-07-29 | 1998-09-22 | Ecomat, Inc. | Biochemical reactor |
| US20110075507A1 (en) * | 1997-10-24 | 2011-03-31 | Revalesio Corporation | Diffuser/emulsifier |
| US7654728B2 (en) * | 1997-10-24 | 2010-02-02 | Revalesio Corporation | System and method for therapeutic application of dissolved oxygen |
| US6386751B1 (en) * | 1997-10-24 | 2002-05-14 | Diffusion Dynamics, Inc. | Diffuser/emulsifier |
| DE19804915A1 (de) * | 1998-02-07 | 1999-08-12 | Basf Ag | Verfahren zur Herstellung von Methylendi(phenylamin) und Methylendi(phenylisocyanat) |
| DE29909312U1 (de) * | 1999-05-27 | 1999-08-12 | Ekato Rühr- und Mischtechnik GmbH, 79650 Schopfheim | Rührwerk |
| JP2001239140A (ja) * | 1999-12-22 | 2001-09-04 | Reika Kogyo Kk | 反応攪拌装置、反応分画濾過装置及び分画方法、生成方法、濾過方法 |
| CN1194962C (zh) * | 2000-12-29 | 2005-03-30 | K·S·T·公司 | 连续制备甲苯二异氰酸酯的方法及其装置 |
| DE10211021A1 (de) * | 2002-03-13 | 2003-09-25 | Bayer Ag | Verfahren zur Herstellung von Polyisocyanaten der Diphenylmethanreihe mit vermindertem Farbwert |
| DE10359627A1 (de) | 2003-12-18 | 2005-07-21 | Bayer Materialscience Ag | Verfahren zur Herstellung von Diisocyanaten |
| JP3746288B2 (ja) * | 2004-07-27 | 2006-02-15 | ファルクサー株式会社 | 粉体原料と液体原料の結合方法およびミキサー |
| DE102004040735B4 (de) * | 2004-08-23 | 2006-11-23 | ETH-Zürich, Institut für Lebensmittelwissenschaft, Laboratorium für Lebensmittelverfahrenstechnik | Verfahren zur mechanisch schonenden Erzeugung von fein dispersen Mikro-/Nano-Emulsionen mit enger Tropfengrößenverteilung und Vorrichtung zum Durchführen des Verfahrens |
| CN101153015B (zh) | 2006-09-28 | 2010-06-16 | 宁波万华聚氨酯有限公司 | 一种孔射流式反应器及利用该反应器制备异氰酸酯的方法 |
| US7455776B2 (en) * | 2006-11-21 | 2008-11-25 | Praxair Technology, Inc. | Method for mixing high viscous liquids with gas |
| CN101209405B (zh) * | 2006-12-27 | 2013-08-28 | 宁波万华聚氨酯有限公司 | 一种孔射流式喷射反应器 |
| US7677791B2 (en) * | 2007-01-23 | 2010-03-16 | Joseph Carl Firey | Rotary residual fuel slurrifier |
| ATE517860T1 (de) * | 2007-04-06 | 2011-08-15 | Ningbo Wanhua Polyurethanes Co | Verfahren zur herstellung von polymethylenpolyphenylpolyamin |
| US9205388B2 (en) * | 2007-06-27 | 2015-12-08 | H R D Corporation | High shear system and method for the production of acids |
| DE102007061688A1 (de) * | 2007-12-19 | 2009-06-25 | Bayer Materialscience Ag | Verfahren und Mischaggregat zur Herstellung von Isocyanaten durch Phosgenierung primärer Amine |
| US8119084B2 (en) * | 2008-05-16 | 2012-02-21 | Exxonmobil Research & Engineering Company | Reactor for isoparaffin olefin alkylation |
| DE102008063728A1 (de) | 2008-12-18 | 2010-06-24 | Bayer Materialscience Ag | Verfahren zur Herstellung von Isocyanaten in der Gasphase |
| US20110028573A1 (en) * | 2009-07-28 | 2011-02-03 | Hrd Corp. | High Shear Production of Value-Added Product From Refinery-Related Gas |
| CN101811019B (zh) * | 2010-04-19 | 2012-01-18 | 烟台万华聚氨酯股份有限公司 | 一种动态孔射流式反应器及采用该反应器制备异氰酸酯的方法 |
| CN101811017B (zh) * | 2010-04-23 | 2012-01-11 | 烟台万华聚氨酯股份有限公司 | 一种搅拌研磨反应器及利用该反应器制备异氰酸酯的方法 |
-
2010
- 2010-12-29 US US13/499,703 patent/US9138717B2/en active Active
- 2010-12-29 WO PCT/CN2010/080434 patent/WO2012088671A1/zh active Application Filing
- 2010-12-29 BR BR112012029403-2A patent/BR112012029403B1/pt active IP Right Grant
- 2010-12-29 EP EP10852321.8A patent/EP2486975B1/en active Active
- 2010-12-29 JP JP2013546549A patent/JP5850345B2/ja active Active
- 2010-12-29 KR KR1020137018951A patent/KR101499758B1/ko active IP Right Grant
- 2010-12-29 HU HUE10852321A patent/HUE026867T2/en unknown
-
2011
- 2011-11-30 SA SA111330016A patent/SA111330016B1/ar unknown
Also Published As
| Publication number | Publication date |
|---|---|
| US20130178596A1 (en) | 2013-07-11 |
| HUE026867T2 (en) | 2016-08-29 |
| JP2014509247A (ja) | 2014-04-17 |
| EP2486975B1 (en) | 2015-09-23 |
| SA111330016B1 (ar) | 2015-01-27 |
| KR101499758B1 (ko) | 2015-03-06 |
| KR20130099200A (ko) | 2013-09-05 |
| BR112012029403B1 (pt) | 2018-11-27 |
| WO2012088671A1 (zh) | 2012-07-05 |
| US9138717B2 (en) | 2015-09-22 |
| EP2486975A1 (en) | 2012-08-15 |
| EP2486975A4 (en) | 2012-09-12 |
| BR112012029403A2 (pt) | 2016-12-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP5850345B2 (ja) | 高速混合反応器およびその使用 | |
| US9975094B2 (en) | Reactive flow static mixer with cross-flow obstructions | |
| JP2014509247A5 (ko) | ||
| CN101811017B (zh) | 一种搅拌研磨反应器及利用该反应器制备异氰酸酯的方法 | |
| JP5334558B2 (ja) | イソシアネートを第１アミンのホスゲン化によって製造するための方法および混合ユニット | |
| US8957245B2 (en) | Method for producing isocyanate | |
| JP5595271B2 (ja) | フローダクトを備えるジェット式反応装置、及びフローダクトを備えるジェット式反応装置を用いたイソシアネート類製造方法 | |
| CN101735109B (zh) | 有机异氰酸酯的连续生产方法 | |
| JP2005126437A (ja) | 気相におけるイソシアネートの調製方法 | |
| TWI464139B (zh) | 氣相中製備異氰酸酯之方法 | |
| CN101583594A (zh) | 生产异氰酸酯的方法 | |
| JP2004067669A (ja) | 気相におけるイソシアネートの製造方法 | |
| US20100305356A1 (en) | Method for producing isocyanates | |
| US9295972B2 (en) | Mixing reactor for heterogeneous fluids using high-speed ejecting | |
| CN211586574U (zh) | 薄膜高效反应器 | |
| CN116847926A (zh) | 间歇反应器 | |
| WO2011130901A1 (zh) | 一种动态孔射流式反应器及采用该反应器制备异氰酸酯的方法 | |
| CN102527312B (zh) | 一种快速混合反应器及其应用 | |
| KR20220088139A (ko) | 회분식 반응장치 | |
| WO2009068920A1 (en) | Mixing device for mixing two liquids and process for the continuous preparation of organic mono-, di- or polyisocyanates | |
| EP4309776A1 (en) | Batch reaction apparatus |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20140718 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20140901 |
|
| A524 | Written submission of copy of amendment under article 19 pct |
Free format text: JAPANESE INTERMEDIATE CODE: A524 Effective date: 20141201 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20150629 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20150928 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20151105 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20151119 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 5850345 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |