JP5719352B2 - 太陽放射に対する耐性が優れかつ断熱特性と機械的性質が最適な発泡製品 - Google Patents
太陽放射に対する耐性が優れかつ断熱特性と機械的性質が最適な発泡製品 Download PDFInfo
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- JP5719352B2 JP5719352B2 JP2012509104A JP2012509104A JP5719352B2 JP 5719352 B2 JP5719352 B2 JP 5719352B2 JP 2012509104 A JP2012509104 A JP 2012509104A JP 2012509104 A JP2012509104 A JP 2012509104A JP 5719352 B2 JP5719352 B2 JP 5719352B2
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- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 239000012159 carrier gas Substances 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
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- 239000000460 chlorine Substances 0.000 description 1
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- 238000004939 coking Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- PXBRQCKWGAHEHS-UHFFFAOYSA-N dichlorodifluoromethane Chemical compound FC(F)(Cl)Cl PXBRQCKWGAHEHS-UHFFFAOYSA-N 0.000 description 1
- 235000019404 dichlorodifluoromethane Nutrition 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- XZTWHWHGBBCSMX-UHFFFAOYSA-J dimagnesium;phosphonato phosphate Chemical compound [Mg+2].[Mg+2].[O-]P([O-])(=O)OP([O-])([O-])=O XZTWHWHGBBCSMX-UHFFFAOYSA-J 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000006261 foam material Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
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- 238000000227 grinding Methods 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 1
- KETWBQOXTBGBBN-UHFFFAOYSA-N hex-1-enylbenzene Chemical compound CCCCC=CC1=CC=CC=C1 KETWBQOXTBGBBN-UHFFFAOYSA-N 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
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- 229910052740 iodine Inorganic materials 0.000 description 1
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- 238000009533 lab test Methods 0.000 description 1
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- 239000003077 lignite Substances 0.000 description 1
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- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
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- 235000019359 magnesium stearate Nutrition 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- ZADYMNAVLSWLEQ-UHFFFAOYSA-N magnesium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[Mg+2].[Si+4] ZADYMNAVLSWLEQ-UHFFFAOYSA-N 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
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- 239000002105 nanoparticle Substances 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
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- 229920001225 polyester resin Polymers 0.000 description 1
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- 229920006389 polyphenyl polymer Polymers 0.000 description 1
- 229920006327 polystyrene foam Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
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- LYBIZMNPXTXVMV-UHFFFAOYSA-N propan-2-yl prop-2-enoate Chemical compound CC(C)OC(=O)C=C LYBIZMNPXTXVMV-UHFFFAOYSA-N 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000002285 radioactive effect Effects 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Chemical class [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 1
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
- 229940001584 sodium metabisulfite Drugs 0.000 description 1
- 235000010262 sodium metabisulphite Nutrition 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- HIFJUMGIHIZEPX-UHFFFAOYSA-N sulfuric acid;sulfur trioxide Chemical compound O=S(=O)=O.OS(O)(=O)=O HIFJUMGIHIZEPX-UHFFFAOYSA-N 0.000 description 1
- 230000036561 sun exposure Effects 0.000 description 1
- 229910000666 supertherm Inorganic materials 0.000 description 1
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- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
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- 150000005691 triesters Chemical class 0.000 description 1
- 230000001960 triggered effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0066—Use of inorganic compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0061—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/22—After-treatment of expandable particles; Forming foamed products
- C08J9/228—Forming foamed products
- C08J9/232—Forming foamed products by sintering expandable particles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
- C08J2325/02—Homopolymers or copolymers of hydrocarbons
- C08J2325/04—Homopolymers or copolymers of styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2471/00—Characterised by the use of polyethers obtained by reactions forming an ether link in the main chain; Derivatives of such polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
- Insulating Bodies (AREA)
Applications Claiming Priority (3)
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| ITMI2009A000764 | 2009-05-05 | ||
| ITMI2009A000764A IT1393962B1 (it) | 2009-05-05 | 2009-05-05 | Articoli espansi con ottima resistenza allo irraggiamento solare e ottime proprieta' termoisolanti e meccaniche |
| PCT/IB2010/000923 WO2010128369A1 (en) | 2009-05-05 | 2010-04-23 | Expanded articles with excellent resistance to solar radiation and optimum thermoinsulating and mechanical properties |
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| JP2012526170A JP2012526170A (ja) | 2012-10-25 |
| JP2012526170A5 JP2012526170A5 (enExample) | 2013-06-13 |
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| EP (1) | EP2427514B1 (enExample) |
| JP (1) | JP5719352B2 (enExample) |
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| RU (1) | RU2524711C2 (enExample) |
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| IT1395379B1 (it) | 2009-09-07 | 2012-09-14 | Polimeri Europa Spa | Procedimento per la preparazione di polimeri vinilaromatici espansibili a ridotta conducibilita' termica mediante polimerizzazione in sospensione |
| IT1401950B1 (it) * | 2010-09-21 | 2013-08-28 | Polimeri Europa Spa | Composizioni di (co)polimeri vinilaromatici espansibili autoestinguenti e procedimento per la loro preparazione. |
| CN102532957B (zh) * | 2011-12-13 | 2014-07-02 | 湛江市聚鑫新能源有限公司 | 一种导热绝缘填料及其制备方法 |
| ITMI20121808A1 (it) | 2012-10-24 | 2014-04-25 | Versalis Spa | Composizioni polimeriche concentrate di polimeri e/o copolimeri vinilaromatici |
| ITMI20121973A1 (it) * | 2012-11-20 | 2014-05-21 | Versalis Spa | Composizione polimerica autoestinguente |
| HRP20170728T1 (hr) | 2012-12-28 | 2017-09-22 | Total Research & Technology Feluy | Rastezljivi vinil aromatski polimeri koji sadrže čestice igličastog koksa |
| HUE046210T2 (hu) | 2012-12-28 | 2020-02-28 | Total Res & Technology Feluy | Polimodális szemcseméret eloszlású grafit szemcséket tartalmazó expandálható vinilaromás polimerek |
| JP6343485B2 (ja) * | 2014-05-09 | 2018-06-13 | 積水化成品工業株式会社 | ポリスチレン系発泡成形体及びその製造方法 |
| KR101575989B1 (ko) * | 2014-12-24 | 2015-12-09 | 고영신 | 팽창흑연을 이용한 경량화된 흡음내화 단열재 및 그 제조방법 |
| MA41342A (fr) | 2015-01-14 | 2017-11-21 | Synthos Sa | Procédé pour la production de granulés de polymère vinylique aromatique expansible ayant une conductivité thermique réduite |
| CA2973630A1 (en) | 2015-01-14 | 2016-07-21 | Synthos S.A. | Geopolymer composite and expandable vinyl aromatic polymer granulate and expanded vinyl aromatic polymer foam comprising the same |
| MA41344B1 (fr) * | 2015-01-14 | 2019-01-31 | Synthos Sa | Combinaison de silice et de graphite et son utilisation pour réduire la conductivité thermique d'une mousse de polymère aromatique vinylique |
| JP6735281B2 (ja) * | 2015-01-14 | 2020-08-05 | シントス エス．アー．Ｓｙｎｔｈｏｓ Ｓ．Ａ． | ペロブスカイト構造を有する鉱物のビニル芳香族ポリマーフォームでの使用 |
| CN104744843B (zh) * | 2015-03-31 | 2018-07-06 | 青岛欧克斯新型建材有限公司 | 一种绝热用石墨聚苯乙烯泡沫塑料挤塑板 |
| US10964620B2 (en) * | 2016-04-11 | 2021-03-30 | Sekisui Polymatech Co., Ltd. | Thermally conductive sheet |
| CN109312108A (zh) * | 2016-05-11 | 2019-02-05 | 欧文斯科宁知识产权资产有限公司 | 包含低水平溴化阻燃剂的聚合物泡沫及其制备方法 |
| IT201600071347A1 (it) | 2016-07-08 | 2018-01-08 | Versalis Spa | Composizioni espandibili contenenti polimeri vinil aromatici aventi proprietà autoestinguenti e migliorata processabilità |
| WO2018015490A1 (en) | 2016-07-20 | 2018-01-25 | Synthos S.A. | Process for the production of geopolymer or geopolymer composite |
| BR112019000605A2 (pt) * | 2016-07-20 | 2019-04-30 | Synthos S.A. | geopolímero modificado e compósito de geopolímero modificado e processo para a produção dos mesmos |
| AU2017300726B2 (en) | 2016-07-20 | 2021-12-02 | Synthos S.A. | Use of geopolymeric additive in combination with non-brominated flame retardant in polymer foams |
| KR102419948B1 (ko) * | 2016-10-10 | 2022-07-12 | 토탈 리서치 앤드 테크놀로지 펠루이 | 개선된 팽창성 비닐 방향족 중합체 |
| EP3523361A1 (en) | 2016-10-10 | 2019-08-14 | Total Research & Technology Feluy | Improved expandable vinyl aromatic polymers |
| US11834563B2 (en) | 2016-10-10 | 2023-12-05 | Totalenergies Onetech Belgium | Expandable vinyl aromatic polymers |
| WO2019092568A1 (en) * | 2017-11-10 | 2019-05-16 | 3M Innovative Properties Company | Roof coating composition, methods of use, and articles |
| IT201800020404A1 (it) * | 2018-12-20 | 2020-06-20 | Versalis Spa | Composizione polimerica espandibile e procedimento per la sua produzione |
| CN114341256A (zh) | 2019-09-04 | 2022-04-12 | 道达尔能源一技术比利时公司 | 具有改进的阻燃性的可膨胀乙烯基芳族聚合物 |
| CN114917852B (zh) * | 2022-06-28 | 2024-01-16 | 桂林电子科技大学 | 一种本体法连续生产石墨可发泡聚苯乙烯的方法 |
| CN117429133B (zh) * | 2023-10-23 | 2024-04-16 | 尤特森新材料集团有限公司 | 一种耐高低温的弹性隔热板及其制备工艺 |
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| US4786543A (en) * | 1987-10-06 | 1988-11-22 | Don Ferm | Ceiling tile of expanded polystyrene laminated with embossed vinyl sheet |
| DE3817631A1 (de) | 1988-05-25 | 1989-11-30 | Basf Ag | Expandierbare polymere in partikelform |
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| GB2448468B (en) * | 2007-10-08 | 2009-09-30 | Gurit | Composite laminated article and manufacture thereof |
| ITMI20080823A1 (it) | 2008-05-07 | 2009-11-08 | Polimeri Europa Spa | Composizioni di polimeri vinilaromatici espansibili a migliorata capacita' di isolamento termico, procedimento per la loro preparazione ed articoli espansi da esse ottenuti |
| DE102008047594A1 (de) | 2008-09-17 | 2010-04-15 | H.C. Carbon Gmbh | Infrarotblocker enthaltende Formkörper aus Polystyrolhartschaum oder Polystyrolpartikelschaum |
| IT1392391B1 (it) | 2008-12-19 | 2012-03-02 | Polimeri Europa Spa | Composizioni di polimeri vinilaromatici espansibili a migliorata capacita' di isolamento termico, procedimento per la loro preparazione ed articoli espansi da loro ottenuti |
-
2009
- 2009-05-05 IT ITMI2009A000764A patent/IT1393962B1/it active
-
2010
- 2010-04-23 EP EP10724573.0A patent/EP2427514B1/en not_active Revoked
- 2010-04-23 ES ES10724573.0T patent/ES2650848T3/es active Active
- 2010-04-23 US US13/318,702 patent/US20120091388A1/en not_active Abandoned
- 2010-04-23 MX MX2011011766A patent/MX352618B/es active IP Right Grant
- 2010-04-23 PL PL10724573T patent/PL2427514T3/pl unknown
- 2010-04-23 BR BRPI1015127A patent/BRPI1015127A2/pt not_active Application Discontinuation
- 2010-04-23 JP JP2012509104A patent/JP5719352B2/ja active Active
- 2010-04-23 HU HUE10724573A patent/HUE035665T2/hu unknown
- 2010-04-23 CN CN201080022645.5A patent/CN102449044B/zh active Active
- 2010-04-23 RU RU2011144444/05A patent/RU2524711C2/ru active
- 2010-04-23 WO PCT/IB2010/000923 patent/WO2010128369A1/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| CN102449044A (zh) | 2012-05-09 |
| RU2524711C2 (ru) | 2014-08-10 |
| CN102449044B (zh) | 2015-07-22 |
| EP2427514B1 (en) | 2017-09-13 |
| ES2650848T3 (es) | 2018-01-22 |
| MX352618B (es) | 2017-11-30 |
| WO2010128369A1 (en) | 2010-11-11 |
| BRPI1015127A2 (pt) | 2016-04-12 |
| RU2011144444A (ru) | 2013-06-10 |
| ITMI20090764A1 (it) | 2010-11-06 |
| JP2012526170A (ja) | 2012-10-25 |
| EP2427514A1 (en) | 2012-03-14 |
| MX2011011766A (es) | 2012-04-19 |
| US20120091388A1 (en) | 2012-04-19 |
| HUE035665T2 (hu) | 2018-05-28 |
| PL2427514T3 (pl) | 2018-03-30 |
| IT1393962B1 (it) | 2012-05-17 |
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