JP2012526170A5 - - Google Patents
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- Publication number
- JP2012526170A5 JP2012526170A5 JP2012509104A JP2012509104A JP2012526170A5 JP 2012526170 A5 JP2012526170 A5 JP 2012526170A5 JP 2012509104 A JP2012509104 A JP 2012509104A JP 2012509104 A JP2012509104 A JP 2012509104A JP 2012526170 A5 JP2012526170 A5 JP 2012526170A5
- Authority
- JP
- Japan
- Prior art keywords
- range
- polymer
- weight
- vinyl aromatic
- mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920002554 vinyl polymer Polymers 0.000 claims 11
- 239000008187 granular material Substances 0.000 claims 10
- 239000000047 product Substances 0.000 claims 10
- 239000000654 additive Substances 0.000 claims 9
- 239000011324 bead Substances 0.000 claims 9
- 239000000203 mixture Substances 0.000 claims 9
- 239000004793 Polystyrene Substances 0.000 claims 8
- 230000000996 additive effect Effects 0.000 claims 8
- 229920001577 copolymer Polymers 0.000 claims 8
- 229920002223 polystyrene Polymers 0.000 claims 8
- 238000000034 method Methods 0.000 claims 7
- 229920000642 polymer Polymers 0.000 claims 7
- 229920001169 thermoplastic Polymers 0.000 claims 7
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims 6
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims 6
- 239000011159 matrix material Substances 0.000 claims 5
- 239000004604 Blowing Agent Substances 0.000 claims 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 4
- 239000000945 filler Substances 0.000 claims 4
- 229920002959 polymer blend Polymers 0.000 claims 4
- 230000009477 glass transition Effects 0.000 claims 3
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 claims 2
- 239000004721 Polyphenylene oxide Substances 0.000 claims 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims 2
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical group CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims 2
- 229910021383 artificial graphite Inorganic materials 0.000 claims 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims 2
- 230000031709 bromination Effects 0.000 claims 2
- 238000005893 bromination reaction Methods 0.000 claims 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims 2
- 239000006229 carbon black Substances 0.000 claims 2
- 230000001413 cellular effect Effects 0.000 claims 2
- 239000000571 coke Substances 0.000 claims 2
- 229910002804 graphite Inorganic materials 0.000 claims 2
- 239000010439 graphite Substances 0.000 claims 2
- 239000004615 ingredient Substances 0.000 claims 2
- 238000009413 insulation Methods 0.000 claims 2
- 229910021382 natural graphite Inorganic materials 0.000 claims 2
- 229920006380 polyphenylene oxide Polymers 0.000 claims 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 1
- 238000010521 absorption reaction Methods 0.000 claims 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims 1
- 239000007900 aqueous suspension Substances 0.000 claims 1
- 239000000440 bentonite Substances 0.000 claims 1
- 229910000278 bentonite Inorganic materials 0.000 claims 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims 1
- 239000000292 calcium oxide Substances 0.000 claims 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims 1
- 238000010276 construction Methods 0.000 claims 1
- 239000006260 foam Substances 0.000 claims 1
- 238000005187 foaming Methods 0.000 claims 1
- 229910010272 inorganic material Inorganic materials 0.000 claims 1
- 239000011147 inorganic material Substances 0.000 claims 1
- 238000002844 melting Methods 0.000 claims 1
- 230000008018 melting Effects 0.000 claims 1
- 239000000178 monomer Substances 0.000 claims 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims 1
- 230000000379 polymerizing effect Effects 0.000 claims 1
- 230000005855 radiation Effects 0.000 claims 1
- 150000004760 silicates Chemical class 0.000 claims 1
- 229910052814 silicon oxide Inorganic materials 0.000 claims 1
- 238000005245 sintering Methods 0.000 claims 1
- 238000001228 spectrum Methods 0.000 claims 1
- 230000003068 static effect Effects 0.000 claims 1
- 239000013589 supplement Substances 0.000 claims 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims 1
- 238000009827 uniform distribution Methods 0.000 claims 1
- 239000011787 zinc oxide Substances 0.000 claims 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITMI2009A000764 | 2009-05-05 | ||
| ITMI2009A000764A IT1393962B1 (it) | 2009-05-05 | 2009-05-05 | Articoli espansi con ottima resistenza allo irraggiamento solare e ottime proprieta' termoisolanti e meccaniche |
| PCT/IB2010/000923 WO2010128369A1 (en) | 2009-05-05 | 2010-04-23 | Expanded articles with excellent resistance to solar radiation and optimum thermoinsulating and mechanical properties |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2012526170A JP2012526170A (ja) | 2012-10-25 |
| JP2012526170A5 true JP2012526170A5 (enExample) | 2013-06-13 |
| JP5719352B2 JP5719352B2 (ja) | 2015-05-20 |
Family
ID=41258264
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2012509104A Active JP5719352B2 (ja) | 2009-05-05 | 2010-04-23 | 太陽放射に対する耐性が優れかつ断熱特性と機械的性質が最適な発泡製品 |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US20120091388A1 (enExample) |
| EP (1) | EP2427514B1 (enExample) |
| JP (1) | JP5719352B2 (enExample) |
| CN (1) | CN102449044B (enExample) |
| BR (1) | BRPI1015127A2 (enExample) |
| ES (1) | ES2650848T3 (enExample) |
| HU (1) | HUE035665T2 (enExample) |
| IT (1) | IT1393962B1 (enExample) |
| MX (1) | MX352618B (enExample) |
| PL (1) | PL2427514T3 (enExample) |
| RU (1) | RU2524711C2 (enExample) |
| WO (1) | WO2010128369A1 (enExample) |
Families Citing this family (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1395379B1 (it) | 2009-09-07 | 2012-09-14 | Polimeri Europa Spa | Procedimento per la preparazione di polimeri vinilaromatici espansibili a ridotta conducibilita' termica mediante polimerizzazione in sospensione |
| IT1401950B1 (it) * | 2010-09-21 | 2013-08-28 | Polimeri Europa Spa | Composizioni di (co)polimeri vinilaromatici espansibili autoestinguenti e procedimento per la loro preparazione. |
| CN102532957B (zh) * | 2011-12-13 | 2014-07-02 | 湛江市聚鑫新能源有限公司 | 一种导热绝缘填料及其制备方法 |
| ITMI20121808A1 (it) | 2012-10-24 | 2014-04-25 | Versalis Spa | Composizioni polimeriche concentrate di polimeri e/o copolimeri vinilaromatici |
| ITMI20121973A1 (it) * | 2012-11-20 | 2014-05-21 | Versalis Spa | Composizione polimerica autoestinguente |
| HRP20170728T1 (hr) | 2012-12-28 | 2017-09-22 | Total Research & Technology Feluy | Rastezljivi vinil aromatski polimeri koji sadrže čestice igličastog koksa |
| HUE046210T2 (hu) | 2012-12-28 | 2020-02-28 | Total Res & Technology Feluy | Polimodális szemcseméret eloszlású grafit szemcséket tartalmazó expandálható vinilaromás polimerek |
| JP6343485B2 (ja) * | 2014-05-09 | 2018-06-13 | 積水化成品工業株式会社 | ポリスチレン系発泡成形体及びその製造方法 |
| KR101575989B1 (ko) * | 2014-12-24 | 2015-12-09 | 고영신 | 팽창흑연을 이용한 경량화된 흡음내화 단열재 및 그 제조방법 |
| MA41342A (fr) | 2015-01-14 | 2017-11-21 | Synthos Sa | Procédé pour la production de granulés de polymère vinylique aromatique expansible ayant une conductivité thermique réduite |
| CA2973630A1 (en) | 2015-01-14 | 2016-07-21 | Synthos S.A. | Geopolymer composite and expandable vinyl aromatic polymer granulate and expanded vinyl aromatic polymer foam comprising the same |
| MA41344B1 (fr) * | 2015-01-14 | 2019-01-31 | Synthos Sa | Combinaison de silice et de graphite et son utilisation pour réduire la conductivité thermique d'une mousse de polymère aromatique vinylique |
| JP6735281B2 (ja) * | 2015-01-14 | 2020-08-05 | シントス エス．アー．Ｓｙｎｔｈｏｓ Ｓ．Ａ． | ペロブスカイト構造を有する鉱物のビニル芳香族ポリマーフォームでの使用 |
| CN104744843B (zh) * | 2015-03-31 | 2018-07-06 | 青岛欧克斯新型建材有限公司 | 一种绝热用石墨聚苯乙烯泡沫塑料挤塑板 |
| US10964620B2 (en) * | 2016-04-11 | 2021-03-30 | Sekisui Polymatech Co., Ltd. | Thermally conductive sheet |
| CN109312108A (zh) * | 2016-05-11 | 2019-02-05 | 欧文斯科宁知识产权资产有限公司 | 包含低水平溴化阻燃剂的聚合物泡沫及其制备方法 |
| IT201600071347A1 (it) | 2016-07-08 | 2018-01-08 | Versalis Spa | Composizioni espandibili contenenti polimeri vinil aromatici aventi proprietà autoestinguenti e migliorata processabilità |
| WO2018015490A1 (en) | 2016-07-20 | 2018-01-25 | Synthos S.A. | Process for the production of geopolymer or geopolymer composite |
| BR112019000605A2 (pt) * | 2016-07-20 | 2019-04-30 | Synthos S.A. | geopolímero modificado e compósito de geopolímero modificado e processo para a produção dos mesmos |
| AU2017300726B2 (en) | 2016-07-20 | 2021-12-02 | Synthos S.A. | Use of geopolymeric additive in combination with non-brominated flame retardant in polymer foams |
| KR102419948B1 (ko) * | 2016-10-10 | 2022-07-12 | 토탈 리서치 앤드 테크놀로지 펠루이 | 개선된 팽창성 비닐 방향족 중합체 |
| EP3523361A1 (en) | 2016-10-10 | 2019-08-14 | Total Research & Technology Feluy | Improved expandable vinyl aromatic polymers |
| US11834563B2 (en) | 2016-10-10 | 2023-12-05 | Totalenergies Onetech Belgium | Expandable vinyl aromatic polymers |
| WO2019092568A1 (en) * | 2017-11-10 | 2019-05-16 | 3M Innovative Properties Company | Roof coating composition, methods of use, and articles |
| IT201800020404A1 (it) * | 2018-12-20 | 2020-06-20 | Versalis Spa | Composizione polimerica espandibile e procedimento per la sua produzione |
| CN114341256A (zh) | 2019-09-04 | 2022-04-12 | 道达尔能源一技术比利时公司 | 具有改进的阻燃性的可膨胀乙烯基芳族聚合物 |
| CN114917852B (zh) * | 2022-06-28 | 2024-01-16 | 桂林电子科技大学 | 一种本体法连续生产石墨可发泡聚苯乙烯的方法 |
| CN117429133B (zh) * | 2023-10-23 | 2024-04-16 | 尤特森新材料集团有限公司 | 一种耐高低温的弹性隔热板及其制备工艺 |
Family Cites Families (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2658877A (en) | 1952-02-09 | 1953-11-10 | Dow Chemical Co | Self-extinguishing alkenylbenzene copolymer composition |
| US4233199A (en) | 1979-07-03 | 1980-11-11 | Visvaldis Abolins | Flame resistant thermoplastic compositions with well balanced physical properties |
| US4782098A (en) | 1987-06-12 | 1988-11-01 | General Electric, Co. | Expandable thermoplastic resin beads |
| US4786543A (en) * | 1987-10-06 | 1988-11-22 | Don Ferm | Ceiling tile of expanded polystyrene laminated with embossed vinyl sheet |
| DE3817631A1 (de) | 1988-05-25 | 1989-11-30 | Basf Ag | Expandierbare polymere in partikelform |
| EP0372343B1 (en) | 1988-11-25 | 2000-01-19 | The Dow Chemical Company | Polystyrene foam containing carbon black |
| DE69328628T2 (de) * | 1992-12-15 | 2001-02-01 | The Dow Chemical Co., Midland | Thermischen russ enthaltende kunststoffbauteile |
| US5679718A (en) * | 1995-04-27 | 1997-10-21 | The Dow Chemical Company | Microcellular foams containing an infrared attenuating agent and a method of using |
| DE19545097A1 (de) | 1995-12-04 | 1997-06-05 | Basf Ag | Schaumstoffplatten mit verminderter Wärmeleitfähigkeit |
| JPH10183011A (ja) | 1996-12-26 | 1998-07-07 | Sumitomo Bakelite Co Ltd | 熱膨張性黒鉛及び難燃性樹脂組成物 |
| DE19709119A1 (de) * | 1997-03-06 | 1998-09-10 | Basf Ag | Schaumstoffplatten mit verminderter Wärmeleitfähigkeit |
| DE10141778A1 (de) * | 2001-08-25 | 2003-03-06 | Basf Ag | Verfahren zur Herstellung von extrudierten offenzelligen Schaumstoffplatten |
| ITMI20012168A1 (it) | 2001-10-18 | 2003-04-18 | Enichem Spa | Polimeri vinilaromatici espandibili e procedimento per la loro preparazione |
| ITMI20020584A1 (it) * | 2002-03-20 | 2003-09-22 | Polimeri Europa Spa | Composizioni a base di polimeri vinilaromatici espandibili a migliorata espandibilita' |
| JP4111437B2 (ja) * | 2002-12-17 | 2008-07-02 | 株式会社ジェイエスピー | ポリスチレン系樹脂押出発泡板の製造方法及びポリスチレン系樹脂押出発泡板 |
| ITMI20030627A1 (it) * | 2003-03-31 | 2004-10-01 | Polimeri Europa Spa | Polimeri vinilaromatici espandibili e procedimento per la loro preparazione. |
| DE102004028768A1 (de) * | 2004-06-16 | 2005-12-29 | Basf Ag | Styrolpolymer-Partikelschaumstoffe mit verringerter Wärmeleitfähigkeit |
| DE102004034514A1 (de) | 2004-07-15 | 2006-02-16 | Basf Ag | Synergistische Flammschutzmischungen für Polystyrolschaumstoffe |
| DE102004058583A1 (de) | 2004-12-03 | 2006-06-14 | Basf Ag | Expandierbare Styrolpolymergranulate und Partikelschaumstoffe mit verringerter Wärmeleitfähigkeit |
| ITMI20050666A1 (it) | 2005-04-15 | 2006-10-16 | Polimeri Europa Spa | Procedimento per il migoioramento del potere isolante di polimeri vinilaromatici espansi e prodotti cosi'ottenuti |
| IT1366567B (it) * | 2005-10-18 | 2009-10-06 | Polimeri Europa Spa | Granulati espandibili a basemdi polimeri vinilaromatici dotati di migliorata espansibilita'e procedimento per la loro preparazione |
| US20070105967A1 (en) | 2005-11-08 | 2007-05-10 | Govind Rauniyar | Thermoplastic material |
| ITMI20062245A1 (it) | 2006-11-23 | 2008-05-24 | Polimeri Europa Spa | Polimeri vinilaromatici espandibili a migliorata capacita' di isolamento termico e procedimento per la loro preparazione |
| GB2448464A (en) * | 2007-01-04 | 2008-10-22 | Donald Campbell | Easy light charcoal barbecue |
| US20080242752A1 (en) * | 2007-03-28 | 2008-10-02 | Yadollah Delaviz | Polystyrene foams incorporating nanographite and HFC-134 |
| ITMI20071003A1 (it) * | 2007-05-18 | 2008-11-19 | Polimeri Europa Spa | Compositi a base di polimeri vinilaromatici aventi migliorate proprieta' di isolamento termico e procedimento per la loro preparazione |
| ITMI20071005A1 (it) * | 2007-05-18 | 2008-11-19 | Polimeri Europa Spa | Procedimento per la preparazione di granuli a base di polimeri termoplastici espandibili e relativo prodotto |
| GB2448468B (en) * | 2007-10-08 | 2009-09-30 | Gurit | Composite laminated article and manufacture thereof |
| ITMI20080823A1 (it) | 2008-05-07 | 2009-11-08 | Polimeri Europa Spa | Composizioni di polimeri vinilaromatici espansibili a migliorata capacita' di isolamento termico, procedimento per la loro preparazione ed articoli espansi da esse ottenuti |
| DE102008047594A1 (de) | 2008-09-17 | 2010-04-15 | H.C. Carbon Gmbh | Infrarotblocker enthaltende Formkörper aus Polystyrolhartschaum oder Polystyrolpartikelschaum |
| IT1392391B1 (it) | 2008-12-19 | 2012-03-02 | Polimeri Europa Spa | Composizioni di polimeri vinilaromatici espansibili a migliorata capacita' di isolamento termico, procedimento per la loro preparazione ed articoli espansi da loro ottenuti |
-
2009
- 2009-05-05 IT ITMI2009A000764A patent/IT1393962B1/it active
-
2010
- 2010-04-23 EP EP10724573.0A patent/EP2427514B1/en not_active Revoked
- 2010-04-23 ES ES10724573.0T patent/ES2650848T3/es active Active
- 2010-04-23 US US13/318,702 patent/US20120091388A1/en not_active Abandoned
- 2010-04-23 MX MX2011011766A patent/MX352618B/es active IP Right Grant
- 2010-04-23 PL PL10724573T patent/PL2427514T3/pl unknown
- 2010-04-23 BR BRPI1015127A patent/BRPI1015127A2/pt not_active Application Discontinuation
- 2010-04-23 JP JP2012509104A patent/JP5719352B2/ja active Active
- 2010-04-23 HU HUE10724573A patent/HUE035665T2/hu unknown
- 2010-04-23 CN CN201080022645.5A patent/CN102449044B/zh active Active
- 2010-04-23 RU RU2011144444/05A patent/RU2524711C2/ru active
- 2010-04-23 WO PCT/IB2010/000923 patent/WO2010128369A1/en not_active Ceased
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