JP5716763B2 - 回路接続材料及びそれを用いた回路部材の接続構造 - Google Patents
回路接続材料及びそれを用いた回路部材の接続構造 Download PDFInfo
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- JP5716763B2 JP5716763B2 JP2013020349A JP2013020349A JP5716763B2 JP 5716763 B2 JP5716763 B2 JP 5716763B2 JP 2013020349 A JP2013020349 A JP 2013020349A JP 2013020349 A JP2013020349 A JP 2013020349A JP 5716763 B2 JP5716763 B2 JP 5716763B2
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- SWAXTRYEYUTSAP-UHFFFAOYSA-N tert-butyl ethaneperoxoate Chemical compound CC(=O)OOC(C)(C)C SWAXTRYEYUTSAP-UHFFFAOYSA-N 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01R—ELECTRICALLY-CONDUCTIVE CONNECTIONS; STRUCTURAL ASSOCIATIONS OF A PLURALITY OF MUTUALLY-INSULATED ELECTRICAL CONNECTING ELEMENTS; COUPLING DEVICES; CURRENT COLLECTORS
- H01R11/00—Individual connecting elements providing two or more spaced connecting locations for conductive members which are, or may be, thereby interconnected, e.g. end pieces for wires or cables supported by the wire or cable and having means for facilitating electrical connection to some other wire, terminal, or conductive member, blocks of binding posts
- H01R11/01—Individual connecting elements providing two or more spaced connecting locations for conductive members which are, or may be, thereby interconnected, e.g. end pieces for wires or cables supported by the wire or cable and having means for facilitating electrical connection to some other wire, terminal, or conductive member, blocks of binding posts characterised by the form or arrangement of the conductive interconnection between the connecting locations
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J163/00—Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J9/00—Adhesives characterised by their physical nature or the effects produced, e.g. glue sticks
- C09J9/02—Electrically-conducting adhesives
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B5/00—Non-insulated conductors or conductive bodies characterised by their form
- H01B5/16—Non-insulated conductors or conductive bodies characterised by their form comprising conductive material in insulating or poorly conductive material, e.g. conductive rubber
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01R—ELECTRICALLY-CONDUCTIVE CONNECTIONS; STRUCTURAL ASSOCIATIONS OF A PLURALITY OF MUTUALLY-INSULATED ELECTRICAL CONNECTING ELEMENTS; COUPLING DEVICES; CURRENT COLLECTORS
- H01R13/00—Details of coupling devices of the kinds covered by groups H01R12/70 or H01R24/00 - H01R33/00
- H01R13/02—Contact members
- H01R13/03—Contact members characterised by the material, e.g. plating, or coating materials
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/02—Details
- H05K1/14—Structural association of two or more printed circuits
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/10—Apparatus or processes for manufacturing printed circuits in which conductive material is applied to the insulating support in such a manner as to form the desired conductive pattern
- H05K3/14—Apparatus or processes for manufacturing printed circuits in which conductive material is applied to the insulating support in such a manner as to form the desired conductive pattern using spraying techniques to apply the conductive material, e.g. vapour evaporation
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
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Description
導電粒子5は、ビッカース硬度300〜1000の金属からなる核体と、該核体の表面を被覆する貴金属からなる最表層とを有し、平均粒径が5〜20μmである。また、導電粒子5は、ニッケルからなる核体と、該核体の表面を被覆する貴金属からなる最表層とを有し、平均粒径が5〜20μmである。このような導電粒子は、回路電極の非導電性の被膜を貫通しやすく、接続抵抗の上昇を抑制しやすい。そのため、上記導電粒子を含有する回路接続材料を用いて、接続信頼性に優れる回路部材の接続構造を作製することができる。
樹脂層3は、遊離ラジカルを発生する硬化剤と、ラジカル重合性物質とを含有することが好ましい。言い換えると、回路接続材料1は、遊離ラジカルを発生する硬化剤と、ラジカル重合性物質とを含む接着剤組成物と、導電粒子5とを含有することが好ましい。回路接続材料1が加熱されたときにラジカル重合性物質の重合により樹脂層3において架橋構造が形成され、回路接続材料1の硬化物が形成される。この場合、回路接続材料1は、ラジカル硬化型の接着剤として機能する。
使用機器:日立L−6000型(日立製作所(株)製)
カラム:ゲルパックGL−R420+ゲルパックGL−R430+ゲルパックGL−R440(計3本)(日立化成工業(株)製)
溶離液:テトラヒドロフラン
測定温度:40℃
流量:1.75mL/分
検出器:L−3300RI(日立製作所(株)製)
(1−1)接着剤組成物を構成する各成分の準備
「パーヘキサ25O」:2,5−ジメチル−2,5−ジ(2−エチルヘキサノイルパーオキシ)ヘキサン(日本油脂製、商品名)
「UN5500」:ウレタンアクリレートオリゴマー(根上工業製、商品名)
「DCP−A」:ジシクロペンタジエン型ジアクリレート(東亞合成製、商品名)
「M−215」:イソシアヌル酸EO変成ジアクリレート(東亞合成製、商品名)
「P−2M」:2−メタクリロイロキシエチルアシッドホスフェート(共栄社化学製、商品名)
「HX3941HP−SS」:アニオン重合型潜在性硬化剤含有エポキシ樹脂(イミダゾール系マイクロカプセル型硬化剤を35質量%含有、旭化成ケミカルズ製、商品名)
「UR−800」:ポリエステルウレタン(東洋紡績製、商品名)
「EV40W」:エチレン−酢酸ビニル共重合体(三井・デュポンポリケミカル製、商品名)
「PKHC」:ビスフェノールA型フェノキシ樹脂(Mw45000、インケム・コーポレーション製、商品名)
「アクリルゴムA」:ブチルアクリレート40質量部−エチルアクリレート30質量部―アクリロニトリル30質量部―グリシジルメタクリレート3質量部の共重合体(重量平均分子量約85万)
「SH6040」:シランカップリング剤(γ−グリシドキシプロピルトリメトキシシラン、東レ・ダウコーニング・シリコーン製、商品名)、
「導電粒子A」として、平均粒径9μmのNi粒子からなる核体と、該核体に金めっきを施して形成された金からなる最表層とを有する導電粒子を準備した。また、「導電粒子B」として、平均粒径9μmのNi粒子からなる導電粒子を準備した。さらに、「導電粒子C」として、表面に多数の突起部を有する、平均粒径4μmのNi粒子からなる導電粒子を準備した。
「パーヘキサ25O」の50質量%炭化水素溶媒溶液8質量部(不揮発分換算で4質量部)、ラジカル重合性物質として、「UN5500」の50質量%トルエン溶液60質量部(不揮発分換算で30質量部)、「DCP−A」8質量部、「M−215」8質量部、「P−2M」2質量部、「UR−8200」の30質量%メチルエチルケトン/トルエン(=50/50)溶液を150質量部(不揮発分換算で45質量部)及び「EV40W」の20質量%トルエン溶液50質量部(不揮発分換算で10質量部)を配合し、更に、「導電粒子A」10質量部を配合した。この混合溶液をアプリケータでPETフィルム上に塗布し、70℃10分の熱風乾燥により、接着剤層の厚みが35μmであるフィルム状の回路接続材料を得た。
導電粒子Aの配合量を5質量部に変更した以外は、参考例1と同様にしてフィルム状の回路接続材料を得た。
「HX3941HP−SS」50質量部、「PKHC」の40質量%トルエン/酢酸エチル(=50/50)溶液37.5質量部(不揮発分換算で15質量部)、「アクリルゴムA」の10質量%トルエン/酢酸エチル(=50/50)溶液350質量部(不揮発分換算で35質量部)及び「SH6040」1質量部を配合し、更に、「導電粒子A」10質量部を配合した。この混合溶液をアプリケータでPETフィルム上に塗布し、70℃10分の熱風乾燥により、接着剤層の厚みが35μmであるフィルム状の回路接続材料を得た。
「導電粒子A」10質量部を「導電粒子B」10質量部に変更した以外は、参考例1と同様にして回路接続材料を得た。
「導電粒子A」10質量部を「導電粒子C」10質量部に変更した以外は、参考例1と同様にして回路接続材料を得た。
「導電粒子A」10質量部を「導電粒子C」5質量部に変更した以外は、参考例1と同様にして回路接続材料を得た。
「導電粒子A」10質量部を「導電粒子B」10質量部に変更した以外は、実施例3と同様にして回路接続材料を得た。
「導電粒子A」10質量部を「導電粒子C」10質量部に変更した以外は、実施例3と同様にして回路接続材料を得た。
(2−1)OSP処理されたプリント配線板(PWB)の作製
ガラス・エポキシ多層プリント配線板上に、ライン幅100μm、ピッチ400μm、厚み35μmの銅回路電極を形成させた(これを以下「PWB」という)。更にPWBの銅回路電極表面に、ベンズイミダゾール化合物(四国化成(株)製、商品名「タフエース」)を用いてOSP処理をし、厚み0.10〜0.32μmのベンズイミダゾール系樹脂錯体の被膜を形成させた(これを以下「OSP−PWB」という)。
厚み25μmのポリイミドフィルム上に、ライン幅100μm、ピッチ400μm、厚み18μmの銅回路電極が直接形成されたフレキシブルプリント配線板(これを以下「FPC」という)を用意した。これに上と同様にして、OSP処理を施し、厚み0.10〜0.32μmのベンズイミダゾール系樹脂錯体の被膜を形成させた(これを以下「OSP−FPC」という)。
OSP−PWB上に、上記のフィルム状の回路接続材料の接着面を貼り付けた後、70℃、1MPaで2秒間加熱及び加圧して仮接続し、その後、PETフィルムを剥離した。次に、OSP−FPCの回路電極とOSP−PWBの回路電極とが向かい合うように位置合わせした後、160℃、4MPaで6秒間加熱及び加圧した。FPCとPWBとの基板間の幅は2mmであった。
(3−1)接続抵抗の測定
作製した接続構造の回路接続部を含む回路間の抵抗値を、デジタルマルチメータを用いて2端子法で測定した。接続抵抗の測定は、接続直後、85℃85%RHの恒温恒湿槽中に1000時間保持する高温高湿処理を行った後、及び、−40℃〜+100℃の熱衝撃試験1000サイクル処理を行った後にそれぞれ測定した。結果を表3に示す。
Claims (2)
- 第一の回路基板の主面上に第一の回路電極が形成された第一の回路部材と、
第二の回路基板の主面上に第二の回路電極が形成され、前記第二の回路電極が前記第一の回路電極と対向配置されるように配置された第二の回路部材と、
前記第一の回路基板と前記第二の回路基板との間に設けられ、前記第一及び前記第二の回路電極が電気的に接続されるように前記第一の回路部材と前記第二の回路部材とを接続する回路接続部と、
を備えた回路部材の接続構造であって、
前記回路接続部が、
接着剤組成物と、導電粒子とを含有し、前記導電粒子は、ビッカース硬度300〜1000の金属からなる核体と、該核体の表面を被覆する貴金属からなる最表層とを有し、平均粒径が8〜20μmであり、前記接着剤組成物が、エポキシ樹脂と、潜在性硬化剤とを含む、回路接続材料の硬化物であり、
前記第一及び前記第二の回路電極のうち少なくとも一方が、イミダゾール化合物から形成される被膜を有する、回路部材の接続構造。 - 第一の回路基板の主面上に第一の回路電極が形成された第一の回路部材と、
第二の回路基板の主面上に第二の回路電極が形成され、前記第二の回路電極が前記第一の回路電極と対向配置されるように配置された第二の回路部材と、
前記第一の回路基板と前記第二の回路基板との間に設けられ、前記第一及び前記第二の回路電極が電気的に接続されるように前記第一の回路部材と前記第二の回路部材とを接続する回路接続部と、
を備えた回路部材の接続構造であって、
前記回路接続部が、
接着剤組成物と、導電粒子とを含有し、前記導電粒子は、ニッケルからなる核体と、該核体の表面を被覆する貴金属からなる最表層とを有し、平均粒径が8〜20μmであり、前記接着剤組成物が、エポキシ樹脂と、潜在性硬化剤とを含む、回路接続材料の硬化物であり、
前記第一及び前記第二の回路電極のうち少なくとも一方が、イミダゾール化合物から形成される被膜を有する、回路部材の接続構造。
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BR112012011692B1 (pt) | 2020-11-17 |
KR101342255B1 (ko) | 2013-12-16 |
BR112012011692A2 (ja) | 2018-03-27 |
WO2011059084A1 (ja) | 2011-05-19 |
TWI494402B (zh) | 2015-08-01 |
JP5518747B2 (ja) | 2014-06-11 |
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