JP5656826B2 - メタン及びメタン含有混合物を脱水素芳香族化するための触媒 - Google Patents

メタン及びメタン含有混合物を脱水素芳香族化するための触媒 Download PDF

Info

Publication number
JP5656826B2
JP5656826B2 JP2011503431A JP2011503431A JP5656826B2 JP 5656826 B2 JP5656826 B2 JP 5656826B2 JP 2011503431 A JP2011503431 A JP 2011503431A JP 2011503431 A JP2011503431 A JP 2011503431A JP 5656826 B2 JP5656826 B2 JP 5656826B2
Authority
JP
Japan
Prior art keywords
catalyst
ammonium
zeolite
group
zsm
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP2011503431A
Other languages
English (en)
Japanese (ja)
Other versions
JP2011518660A5 (https=
JP2011518660A (ja
Inventor
キースリッヒ フランク
キースリッヒ フランク
コエーリョ ツォウ ジョアナ
コエーリョ ツォウ ジョアナ
イルマッツ ビルジ
イルマッツ ビルジ
アーレンス セバスティアン
アーレンス セバスティアン
トーマス　ハイデマン
ハイデマン トーマス
ヴィル ヴェロニカ
ヴィル ヴェロニカ
ベヒトルト クリスティアン
ベヒトルト クリスティアン
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Publication of JP2011518660A publication Critical patent/JP2011518660A/ja
Publication of JP2011518660A5 publication Critical patent/JP2011518660A5/ja
Application granted granted Critical
Publication of JP5656826B2 publication Critical patent/JP5656826B2/ja
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/48—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing arsenic, antimony, bismuth, vanadium, niobium tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/78—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J29/7876—MWW-type, e.g. MCM-22, ERB-1, ITQ-1, PSH-3 or SSZ-25
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/76—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/16—After treatment, characterised by the effect to be obtained to increase the Si/Al ratio; Dealumination
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C07C2529/48—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11 containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
JP2011503431A 2008-04-08 2009-04-08 メタン及びメタン含有混合物を脱水素芳香族化するための触媒 Expired - Fee Related JP5656826B2 (ja)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
EP08154195.5 2008-04-08
EP08154195 2008-04-08
EP08172159.9 2008-12-18
EP08172159 2008-12-18
PCT/EP2009/054201 WO2009124960A1 (de) 2008-04-08 2009-04-08 Katalysator zur dehydroaromatisierung von methan und methanhaltigen gemischen

Publications (3)

Publication Number Publication Date
JP2011518660A JP2011518660A (ja) 2011-06-30
JP2011518660A5 JP2011518660A5 (https=) 2012-06-07
JP5656826B2 true JP5656826B2 (ja) 2015-01-21

Family

ID=40791629

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2011503431A Expired - Fee Related JP5656826B2 (ja) 2008-04-08 2009-04-08 メタン及びメタン含有混合物を脱水素芳香族化するための触媒

Country Status (4)

Country Link
US (1) US8742189B2 (https=)
EP (1) EP2276566A1 (https=)
JP (1) JP5656826B2 (https=)
WO (1) WO2009124960A1 (https=)

Families Citing this family (46)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010057905A1 (de) 2008-11-19 2010-05-27 Basf Se Oligomerisierung von olefinen
DE102008063308B4 (de) 2008-12-29 2013-03-07 Basf Se Verfahren zur Herstellung von Toluylendiamin durch Hydrierung von Dinitrotoluol
WO2010099649A1 (en) 2009-03-03 2010-09-10 Basf Se Process for preparation of pillared silicates
KR20120022756A (ko) 2009-04-06 2012-03-12 바스프 에스이 수소를 전기화학적으로 제거하고 그 수소를 전기화학적으로 물로 전환시키면서 천연 가스를 방향족화합물로 전환시키는 방법
PL2417058T5 (pl) 2009-04-06 2021-12-13 Basf Se Sposób elektrochemicznego oddzielania wodoru z mieszaniny reakcyjnej
EP2417059B1 (de) 2009-04-06 2014-12-10 Basf Se Verfahren zur umsetzung von erdgas zu aromaten mit elektrochemischer abtrennung von wasserstoff
US8487152B2 (en) 2009-04-06 2013-07-16 Basf Se Process for converting natural gas to aromatics with electrochemical removal of hydrogen to generate electrical power and obtain hydrogen
PT2451770E (pt) 2009-07-10 2015-03-04 Basf Se Processo para a aminação direta de hidrocarbonetos em amino-hidrocarbonetos com a separação eletroquímica de hidrogénio e a transformação eletroquímica do hidrogénio em água
CN102548952B (zh) 2009-07-10 2014-05-14 巴斯夫欧洲公司 在电化学分离氢气的情况下将烃直接胺化成氨基烃的方法
US8796496B2 (en) 2009-09-03 2014-08-05 Basf Se Process for preparing benzene from methane
CN102648051B (zh) * 2009-10-08 2016-05-18 巴斯夫欧洲公司 生产Si键合流化床催化剂的方法
KR101855534B1 (ko) 2009-12-18 2018-05-04 바스프 에스이 철 함유 제올라이트, 철 함유 제올라이트의 제조 방법 및 질소 산화물의 촉매 환원 방법
SG185117A1 (en) * 2010-05-12 2012-12-28 Shell Int Research Methane aromatization catalyst, method of making and method of using the catalyst
US9580660B2 (en) * 2010-06-18 2017-02-28 The Texas A&M University System Deoxygenation of biomass derived oxygenates to hydrocarbons via direct methane intervention
JP2012012340A (ja) * 2010-07-01 2012-01-19 Meidensha Corp 芳香族炭化水素製造方法
BR112013018701A2 (pt) * 2011-01-26 2016-10-25 Shell Int Research catalisador de aromatização de metano, e, processos para preparar um catalisador de aromatização de metano e para produzir hidrocarbonetos aromáticos
CA3092028C (en) 2012-01-13 2022-08-30 Lummus Technology Llc Process for separating hydrocarbon compounds
US9969660B2 (en) 2012-07-09 2018-05-15 Siluria Technologies, Inc. Natural gas processing and systems
WO2014089479A1 (en) 2012-12-07 2014-06-12 Siluria Technologies, Inc. Integrated processes and systems for conversion of methane to multiple higher hydrocarbon products
WO2014181241A1 (en) * 2013-05-06 2014-11-13 Saudi Basic Industries Corporation Promoted molybdenum-based supported catalyst composition for high selectivity for converting by methane to an aromatic compound
US10047020B2 (en) 2013-11-27 2018-08-14 Siluria Technologies, Inc. Reactors and systems for oxidative coupling of methane
EP3092286A4 (en) 2014-01-08 2017-08-09 Siluria Technologies, Inc. Ethylene-to-liquids systems and methods
US10377682B2 (en) 2014-01-09 2019-08-13 Siluria Technologies, Inc. Reactors and systems for oxidative coupling of methane
CA2935946C (en) 2014-01-09 2022-05-03 Siluria Technologies, Inc. Oxidative coupling of methane implementations for olefin production
US9334204B1 (en) 2015-03-17 2016-05-10 Siluria Technologies, Inc. Efficient oxidative coupling of methane processes and systems
US10793490B2 (en) 2015-03-17 2020-10-06 Lummus Technology Llc Oxidative coupling of methane methods and systems
US20160289143A1 (en) 2015-04-01 2016-10-06 Siluria Technologies, Inc. Advanced oxidative coupling of methane
WO2016196517A1 (en) * 2015-05-29 2016-12-08 The Board Of Regents For Oklahoma State University Synergistic co-pyrolysis of biomass and methane for hydrocarbon fuels and chemicals production
US9328297B1 (en) 2015-06-16 2016-05-03 Siluria Technologies, Inc. Ethylene-to-liquids systems and methods
CN105016947B (zh) * 2015-07-15 2017-01-18 河南师范大学 羧甲基纤维素铜（ii）催化端基炔类化合物合成1,3‑丁二炔类化合物的方法
CN106423254B (zh) * 2015-08-12 2019-05-14 中国石油化工股份有限公司 由乙酸和苯合成乙苯的催化剂
CN106423257B (zh) * 2015-08-12 2019-06-11 中国石油化工股份有限公司 由乙酸乙酯和苯合成乙苯的催化剂
US9796643B2 (en) 2015-09-25 2017-10-24 Exxonmobil Chemical Patents Inc. Hydrocarbon dehydrocyclization in the presence of carbon dioxide
EP3786138A1 (en) 2015-10-16 2021-03-03 Lummus Technology LLC Oxidative coupling of methane
WO2017097741A1 (en) * 2015-12-10 2017-06-15 Philips Lighting Holding B.V. Dynamic light effect based on an image
EP4071131A1 (en) 2016-04-13 2022-10-12 Lummus Technology LLC Apparatus and method for exchanging heat
CN109310999A (zh) * 2016-04-25 2019-02-05 埃克森美孚化学专利公司 催化芳构化
WO2018118105A1 (en) 2016-12-19 2018-06-28 Siluria Technologies, Inc. Methods and systems for performing chemical separations
KR102524765B1 (ko) 2017-02-16 2023-04-25 엑손모빌 테크놀로지 앤드 엔지니어링 컴퍼니 경질 파라핀 전환을 위한 고정층 방사류 반응기
KR20200034961A (ko) 2017-05-23 2020-04-01 루머스 테크놀로지 엘엘씨 메탄의 산화적 커플링 공정의 통합
EP3649097A4 (en) 2017-07-07 2021-03-24 Lummus Technology LLC SYSTEMS AND PROCESSES FOR THE OXIDATIVE COUPLING OF METHANE
KR102496526B1 (ko) * 2017-09-20 2023-02-03 고려대학교 산학협력단 메탄 및 c2 내지 c4 알칸 화합물의 공동 탈수소방향족화 반응에 의한 방향족 화합물 제조용 이종금속 담지 촉매 및 이를 이용한 방향족 화합물의 제조방법
CN111151292B (zh) * 2020-01-13 2021-03-05 中国科学院山西煤炭化学研究所 一种芳构化催化剂及其制备方法与应用
US12227466B2 (en) 2021-08-31 2025-02-18 Lummus Technology Llc Methods and systems for performing oxidative coupling of methane
CN117983261B (zh) * 2022-11-02 2026-02-24 中国科学院大连化学物理研究所 一种用于环己烷脱氢制备苯的催化剂及其制备方法和应用
WO2024243137A1 (en) * 2023-05-19 2024-11-28 Surendhran Roshaan Process for encapsulation of zeolite encapsulated transition metal particles

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4259537A (en) 1980-03-17 1981-03-31 Mobil Oil Corporation Shape selective reactions with group via modified zeolite catalysts
EP1307415A2 (en) * 2000-07-27 2003-05-07 Conoco Inc. Catalyst and process for aromatic hydrocarbons production from methane
AU2003278771A1 (en) * 2003-09-08 2005-04-21 Uop Llc A process for preparing a catalyst with a non-acidic binder and a process for using the catalyst to produce aromatics
JP4790356B2 (ja) * 2005-09-16 2011-10-12 勝 市川 低級炭化水素改質触媒
US7659437B2 (en) * 2006-04-21 2010-02-09 Exxonmobil Chemical Patents Inc. Process for methane conversion
DE112009000581A5 (de) 2008-04-08 2011-02-17 Basf Se Katalysator zur Dehydroaromatisierung von aliphatischen Kohlenwasserstoffen mit siliziumhaltigem Bindemittel
DE102008063308B4 (de) 2008-12-29 2013-03-07 Basf Se Verfahren zur Herstellung von Toluylendiamin durch Hydrierung von Dinitrotoluol

Also Published As

Publication number Publication date
WO2009124960A1 (de) 2009-10-15
US8742189B2 (en) 2014-06-03
JP2011518660A (ja) 2011-06-30
EP2276566A1 (de) 2011-01-26
US20110124933A1 (en) 2011-05-26

Similar Documents

Publication Publication Date Title
JP5656826B2 (ja) メタン及びメタン含有混合物を脱水素芳香族化するための触媒
JP5535192B2 (ja) メタン含有混合物を相応する貴金属不含触媒の再生下に脱水素環化する方法
CN114025875B (zh) 用于热解油改质的中孔沸石多功能催化剂的制备方法
Zhang et al. Ethane aromatization and evolution of carbon deposits over nanosized and microsized Zn/ZSM-5 catalysts
EA018593B1 (ru) Способ получения модифицированных молекулярных сит
JP5499669B2 (ja) 低級炭化水素及び芳香族化合物の製造方法及び製造触媒
WO2018002012A1 (en) Preparation of a zsm-5-based catalyst; use in ethylbenzene dealkylation process
WO2009124902A1 (de) Katalysator zur dehydroaromatisierung von aliphatischen kohlenwasserstoffen mit siliziumhaltigem bindemittel
RU2753868C2 (ru) Алкилароматический катализатор конверсии
RU2751703C1 (ru) Цеолитный катализатор дегидрирования пропана и способ получения пропилена с использованием этого катализатора
KR20150135306A (ko) 유동층 내 제올라이트 촉매의 부동태화
WO2012002269A1 (ja) 芳香族炭化水素製造方法
JP6259455B2 (ja) 金属含有ゼオライト触媒を用いた不飽和炭化水素類の製造方法
JP7181785B2 (ja) 酸化亜鉛修飾ｍｆｉ型ゼオライト及びそれを用いた芳香族化合物の製造方法
CN115501901B (zh) 一种富芳烃油脱烯烃催化剂及制备方法和应用
CN108970636B (zh) 一种苯烷基化催化剂的制备方法
WO2014027670A1 (ja) 触媒組成物、および該触媒組成物を用いた芳香族炭化水素の製造方法
RU2585289C1 (ru) Катализатор ароматизации метана, способ его получения и способ конверсии метана с получением ароматических углеводородов
CN114713270B (zh) 一种轻油型加氢裂化催化剂及其制备方法、硫化型加氢裂化催化剂
JP2025067820A (ja) プロピレン製造用触媒
CN117258810A (zh) 脱除烯烃及含氧化合物催化剂、制备方法及加氢精制方法
WO2013150845A1 (ja) 低級炭化水素芳香族化触媒及び低級炭化水素芳香族化触媒の製造方法
WO2017031098A1 (en) Alkylaromatic conversion catalyst

Legal Events

Date Code Title Description
A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20120406

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20120406

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20130917

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20131213

A602 Written permission of extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A602

Effective date: 20131220

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20140107

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20140526

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20140813

A602 Written permission of extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A602

Effective date: 20140820

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20140916

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20141027

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20141125

R150 Certificate of patent or registration of utility model

Ref document number: 5656826

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

LAPS Cancellation because of no payment of annual fees