JP5634512B2 - 着色された焼結ジルコニア - Google Patents
着色された焼結ジルコニア Download PDFInfo
- Publication number
- JP5634512B2 JP5634512B2 JP2012516966A JP2012516966A JP5634512B2 JP 5634512 B2 JP5634512 B2 JP 5634512B2 JP 2012516966 A JP2012516966 A JP 2012516966A JP 2012516966 A JP2012516966 A JP 2012516966A JP 5634512 B2 JP5634512 B2 JP 5634512B2
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- JP
- Japan
- Prior art keywords
- mixture
- iron
- cobalt
- chromium
- perovskite structure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 title claims description 114
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 377
- 239000000203 mixture Substances 0.000 claims description 368
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 194
- 239000011651 chromium Substances 0.000 claims description 188
- 229910052742 iron Inorganic materials 0.000 claims description 133
- 239000011572 manganese Substances 0.000 claims description 120
- 239000010941 cobalt Substances 0.000 claims description 102
- 229910017052 cobalt Inorganic materials 0.000 claims description 102
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 102
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 101
- 229910052804 chromium Inorganic materials 0.000 claims description 101
- 239000002245 particle Substances 0.000 claims description 91
- 229910052759 nickel Inorganic materials 0.000 claims description 68
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 53
- 229910052746 lanthanum Inorganic materials 0.000 claims description 53
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims description 53
- 229910052748 manganese Inorganic materials 0.000 claims description 53
- 239000010936 titanium Substances 0.000 claims description 52
- 239000002243 precursor Substances 0.000 claims description 51
- 239000011575 calcium Substances 0.000 claims description 47
- 238000005245 sintering Methods 0.000 claims description 42
- 239000003381 stabilizer Substances 0.000 claims description 42
- 239000000843 powder Substances 0.000 claims description 41
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 33
- 229910052719 titanium Inorganic materials 0.000 claims description 33
- 229910052684 Cerium Inorganic materials 0.000 claims description 32
- 229910052777 Praseodymium Inorganic materials 0.000 claims description 32
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims description 32
- PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 claims description 32
- 229910052797 bismuth Inorganic materials 0.000 claims description 31
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims description 31
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 28
- 229910052791 calcium Inorganic materials 0.000 claims description 28
- 239000010949 copper Substances 0.000 claims description 28
- 229910052712 strontium Inorganic materials 0.000 claims description 28
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims description 28
- 239000000654 additive Substances 0.000 claims description 25
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 24
- 238000000034 method Methods 0.000 claims description 24
- 239000007858 starting material Substances 0.000 claims description 23
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 22
- 229910052779 Neodymium Inorganic materials 0.000 claims description 22
- 229910052788 barium Inorganic materials 0.000 claims description 22
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 22
- 229910052802 copper Inorganic materials 0.000 claims description 22
- 239000011777 magnesium Substances 0.000 claims description 22
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 claims description 22
- 238000004519 manufacturing process Methods 0.000 claims description 20
- 230000000996 additive effect Effects 0.000 claims description 18
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 13
- 229910052749 magnesium Inorganic materials 0.000 claims description 13
- 239000010955 niobium Substances 0.000 claims description 13
- 238000004458 analytical method Methods 0.000 claims description 12
- 238000002441 X-ray diffraction Methods 0.000 claims description 10
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 9
- 238000010586 diagram Methods 0.000 claims description 8
- 239000012535 impurity Substances 0.000 claims description 8
- 229910052758 niobium Inorganic materials 0.000 claims description 8
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 8
- 239000000126 substance Substances 0.000 claims description 8
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 6
- 229910052750 molybdenum Inorganic materials 0.000 claims description 6
- 239000011733 molybdenum Substances 0.000 claims description 6
- 239000010937 tungsten Substances 0.000 claims description 6
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 6
- 229910052721 tungsten Inorganic materials 0.000 claims description 6
- 229910052720 vanadium Inorganic materials 0.000 claims description 6
- 239000000919 ceramic Substances 0.000 claims description 5
- 229910052861 titanite Inorganic materials 0.000 claims description 5
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 4
- RKTYLMNFRDHKIL-UHFFFAOYSA-N copper;5,10,15,20-tetraphenylporphyrin-22,24-diide Chemical compound [Cu+2].C1=CC(C(=C2C=CC([N-]2)=C(C=2C=CC=CC=2)C=2C=CC(N=2)=C(C=2C=CC=CC=2)C2=CC=C3[N-]2)C=2C=CC=CC=2)=NC1=C3C1=CC=CC=C1 RKTYLMNFRDHKIL-UHFFFAOYSA-N 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 239000002994 raw material Substances 0.000 claims description 4
- -1 and Chemical compound 0.000 claims description 3
- 238000004806 packaging method and process Methods 0.000 claims description 3
- XLOMVQKBTHCTTD-UHFFFAOYSA-N zinc oxide Inorganic materials [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 3
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims 2
- 238000005034 decoration Methods 0.000 claims 1
- 230000003647 oxidation Effects 0.000 claims 1
- 238000007254 oxidation reaction Methods 0.000 claims 1
- 239000012071 phase Substances 0.000 description 26
- 239000000047 product Substances 0.000 description 10
- 150000001875 compounds Chemical class 0.000 description 7
- 239000011872 intimate mixture Substances 0.000 description 7
- YMVZSICZWDQCMV-UHFFFAOYSA-N [O-2].[Mn+2].[Sr+2].[La+3] Chemical compound [O-2].[Mn+2].[Sr+2].[La+3] YMVZSICZWDQCMV-UHFFFAOYSA-N 0.000 description 6
- 238000005498 polishing Methods 0.000 description 6
- 239000007921 spray Substances 0.000 description 6
- 229910002076 stabilized zirconia Inorganic materials 0.000 description 6
- 238000000889 atomisation Methods 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 238000005259 measurement Methods 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 239000002202 Polyethylene glycol Substances 0.000 description 4
- 239000004372 Polyvinyl alcohol Substances 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 238000000227 grinding Methods 0.000 description 4
- 239000000049 pigment Substances 0.000 description 4
- 229920001223 polyethylene glycol Polymers 0.000 description 4
- 229920002451 polyvinyl alcohol Polymers 0.000 description 4
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 4
- 238000004438 BET method Methods 0.000 description 3
- 239000011324 bead Substances 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000007906 compression Methods 0.000 description 3
- 230000006835 compression Effects 0.000 description 3
- 239000010432 diamond Substances 0.000 description 3
- 229910003460 diamond Inorganic materials 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 229910000449 hafnium oxide Inorganic materials 0.000 description 3
- WIHZLLGSGQNAGK-UHFFFAOYSA-N hafnium(4+);oxygen(2-) Chemical compound [O-2].[O-2].[Hf+4] WIHZLLGSGQNAGK-UHFFFAOYSA-N 0.000 description 3
- 239000000314 lubricant Substances 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- 239000004925 Acrylic resin Substances 0.000 description 2
- 229920000178 Acrylic resin Polymers 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 229910002204 La0.8Sr0.2MnO3 Inorganic materials 0.000 description 2
- XGPJPLXOIJRLJN-UHFFFAOYSA-N [Mn].[Sr].[La] Chemical compound [Mn].[Sr].[La] XGPJPLXOIJRLJN-UHFFFAOYSA-N 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- 238000000975 co-precipitation Methods 0.000 description 2
- FJIZIYBZVDPQGR-UHFFFAOYSA-N cobalt(2+) iron(2+) lanthanum(3+) manganese(2+) oxygen(2-) Chemical compound [O-2].[Mn+2].[Fe+2].[Co+2].[La+3] FJIZIYBZVDPQGR-UHFFFAOYSA-N 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 238000002149 energy-dispersive X-ray emission spectroscopy Methods 0.000 description 2
- 238000001513 hot isostatic pressing Methods 0.000 description 2
- 238000007731 hot pressing Methods 0.000 description 2
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 2
- 229910052738 indium Inorganic materials 0.000 description 2
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 150000001247 metal acetylides Chemical class 0.000 description 2
- 239000006199 nebulizer Substances 0.000 description 2
- 150000004767 nitrides Chemical class 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 238000003921 particle size analysis Methods 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 238000004062 sedimentation Methods 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 230000003746 surface roughness Effects 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- MOMKYJPSVWEWPM-UHFFFAOYSA-N 4-(chloromethyl)-2-(4-methylphenyl)-1,3-thiazole Chemical compound C1=CC(C)=CC=C1C1=NC(CCl)=CS1 MOMKYJPSVWEWPM-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 101100496858 Mus musculus Colec12 gene Proteins 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- AUFVVJFBLFWLJX-UHFFFAOYSA-N [Mn].[La] Chemical compound [Mn].[La] AUFVVJFBLFWLJX-UHFFFAOYSA-N 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 230000001174 ascending effect Effects 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 229910052729 chemical element Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- LJAOOBNHPFKCDR-UHFFFAOYSA-K chromium(3+) trichloride hexahydrate Chemical compound O.O.O.O.O.O.[Cl-].[Cl-].[Cl-].[Cr+3] LJAOOBNHPFKCDR-UHFFFAOYSA-K 0.000 description 1
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 1
- QGUAJWGNOXCYJF-UHFFFAOYSA-N cobalt dinitrate hexahydrate Chemical compound O.O.O.O.O.O.[Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O QGUAJWGNOXCYJF-UHFFFAOYSA-N 0.000 description 1
- 229910001981 cobalt nitrate Inorganic materials 0.000 description 1
- 229910000428 cobalt oxide Inorganic materials 0.000 description 1
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 1
- 238000009694 cold isostatic pressing Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000002447 crystallographic data Methods 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 238000009616 inductively coupled plasma Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- QZRHHEURPZONJU-UHFFFAOYSA-N iron(2+) dinitrate nonahydrate Chemical compound O.O.O.O.O.O.O.O.O.[Fe+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O QZRHHEURPZONJU-UHFFFAOYSA-N 0.000 description 1
- MVFCKEFYUDZOCX-UHFFFAOYSA-N iron(2+);dinitrate Chemical compound [Fe+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MVFCKEFYUDZOCX-UHFFFAOYSA-N 0.000 description 1
- FYDKNKUEBJQCCN-UHFFFAOYSA-N lanthanum(3+);trinitrate Chemical compound [La+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O FYDKNKUEBJQCCN-UHFFFAOYSA-N 0.000 description 1
- HVMFKXBHFRRAAD-UHFFFAOYSA-N lanthanum(3+);trinitrate;hydrate Chemical compound O.[La+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O HVMFKXBHFRRAAD-UHFFFAOYSA-N 0.000 description 1
- MIVBAHRSNUNMPP-UHFFFAOYSA-N manganese(2+);dinitrate Chemical compound [Mn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MIVBAHRSNUNMPP-UHFFFAOYSA-N 0.000 description 1
- HBTFASPVVFSRRI-UHFFFAOYSA-N manganese(2+);dinitrate;hydrate Chemical compound O.[Mn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O HBTFASPVVFSRRI-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 238000013001 point bending Methods 0.000 description 1
- LXXCECZPOWZKLC-UHFFFAOYSA-N praseodymium(3+);trinitrate;hexahydrate Chemical compound O.O.O.O.O.O.[Pr+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O LXXCECZPOWZKLC-UHFFFAOYSA-N 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 238000007569 slipcasting Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 235000019983 sodium metaphosphate Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000003746 solid phase reaction Methods 0.000 description 1
- 238000010532 solid phase synthesis reaction Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000011029 spinel Substances 0.000 description 1
- 229910052596 spinel Inorganic materials 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 229940047908 strontium chloride hexahydrate Drugs 0.000 description 1
- AMGRXJSJSONEEG-UHFFFAOYSA-L strontium dichloride hexahydrate Chemical compound O.O.O.O.O.O.Cl[Sr]Cl AMGRXJSJSONEEG-UHFFFAOYSA-L 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- 238000002604 ultrasonography Methods 0.000 description 1
- 238000004876 x-ray fluorescence Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/48—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on zirconium or hafnium oxides, zirconates, zircon or hafnates
- C04B35/486—Fine ceramics
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/10—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on aluminium oxide
- C04B35/111—Fine ceramics
- C04B35/117—Composites
- C04B35/119—Composites with zirconium oxide
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/46—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on titanium oxides or titanates
- C04B35/462—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on titanium oxides or titanates based on titanates
- C04B35/478—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on titanium oxides or titanates based on titanates based on aluminium titanates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/48—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on zirconium or hafnium oxides, zirconates, zircon or hafnates
- C04B35/482—Refractories from grain sized mixtures
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
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- C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
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- C04B2235/5445—Particle size related information expressed by the size of the particles or aggregates thereof submicron sized, i.e. from 0,1 to 1 micron
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
- C04B2235/963—Surface properties, e.g. surface roughness
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
- C04B2235/9646—Optical properties
- C04B2235/9661—Colour
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- G—PHYSICS
- G04—HOROLOGY
- G04B—MECHANICALLY-DRIVEN CLOCKS OR WATCHES; MECHANICAL PARTS OF CLOCKS OR WATCHES IN GENERAL; TIME PIECES USING THE POSITION OF THE SUN, MOON OR STARS
- G04B37/00—Cases
- G04B37/22—Materials or processes of manufacturing pocket watch or wrist watch cases
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- G—PHYSICS
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- G04B—MECHANICALLY-DRIVEN CLOCKS OR WATCHES; MECHANICAL PARTS OF CLOCKS OR WATCHES IN GENERAL; TIME PIECES USING THE POSITION OF THE SUN, MOON OR STARS
- G04B45/00—Time pieces of which the indicating means or cases provoke special effects, e.g. aesthetic effects
- G04B45/0015—Light-, colour-, line- or spot-effects caused by or on stationary parts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24355—Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
- Y10T428/24372—Particulate matter
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
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- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Composite Materials (AREA)
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Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
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| FR0954475 | 2009-06-30 | ||
| FR0954475A FR2947261B1 (fr) | 2009-06-30 | 2009-06-30 | Zircone frittee coloree. |
| PCT/IB2010/052952 WO2011001368A1 (fr) | 2009-06-30 | 2010-06-29 | Zircone frittee coloree |
Publications (3)
| Publication Number | Publication Date |
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| JP2012532080A JP2012532080A (ja) | 2012-12-13 |
| JP2012532080A5 JP2012532080A5 (enExample) | 2013-07-25 |
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| JP2012516966A Expired - Fee Related JP5634512B2 (ja) | 2009-06-30 | 2010-06-29 | 着色された焼結ジルコニア |
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| FR (1) | FR2947261B1 (enExample) |
| TW (1) | TW201111320A (enExample) |
| WO (1) | WO2011001368A1 (enExample) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| FR2969601A1 (fr) * | 2010-12-22 | 2012-06-29 | Saint Gobain Ct Recherches | Piece frittee coloree. |
| FR2977251B1 (fr) * | 2011-06-30 | 2013-06-28 | Commissariat Energie Atomique | Procede de fabrication de pieces colorees en ceramique par pim |
| ITVR20120007A1 (it) | 2012-01-13 | 2013-07-14 | Patros S R L | Prodotto manufatto per la gioielleria e/o l'orificeria e/o la bigiotteria a base di ossido di zirconio e relativo metodo |
| CN102627457A (zh) * | 2012-04-27 | 2012-08-08 | 赣州虔东稀土集团股份有限公司 | 一种陶瓷及其制备方法与应用 |
| CN102887706A (zh) * | 2012-09-17 | 2013-01-23 | 上海大学 | 一种铈稳定的立方氧化锆陶瓷材料及其制备方法 |
| EP2799411A1 (fr) * | 2013-05-03 | 2014-11-05 | Comadur S.A. | Procédé de fabrication d'un article coloré; en particulier de couleur orange; à base de zircone et article décoratif coloré à base de zircone obtenu selon ce procédé |
| CN104710845A (zh) * | 2013-12-13 | 2015-06-17 | 通用电气公司 | 组合物及其相应的装置、方法 |
| CN103755341B (zh) * | 2013-12-27 | 2016-04-27 | 中国神华能源股份有限公司 | 一种耐酸腐蚀的氧化锆复合陶瓷材料及其制备方法 |
| CN104230378B (zh) * | 2014-08-29 | 2016-03-02 | 华北水利水电大学 | 一种钙钛矿型超细黄色陶瓷颜料及其制备方法 |
| CN118344140A (zh) * | 2014-10-31 | 2024-07-16 | 可乐丽则武齿科株式会社 | 氧化锆组合物、氧化锆预烧体和氧化锆烧结体、以及齿科用制品 |
| US20160167023A1 (en) * | 2014-12-11 | 2016-06-16 | Clean Diesel Technologies, Inc. | ZPGM Catalyst Including Co-Mn-Fe and Cu-Mn-Fe Materials for TWC Applications |
| CN104802278B (zh) * | 2015-04-07 | 2018-01-12 | 浙江省地质矿产研究所 | 一种采用3d打印技术制备玉器的方法 |
| CN105036737B (zh) * | 2015-06-20 | 2018-02-27 | 宁波博莱特光电科技股份有限公司 | 一种高精度陶瓷插芯的制备方法 |
| CN104944948B (zh) * | 2015-06-20 | 2018-02-27 | 宁波博莱特光电科技股份有限公司 | 一种氧化锆陶瓷插芯的制备方法 |
| US10550040B2 (en) * | 2015-09-03 | 2020-02-04 | Tosoh Corporation | Red zirconia sintered body and method for manufacturing the same |
| CN106810245A (zh) * | 2015-11-30 | 2017-06-09 | 比亚迪股份有限公司 | 锆基复合陶瓷材料（粉色）及其制备方法与外壳或装饰品 |
| CN106810244B (zh) * | 2015-11-30 | 2020-03-31 | 比亚迪股份有限公司 | 锆基复合陶瓷材料及其制备方法与外壳或装饰品 |
| CN106810243A (zh) * | 2015-11-30 | 2017-06-09 | 比亚迪股份有限公司 | 锆基复合陶瓷材料（黑色）及其制备方法与外壳或装饰品 |
| CN106810239A (zh) * | 2015-11-30 | 2017-06-09 | 比亚迪股份有限公司 | 锆基复合陶瓷材料(咖啡色)及其制备方法与外壳或装饰品 |
| CN106810246A (zh) * | 2015-11-30 | 2017-06-09 | 比亚迪股份有限公司 | 锆基复合陶瓷材料及其制备方法与外壳或装饰品 |
| CN106810241A (zh) * | 2015-11-30 | 2017-06-09 | 比亚迪股份有限公司 | 锆基复合陶瓷材料（黑灰色）及其制备方法与外壳或装饰品 |
| CN106810240A (zh) * | 2015-11-30 | 2017-06-09 | 比亚迪股份有限公司 | 锆基复合陶瓷材料(冷白色)及其制备方法与外壳或装饰品 |
| CN106810242A (zh) * | 2015-11-30 | 2017-06-09 | 比亚迪股份有限公司 | 锆基复合陶瓷材料（杏色）及其制备方法与外壳或装饰品 |
| CN107311653A (zh) * | 2016-04-27 | 2017-11-03 | 比亚迪股份有限公司 | 锆基复合陶瓷材料及其制备方法与外壳或装饰品 |
| CN107311652A (zh) * | 2016-04-27 | 2017-11-03 | 比亚迪股份有限公司 | 锆基复合陶瓷材料及其制备方法与外壳或装饰品 |
| CN107311651A (zh) * | 2016-04-27 | 2017-11-03 | 比亚迪股份有限公司 | 锆基复合陶瓷材料及其制备方法与外壳或装饰品 |
| CN107311650A (zh) * | 2016-04-27 | 2017-11-03 | 比亚迪股份有限公司 | 锆基复合陶瓷材料及其制备方法与外壳或装饰品 |
| CN108083796B (zh) * | 2016-11-22 | 2021-01-19 | 比亚迪股份有限公司 | 锆基复合陶瓷材料及其制备方法与外壳或装饰品 |
| CN107129296A (zh) * | 2017-04-01 | 2017-09-05 | 景德镇晶隆陶瓷科技有限公司 | 一种用于拉线轮的掺杂改性黄色氧化锆陶瓷及其拉线轮的生产方法 |
| FR3068035A1 (fr) * | 2017-06-22 | 2018-12-28 | Saint-Gobain Centre De Recherches Et D'etudes Europeen | Produit fritte a base d'alumine et de zircone |
| CN108341668B (zh) * | 2018-04-20 | 2020-04-21 | 内蒙古科技大学 | 一种黑色氧化锆陶瓷及其制备方法 |
| CN110922185A (zh) * | 2018-09-19 | 2020-03-27 | 比亚迪股份有限公司 | 锆基复合陶瓷材料及其制备方法与外壳或装饰品 |
| FR3088637A1 (fr) | 2018-11-16 | 2020-05-22 | Commissariat A L'energie Atomique Et Aux Energies Alternatives | Procede de fabrication d'un article de couleur rouge, article de couleur rouge, ses utilisations et piece comprenant un tel article |
| CN110002869A (zh) * | 2019-05-16 | 2019-07-12 | 金业新材料科技(昆山)有限公司 | 一种热脱氧化锆陶瓷注塑喂料及其制备方法 |
| FR3108905B1 (fr) * | 2020-04-03 | 2023-04-07 | Saint Gobain Ct Recherches | Zircone coloree |
| CN114621005B (zh) * | 2020-12-14 | 2023-07-14 | 万华化学(四川)有限公司 | 一种纳米复相彩色氧化锆陶瓷及其制备方法和应用 |
| CN115819080B (zh) * | 2022-10-13 | 2023-07-25 | 山东国瓷功能材料股份有限公司 | 浅灰色氧化锆烧结体及其制备方法和应用 |
| DE102023000840A1 (de) * | 2023-03-07 | 2024-09-12 | Caddent Gmbh | Otoplastiken und Brillen |
| WO2025061627A1 (de) * | 2023-09-19 | 2025-03-27 | Vita Zahnfabrik H. Rauter Gmbh & Co. Kg | Mehrschichtiger aufbau |
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| US4465778A (en) * | 1982-02-03 | 1984-08-14 | National Research Development Corporation | Sinterable fluorite oxide ceramics |
| US4596750A (en) * | 1985-03-15 | 1986-06-24 | Westinghouse Electric Corp. | Support tube for high temperature solid electrolyte electrochemical cell |
| JPH075325B2 (ja) * | 1989-07-05 | 1995-01-25 | 住友セメント株式会社 | ジルコニア系ファインセラミックスの着色顔料及びその製造方法 |
| CH687680A5 (fr) | 1994-04-19 | 1997-01-31 | Asulab Sa | Procédé de fabrication d'un article en zircone noire et article décoratif noir obtenu selon ce procédé. |
| JP2984758B2 (ja) * | 1996-04-30 | 1999-11-29 | 工業技術院長 | セラミックス複合体 |
| JP4399886B2 (ja) * | 1999-03-12 | 2010-01-20 | 戸田工業株式会社 | 非磁性黒色顔料用ストロンチウム鉄酸化物粒子粉末及びその製造方法 |
| US6136232A (en) * | 1999-08-13 | 2000-10-24 | Xylon Ceramic Materials Inc. | Electro-static dissipative zirconia |
| US6541112B1 (en) * | 2000-06-07 | 2003-04-01 | Dmc2 Degussa Metals Catalysts Cerdec Ag | Rare earth manganese oxide pigments |
| US6669871B2 (en) * | 2000-11-21 | 2003-12-30 | Saint-Gobain Ceramics & Plastics, Inc. | ESD dissipative ceramics |
| EP1527486A4 (en) * | 2001-06-29 | 2008-04-30 | Nextech Materials Ltd | NANO-COMPOSITE ELECTRODES AND METHOD FOR THE PRODUCTION THEREOF |
| JP4409169B2 (ja) * | 2002-12-26 | 2010-02-03 | 日揮触媒化成株式会社 | 着色顔料粒子を含む塗料、可視光遮蔽膜付基材 |
| JP2005289721A (ja) | 2004-03-31 | 2005-10-20 | Tosoh Corp | 着色ジルコニア焼結体及びその製造方法 |
| JP5158298B2 (ja) * | 2005-06-10 | 2013-03-06 | 東ソー株式会社 | 黒色ジルコニア焼結体、その原料粉末ならびにそれらの製造方法 |
| JP4853103B2 (ja) | 2006-05-18 | 2012-01-11 | 東ソー株式会社 | 黒色ジルコニア焼結体用粉末及びその焼結体並びに着色剤 |
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2009
- 2009-06-30 FR FR0954475A patent/FR2947261B1/fr not_active Expired - Fee Related
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- 2010-06-29 KR KR1020127002488A patent/KR101822542B1/ko not_active Expired - Fee Related
- 2010-06-30 TW TW099121559A patent/TW201111320A/zh unknown
Also Published As
| Publication number | Publication date |
|---|---|
| FR2947261B1 (fr) | 2012-05-04 |
| WO2011001368A1 (fr) | 2011-01-06 |
| FR2947261A1 (fr) | 2010-12-31 |
| KR20120059489A (ko) | 2012-06-08 |
| EP2448881A1 (fr) | 2012-05-09 |
| CN102482163B (zh) | 2013-11-20 |
| KR101822542B1 (ko) | 2018-01-26 |
| US9126870B2 (en) | 2015-09-08 |
| TW201111320A (en) | 2011-04-01 |
| EP2448881B1 (fr) | 2013-09-25 |
| US20120121859A1 (en) | 2012-05-17 |
| CN102482163A (zh) | 2012-05-30 |
| JP2012532080A (ja) | 2012-12-13 |
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Free format text: JAPANESE INTERMEDIATE CODE: R250 |
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| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
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| LAPS | Cancellation because of no payment of annual fees |