JP5575885B2 - 低い表面張力、低い液体粘度および高い固体含量を有するフルオロイオノマー分散体 - Google Patents

低い表面張力、低い液体粘度および高い固体含量を有するフルオロイオノマー分散体 Download PDF

Info

Publication number
JP5575885B2
JP5575885B2 JP2012514476A JP2012514476A JP5575885B2 JP 5575885 B2 JP5575885 B2 JP 5575885B2 JP 2012514476 A JP2012514476 A JP 2012514476A JP 2012514476 A JP2012514476 A JP 2012514476A JP 5575885 B2 JP5575885 B2 JP 5575885B2
Authority
JP
Japan
Prior art keywords
per
fluoroionomer
group
solvent
liquid composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
JP2012514476A
Other languages
English (en)
Japanese (ja)
Other versions
JP2012529549A5 (https=
JP2012529549A (ja
Inventor
ルカ・メルロ
アレッサンドロ・ギエルミ
ヴィンセンツォ・アルセッラ
Original Assignee
ソルヴェイ・スペシャルティ・ポリマーズ・イタリー・エッセ・ピ・ア
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ソルヴェイ・スペシャルティ・ポリマーズ・イタリー・エッセ・ピ・ア filed Critical ソルヴェイ・スペシャルティ・ポリマーズ・イタリー・エッセ・ピ・ア
Publication of JP2012529549A publication Critical patent/JP2012529549A/ja
Publication of JP2012529549A5 publication Critical patent/JP2012529549A5/ja
Application granted granted Critical
Publication of JP5575885B2 publication Critical patent/JP5575885B2/ja
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • C08F8/18Introducing halogen atoms or halogen-containing groups
    • C08F8/20Halogenation
    • C08F8/22Halogenation by reaction with free halogens
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/1016Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018Polymeric electrolyte materials
    • H01M8/1039Polymeric electrolyte materials halogenated, e.g. sulfonated polyvinylidene fluorides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J39/00Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/08Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/16Organic material
    • B01J39/18Macromolecular compounds
    • B01J39/20Macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/18Monomers containing fluorine
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/18Monomers containing fluorine
    • C08F14/26Tetrafluoroethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20Manufacture of shaped structures of ion-exchange resins
    • C08J5/22Films, membranes or diaphragms
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20Manufacture of shaped structures of ion-exchange resins
    • C08J5/22Films, membranes or diaphragms
    • C08J5/2206Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2275Heterogeneous membranes
    • C08J5/2281Heterogeneous membranes fluorine containing heterogeneous membranes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/1016Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018Polymeric electrolyte materials
    • H01M8/102Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1025Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon and oxygen, e.g. polyethers, sulfonated polyetheretherketones [S-PEEK], sulfonated polysaccharides, sulfonated celluloses or sulfonated polyesters
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/1016Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018Polymeric electrolyte materials
    • H01M8/1058Polymeric electrolyte materials characterised by a porous support having no ion-conducting properties
    • H01M8/106Polymeric electrolyte materials characterised by a porous support having no ion-conducting properties characterised by the chemical composition of the porous support
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/1016Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018Polymeric electrolyte materials
    • H01M8/1058Polymeric electrolyte materials characterised by a porous support having no ion-conducting properties
    • H01M8/1062Polymeric electrolyte materials characterised by a porous support having no ion-conducting properties characterised by the physical properties of the porous support, e.g. its porosity or thickness
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/12Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08J2327/18Homopolymers or copolymers of tetrafluoroethylene
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M2008/1095Fuel cells with polymeric electrolytes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00Electrolytes
    • H01M2300/0017Non-aqueous electrolytes
    • H01M2300/0065Solid electrolytes
    • H01M2300/0082Organic polymers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24752Laterally noncoextensive components

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Sustainable Energy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Electrochemistry (AREA)
  • Sustainable Development (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
JP2012514476A 2009-06-12 2010-06-10 低い表面張力、低い液体粘度および高い固体含量を有するフルオロイオノマー分散体 Active JP5575885B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP09162625 2009-06-12
EP09162625.9 2009-06-12
PCT/EP2010/058182 WO2010142772A1 (en) 2009-06-12 2010-06-10 Fluoroionomers dispersions having low surface tension, low liquid viscosity and high solid content

Publications (3)

Publication Number Publication Date
JP2012529549A JP2012529549A (ja) 2012-11-22
JP2012529549A5 JP2012529549A5 (https=) 2014-06-26
JP5575885B2 true JP5575885B2 (ja) 2014-08-20

Family

ID=41202555

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2012514476A Active JP5575885B2 (ja) 2009-06-12 2010-06-10 低い表面張力、低い液体粘度および高い固体含量を有するフルオロイオノマー分散体

Country Status (6)

Country Link
US (2) US9450262B2 (https=)
EP (1) EP2440586B1 (https=)
JP (1) JP5575885B2 (https=)
KR (1) KR101740746B1 (https=)
CN (2) CN110272512A (https=)
WO (1) WO2010142772A1 (https=)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102317324B (zh) * 2008-12-11 2014-12-24 索尔维索莱克西斯公司 氟代离聚物组合物的纯化
US8709199B2 (en) * 2011-09-13 2014-04-29 GM Global Technology Operations LLC Method of preparing a water vapor transfer membrane
EP2774203B8 (en) * 2011-11-04 2016-06-01 Greenerity GmbH Method for the preparation of catalyst-coated membranes
US10020526B2 (en) 2012-09-12 2018-07-10 GM Global Technology Operations LLC Reverse osmosis membranes made with PFSA ionomer and ePTFE
FR3001732B1 (fr) 2013-02-04 2016-02-26 Rhodia Operations Utilisation d'agents dispersants pour la preparation d'encres pour piles a combustible
KR20140128895A (ko) * 2013-04-29 2014-11-06 주식회사 엘지화학 고분자 전해질막, 고분자 전해질막을 포함하는 막전극 접합체 및 막 전극 접합체를 포함하는 연료전지
JP6151111B2 (ja) * 2013-07-02 2017-06-21 旭化成株式会社 電解質溶液の製造方法、電解質溶液、電解質膜、電極触媒層、膜電極接合体、及び固体高分子電解質型燃料電池
EP2842620A1 (en) 2013-08-26 2015-03-04 Agfa-Gevaert A method for preparing a composite membrane
WO2020183306A1 (en) * 2019-03-12 2020-09-17 3M Innovative Properties Company Dispersible perfluorosulfonic acid ionomer compositions
CN115805185B (zh) * 2019-06-06 2024-04-19 W.L.戈尔及同仁股份有限公司 润湿低表面能基材的方法以及用于该方法的系统
KR102507911B1 (ko) * 2021-03-31 2023-03-07 도레이첨단소재 주식회사 양이온 교환막 및 이의 제조방법

Family Cites Families (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3282875A (en) * 1964-07-22 1966-11-01 Du Pont Fluorocarbon vinyl ether polymers
NL160013C (nl) 1968-11-26 1979-09-17 Du Pont Werkwijze ter bereiding van oplossingen van een sulfonyl- groepen bevattend fluorkoolstofpolymeer.
US4433082A (en) * 1981-05-01 1984-02-21 E. I. Du Pont De Nemours And Company Process for making liquid composition of perfluorinated ion exchange polymer, and product thereof
JPH01217042A (ja) * 1986-09-26 1989-08-30 Dow Chem Co:The パーフルオロスルホネートイオノマー薄膜の製造方法
WO1998016581A1 (en) 1996-10-15 1998-04-23 E.I. Du Pont De Nemours And Company Compositions containing particles of highly fluorinated ion exchange polymer
US6025092A (en) * 1998-02-13 2000-02-15 E. I. Du Pont De Nemours And Company Fluorinated ionomers and their uses
US6100324A (en) * 1998-04-16 2000-08-08 E. I. Du Pont De Nemours And Company Ionomers and ionically conductive compositions
IT1303779B1 (it) 1998-11-23 2001-02-23 Ausimont Spa Preparazione di soluzioni di polimeri fluorurati solfonici.
DE60119307T2 (de) 2000-02-16 2007-04-12 Daikin Industries, Ltd. Verfahren zur herstellung eines fluorionomers, verfahren zur reinigung und konzentrierung von ionomeren und verfahren zur filmbildung
ITMI20010921A1 (it) 2001-05-07 2002-11-07 Ausimont Spa Polimeri (per)fluorurati amorfi
US6713567B2 (en) * 2001-07-13 2004-03-30 E. I. Du Pont De Nemours And Company Method for forming fluorinated ionomers
EP1602687B1 (en) * 2003-03-03 2012-01-04 Daikin Industries, Ltd. Liquid fluoropolymer composition, process for producing organosol, film, and fuel cell
WO2004102714A1 (ja) 2003-05-13 2004-11-25 Asahi Glass Company, Limited 固体高分子型燃料電池用電解質ポリマー、その製造方法及び膜・電極接合体
US20070129500A1 (en) 2003-09-10 2007-06-07 Eiji Honda Stabilized fluoropolymer and method for producing same
US6986947B2 (en) * 2003-10-09 2006-01-17 3M Innovative Properties Company Method of modifying a fluoropolymer and articles thereby
US7173067B2 (en) * 2003-12-17 2007-02-06 3M Innovative Properties Company Polymer electrolyte membranes crosslinked by direct fluorination
JP4437407B2 (ja) 2004-01-22 2010-03-24 旭化成株式会社 フッ素化スルホン酸ポリマーの製造方法
ITMI20040789A1 (it) 2004-04-22 2004-07-22 Solvay Solexis Spa Membrane fluorurate
US20060014887A1 (en) 2004-07-19 2006-01-19 3M Innovative Properties Company Method of hydrolyzing a dispersion of ionic fluoropolymer
US7304101B2 (en) 2004-07-19 2007-12-04 3M Innovative Properties Company Method of purifying a dispersion of ionic fluoropolymer
WO2006019097A1 (ja) * 2004-08-18 2006-02-23 Asahi Glass Company, Limited 燃料電池用電解質ポリマー、その製造方法、電解質膜、及び膜・電極接合体
ITMI20042554A1 (it) * 2004-12-30 2005-03-30 Solvay Solexis Spa Procedimento per la preparazione di dispersioni di fluoropolimeri
US7214740B2 (en) 2005-05-03 2007-05-08 3M Innovative Properties Company Fluorinated ionomers with reduced amounts of carbonyl end groups
US8617765B2 (en) 2005-12-22 2013-12-31 E I Du Pont De Nemours And Company Chemically stabilized ionomers containing inorganic fillers
WO2007073500A2 (en) 2005-12-22 2007-06-28 E. I. Du Pont De Nemours And Company Methods to prepare chemically stabilized ionomers containing inorganic fillers
WO2007089017A1 (ja) * 2006-02-03 2007-08-09 Daikin Industries, Ltd. -so3h基含有フルオロポリマー製造方法及び-so3h基含有フルオロポリマー
EP1914251A1 (en) 2006-10-17 2008-04-23 Solvay Solexis S.p.A. Process for stabilizing fluoropolymer having ion exchange groups
CN101606262B (zh) * 2006-12-22 2013-10-02 索维索莱克西斯公开有限公司 干燥条件下操作燃料电池的方法
CN101020758B (zh) * 2007-02-25 2010-05-19 山东东岳神舟新材料有限公司 一种聚合物离子交换膜及其制备方法

Also Published As

Publication number Publication date
KR20120046117A (ko) 2012-05-09
EP2440586B1 (en) 2020-02-05
KR101740746B1 (ko) 2017-05-26
US9450262B2 (en) 2016-09-20
US20120076990A1 (en) 2012-03-29
US20170194661A1 (en) 2017-07-06
CN102459361A (zh) 2012-05-16
WO2010142772A1 (en) 2010-12-16
JP2012529549A (ja) 2012-11-22
CN102459361B (zh) 2019-07-05
CN110272512A (zh) 2019-09-24
EP2440586A1 (en) 2012-04-18
US9947952B2 (en) 2018-04-17

Similar Documents

Publication Publication Date Title
JP5575885B2 (ja) 低い表面張力、低い液体粘度および高い固体含量を有するフルオロイオノマー分散体
JP5849148B2 (ja) 高分子電解質膜
JP5823601B2 (ja) 高分子電解質膜
JP4293765B2 (ja) 多孔性基体の含浸方法
US9162190B2 (en) Composite ionomeric membrane
JP2014502776A (ja) 燃料電池の1種以上の電極として使用するための高分子量アイオノマーおよびイオン伝導性組成物
JP2014500392A (ja) アイオノマー及びイオン伝導性組成物
JP6219812B2 (ja) 架橋フッ素化ポリマーを製造する方法
JP2014507753A (ja) 燃料電池の1つ以上の電極として使用するためのアイオノマー及びイオン伝導性組成物
JP5175445B2 (ja) イオノマー膜
JP5989658B2 (ja) フッ素化イオン交換ポリマーの液体組成物
WO2021054253A1 (ja) 複合電解質膜、触媒層付電解質膜、膜電極複合体、固体高分子形燃料電池および複合電解質膜の製造方法
JP2005179447A (ja) 膜体、膜・電極接合体及び固体高分子型燃料電池
CN107075291B (zh) 用于质子交换膜的液体组合物
JP2021052001A (ja) 複合電解質膜およびそれを用いた膜電極複合体、固体高分子形燃料電池

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20130509

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20140129

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20140203

A524 Written submission of copy of amendment under article 19 pct

Free format text: JAPANESE INTERMEDIATE CODE: A524

Effective date: 20140507

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20140602

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20140702

R150 Certificate of patent or registration of utility model

Ref document number: 5575885

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250