JP5508013B2 - オリゴマー状のビスホスフェート難燃剤およびこれを含有する組成物 - Google Patents
オリゴマー状のビスホスフェート難燃剤およびこれを含有する組成物 Download PDFInfo
- Publication number
- JP5508013B2 JP5508013B2 JP2009526738A JP2009526738A JP5508013B2 JP 5508013 B2 JP5508013 B2 JP 5508013B2 JP 2009526738 A JP2009526738 A JP 2009526738A JP 2009526738 A JP2009526738 A JP 2009526738A JP 5508013 B2 JP5508013 B2 JP 5508013B2
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- JP
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- Prior art keywords
- phosphate
- resin
- resin composition
- oligomeric
- flame retardant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000003063 flame retardant Substances 0.000 title claims description 34
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims description 23
- 239000000203 mixture Substances 0.000 title claims description 18
- 125000005340 bisphosphate group Chemical group 0.000 title description 7
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 claims description 40
- 239000004417 polycarbonate Substances 0.000 claims description 30
- 229920000515 polycarbonate Polymers 0.000 claims description 29
- 239000011342 resin composition Substances 0.000 claims description 27
- 229910019142 PO4 Inorganic materials 0.000 claims description 24
- 239000010452 phosphate Substances 0.000 claims description 20
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 18
- 239000011347 resin Substances 0.000 claims description 16
- 229920005989 resin Polymers 0.000 claims description 16
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims description 15
- ASMQGLCHMVWBQR-UHFFFAOYSA-M diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(=O)([O-])OC1=CC=CC=C1 ASMQGLCHMVWBQR-UHFFFAOYSA-M 0.000 claims description 14
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 claims description 11
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 10
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 claims description 9
- 239000000843 powder Substances 0.000 claims description 9
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 6
- 230000009969 flowable effect Effects 0.000 claims description 6
- 229920005669 high impact polystyrene Polymers 0.000 claims description 6
- 239000004797 high-impact polystyrene Substances 0.000 claims description 6
- 229920006380 polyphenylene oxide Polymers 0.000 claims description 6
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 4
- 229920000642 polymer Polymers 0.000 claims description 4
- 229920001577 copolymer Polymers 0.000 claims description 2
- 239000002131 composite material Substances 0.000 description 22
- 235000021317 phosphate Nutrition 0.000 description 20
- 239000000805 composite resin Substances 0.000 description 13
- OWICEWMBIBPFAH-UHFFFAOYSA-N (3-diphenoxyphosphoryloxyphenyl) diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=C(OP(=O)(OC=2C=CC=CC=2)OC=2C=CC=CC=2)C=CC=1)(=O)OC1=CC=CC=C1 OWICEWMBIBPFAH-UHFFFAOYSA-N 0.000 description 12
- 238000000034 method Methods 0.000 description 10
- 239000000047 product Substances 0.000 description 10
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- BHIIGRBMZRSDRI-UHFFFAOYSA-N [chloro(phenoxy)phosphoryl]oxybenzene Chemical compound C=1C=CC=CC=1OP(=O)(Cl)OC1=CC=CC=C1 BHIIGRBMZRSDRI-UHFFFAOYSA-N 0.000 description 8
- 238000004128 high performance liquid chromatography Methods 0.000 description 8
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 8
- 230000007062 hydrolysis Effects 0.000 description 7
- 238000006460 hydrolysis reaction Methods 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 6
- 230000003301 hydrolyzing effect Effects 0.000 description 6
- 230000000704 physical effect Effects 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- PWAYUHFEKDQEMK-UHFFFAOYSA-N benzene-1,4-diol;phosphoric acid Chemical compound OP(O)(O)=O.OP(O)(O)=O.OC1=CC=C(O)C=C1 PWAYUHFEKDQEMK-UHFFFAOYSA-N 0.000 description 5
- TXFOLHZMICYNRM-UHFFFAOYSA-N dichlorophosphoryloxybenzene Chemical compound ClP(Cl)(=O)OC1=CC=CC=C1 TXFOLHZMICYNRM-UHFFFAOYSA-N 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 229920002842 oligophosphate Polymers 0.000 description 5
- 239000011541 reaction mixture Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 239000000654 additive Substances 0.000 description 4
- 150000004712 monophosphates Chemical class 0.000 description 4
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- ASONQZPECNCPCA-UHFFFAOYSA-N P(=O)(OC1(C(C=CC=C1)C)C)(OC1(C(C=CC=C1)C)C)OC1=CC(O)=CC=C1 Chemical compound P(=O)(OC1(C(C=CC=C1)C)C)(OC1(C(C=CC=C1)C)C)OC1=CC(O)=CC=C1 ASONQZPECNCPCA-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- BQPNUOYXSVUVMY-UHFFFAOYSA-N [4-[2-(4-diphenoxyphosphoryloxyphenyl)propan-2-yl]phenyl] diphenyl phosphate Chemical compound C=1C=C(OP(=O)(OC=2C=CC=CC=2)OC=2C=CC=CC=2)C=CC=1C(C)(C)C(C=C1)=CC=C1OP(=O)(OC=1C=CC=CC=1)OC1=CC=CC=C1 BQPNUOYXSVUVMY-UHFFFAOYSA-N 0.000 description 3
- 239000008367 deionised water Substances 0.000 description 3
- 229910021641 deionized water Inorganic materials 0.000 description 3
- 239000000539 dimer Substances 0.000 description 3
- 238000005562 fading Methods 0.000 description 3
- -1 phosphate ester Chemical class 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 239000004429 Calibre Substances 0.000 description 2
- 229920004313 LEXAN™ RESIN 141 Polymers 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- UNXRWKVEANCORM-UHFFFAOYSA-N triphosphoric acid Polymers OP(O)(=O)OP(O)(=O)OP(O)(O)=O UNXRWKVEANCORM-UHFFFAOYSA-N 0.000 description 2
- 0 **c(cc1)ccc1O Chemical compound **c(cc1)ccc1O 0.000 description 1
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- 239000004114 Ammonium polyphosphate Substances 0.000 description 1
- IISBACLAFKSPIT-UHFFFAOYSA-N Bisphenol A Natural products C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- ASMQGLCHMVWBQR-UHFFFAOYSA-N Diphenyl phosphate Chemical class C=1C=CC=CC=1OP(=O)(O)OC1=CC=CC=C1 ASMQGLCHMVWBQR-UHFFFAOYSA-N 0.000 description 1
- UUGLJVMIFJNVFH-UHFFFAOYSA-N Hexyl benzoate Chemical compound CCCCCCOC(=O)C1=CC=CC=C1 UUGLJVMIFJNVFH-UHFFFAOYSA-N 0.000 description 1
- 229920004142 LEXAN™ Polymers 0.000 description 1
- 239000004418 Lexan Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 235000019826 ammonium polyphosphate Nutrition 0.000 description 1
- 229920001276 ammonium polyphosphate Polymers 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical group BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Chemical group 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229930003836 cresol Natural products 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000000368 destabilizing effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000011491 glass wool Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- ZQKXQUJXLSSJCH-UHFFFAOYSA-N melamine cyanurate Chemical compound NC1=NC(N)=NC(N)=N1.O=C1NC(=O)NC(=O)N1 ZQKXQUJXLSSJCH-UHFFFAOYSA-N 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- YCWSUKQGVSGXJO-NTUHNPAUSA-N nifuroxazide Chemical group C1=CC(O)=CC=C1C(=O)N\N=C\C1=CC=C([N+]([O-])=O)O1 YCWSUKQGVSGXJO-NTUHNPAUSA-N 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- XZTOTRSSGPPNTB-UHFFFAOYSA-N phosphono dihydrogen phosphate;1,3,5-triazine-2,4,6-triamine Chemical compound NC1=NC(N)=NC(N)=N1.OP(O)(=O)OP(O)(O)=O XZTOTRSSGPPNTB-UHFFFAOYSA-N 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 125000004437 phosphorous atom Chemical group 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000004431 polycarbonate resin Substances 0.000 description 1
- 229920005668 polycarbonate resin Polymers 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- GGRIQDPLLHVRDU-UHFFFAOYSA-M potassium;2-(benzenesulfonyl)benzenesulfonate Chemical compound [K+].[O-]S(=O)(=O)C1=CC=CC=C1S(=O)(=O)C1=CC=CC=C1 GGRIQDPLLHVRDU-UHFFFAOYSA-M 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/08—Esters of oxyacids of phosphorus
- C07F9/09—Esters of phosphoric acids
- C07F9/12—Esters of phosphoric acids with hydroxyaryl compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/08—Esters of oxyacids of phosphorus
- C07F9/09—Esters of phosphoric acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
- C08K5/5317—Phosphonic compounds, e.g. R—P(:O)(OR')2
- C08K5/5333—Esters of phosphonic acids
- C08K5/5357—Esters of phosphonic acids cyclic
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Fireproofing Substances (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US84145906P | 2006-08-31 | 2006-08-31 | |
| US60/841,459 | 2006-08-31 | ||
| PCT/US2007/019172 WO2008027536A1 (fr) | 2006-08-31 | 2007-08-30 | Agents ignifuges à base de bis-phosphate oligomère et compositions contenant ce composé |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2010502625A JP2010502625A (ja) | 2010-01-28 |
| JP5508013B2 true JP5508013B2 (ja) | 2014-05-28 |
Family
ID=38805825
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2009526738A Active JP5508013B2 (ja) | 2006-08-31 | 2007-08-30 | オリゴマー状のビスホスフェート難燃剤およびこれを含有する組成物 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US8119711B2 (fr) |
| EP (1) | EP2089402B1 (fr) |
| JP (1) | JP5508013B2 (fr) |
| KR (1) | KR101416843B1 (fr) |
| CN (1) | CN101511850B (fr) |
| TW (1) | TWI400246B (fr) |
| WO (1) | WO2008027536A1 (fr) |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101701395B1 (ko) * | 2008-12-22 | 2017-02-01 | 아이씨엘-아이피 아메리카 아이엔씨. | 비스포스페이트를 정제하기 위한 수용성 용매 기반 정제 방법 |
| EP2406307B1 (fr) * | 2009-02-26 | 2012-12-12 | ICL-IP America Inc. | Composition de polymère styrénique |
| WO2010104689A1 (fr) * | 2009-03-09 | 2010-09-16 | Icl-Ip America Inc. | Composition polyoléfinique ignifugeante |
| WO2011095552A1 (fr) | 2010-02-05 | 2011-08-11 | Basf Se | Agents ignifuges |
| CN102532191B (zh) * | 2010-12-22 | 2014-11-12 | 第一毛织株式会社 | 新型磷化合物、其制备方法以及包括该磷化合物的阻燃热塑性树脂组合物 |
| JP2013076057A (ja) * | 2011-09-14 | 2013-04-25 | Daicel Polymer Ltd | 可塑剤及びセルロースエステル組成物 |
| KR20130046974A (ko) * | 2011-10-28 | 2013-05-08 | 엘지이노텍 주식회사 | 광학 부재, 이를 포함하는 표시장치 및 이의 제조방법 |
| KR101489956B1 (ko) * | 2011-12-30 | 2015-02-06 | 제일모직주식회사 | 난연성 열가소성 수지 조성물 |
| JP2014009297A (ja) * | 2012-06-29 | 2014-01-20 | Daicel Polymer Ltd | 酢酸セルロース用可塑剤 |
| JP2014177596A (ja) * | 2013-03-15 | 2014-09-25 | Ricoh Co Ltd | 再生樹脂組成物、成形品、画像形成装置及び再生樹脂組成物の製造方法 |
| US20150099845A1 (en) * | 2013-10-07 | 2015-04-09 | Sabic Innovative Plastics Ip B.V. | Flame retardant thermoplastic compositions with improved properties |
| KR20160043610A (ko) * | 2014-10-13 | 2016-04-22 | 삼성에스디아이 주식회사 | 투명성 및 기계적 강도가 우수한 열가소성 수지 조성물 및 이를 포함하는 성형품 |
| US10240039B2 (en) | 2014-12-23 | 2019-03-26 | Sabic Global Technologies B.V. | Reinforced polycarbonate compositions |
| JP6789248B2 (ja) | 2015-06-09 | 2020-11-25 | ブローミン コンパウンズ リミテッド | 織物のためのアンチモンフリー臭素化難燃剤システム |
| CN109642050B (zh) * | 2016-08-29 | 2024-02-23 | 爱思乐-艾博美国有限公司 | 阻燃的聚酰胺组合物 |
| CN109689759B (zh) * | 2016-09-08 | 2021-07-09 | 溴化合物有限公司 | 阻燃的透明聚碳酸酯组合物 |
| KR102402371B1 (ko) | 2016-10-18 | 2022-05-27 | 브로민 콤파운드 리미티드 | 난연성 폴리에스테르 조성물 |
| WO2018073819A1 (fr) | 2016-10-18 | 2018-04-26 | Bromine Compounds Ltd. | Formulations de polyester ignifugées |
| PL3601425T3 (pl) | 2017-03-30 | 2021-09-20 | Bromine Compounds Ltd. | Kompozycje zawierające styren o zmniejszonej palności |
| PL3601436T3 (pl) | 2017-03-30 | 2021-11-15 | Bromine Compounds Ltd. | Preparaty zawierające styren o zmniejszonej palności |
| KR102110435B1 (ko) * | 2018-06-27 | 2020-06-08 | 듀라원 주식회사 | 난연성을 갖는 방폭 및 내진용 방수재 폴리우레아수지 도료조성물 및 그 제조방법 |
| JP7280133B2 (ja) * | 2019-07-17 | 2023-05-23 | 旭化成株式会社 | ポリフェニレンエーテル系樹脂組成物 |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1405983A (en) | 1972-03-03 | 1975-09-10 | Mitsubishi Rayon Co | Fireproof polyester composition |
| JPS5139272B2 (fr) | 1972-04-21 | 1976-10-27 | ||
| CH583269A5 (fr) | 1973-03-09 | 1976-12-31 | Sandoz Ag | |
| JPS63227632A (ja) * | 1987-03-17 | 1988-09-21 | Daihachi Kagaku Kogyosho:Kk | 難燃剤の製造方法 |
| JP2699397B2 (ja) * | 1988-04-18 | 1998-01-19 | ダイアホイルヘキスト株式会社 | 複合ポリエステルフィルム |
| US5219510A (en) * | 1990-09-26 | 1993-06-15 | Eastman Kodak Company | Method of manufacture of cellulose ester film |
| JPH06184357A (ja) * | 1992-08-28 | 1994-07-05 | Asahi Chem Ind Co Ltd | 樹脂組成物 |
| US5420327A (en) * | 1992-09-14 | 1995-05-30 | Akzo Nobel N.V. | Process for forming hydrocarbyl bisphosphate compound |
| US5457221A (en) * | 1993-03-03 | 1995-10-10 | Akzo Nobel N.V. | Process for the manufacture of poly (hydrocarbylene aryl phosphate) compositions |
| JP3269218B2 (ja) | 1993-10-15 | 2002-03-25 | 東レ株式会社 | 難燃化液晶ポリエステル組成物 |
| KR950032580A (ko) * | 1994-03-14 | 1995-12-22 | 마에다 가츠노스케 | 난연성 폴리머조성물 및 성형물품 |
| JP3484802B2 (ja) * | 1994-03-14 | 2004-01-06 | 東レ株式会社 | 難燃性ポリマ組成物および成形物品 |
| JPH0812868A (ja) * | 1994-04-28 | 1996-01-16 | Toray Ind Inc | 熱可塑性樹脂組成物 |
| US5952408A (en) * | 1994-12-01 | 1999-09-14 | Cheil Industries, Inc. | Flameproof thermoplastic resin compositions |
| JP2814214B2 (ja) * | 1995-08-10 | 1998-10-22 | 三洋化成工業株式会社 | リン酸エステル化合物、難燃性付与剤および難燃性樹脂組成物 |
| JPH09132720A (ja) | 1995-09-06 | 1997-05-20 | Toray Ind Inc | 難燃性樹脂組成物 |
| JP3724861B2 (ja) * | 1995-10-19 | 2005-12-07 | 旭化成ケミカルズ株式会社 | ポリフェニレンエーテルを含有する難燃性樹脂組成物の製造方法 |
| JP3558454B2 (ja) * | 1996-06-28 | 2004-08-25 | 旭化成ケミカルズ株式会社 | 燐酸エステルの製造方法 |
| GB2325933A (en) | 1997-06-02 | 1998-12-09 | Samsung General Chemicals Co | Flame retardant bis-[2,4-bis(dimethylethyl)phenyl-2,6-dimethylphenyl] aryl diphosphate compounds, method for their production & resin compositions of the same |
| JP2000159980A (ja) * | 1998-11-27 | 2000-06-13 | Toshiba Chem Corp | エポキシ樹脂組成物、コイル注型物および半導体封止装置 |
| JP2002105335A (ja) * | 2000-07-26 | 2002-04-10 | Polyplastics Co | 難燃性樹脂組成物 |
| DE10234420A1 (de) * | 2002-07-29 | 2004-02-12 | Bayer Ag | Schlagzähmodifizierte Polycarbonat Blends |
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2007
- 2007-08-30 JP JP2009526738A patent/JP5508013B2/ja active Active
- 2007-08-30 US US12/310,454 patent/US8119711B2/en active Active
- 2007-08-30 EP EP07837596.1A patent/EP2089402B1/fr active Active
- 2007-08-30 CN CN2007800323754A patent/CN101511850B/zh active Active
- 2007-08-30 KR KR1020097006418A patent/KR101416843B1/ko active IP Right Grant
- 2007-08-30 TW TW096132309A patent/TWI400246B/zh active
- 2007-08-30 WO PCT/US2007/019172 patent/WO2008027536A1/fr active Application Filing
Also Published As
| Publication number | Publication date |
|---|---|
| CN101511850B (zh) | 2013-04-24 |
| TWI400246B (zh) | 2013-07-01 |
| JP2010502625A (ja) | 2010-01-28 |
| EP2089402A1 (fr) | 2009-08-19 |
| EP2089402B1 (fr) | 2015-08-05 |
| KR20090045407A (ko) | 2009-05-07 |
| WO2008027536A1 (fr) | 2008-03-06 |
| CN101511850A (zh) | 2009-08-19 |
| TW200831522A (en) | 2008-08-01 |
| KR101416843B1 (ko) | 2014-07-08 |
| US20110034597A1 (en) | 2011-02-10 |
| US8119711B2 (en) | 2012-02-21 |
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