JP5466406B2 - 低溶解速度の被覆金属酸化物粒子、その作製方法およびこれを電気化学系で用いる使用法 - Google Patents
低溶解速度の被覆金属酸化物粒子、その作製方法およびこれを電気化学系で用いる使用法 Download PDFInfo
- Publication number
- JP5466406B2 JP5466406B2 JP2008551606A JP2008551606A JP5466406B2 JP 5466406 B2 JP5466406 B2 JP 5466406B2 JP 2008551606 A JP2008551606 A JP 2008551606A JP 2008551606 A JP2008551606 A JP 2008551606A JP 5466406 B2 JP5466406 B2 JP 5466406B2
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- Prior art keywords
- polymer
- mixture
- carbon
- metal oxide
- coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/621—Binders
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/136—Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/139—Processes of manufacture
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/362—Composites
- H01M4/366—Composites as layered products
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/483—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides for non-aqueous cells
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
- H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/624—Electric conductive fillers
- H01M4/625—Carbon or graphite
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0565—Polymeric materials, e.g. gel-type or solid-type
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49002—Electrical device making
- Y10T29/49108—Electric battery cell making
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Composite Materials (AREA)
- Inorganic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Crystallography & Structural Chemistry (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Cell Electrode Carriers And Collectors (AREA)
- Cell Separators (AREA)
- Secondary Cells (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA2,534,243 | 2006-01-25 | ||
| CA002534243A CA2534243A1 (fr) | 2006-01-25 | 2006-01-25 | Particules d'oxyde metallique enrobees a faible taux de dissolution, procedes de preparation et utilisation dans les systemes electrochimiques |
| PCT/CA2007/000091 WO2007085077A1 (fr) | 2006-01-25 | 2007-01-24 | Particules d’oxyde metallique enrobees a faible taux de dissolution, procedes de preparation et utilisation dans les systemes electrochimiques |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2009524568A JP2009524568A (ja) | 2009-07-02 |
| JP2009524568A5 JP2009524568A5 (enExample) | 2010-03-11 |
| JP5466406B2 true JP5466406B2 (ja) | 2014-04-09 |
Family
ID=38308796
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2008551606A Expired - Fee Related JP5466406B2 (ja) | 2006-01-25 | 2007-01-24 | 低溶解速度の被覆金属酸化物粒子、その作製方法およびこれを電気化学系で用いる使用法 |
Country Status (8)
| Country | Link |
|---|---|
| US (2) | US20090017378A1 (enExample) |
| EP (1) | EP1997169B1 (enExample) |
| JP (1) | JP5466406B2 (enExample) |
| KR (1) | KR101446812B1 (enExample) |
| CN (2) | CN101375437A (enExample) |
| CA (2) | CA2534243A1 (enExample) |
| ES (1) | ES2550143T3 (enExample) |
| WO (1) | WO2007085077A1 (enExample) |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2534276A1 (fr) * | 2006-01-26 | 2007-07-26 | Hydro Quebec | Melange cobroye d'un materiau actif et d'un materiau de conduction, ses procedes de preparation et ses applications |
| CA2559657A1 (en) * | 2006-09-13 | 2008-03-13 | Valence Technology, Inc. | Method of processing active materials for use in secondary electrochemical cells |
| CN105322166B (zh) * | 2008-10-22 | 2020-06-12 | 株式会社Lg化学 | 橄榄石型锂铁磷酸盐、包含其的正极混合物及其分析方法 |
| WO2010098452A1 (ja) * | 2009-02-27 | 2010-09-02 | 日本ゼオン株式会社 | リチウムイオン二次電池用負極活物質およびリチウムイオン二次電池 |
| KR101613498B1 (ko) * | 2009-12-23 | 2016-04-20 | 삼성에스디아이 주식회사 | 양극 활물질, 이를 채용한 양극과 리튬 전지 및 이의 제조방법 |
| WO2012129279A2 (en) * | 2011-03-22 | 2012-09-27 | Cornell University | Nanoscale ionic material (nim) compositions via acid/base reaction |
| CN103534843B (zh) * | 2012-05-07 | 2017-02-22 | 西奥公司 | 用于锂电池阴极的涂覆颗粒 |
| FR3010236B1 (fr) * | 2013-09-05 | 2017-01-13 | Arkema France | Additifs pour ameliorer la conductivite ionique des electrodes de batteries li-ion |
| WO2020252389A1 (en) | 2019-06-12 | 2020-12-17 | HHeLI, LLC | Blended active materials for battery cells |
| CA3005637A1 (en) | 2015-11-16 | 2017-05-26 | HHeLI, LLC | Synthesized, surface-functionalized, acidified metal oxide materials for energy storage, catalytic, photovoltaic, and sensor applications |
| WO2018084652A2 (ko) * | 2016-11-03 | 2018-05-11 | 주식회사 엘지화학 | 리튬이온이차 전지 |
| WO2018093945A1 (en) | 2016-11-15 | 2018-05-24 | Hheli, Llc. | A surface-functionalized, acidified metal oxide material in an acidified electrolyte system or an acidified electrode system |
| DE102016224420A1 (de) | 2016-12-08 | 2018-06-14 | Robert Bosch Gmbh | Verfahren zur Herstellung eines Festelektrolyten |
| KR20200015476A (ko) | 2017-04-10 | 2020-02-12 | 에이치헬리, 엘엘씨 | 신규 성분을 가진 배터리 |
| KR20200008587A (ko) | 2017-05-17 | 2020-01-28 | 에이치헬리, 엘엘씨 | 신규 구성을 가진 배터리 셀 |
| KR102721312B1 (ko) * | 2017-05-17 | 2024-10-24 | 에이치헬리, 엘엘씨 | 산성화 캐소드와 리튬 애노드를 가진 배터리 |
| US10978731B2 (en) | 2017-06-21 | 2021-04-13 | HHeLI, LLC | Ultra high capacity performance battery cell |
| US11165090B2 (en) | 2017-09-22 | 2021-11-02 | HHeLI, LLC | Construction of ultra high capacity performance battery cells |
| US11283267B2 (en) | 2018-09-10 | 2022-03-22 | HHeLI, LLC | Methods of use of ultra high capacity performance battery cell |
| US12278342B2 (en) | 2019-06-12 | 2025-04-15 | HHeLI, LLC | Alkaline and acidified metal oxide blended active materials |
| CN111823126B (zh) * | 2020-06-10 | 2022-07-01 | 广东风华高新科技股份有限公司 | 一种陶瓷片式元器件倒角工艺 |
| JP2022060673A (ja) * | 2020-10-05 | 2022-04-15 | 本田技研工業株式会社 | 非水電解質二次電池用負極及びこれを備える非水電解質二次電池 |
| CN112517317A (zh) * | 2020-11-27 | 2021-03-19 | 张凯旋 | 一种锂电池电极制备用的浆液涂覆装置 |
| CN116487520B (zh) * | 2022-01-13 | 2024-10-29 | 比亚迪股份有限公司 | 锂离子电池的正极极片及锂离子电池 |
| CN116332146A (zh) * | 2023-03-10 | 2023-06-27 | 无锡晶石新型能源股份有限公司 | 一种熔融包覆法提升磷酸锰铁锂比表面的方法 |
Family Cites Families (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4808496A (en) * | 1987-03-13 | 1989-02-28 | Mhb Joint Venture | Electrode construction for solid state electrochemical cell |
| DE69328172T2 (de) * | 1992-12-25 | 2000-12-21 | Tdk Corp | Lithium-sekundärbatterie |
| EP0609101B1 (en) * | 1993-01-29 | 2002-06-26 | Canon Kabushiki Kaisha | Electric power accumulating apparatus and electric power system |
| US5366829A (en) * | 1993-06-14 | 1994-11-22 | Valence Technology, Inc. | Method of forming an anode material for lithium-containing solid electrochemical cells |
| US6174623B1 (en) * | 1994-03-08 | 2001-01-16 | Valence Technology, Inc. | Conductive-polymer-coated electrode particles |
| US5565084A (en) * | 1994-10-11 | 1996-10-15 | Qnix Computer Co., Ltd. | Electropolishing methods for etching substrate in self alignment |
| US5656393A (en) * | 1994-10-21 | 1997-08-12 | W. R. Grace & Co.-Conn. | Flexible electrode, product and process of forming same |
| JPH08203539A (ja) * | 1994-12-13 | 1996-08-09 | Pioneer Electron Corp | 積層型電池 |
| WO1997020768A1 (en) * | 1995-12-07 | 1997-06-12 | Sandia Corporation | Methods of preparation of carbon materials for use as electrodes in rechargeable batteries |
| JP4831588B2 (ja) * | 1997-01-17 | 2011-12-07 | バシウム・カナダ・インコーポレーテッド | 電気化学発電装置 |
| US5888672A (en) * | 1997-02-12 | 1999-03-30 | Gustafson; Scott D. | Polyimide battery |
| JP4005192B2 (ja) * | 1997-12-09 | 2007-11-07 | 第一工業製薬株式会社 | 固体電池 |
| JP2001118570A (ja) * | 1999-10-19 | 2001-04-27 | Nec Corp | ポリマー二次電池用電極の製造方法 |
| DE60140163D1 (de) * | 2000-08-28 | 2009-11-26 | Nissan Motor | Wiederaufladbare Lithiumionenbatterie |
| US7135251B2 (en) * | 2001-06-14 | 2006-11-14 | Samsung Sdi Co., Ltd. | Active material for battery and method of preparing the same |
| CA2367290A1 (fr) * | 2002-01-16 | 2003-07-16 | Hydro Quebec | Electrolyte polymere a haute stabilite > 4 volts comme electrolyte pour supercondensateur hybride et generateur electrochimique |
| CA2478374C (en) | 2002-03-13 | 2009-01-06 | Eli M. Wallace | N3 alkylated benzimidazole derivatives as mek inhibitors |
| KR100846578B1 (ko) * | 2002-06-01 | 2008-07-16 | 삼성에스디아이 주식회사 | 리튬 전지 |
| US7087348B2 (en) * | 2002-07-26 | 2006-08-08 | A123 Systems, Inc. | Coated electrode particles for composite electrodes and electrochemical cells |
| US20050053834A1 (en) * | 2003-09-04 | 2005-03-10 | Advanced Battery Technology, Ltd. | Positive electrode material and method |
| CN1617371B (zh) | 2003-11-12 | 2010-04-28 | 中国科学院青海盐湖研究所 | 表面修饰锂离子电池正极材料及其制备方法 |
| KR100599602B1 (ko) * | 2004-10-28 | 2006-07-13 | 삼성에스디아이 주식회사 | 리튬 이차 전지용 양극 및 이를 포함하는 리튬 이차 전지 |
| CN1316653C (zh) * | 2005-01-28 | 2007-05-16 | 中国科学院成都有机化学有限公司 | 一种锂离子电池正极材料、其制备方法及锂离子电池 |
| JP4959145B2 (ja) * | 2005-03-30 | 2012-06-20 | 日本碍子株式会社 | 非水電解質二次電池用正極及び非水電解質二次電池 |
| EP1889311B1 (en) * | 2005-04-19 | 2010-05-05 | LG Chem, Ltd. | Safety-improved electrode by introducing crosslinkable polymer and electrochemical device comprising the same |
-
2006
- 2006-01-25 CA CA002534243A patent/CA2534243A1/fr not_active Abandoned
-
2007
- 2007-01-24 JP JP2008551606A patent/JP5466406B2/ja not_active Expired - Fee Related
- 2007-01-24 CN CNA2007800033287A patent/CN101375437A/zh active Pending
- 2007-01-24 CA CA2637436A patent/CA2637436C/fr active Active
- 2007-01-24 ES ES07701717.6T patent/ES2550143T3/es active Active
- 2007-01-24 US US12/162,095 patent/US20090017378A1/en not_active Abandoned
- 2007-01-24 KR KR1020087020570A patent/KR101446812B1/ko not_active Expired - Fee Related
- 2007-01-24 EP EP07701717.6A patent/EP1997169B1/fr active Active
- 2007-01-24 CN CN201510187851.6A patent/CN104916817B/zh active Active
- 2007-01-24 WO PCT/CA2007/000091 patent/WO2007085077A1/fr not_active Ceased
-
2017
- 2017-08-11 US US15/675,184 patent/US11050059B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| ES2550143T3 (es) | 2015-11-04 |
| EP1997169A1 (fr) | 2008-12-03 |
| JP2009524568A (ja) | 2009-07-02 |
| CA2534243A1 (fr) | 2007-07-25 |
| CA2637436C (fr) | 2014-11-25 |
| WO2007085077A1 (fr) | 2007-08-02 |
| US20090017378A1 (en) | 2009-01-15 |
| KR101446812B1 (ko) | 2014-10-02 |
| US11050059B2 (en) | 2021-06-29 |
| KR20080088651A (ko) | 2008-10-02 |
| EP1997169B1 (fr) | 2015-08-12 |
| EP1997169A4 (fr) | 2013-08-07 |
| US20170346096A1 (en) | 2017-11-30 |
| CN101375437A (zh) | 2009-02-25 |
| CA2637436A1 (fr) | 2007-08-02 |
| CN104916817A (zh) | 2015-09-16 |
| CN104916817B (zh) | 2018-04-06 |
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