JP5358533B2 - マグネシウム電池 - Google Patents
マグネシウム電池 Download PDFInfo
- Publication number
- JP5358533B2 JP5358533B2 JP2010179770A JP2010179770A JP5358533B2 JP 5358533 B2 JP5358533 B2 JP 5358533B2 JP 2010179770 A JP2010179770 A JP 2010179770A JP 2010179770 A JP2010179770 A JP 2010179770A JP 5358533 B2 JP5358533 B2 JP 5358533B2
- Authority
- JP
- Japan
- Prior art keywords
- magnesium
- negative electrode
- ions
- magnesium battery
- battery
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000011777 magnesium Substances 0.000 title claims description 67
- 229910052749 magnesium Inorganic materials 0.000 title claims description 65
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 title claims description 64
- -1 citrate ions Chemical class 0.000 claims description 39
- 239000007864 aqueous solution Substances 0.000 claims description 28
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 26
- 239000001301 oxygen Substances 0.000 claims description 26
- 229910052760 oxygen Inorganic materials 0.000 claims description 26
- 239000003792 electrolyte Substances 0.000 claims description 25
- 239000008151 electrolyte solution Substances 0.000 claims description 25
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical class [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 14
- 239000007788 liquid Substances 0.000 claims description 12
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims description 11
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 claims description 8
- 229910001425 magnesium ion Inorganic materials 0.000 claims description 8
- 239000007774 positive electrode material Substances 0.000 claims description 5
- 239000007773 negative electrode material Substances 0.000 claims description 4
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims 2
- 239000000654 additive Substances 0.000 claims 1
- 230000000996 additive effect Effects 0.000 claims 1
- JIRRNZWTWJGJCT-UHFFFAOYSA-N carbamothioylthiourea Chemical compound NC(=S)NC(N)=S JIRRNZWTWJGJCT-UHFFFAOYSA-N 0.000 claims 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 9
- 150000007942 carboxylates Chemical class 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 239000000395 magnesium oxide Substances 0.000 description 6
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 6
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 6
- 239000003463 adsorbent Substances 0.000 description 5
- 239000011780 sodium chloride Substances 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000005868 electrolysis reaction Methods 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 3
- 239000000347 magnesium hydroxide Substances 0.000 description 3
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 3
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 238000003411 electrode reaction Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000005984 hydrogenation reaction Methods 0.000 description 2
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- MPCRDALPQLDDFX-UHFFFAOYSA-L Magnesium perchlorate Chemical compound [Mg+2].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O MPCRDALPQLDDFX-UHFFFAOYSA-L 0.000 description 1
- MUBZPKHOEPUJKR-UHFFFAOYSA-L Oxalate Chemical compound [O-]C(=O)C([O-])=O MUBZPKHOEPUJKR-UHFFFAOYSA-L 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000003139 buffering effect Effects 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 238000010668 complexation reaction Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 150000002680 magnesium Chemical class 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- BFDHFSHZJLFAMC-UHFFFAOYSA-L nickel(ii) hydroxide Chemical compound [OH-].[OH-].[Ni+2] BFDHFSHZJLFAMC-UHFFFAOYSA-L 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/054—Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M12/00—Hybrid cells; Manufacture thereof
- H01M12/04—Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type
- H01M12/06—Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type with one metallic and one gaseous electrode
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
- H01M4/46—Alloys based on magnesium or aluminium
- H01M4/466—Magnesium based
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/04—Cells with aqueous electrolyte
- H01M6/045—Cells with aqueous electrolyte characterised by aqueous electrolyte
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0002—Aqueous electrolytes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Hybrid Cells (AREA)
- Primary Cells (AREA)
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2010179770A JP5358533B2 (ja) | 2010-08-10 | 2010-08-10 | マグネシウム電池 |
| EP11816455.7A EP2605329A4 (en) | 2010-08-10 | 2011-08-10 | MAGNESIUM BATTERY |
| CN201180049040XA CN103314479A (zh) | 2010-08-10 | 2011-08-10 | 镁电池 |
| PCT/JP2011/068258 WO2012020791A1 (ja) | 2010-08-10 | 2011-08-10 | マグネシウム電池 |
| US13/816,017 US20130202954A1 (en) | 2010-08-10 | 2011-08-10 | Magnesium battery |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2010179770A JP5358533B2 (ja) | 2010-08-10 | 2010-08-10 | マグネシウム電池 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2012038666A JP2012038666A (ja) | 2012-02-23 |
| JP2012038666A5 JP2012038666A5 (enExample) | 2013-07-04 |
| JP5358533B2 true JP5358533B2 (ja) | 2013-12-04 |
Family
ID=45567753
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2010179770A Expired - Fee Related JP5358533B2 (ja) | 2010-08-10 | 2010-08-10 | マグネシウム電池 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US20130202954A1 (enExample) |
| EP (1) | EP2605329A4 (enExample) |
| JP (1) | JP5358533B2 (enExample) |
| CN (1) | CN103314479A (enExample) |
| WO (1) | WO2012020791A1 (enExample) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9461305B2 (en) | 2011-04-18 | 2016-10-04 | Tohoku University | Magnesium alloy fuel cell |
| JP2013206872A (ja) * | 2012-03-29 | 2013-10-07 | Honda Motor Co Ltd | 金属酸素電池 |
| JP5737727B2 (ja) * | 2012-12-27 | 2015-06-17 | 株式会社東洋製作所 | マグネシウム電池 |
| CN103545578B (zh) * | 2013-09-30 | 2016-03-02 | 刘甲祥 | 一种镁空气电池的电解液 |
| JP6589439B2 (ja) * | 2015-07-30 | 2019-10-16 | 株式会社Gsユアサ | アルカリ蓄電池 |
| TWI553948B (zh) * | 2015-08-31 | 2016-10-11 | 吳佳典 | 電池 |
| JP2021073635A (ja) * | 2017-01-11 | 2021-05-13 | 幸信 森 | ニッケル−マグネシウム電池 |
| US11717671B2 (en) * | 2017-04-21 | 2023-08-08 | Nippon Telegraph And Telephone Corporation | Biological tissue transdermal patch |
| CN108054403A (zh) * | 2017-12-05 | 2018-05-18 | 河南科技大学 | 海藻酸钠的应用、镁-空气电池用电解液缓蚀剂、电解液及其制备方法、镁-空气电池 |
| JP7711070B2 (ja) * | 2020-01-06 | 2025-07-22 | エル3ハリス オープン ウォーター パワー, インコーポレイテッド | 電解質の設計方法およびシステム |
| CN111951649A (zh) * | 2020-09-02 | 2020-11-17 | 西南大学 | 一种新型教学展示柠檬发电装置及其操作方法 |
| CN114552072B (zh) * | 2020-11-25 | 2024-05-07 | 中国科学院大连化学物理研究所 | 一种水系镁电池电解液 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3258368A (en) * | 1963-05-20 | 1966-06-28 | Dow Chemical Co | Organic electrolyte for magnesium primary cells |
| US3433678A (en) * | 1967-08-29 | 1969-03-18 | Esb Inc | Seawater battery having magnesium or zinc anode and manganese dioxide cathode |
| JPH071566U (ja) * | 1992-05-11 | 1995-01-10 | 久也 広瀬 | クエン酸電解液で満たされているマンガン一次乾電池 |
| IT1302953B1 (it) * | 1998-12-29 | 2000-10-10 | Consiglio Nazionale Ricerche | Batteria primaria attivata da acqua particolarmente adatta per unimpiego subacqueo anche ecologico. |
| US6706432B2 (en) * | 2001-08-01 | 2004-03-16 | Magpower Systems, Inc. | Methods and products for improving performance of batteries/fuel cells |
| JP2003338492A (ja) | 2002-05-21 | 2003-11-28 | Tokyo Electron Ltd | プラズマ処理装置 |
| US7455929B2 (en) * | 2003-11-26 | 2008-11-25 | Eveready Battery Company, Inc. | Air cell with improved leakage resistance |
| WO2007116872A1 (ja) * | 2006-04-03 | 2007-10-18 | Tsc Co., Ltd. | 水発電用合金、前記合金を用いる水発電装置、及び水発電方法 |
| JP2010182435A (ja) * | 2009-02-03 | 2010-08-19 | Suzuki Senkei | マグネシウム電池 |
-
2010
- 2010-08-10 JP JP2010179770A patent/JP5358533B2/ja not_active Expired - Fee Related
-
2011
- 2011-08-10 CN CN201180049040XA patent/CN103314479A/zh active Pending
- 2011-08-10 US US13/816,017 patent/US20130202954A1/en not_active Abandoned
- 2011-08-10 EP EP11816455.7A patent/EP2605329A4/en not_active Withdrawn
- 2011-08-10 WO PCT/JP2011/068258 patent/WO2012020791A1/ja not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| WO2012020791A1 (ja) | 2012-02-16 |
| CN103314479A (zh) | 2013-09-18 |
| US20130202954A1 (en) | 2013-08-08 |
| EP2605329A1 (en) | 2013-06-19 |
| EP2605329A4 (en) | 2015-01-21 |
| JP2012038666A (ja) | 2012-02-23 |
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