200810206 (1) 九、發明說明 【發明所屬之技術領域】 本發明係關於水發電用合金、使用前述水發電用合金 之裝置，及使用前述水發電用合金之水發電方法。更詳細 ~ 地說，是關於具有特定的組成之合金、藉由使前述合金與 水接觸而產生電力之水發電裝置，及使前述合金與水接觸 而進行發電之水發電方法。 【先前技術】 從前，乾電池伴隨著電晶體收音機的普及，而要求著 使用於可攜收音機用的錳電池的放電性能、耐漏液性能等 之高性能化，並開發出高性能錳乾電池，鹼錳乾電池等。 此外，對使用於石英手錶或電玩相關商品的氧化銀電池也 有所改良，開發出鹼性鈕釦電池或一次性鋰電池。 另一方面，堅固且即使長時間放置後亦少有性能降低 春 ，對於負荷特性優異的鎳鎘電池或鎳氫電池、鋰離子電池 等二次電池也被開發出來，應用於電動工具或者無線電話 【發明內容】 [發明之揭示] [發明所欲解決之課題] 這些電池，功率很小，應用在收音機、手錶、計算機 及其他小型電子機器等的用途上，性能相當優秀。 200810206 (2) 但是，這些的放電電壓即使是最高的鋰離子電池也只 有3.7V，因此可以使用的機械/器具受到某種程度的限定 。此外，即使是可以反覆充電使用，在完全沒有送電設備 的偏僻地點或者是送電設備被破壞的災區等地，要使必要 ‘的機器類等運作則仍然不夠用。 進而，使用完畢後因爲含有重金屬的緣故，不能與其 他垃圾混在一起而必須另行回收，若沒有完備的回收體系 φ 的話在環境上會產生問題。 此外，伴隨著電子機器的高機能化與小型化，對於電 池或小型發電裝置之需求也變大。 此外，近年來，在接連發生大地震，及伴隨著引起海 嘯等的災區，送電設備多已被破壞，災民很難取得災害資 訊或救援資訊。即使在手邊有可攜收音機，也因爲考量到 電池的壽命而不能持續地打開，此外，即使是可充電式的 ，只要送電設備被破壞，就無法充電了，問題還是沒解決 在這樣的場合，如果有可以長時間使用的發電裝置的 話，災民可以獲得適當的災害資訊或者救援資訊，可以防 止二次災害。 ^ 亦即，從防災的角度來看，對小型發電裝置的需求相 當強。 此外，針對行動電話，隨著機種的不同有些即使關機 ，剩餘電量也會減少，所以必須經常充電，因而期待著容 量更大的電池的開發。 -5- 200810206 (3) [供解決課題之手段] 本發明有鑑於以上所述的狀況，進行了積極的硏 開發出含有特定成分的合金，並且發現藉由使此合金 反應，可以得到高放電電壓，因而完成了本發明°本 之目的在於提供藉由與水接觸而可長時間發電的合金 用該合金的小型發電裝置，及發電方法。 亦即，本發明之水發電用合金特徵爲：總重量的 〜9 7.7重量百分比爲鎂、鋁、鈉及鐵所構成，總重 1.7〜8.5重量百分比爲鈣、銅及鋰所構成，總重量之 〜3.5重量百分比爲鎳、鈦、鎢及鉍所構成之群之中 至少三種以上的金屬所構成。 此處，前述合金，最好含有5 9 . 〇〜8 6 · 0重量百分 簡寫爲「重量％」）之鎂，10.5〜15.5重量％之鋁，（ 10.0重量％之金屬鈉，0.2〜3.0重量％之鋰，〇·3〜1 量％鎳，0.2〜1.3重量％之鈦，0.1〜0.6%之鎢，1.0' 重量％之鐵，1.0〜3.5重量％之鈣，〇·5〜2.0重量％ 〇 此外，本發明係一種水發電裝置，其特徵爲具備 申請專利範圍第1項之合金所製作的負極構件、正極 材、隔離前述負極構件與前述正極塡充材之吸水性分 、聚集在前述正極塡充材所產生的電荷之集電體、及 一面以前述分隔板之一部分構成的供適當注入發電用 之水室。 究， 與水 發明 、使 8 8.0 量之 0.6 選出 比（ ).2〜 • 6重 -3.5 之銅 :以 塡充 隔板 至少 的水 -6- 200810206 (4) 此處，前述負極構件，最好係供塡充前述正殛構件之 用的圚柱狀或者多角形狀的外筒。於本發明之發電裝置， 外筒的深度並未有特別限定，可以因應於機器的大小或必 要的電力，而自由改變大小。 > 此外，前述負極構件，最好係於被塡充於以絕緣材料 構成的圓柱狀或多角形狀的外筒中的前述正極塡充材中所 被配置之由板狀、棒狀、筒狀及多角柱狀所構成的群中選 φ 出的形狀的構件。前述負極構件，如前所述可以作爲構成 外筒者來使用，也可以用其他絕緣構件構成外筒之後，單 獨作爲負極構件而構成。此外，在此場合，可以適當變更 配置的負極構件的數目。 進而，前述分隔板，最好是具有2〜10 μπι之厚度，爲 吸水性之板狀構件較佳。將前述分隔板，以具有其乾燥重 量的1 0 0〜2 0 0倍的吸水能力的紙、布帛及層積這些所形 成的板狀材料構成的話，發電所必須的水可跨長期間被保 φ 持，可以持續進行發電。 此外，前述分隔板，可以在前述負極端子側被折曲， 形成包住前述正極塡充材料的底面，而在前述底面與具有 開口部的水室形成用環狀構件之間形成水室。此外，最好 ^ 形成由覆蓋前述負極構件的板狀構件以及形成包覆前述正 極材料的底面的板狀構件所構成，透過前述底面使前述正 極構件持續與水接觸的水室。此外，前述集電體以係碳棒 爲佳。 本發明之水發電裝置使用的正極塡充材，最好是以含 200810206 (5) 有銨離子與氟離子之pH爲8〜11之35〜50 °C之處理液浸 漬處理，而後乾燥之活性炭。此外，最好含有特定量之由 蘋果酸、檸檬酸及枸橼酸所構成的群中選出的1種酸，與 特定量之銅粉及二氧化錳，以及特定量的氯化鈣或者氯化 ‘鈉之活性炭、富勒嫌（fullerene )、奈米碳管所構成的群 中選出之任一。 此外，此處，前述正極塡充材，最好爲含有特定量之 φ 由蘋果酸、檸檬酸及枸橼酸所構成的群中選出的1種酸， 與特定量之銅粉及二氧化錳，以及特定量的氯化鈣或者氯 化鈉，且成形爲海綿狀之活性炭、富勒烯（fullerene )、 奈米碳管所構成的群中選出之任一。 本發明，係進而以前述合金爲負極構件，以含有銨離 子之pH爲8〜11之35〜50 °C之處理液浸漬處理，乾燥之 後，以氫氟酸處理，乾燥後之活性炭、富勒烯（fullerene )、奈米碳管所構成的群中所選出之任一作爲正極塡充材 φ 料，以吸水性分隔板隔離前述負極構件與前述正極塡充材 料，使前述分隔板吸水，而藉由使前述正極塡充材料與水 持續地接觸產生電位差之水發電方法。 前述正極塡充材，最好具有與負極構件的剖面相同形 ‘ 狀與大小，且以具備保濕性的板狀構件隔開。作爲這樣的 板狀構件，可以舉出例如洋紙、和紙或其他紙類、天然或 合成之高分子樹脂所構成的不織布，以使用與前述分隔板 相同的材料較佳。 藉由如此構成’使對前述正極構件中之水的擴散成爲 -8- 200810206 (6) 均一，可以得到高的電位差。 本發明亦可係一種水發電方法，其特徵爲：以前述方 式製造之合金爲負極構件，以含有特定量之由蘋果酸、檸 檬酸及枸橼酸所構成的群中選出的1種酸，與特定量之銅 粉及二氧化錳，以及特定量的氯化鈣或者氯化鈉之活性炭 、富勒烯（fullerene )、奈米碳管所構成的群中選出之任 一爲IE極塡充材料，以吸水性分隔板隔離前述負極構件與 φ 前述正極塡充材料，使前述分隔板吸水，而藉由使前述正 極塡充材料與水持續地接觸產生電位差。 藉由採用如前述之水發電方法，可以跨長期間得到所 要的電位差。 此外，本發明，可以採如前述方式製造之合金爲負極 構件’含有前述之特定的酸、特定量之銅粉以及二氧化錳 以及特定量之鹽，而以被成形爲海綿狀的活性炭、富勒烯 (fullerene )、奈米碳管所構成的群中選出之任一爲正極 _ 塡充材料。 此處，前述分隔板，最好覆蓋前述負極構件，在前述 一方之側被折彎，形成包住前述正極塡充材料的底面，或 者由覆蓋前述負極構件的板狀構件與形成包住前述正極材 料的底面之板狀構件所構成，介由前述底面前述正極構件 與水持續接觸。 [發明之效果] 根據本發明之發電用合金，僅使與水接觸就可以達成 -9- 200810206 (7) 可使其產生電位差的效果。 此外，根據將本發明之發電用合金作爲負極構件使用 ，而使用如上述般進行處理所製造之正極塡充材的水發電 裝置，可以跨長時間安定地產生大的電位差，可以使電子 + 機器等正常工作。 進而，根據本發明之水發電方法，可以跨長時間安定 地產生大的電位差。 【實施方式】 [供實施發明之最佳型態] 以下，說明本發明之水發電用合金之實施型態。 本發明之水發電用合金，如前所述，係總重量的88.0 〜97.7重量百分比爲鎂、鋁、鈉及鐵所構成，總重量之 1·7〜8.5重量百分比爲鈣、銅、鋰及鉍所構成的群中所選 出之至少3種以上的元素所構成，總重量之0 · 6〜3 · 5重量 • 百分比爲鎳、鈦及鎢所構成。 構成前述合金的元素的組成比，在前述的數値範圍以 外的場合，所產生的電位差會變得不充分。 此外，鎂、鋁、鈉以及鐵的組成比，最好是59.0〜 86.0重量％之鎂、10.5〜15.5重量％之鋁、0.2〜1〇·〇重 量％之金屬鈉與1.0〜3.5重量％之鐵較佳。 此外’最好爲含有0.2〜3.0重量％之銀、0.3〜1.6重 量％之鎳、0.2〜1·3重量％之鈦、0·1〜0.6重量％之鎢、 1.0〜3.5重量％之鈣、〇.5〜2.0重量％之銅。 -10- 200810206 (8) 此處，、銅、鋰以及_ IIL所構成的群中選出最少3種 類以上之組合，發生的電荷很大，所以鈣、銅以及鋰之組 合可適合於使用。 前述之本發明的合金，可以如以下方式製造。 最初’舉製造100g之合金的場合爲例加以說明。首 先，以使前述各元素成爲分別的含有量的方式進行秤重， 在容器中混合。接著，將這混合物在約12〇〇〜1 800 °C下加 Φ 熱10〜3 0分鐘，熔融而成爲合金。 把所得到的合金，以常法藉由壓出成型法進行成型， 成爲內徑約6〜1 1mm、外徑約10〜14mm、壁厚約0.8〜 約1 · 4mm的管狀構件。接著，將此管切斷爲所要的長度， 製造例如與4號電池同等大小的圓筒狀外筒（^10.3mm X 44.1mm)，作爲負極構件。 又’此合金，亦可做成如前述之管狀構件，亦可做成 厚度約〇·8〜約1.4mm之板狀構件，或直徑約1〜3mm的 φ 線狀構件。以前述金屬或以其他的金屬製造外筒時，例如 ’將作爲板狀構件之前述合金切斷爲具有所要的寬幅的與 長度的短片狀構件，將此作爲負極構件使用亦可。此外， 作爲線狀構件將前述合金切斷爲所要的長度，作爲負極構 件使用亦可。在此場合，負極構件的數目並無特別限定， 可以應必要而增減。 其次’參照圖1〜圖7說明使用本發明之水發電用合 金之水發電裝置之一實施型態。 於圖1，顯示相關於本發明之一實施型態之發電裝置 -11 - 200810206 Ο) 1 〇的構成之xz剖面圖。圖1所記載之發電裝置’具備： (a )以前述之合金所製作的管狀負極構件8、及（b )以 後述之鹼性溶液浸漬處理之正極塡充材（活性炭）1 2、及 (c)隔離負極構件8與正極塡充材12之吸水性的分隔板 > 6、及（d)聚集在正極塡充材12所產生的電荷之集電體4 、及（e)至少一面以分隔板6之一部分構成的供適當注 入發電用的水之水室20。 φ 此處，管狀之負極構件8，如前所述，可以做成厚度 約0 · 6〜約1.4 mm之管狀構件。此負極構件8，在本實施 型態是做成與4號乾電池相同大小的圓筒。 此外，作爲集電器4，例如可以使用直徑1.2〜1.5mm 之市售的炭棒。具體而言，可以使用第一炭素（製）公司 之乾電池用炭棒等。又，作爲集電體，除了炭棒以外，也 可以使用不绣鋼棒、膠木（ebonite)棒等。 此外’分隔板6沿著如前所述製造的外筒的內壁而配 # 置。分隔板6，最好是具有約2〜1 0 μιη之厚度的吸水性板 狀構件，更好的是具有約4 μ ιη之厚度者。 此外’前述分隔板6，最好係具有其乾燥重量的1〇〇 〜2 00倍的吸水能力的紙、布帛、不織布及層積這些所形 成的板狀材料所構成的群中所選出之任一者。前述之紙、 布帛以及不織布，亦可使用和紙或其他天然材料來製造， 亦可使用聚酯或其他合成高分子來製造。 層積這些而形成的板狀構件，·亦可以爲層積2層使用 和紙或其他天然材料而製造之板，亦可層積2層使用合成 -12- 200810206 (10) 筒分子製造之板，亦可層積使用天然材料之板與使用合成 高分子製造之板而形成者。 雖然使用具有前述之厚度與吸水能之紙、布帛以及不 織布以及層積這些而形成的板狀構件，但最好能使前述之 ~ 合金不生鏽而維持與水之接觸。 作爲這樣的紙、布帛、不織布以及層積這些而形成的 板狀材料，例如可以使用楮樹（Broussonetia kazinoki) ^ 或結香（Edgeworthia chrysantha )爲原料之和紙、碳纖維 、絲等或其他、三菱製紙（股）製造之不織布（ Dyaspanless (音譯））、東洋紡織（股）之Lanceal (登 錄商標）F、Wattman股份有限公司製造之厚質濾紙等。 本發電裝置10所使用的正極塡充材，使用處理過的 活性炭。活性炭，亦可爲購入市售的200〜300目者，以 鹼性液體進行浸漬處理，或者與後述之其他成分以特定比 例混合調製。 • 具體而言，調製含有銨離子與氟離子之PH8〜11的溶 液，使此溶液爲35〜50 °C，於其中浸漬前述活性炭約15[Technical Field] The present invention relates to an alloy for water power generation, an apparatus using the above-described water power generation alloy, and a water power generation method using the water power generation alloy. More specifically, it is a water power generation device having an alloy having a specific composition, generating electric power by bringing the alloy into contact with water, and a water power generation method for generating electricity by bringing the alloy into contact with water. [Prior Art] In the past, dry batteries have become popular with transistor radios, and have required high performance in discharge performance and liquid leakage resistance of manganese batteries for portable radios, and developed high-performance manganese dry batteries, alkali manganese. Dry battery, etc. In addition, silver oxide batteries used in quartz watches or video games have also been improved, and alkaline button batteries or disposable lithium batteries have been developed. On the other hand, it is sturdy and has little performance degradation after a long period of time. For secondary batteries such as nickel-cadmium batteries, nickel-hydrogen batteries, and lithium-ion batteries, which have excellent load characteristics, they have been developed for use in power tools or wireless phones. DISCLOSURE OF THE INVENTION [Disclosure of the Invention] [Problems to be Solved by the Invention] These batteries have low power and are excellent for use in applications such as radios, watches, computers, and other small electronic devices. 200810206 (2) However, these discharge voltages are only 3.7V even for the highest lithium-ion batteries, so the machines/appliances that can be used are somewhat limited. In addition, even if it can be used for repeated charging, in places where there is no power transmission equipment at all, or in a disaster area where power transmission equipment is destroyed, it is still not enough to make necessary equipment operations. Further, since it is contained in heavy metals, it cannot be mixed with other garbage and must be separately recovered. If there is no complete recovery system φ, there is a problem in the environment. In addition, with the increase in the performance and miniaturization of electronic equipment, the demand for batteries or small-sized power generation devices has also increased. In addition, in recent years, in large-scale earthquakes and disaster areas that cause tsunami, power transmission equipment has been destroyed, and it is difficult for victims to obtain disaster information or rescue information. Even if there is a portable radio at hand, it cannot be continuously turned on because of the life of the battery. In addition, even if it is rechargeable, as long as the power transmission device is destroyed, it cannot be charged. The problem is still not solved in such a situation. If there is a power generation device that can be used for a long time, the disaster victims can obtain appropriate disaster information or rescue information to prevent secondary disasters. ^ That is, from the perspective of disaster prevention, the demand for small power generation units is quite strong. In addition, for mobile phones, depending on the model, even if the power is turned off, the remaining power is reduced, so it is necessary to charge frequently, and thus it is expected to develop a battery with a larger capacity. -5-200810206 (3) [Means for Solving the Problem] In view of the above-described circumstances, the present invention has actively developed an alloy containing a specific component, and found that a high discharge can be obtained by reacting the alloy. The present invention has been completed in order to provide a small-sized power generation device for an alloy which can generate electricity for a long period of time by contact with water, and a power generation method. That is, the alloy for water power generation of the present invention is characterized in that: ～ 7.7 wt% of the total weight is composed of magnesium, aluminum, sodium and iron, and the total weight is 1.7 to 8.5 wt% composed of calcium, copper and lithium, and the total weight The 3.5% by weight is composed of at least three or more metals selected from the group consisting of nickel, titanium, tungsten and rhenium. Here, the alloy preferably contains 5 9 . 〇 8 8 · 0 wt% abbreviated as "% by weight" of magnesium, 10.5 to 15.5 wt% of aluminum, (10.0 wt% of sodium metal, 0.2 to 3.0) % by weight of lithium, 〇·3~1 by volume of nickel, 0.2 to 1.3% by weight of titanium, 0.1 to 0.6% of tungsten, 1.0% by weight of iron, 1.0 to 3.5% by weight of calcium, 〇·5 to 2.0 by weight Further, the present invention is a water power generation device characterized in that the negative electrode member, the positive electrode material, the isolation of the negative electrode member, and the positive electrode chelating material produced by the alloy of the first application of the patent application range are aggregated. The current collector of the electric charge generated by the positive electrode enthalpy and the water chamber which is formed by a part of the partition plate for proper injection into power generation. In comparison with the water invention, the ratio of 0.6 of 8 8.0 is selected ( ) .2~ • 6-3.5 copper: at least water-filled separator -6- 200810206 (4) Here, the negative electrode member is preferably a columnar shape for the purpose of filling the above-mentioned normal member or a polygonal outer cylinder. In the power generating device of the present invention, the depth of the outer cylinder is not In particular, the size of the negative electrode member can be freely changed in accordance with the size of the machine or the necessary electric power. Further, the negative electrode member is preferably attached to the outer cylinder of a cylindrical or polygonal shape formed of an insulating material. A member having a shape selected from the group consisting of a plate shape, a rod shape, a cylindrical shape, and a polygonal column shape disposed in the positive electrode 塡 filling material. The negative electrode member may be configured as an outer cylinder as described above. In the case where the outer cylinder is formed of another insulating member, it may be configured as a negative electrode member alone. In this case, the number of the negative electrode members to be disposed may be appropriately changed. Further, the partition plate preferably has 2 to 10 The thickness of μπι is preferably a plate-like member that absorbs water. The separator plate is formed into a plate shape by a paper having a water absorption capacity of 10 to 200 times its dry weight, a cloth, and a laminate. In the case of the material, the water necessary for power generation can be maintained for a long period of time, and power generation can be continued. Further, the partition plate can be bent at the side of the negative electrode terminal to form a package. A water chamber is formed between the bottom surface and the annular member for forming a water chamber having an opening in the bottom surface of the positive electrode aging material. Further, it is preferable to form a plate member covering the negative electrode member and to form a coating. The plate-shaped member on the bottom surface of the positive electrode material is configured to pass through the bottom surface to keep the positive electrode member in contact with water in the water chamber. The current collector is preferably a carbon rod. The positive electrode charging device used in the water power generating device of the present invention The material is preferably immersed in a treatment liquid containing 200810206 (5) having a pH of 8 to 11 at a pH of 8 to 11 and then drying the activated carbon. Further, it is preferable to contain a specific amount of apple. An acid selected from the group consisting of acid, citric acid and citric acid, with a specific amount of copper powder and manganese dioxide, and a specific amount of calcium chloride or sodium chlorinated activated carbon, fullerene ), one of the groups consisting of carbon nanotubes. Further, the positive electrode enthalpy is preferably one type of acid selected from the group consisting of malic acid, citric acid and citric acid in a specific amount of φ, and a specific amount of copper powder and manganese dioxide. And a selected amount of calcium chloride or sodium chloride, and selected from the group consisting of sponge-like activated carbon, fullerene, and carbon nanotubes. According to the present invention, the alloy is used as a negative electrode member, and is immersed in a treatment liquid containing ammonium ions at a pH of 8 to 11 at 35 to 50 ° C, dried, and then treated with hydrofluoric acid, and dried activated carbon, Fuller Any one selected from the group consisting of a fullerene and a carbon nanotube as the positive electrode ruthenium material, isolating the negative electrode member and the positive electrode chelating material with a water absorbing partition plate, so that the partition plate absorbs water A water power generation method in which a potential difference is generated by continuously bringing the positive electrode enthalpy material into contact with water. Preferably, the positive electrode enthalpy is formed in the same shape as the cross section of the negative electrode member, and is separated by a plate-like member having moisture absorbing properties. As such a plate-like member, for example, a non-woven fabric made of paper, paper or other paper, or a natural or synthetic polymer resin is used, and it is preferable to use the same material as the above-mentioned separator. By thus configuring the diffusion of water in the positive electrode member to be -8-200810206 (6), a high potential difference can be obtained. The present invention may also be a water power generation method, characterized in that the alloy produced in the above manner is a negative electrode member, and contains a specific amount of one acid selected from the group consisting of malic acid, citric acid and citric acid. Any one selected from the group consisting of a specific amount of copper powder and manganese dioxide, and a specific amount of calcium chloride or sodium chloride activated carbon, fullerene, and carbon nanotubes is IE. In the material, the negative electrode member and the positive electrode chelating material are separated by a water-absorptive partitioning plate to cause the separator to absorb water, and a potential difference is generated by continuously contacting the positive electrode chelating material with water. By using the water power generation method as described above, the desired potential difference can be obtained over a long period of time. Further, in the present invention, the alloy produced as described above may be a negative electrode member containing a specific acid as described above, a specific amount of copper powder, manganese dioxide, and a specific amount of salt, and is formed into a sponge-like activated carbon, rich. Any one selected from the group consisting of fullerene and carbon nanotubes is a positive electrode _ 塡 filling material. Here, it is preferable that the partition plate covers the negative electrode member, and is bent on one side to form a bottom surface of the positive electrode accommodating material, or a plate-shaped member covering the negative electrode member and formed to wrap the aforementioned The plate-shaped member of the bottom surface of the positive electrode material is formed, and the positive electrode member is continuously in contact with water via the bottom surface. [Effects of the Invention] According to the alloy for power generation of the present invention, it is possible to achieve a potential difference by merely bringing it into contact with water -9-200810206 (7). In addition, according to the water power generation device using the alloy for power generation of the present invention as a negative electrode member and using the positive electrode enthalpy material produced by the above-described treatment, it is possible to stably generate a large potential difference over a long period of time, and to make an electronic + machine Waiting for normal work. Further, according to the water power generation method of the present invention, it is possible to stably generate a large potential difference over a long period of time. [Embodiment] [Best Mode for Carrying Out the Invention] Hereinafter, an embodiment of the alloy for water power generation of the present invention will be described. The alloy for water power generation of the present invention is composed of magnesium, aluminum, sodium and iron in a total weight of 88.0 to 97.7 by weight, as described above, and the total weight of 1.7 to 8.5 weight percent is calcium, copper, lithium and It consists of at least three or more elements selected from the group consisting of 铋, and the total weight is 0·6~3 · 5 weights • The percentage is composed of nickel, titanium and tungsten. When the composition ratio of the elements constituting the alloy is outside the range of the above-mentioned number, the potential difference generated may be insufficient. Further, the composition ratio of magnesium, aluminum, sodium and iron is preferably 59.0 to 86.0% by weight of magnesium, 10.5 to 15.5% by weight of aluminum, 0.2 to 1% by weight of metallic sodium and 1.0 to 3.5% by weight. Iron is preferred. Further, it is preferable to contain 0.2 to 3.0% by weight of silver, 0.3 to 1.6% by weight of nickel, 0.2 to 1.3% by weight of titanium, 0.1 to 0.6% by weight of tungsten, 1.0 to 3.5% by weight of calcium, 〇. 5~2.0% by weight of copper. -10- 200810206 (8) Here, a combination of at least three types of copper, lithium, and _ IIL is selected to have a large charge, so that a combination of calcium, copper, and lithium can be used. The alloy of the present invention described above can be produced in the following manner. First, a case where an alloy of 100 g is produced will be described as an example. First, the respective elements are weighed so as to have a respective content, and are mixed in a container. Next, the mixture was heated at about 12 Torr to 1 800 ° C for 10 to 30 minutes, and melted to form an alloy. The obtained alloy was molded by an extrusion molding method in a usual manner to obtain a tubular member having an inner diameter of about 6 to 11 mm, an outer diameter of about 10 to 14 mm, and a wall thickness of about 0.8 to about 1. 4 mm. Next, the tube is cut to a desired length, and a cylindrical outer cylinder (^10.3 mm X 44.1 mm) having a size equivalent to that of the No. 4 battery is produced, for example, as a negative electrode member. Further, the alloy may be formed into a tubular member as described above, or may be formed into a plate-like member having a thickness of about 〇8 to about 1.4 mm or a φ linear member having a diameter of about 1 to 3 mm. When the outer cylinder is made of the metal or another metal, for example, the alloy which is a plate-like member is cut into a short sheet-like member having a desired width and length, and this may be used as a negative electrode member. Further, the alloy may be cut into a desired length as a linear member, and may be used as a negative electrode member. In this case, the number of the negative electrode members is not particularly limited, and may be increased or decreased as necessary. Next, an embodiment of a water power generator using the water for power generation of the present invention will be described with reference to Figs. 1 to 7 . Fig. 1 is a cross-sectional view showing the configuration of a power generating device -11 - 200810206 Ο) 1 〇 according to an embodiment of the present invention. The power generating device described in Fig. 1 includes: (a) a tubular negative electrode member 8 made of the above-described alloy, and (b) an anode immersion material (activated carbon) impregnated with an alkaline solution to be described later (2, and ( c) a separator for isolating the water absorbing property of the negative electrode member 8 and the positive electrode chelating material> 6, and (d) a current collector 4 which accumulates charges generated by the positive electrode hydride material 12, and (e) at least one side A water chamber 20 of a portion of the partitioning plate 6 for appropriately injecting water for power generation. φ Here, the tubular negative electrode member 8, as described above, can be formed into a tubular member having a thickness of about 0.6 to about 1.4 mm. In the present embodiment, the negative electrode member 8 is a cylinder having the same size as that of the No. 4 dry battery. Further, as the current collector 4, for example, a commercially available carbon rod having a diameter of 1.2 to 1.5 mm can be used. Specifically, a carbon rod for dry batteries of the first carbon company can be used. Further, as the current collector, in addition to the carbon rod, a stainless steel rod, an ebonite rod or the like may be used. Further, the partition plate 6 is disposed along the inner wall of the outer cylinder manufactured as described above. The partitioning plate 6, preferably a water-absorbent plate-like member having a thickness of about 2 to 10 μm, more preferably has a thickness of about 4 μm. Further, the above-mentioned partitioning plate 6 is preferably selected from the group consisting of paper having a water absorption capacity of 1 to 20,000 times its dry weight, cloth, non-woven fabric, and laminating material formed by lamination. Either. The aforementioned paper, cloth and non-woven fabrics may also be produced using paper or other natural materials, or may be made of polyester or other synthetic polymers. A plate-like member formed by laminating these may be a plate produced by laminating two layers of paper or other natural materials, or a laminate of two layers using a synthetic -12-200810206 (10) tube molecule. It is also possible to laminate a plate made of a natural material and a plate made of a synthetic polymer. Although a plate-like member formed by laminating paper having a thickness and water absorption energy as described above and laminating is used, it is preferable that the alloy can be kept from contact with water without rusting. As the plate-like material formed by such paper, cloth, non-woven fabric, and laminated, for example, Broussonetia kazinoki or Edgeworthia chrysantha can be used as a raw material for paper, carbon fiber, silk, or the like, or Mitsubishi paper ( Non-woven fabrics (Dyaspanless), Lancel (registered trademark) F of Toyo Textile Co., Ltd., and thick filter paper manufactured by Wattman Co., Ltd. The positive electrode ruthenium used in the power generator 10 uses treated activated carbon. The activated carbon may be immersed in an alkaline liquid or purchased in a specific ratio with other components described later, in the case of commercially available 200 to 300 mesh. • Specifically, a solution containing pH 8 to 11 of ammonium ion and fluoride ion is prepared, and the solution is 35 to 50 ° C, and the activated carbon is immersed therein for about 15
〜6〇分鐘，其後撈起使自然乾燥。將此作爲正極塡充材A 〇 ’ 此外，此正極塡充材可以藉由含有特定量之由蘋果酸 、檸檬酸及枸橼酸所構成的群中選出的1種酸，與特定量 之銅粉及二氧化錳，以及特定量的氯化鈣或者氯化鈉，與 活性炭成爲均勻的方式混合而進行調製。 具體而言，首先，將活性炭之1/60〜1/10量（體積比 -13- 200810206 (11) )之蘋果酸、檸檬酸及枸橼酸所構成的群中選出的至少1 種酸，與活性炭混合攪拌。接著於此混合物，加_人1/200 〜1/20量（體積比）之二氧化錳、1/50〜1/10量（體積比 )之氯化鈣或氯化鈉以使其成爲均勻的方式攪拌，將此作 _ 爲正極塡充材B。 如以上所述進行而將處理、調整之活性炭作爲正極塡 充材料使用。又使用由竹炭製造的活性炭的話，發電效果 φ 較高。 又，作爲正極塡充材，可以在（1 )海綿狀的炭薄板 (PERMA-FOIL (登錄商標）、東洋炭素（股））上，使 其重量的1/60〜1/10 (體積比）之蘋果酸、檸檬酸及枸橼 酸所構成的群中選出的至少1種酸，與1/200〜1/20量（ 體積比）之二氧化錳、1/50〜1/10量（體積比）之氯化鈣 或氯化鈉以使其成爲均勻的方式混合而成的混合物附著於 其上及將銅網（網狀構件）作爲正極塡充材C使用。 φ 將前述正極塡充材塡充於負極構件時，可以用具有與 負極構件的剖面相同形狀與大小，且以具備保濕性的板狀 構件之隔壁用構件隔開的方式構成。 於這樣的板狀構件，例如可以使用洋紙、和紙或其他 J 紙類、天然或合成之高分子樹脂所構成的不織布，作爲前 述之分隔板使用的板狀材料等。 這些之中，由保濕性高以及製造成本的角度看，最好 是能夠使用與前述分隔板相同的材料。 接著，藉由如此構成，被注入往前述正極構件中的水 -14- 200810206 (12) 暫時先保持於隔壁用構件，其後，擴散至正極塡充材中。 藉此，正極構件中之水的擴散更爲均勻，而可以得到高的 電位差。 具體而言，首先，將一定量的前述正極塡充材塡充於 ~ 負極構件中。於其上載設具有如前所述的形狀與大小的隔 壁用構件，進而塡充前述正極構件。隔壁用構件，僅1枚 即可，適當使用2枚以上亦可。 φ 水室20係以管狀的負極構件8的內壁，及後述之分 隔板6包住正極塡充材12的方式被折曲的面，及絕緣構 件14(墊片）所構成。於此水室20，可以貯流由後述之 開口部注入的水。 前述發電裝置進而具備（f)由正極部2a與絕緣部2b 所構成的正極端子2、（ g )具有開口部的絕緣構件14、 (h )被安裝於正極端子的相反側之具有開口部，且與負 極構件8電氣性導通之負極端子1 6。 Φ 絕緣構件14具有開口部，由此開口部使用注射器等 注入水的話，注入的水進入此水室20，透過形成於前述底 面的分隔板6接觸於正極塡充材12。接著，藉由分隔板6 吸水而由分隔板6的全面與前述正極塡充材1 2接觸，而 發生電荷。 此處發生的電荷，以集電體4集電，經由正極端子2 而取出。 製造此發電裝置1 〇時，首先如圖2所示，於正極部 2a的凹部安裝集電體4，於此處設置絕緣部2b，組合正極 -15- 200810206 (13) 端子2與集電體4。接著，將此嵌入負極構俗8 (外筒） 之一方之端。 其次，如圖3 A所示’以接於正極端子2的內側，且 與外筒8的內壁無間隙地接觸的方式’配置前述之吸水性 之分隔板。接著’前述分隔板’如圖1所不’以包住正極 構件之活性炭1 2的方式折曲同時形成水室2 0之一面。 接著，將如前述般處理之正極塡充材1 2 (活性炭）， φ 定量裝入成爲前述狀態的外筒中’折曲分隔板6之端而包 入活性炭。接著，依序設置具有開口部的絕緣構件1 4 (墊 片），與具有開口部的負極端子1 6，以絕緣材料絕緣外筒 的外側，成爲本實施型態的發電裝置1 〇。 又，圖8係模式顯示使用正極塡充材C的場合之圖。 又，在本實施型態，將負極構件做成與4號電池同大 的圓筒形，亦可以做成與市售之各種一次電池或二次電池 相同的大小。在此場合，藉由耐熱性聚乙烯、鐵氟龍、芳 # 香族聚醯胺（aramid )等其他絕緣材料構成的圓柱狀或多 角形狀之外筒，可以替代而使用於各種機器。 _ 此外，以這樣的絕緣材料構成外筒的場合，將負極構 件做成從板狀、棒狀、筒狀以及多角柱狀所構成的群中選 出的形狀，於被塡充於外筒的正極塡充材中，可以適當配 置。 [實施例] 以下’使用實施例詳細說明本發明之發電裝置。又， -16- 200810206 (14) 本發明並不限於以下之實施例。 (實施例1)水發電用合金及集電材之調製 (1)水發電用合金之調製 將各元素以表1所示之量進行秤重依序放入容器中進 行攪拌，成爲混合物。這些金屬皆使用市售品。 接著，將這混合物在1200°C下加熱1 5分鐘，得到合 金將此合金依據常法壓出成形，成爲內徑7.2mm、外 徑10.4mm的中空棒，切斷爲長度44mm的筒狀，作爲外 筒。 【表1】 金屬 合金組成（g ) Mg 78.0 A1 9.0 Na 0.6 Li 2.0 Ni 1.4 Τϊ 1.1 ................................................w... 0.4 F e 3.0 Ca 3.2 Cu 1.3~6〇 minutes, then pick up to make it dry naturally. This is used as the positive electrode A filling material A 〇 ' In addition, the positive electrode lanthanum material can be selected from a group consisting of malic acid, citric acid and citric acid, and a specific amount of copper. The powder and manganese dioxide, as well as a specific amount of calcium chloride or sodium chloride, are mixed with activated carbon in a uniform manner. Specifically, first, at least one acid selected from the group consisting of malic acid, citric acid, and citric acid in an amount of 1/60 to 1/10 of the activated carbon (volume ratio -13 - 200810206 (11)), Mix and stir with activated carbon. Next to this mixture, add 1/2 person to 1/200 to 1/20 (volume ratio) of manganese dioxide, 1/50 to 1/10 (volume ratio) of calcium chloride or sodium chloride to make it uniform. Stir in the way, and make this _ for the positive electrode 塡 filling material B. The activated carbon which was treated and adjusted as described above was used as a positive electrode hydride material. When activated carbon made of bamboo charcoal is used, the power generation effect φ is high. In addition, as the positive electrode ruthenium, it can be 1/60 to 1/10 (volume ratio) of (1) sponge-like carbon sheet (PERMA-FOIL (registered trademark), Toyo carbon (strand)) At least one acid selected from the group consisting of malic acid, citric acid and citric acid, and 1/200 to 1/20 (volume ratio) of manganese dioxide, 1/50 to 1/10 (volume A mixture of calcium chloride or sodium chloride mixed so as to be uniform is attached thereto, and a copper mesh (mesh member) is used as the positive electrode C. φ When the positive electrode enthalpy is filled in the negative electrode member, it may be configured to be partitioned by a partition member having the same shape and size as the cross section of the negative electrode member and having a plate member having moisture resistance. For such a plate-like member, for example, a non-woven fabric made of paper, paper or other J paper, natural or synthetic polymer resin, or a plate-like material used as the separator described above can be used. Among these, it is preferable to use the same material as the above-mentioned partition plate from the viewpoint of high moisture retention and manufacturing cost. Then, in this configuration, the water-14-200810206 (12) injected into the positive electrode member is temporarily held by the partition member, and then diffused into the positive electrode material. Thereby, the diffusion of water in the positive electrode member is more uniform, and a high potential difference can be obtained. Specifically, first, a certain amount of the above positive electrode ruthenium is filled in the negative electrode member. The partition member having the shape and size as described above is placed thereon to further fill the positive electrode member. The number of members for the partition wall may be one, and two or more may be used as appropriate. The φ water chamber 20 is composed of an inner wall of the tubular negative electrode member 8 and a surface on which the separator 6 is wrapped so as to surround the positive electrode material 12, and an insulating member 14 (gasket). In the water chamber 20, water injected from an opening portion to be described later can be stored. Further, the power generating device further includes (f) a positive electrode terminal 2 composed of the positive electrode portion 2a and the insulating portion 2b, and (h) an insulating member 14 having an opening, and (h) an opening portion attached to the opposite side of the positive electrode terminal. And a negative electrode terminal 16 electrically connected to the negative electrode member 8. Φ The insulating member 14 has an opening, and when the opening is filled with water using a syringe or the like, the injected water enters the water chamber 20, and passes through the partition plate 6 formed on the bottom surface to contact the positive electrode material 12. Next, by the water absorption of the partitioning plate 6, the entire surface of the partitioning plate 6 is brought into contact with the positive electrode enthalpy material 12, and electric charges are generated. The electric charge generated here is collected by the current collector 4 and taken out through the positive electrode terminal 2. When manufacturing the power generating device 1 ,, first, as shown in FIG. 2, the current collector 4 is attached to the concave portion of the positive electrode portion 2a, and the insulating portion 2b is provided here, and the positive electrode -15-200810206 (13) terminal 2 and the current collector are combined. 4. Next, this is embedded in one end of the negative electrode configuration 8 (outer tube). Then, as shown in Fig. 3A, the above-mentioned water-absorbent partitioning plate is disposed in such a manner as to be in contact with the inner side of the positive electrode terminal 2 and in contact with the inner wall of the outer cylinder 8 without a gap. Then, the above-mentioned partitioning plate is folded as shown in Fig. 1 so as to enclose the activated carbon 12 of the positive electrode member, and one surface of the water chamber 20 is formed. Then, the positive electrode crucible 1 2 (activated carbon) treated as described above, φ is quantitatively loaded into the outer cylinder of the above-described state, and the end of the baffle plate 6 is folded to incorporate activated carbon. Then, the insulating member 14 (pad) having the opening portion is provided in this order, and the negative electrode terminal 16 having the opening portion is insulated from the outer side of the outer tube by an insulating material to form the power generating device 1 of the present embodiment. Further, Fig. 8 is a view showing a case where the positive electrode fulcress C is used. Further, in the present embodiment, the negative electrode member has a cylindrical shape which is as large as the No. 4 battery, and may be made to have the same size as various commercially available primary batteries or secondary batteries. In this case, a cylindrical or polygonal outer cylinder made of other insulating materials such as heat-resistant polyethylene, Teflon, or aromatic aramid may be used instead of various machines. In the case where the outer cylinder is made of such an insulating material, the negative electrode member is formed into a shape selected from the group consisting of a plate shape, a rod shape, a cylindrical shape, and a polygonal column shape, and is attached to the positive electrode of the outer cylinder. In the 塡 filling material, it can be properly configured. [Examples] Hereinafter, a power generating apparatus of the present invention will be described in detail using examples. Further, -16- 200810206 (14) The present invention is not limited to the following embodiments. (Example 1) Preparation of alloy for water power generation and current collector (1) Preparation of alloy for water power generation Each element was weighed and placed in a container in the amounts shown in Table 1 and stirred to form a mixture. Commercially available products are used for these metals. Next, the mixture was heated at 1200 ° C for 15 minutes to obtain an alloy. The alloy was extrusion molded according to a conventional method to obtain a hollow rod having an inner diameter of 7.2 mm and an outer diameter of 10.4 mm, and was cut into a cylindrical shape having a length of 44 mm. As an outer cylinder. [Table 1] Metal alloy composition (g) Mg 78.0 A1 9.0 Na 0.6 Li 2.0 Ni 1.4 Τϊ 1.1 ............................ ....................w... 0.4 F e 3.0 Ca 3.2 Cu 1.3
(2)正極塡充材之調製 (2-1 )正極塡充材A之調製 調製含有氫氧化銨的浸漬液（約3L，pH9〜10)使用覆 套式電阻加熱器（mantle heater)加溫至36〜44°C。氫氧 -17- 200810206 (15) 化錢以及後述之氫氟酸是由Naealai Tesque公司購入。 接著，於其中加入市售之活性炭 500g ( Futamura Chemical Co·，Ltd·製造，200〜300目），於前述浸漬液 浸漬約2 0〜4 5分鐘’其後撈起使自然乾燥。將此浸漬於 ^ 含有氫氟酸之浸漬液（約3L)使其自然乾燥，調整正極 塡充材A。 g ( 2-2)正極塡充材B之調製 於6 0 0g活性炭，添加活性炭重量的1/20量之蘋果酸 、檸檬酸或枸橼酸之粉末，1 g之銅粉、及〇. 5g之氯化鈉 或二氧化錳而混和，調製正極塡充材B。此處使用的蘋果 酸、檸檬酸、枸橼酸係由藤井藥品工業（股）、關東化學 (股）所購入。此外，氯化鈉或二氧化錳，係由Nacalai Tesque公司購入，以硏缽磨細再使用。銅粉末使用三津和 化學藥品（股）製造之200〜400目之粉末。 (3)正極塡充劑C之調製 將厚度約5mm海綿狀的薄板切斷爲約25mmx3 6mm之 大小，此處，使混合了前述薄板的重量的1 /2 0量之蘋果 ^ 酸、檸檬酸或枸橼酸之粉末，1/600重量％之銅粉末、及 其一半量之氯化鈉或二氧化錳之混和物附著。將此正極塡 充劑與配置於其外側之市售的銅網作爲正極塡充材C。 (實施例2)水發電裝置之製造 -18- 200810206 (16) (l )沒有隔壁用構件之水發電裝置之製造 (1 -1 )使用正極塡充劑A或B之水發電裝置的製 造 作爲正極塡充材使用如實施例1 (2)所述般處理之正 極塡充材A或B。此外，於正極端子用絕緣構件，購入並 使用市售的鋁蓋。作爲集電體，購入並使用第一碳素（股 )製造的乾電池用炭素棒。作爲分隔板，購入較厚之濾紙 ·( Whatman社（股）製造），切斷爲約25mmx約3 6mm之 大小而使用。 具有開口部的絕緣構件（墊片）及具有開口部的負極 構件（環狀構件），購入使用市售品。 使前述之正極構件、正極端子用絕緣構件、集電體， 如圖2所示嵌入前述管狀構件之一端，作爲有底外筒。接 著，沿此外筒之內壁以不產生間隙的方式配置如上述般加 工的分隔板。 • 於此有底圓筒內，放入約1 8〜20g如實施例i所述地 處理之活性炭，折曲分隔板之端，以不會倒出活性炭的方 式包好。 其次，將前述之墊片設置於離開被折曲的分隔板約 5mm的位置’將前述環狀構件載置其上。塗布液狀的絕緣 構件使此外筒的外側絕緣，而製造本發明之水發電裝置。 (1-2 )使用正極塡充劑C之水發電裝置的製造方 法 -19- 200810206 (17) 如上所述將製作的正極塡充劑C以捲包炭棒的方式放 入。其次，在正極塡充劑C與有底外筒C之間，使市售的 銅網以成爲約25mmX約3 6mm大小的方式切斷，以包捲 正極塡充劑C的方式放入。 墊片、環狀構件等與前述（1-1)所述同樣的置入， 放入管狀的絕緣構件之中，使此外筒的外側絕緣，製造本 發明之水發電裝置。 (2)設有隔壁用構件之水發電裝置之製造 作爲隔壁用構件，把與前述分隔板相同的材料，切斷 爲與負極構件的剖面相同形狀及大小而作爲隔壁用構件， 如下所述除了塡充正極塡充材以外與前述（1 )同樣進行 ，而製造設有隔壁用構件之水發電袭置。 其次，將塡充於前述負極構件中的正極塡充材槪略分 爲1/3，首先，將最初的1/3以與前述（1 )同樣的方式塡 • 充。此處載設1枚如前述之隔壁用構件，於其上，塡充下 個1 /3之正極塡充材。其後，塡充剩餘的正極塡充材。 (實施例3)發電裝置之評價 ^ ( 1 )電位差之測定 使用在實施例1所製造的合金、及如前述處理之正極 塡充材A及B，依照實施例2所示的步驟，分別製造5個 4號電池尺寸的水發電裝置。使用電流計（秋月電子（股 )製造），進行電流的測定。又，電流係於電流計與水發 -20- 200810206 (18) 電裝置之間連接1 κ歐姆的電阻再進行測定。結果顯示於 表2。 【表2】(2) Preparation of positive electrode ruthenium material (2-1) Preparation of positive electrode ruthenium material A The immersion liquid containing ammonium hydroxide (about 3 L, pH 9 to 10) was heated using a mantle heater. To 36~44 °C. Hydrogen oxygen -17- 200810206 (15) The money and the hydrofluoric acid described later were purchased from Naealai Tesque. Then, 500 g of commercially available activated carbon (manufactured by Futamura Chemical Co., Ltd., 200 to 300 mesh) was added thereto, and the immersion liquid was immersed for about 20 to 45 minutes, and then picked up to be naturally dried. This was immersed in an impregnation liquid containing hydrofluoric acid (about 3 L) to be naturally dried, and the positive electrode ruthenium A was adjusted. g ( 2-2) The positive electrode 塡 filling material B is prepared on 60 g of activated carbon, adding 1/20 of the weight of activated carbon, malic acid, citric acid or citric acid powder, 1 g of copper powder, and 〇. 5 g The sodium hydride or manganese dioxide is mixed and the positive electrode 塡 filling material B is prepared. The malic acid, citric acid, and citric acid used herein were purchased from Fujii Pharmaceutical Industry Co., Ltd. and Kanto Chemical Co., Ltd. In addition, sodium chloride or manganese dioxide is purchased from Nacalai Tesque and used in honing. The copper powder is a powder of 200 to 400 mesh manufactured by Sanjin and Chemicals Co., Ltd. (3) Preparation of positive electrode squeezing agent C A sponge-like thin plate having a thickness of about 5 mm is cut into a size of about 25 mm x 3 6 mm, and here, an amount of 1 / 2 0 of apple acid and citric acid mixed with the weight of the above-mentioned thin plate is mixed. Or a mixture of citric acid powder, 1/600% by weight of copper powder, and a half amount of sodium chloride or manganese dioxide. This positive electrode hydride agent and a commercially available copper mesh disposed outside thereof were used as the positive electrode sputum C. (Example 2) Manufacture of a water-power generating device -18- 200810206 (16) (1) Production of a water-power generating device without a partition member (1 -1) Manufacturing of a water-power generating device using a positive electrode sizing agent A or B As the positive electrode ruthenium, the positive electrode ruthenium A or B treated as described in Example 1 (2) was used. Further, a commercially available aluminum cover was purchased and used for the insulating member for a positive electrode terminal. As a current collector, a carbon rod for a dry battery manufactured by using a first carbon (stock) was purchased and used. As a separator, a thick filter paper (manufactured by Whatman Co., Ltd.) was purchased, and it was cut to a size of about 25 mm x about 36 mm. An insulating member (gasket) having an opening and a negative electrode member (annular member) having an opening are commercially available. The positive electrode member, the positive electrode terminal insulating member, and the current collector are fitted into one end of the tubular member as shown in Fig. 2 to serve as a bottomed outer cylinder. Next, the partition plate processed as described above is disposed along the inner wall of the outer cylinder so as not to create a gap. • In this bottomed cylinder, put about 18 to 20 g of activated carbon treated as described in Example i, and bend the end of the separator to wrap it in such a way that it does not pour off the activated carbon. Next, the above-mentioned spacer was placed at a position of about 5 mm away from the bent partition plate, and the above-mentioned annular member was placed thereon. The liquid power generating device of the present invention is produced by coating a liquid insulating member to insulate the outer side of the outer cylinder. (1-2) Method for Producing Water Power Generation Apparatus Using Positive Electrode Charge C -19-200810206 (17) The positive electrode sitter C produced as described above is placed as a carbon-coated carbon rod. Next, between the positive electrode squeezing agent C and the bottomed outer cylinder C, a commercially available copper mesh was cut so as to have a size of about 25 mm X and about 36 mm, and was placed so as to wrap the positive electrode squeezing agent C. The spacer, the ring member, and the like are placed in the same manner as described in the above (1-1), and placed in a tubular insulating member to insulate the outside of the cylinder to manufacture the water power generating device of the present invention. (2) The water-power generating device provided with the partition member is used as a partition member, and the same material as the partition plate is cut into the same shape and size as the cross-section of the negative electrode member, and is used as a partition member as follows. In the same manner as in the above (1) except that the positive electrode ruthenium was filled, the water provided with the partition member was used to generate electricity. Next, the positive electrode crucible filled in the negative electrode member is slightly divided into 1/3. First, the first 1/3 is charged in the same manner as in the above (1). Here, one member for the partition wall as described above is placed, and the next one-third of the positive electrode is filled. Thereafter, the remaining positive electrode is filled. (Example 3) Evaluation of power generation device ^ (1) Measurement of potential difference The alloy produced in Example 1 and the positive electrode materials A and B treated as described above were used in accordance with the procedure shown in Example 2, respectively. Five 4th battery size water power units. The current was measured using an ammeter (manufactured by Qiuyue Electronics Co., Ltd.). Further, the current is measured by connecting a κ ohm resistor between the galvanometer and the water generator -20- 200810206 (18). The results are shown in Table 2. 【Table 2】
No. 測定修（mA ) 正極塡充材A 正極塡充材Β 1 71.5 248.1 2 68.3 255.2 3 7 4,1 246.7 4 69.2 253.5 5 7:0.8 2 5 1.9 平均±S.D. 70·8 ± 2,01 2 8 1 · 1 ± 3.2 1No. Measurement repair (mA) Positive electrode 塡 filling material A Positive electrode 塡 filling material 7 1 71.5 248.1 2 68.3 255.2 3 7 4,1 246.7 4 69.2 253.5 5 7:0.8 2 5 1.9 Average ± SD 70·8 ± 2,01 2 8 1 · 1 ± 3.2 1
如表2所示，使用正極塡充材Α的場合’顯示具有約 70.8±2.01mA之電流値，使用正極塡充材B的場合，顯不 具有約2 8 1 · 1 ± 3.2 1 m A之電流値。 (2 )發電時間之測定 測定使用在實施例1所製造的合金，依照實施例2的 步驟製造的本發明之水發電裝置之發電時間。此測定，以 能夠使市售的LED燈點亮多少小時爲指標，對照與比較 的同時進行測定。作爲對照，使用2個市售的錳乾電池（ 4號）。 在本發明之發明裝置，LED的點燈時間逐漸變短，一 旦熄滅後，從注水口注X數滴水後，變得再度點亮。因此 ，直到LED完全熄滅爲止，反覆前述之實驗。結果之一 部分顯示於表3。又，在本發明之發電裝置產生的電流量 -21 - 200810206 (19) 爲1 80mA。表3中，一代表LED熄滅。 【表3】As shown in Table 2, when the positive electrode is used, it has a current of about 70.8 ± 2.01 mA, and when the positive electrode is used, it has no about 2 8 1 · 1 ± 3.2 1 m A. Current 値. (2) Measurement of power generation time The power generation time of the water-power generating apparatus of the present invention produced in accordance with the procedure of Example 2 using the alloy produced in Example 1 was measured. In this measurement, the number of hours that a commercially available LED lamp can be lit is used as an index, and the measurement is performed at the same time as the comparison and comparison. As a control, two commercially available manganese dry batteries (No. 4) were used. In the device of the present invention, the lighting time of the LED is gradually shortened, and once it is extinguished, the X water is dripped from the water injection port and then turned on again. Therefore, until the LED is completely extinguished, the aforementioned experiment is repeated. One of the results is shown in Table 3. Further, the amount of current -21 - 200810206 (19) generated by the power generating device of the present invention is 1 80 mA. In Table 3, one represents the LED being extinguished. 【table 3】
次數 到熄滅爲止的時間（小時） 對照 本發明例1 (正極塡充劑A) 本發明例2 (正極塡充劑B) 1 23 27 2 0 2 — 22 18 3 — 18 13 4 — 14 10 5 一 10 7 6 — 6.5 4 7 — 3 I 8 — 22* 17* 9 — 18 1 3.5 10 — 13 8 11 一 8.5 6 12 — 4 3 13 — 0.5 — 14 — 18* 12* 15 — 14 9.5 16 — 9.5 6 17 一 5.5 3 18 — 1 — 19 一 16* 幸 11 20 一 10.5 7 21 —I 5 3.5 如表3所示，錳電池23小時LED就熄滅了，次日進 行第2次實驗時，LED只亮一下就馬上熄滅。 另一方面，在本發明例1之發電裝置，初次經過2 7 小時LED就熄滅，但是在熄滅的時間點注入（* )數滴 -22- 200810206 (20) 水的話，再度恢復點亮。點燈持續時間，在第2次持續22 小時，在第3次持續18小诗，依此逐漸縮短，在第7次 點亮之後經過3小時就熄滅。 此時注入數滴水的話，LED再度點亮，1^0持續點亮 22小時。與前述同樣，LED之點亮時間逐漸變短，點亮 持續到第6次爲止。 以後，也反覆在LED熄滅時注水而使其再度點亮， % LED之點亮時間累計可達250小時。 於本發明例2之發電裝置，可確認幾乎有相同的傾向 ，點亮時間爲本發明例1之約2/3程度。 [產業上利用可能性] 如以上所說明的，使用本發明之水發電用合金之水發 電裝置，與水接觸即可跨長時間進行發電，所以對於各種 家電製品不僅可替代乾電池使用，對於災區之需要用電的 • 設備或機器的運作，或者是藉由安裝於救生衣或發報機而 對於山難事故或者海難事故的搜索也很有用。 【圖式簡單說明】 圖1係顯示相關於本發明之一實施型態之發電裝置的 Mil面圖。 圖2係顯示本發明之發電裝置之製造工程之圖（其1 圖3A係顯示本發明之發電裝置之製造工程之圖（其 -23- )0 200810206 (21) 2)。 圖3B係顯示本發明之發電裝置之製造工程之圖（其 3)〇 圖4係顯示本發明之發電裝置之製造工程之圖（其4 )° 圖5係顯示本發明之發電裝置之製造工程-之圖（其5 )° 圖6係顯示本發明之發電裝置之製造工程之圖（其6 )° 圖7係顯示本發明之發電裝置之製造工程之圖（其7 )° 圖8係顯示相關於本發明的其他實施型態之發電裝置 的構成之模式圖。 【主要元件符號說明】 2 :正極端子 4 :集電體 6 :分隔板 8 :負極構件 1 〇 :發電裝置 1 2 :正極塡充物 - 24-Time (hours) until the time of extinction Comparative Example 1 of the present invention (positive electrode charge A) Example 2 of the present invention (positive electrode charge B) 1 23 27 2 0 2 — 22 18 3 — 18 13 4 — 14 10 5 1 10 7 6 — 6.5 4 7 — 3 I 8 — 22* 17* 9 — 18 1 3.5 10 — 13 8 11 8.5 6 12 — 4 3 13 — 0.5 — 14 — 18* 12* 15 — 14 9.5 16 — 9.5 6 17 a 5.5 3 18 — 1 — 19 a 16* Fortunate 11 20 a 10.5 7 21 —I 5 3.5 As shown in Table 3, the manganese battery is extinguished for 23 hours, and the second experiment is performed the next day. Just turn it off and it will go out immediately. On the other hand, in the power generating apparatus of the first embodiment of the present invention, the LED is turned off after the first 27 hours, but when a small amount of -22-200810206 (20) water is injected (*) at the time of extinction, the lighting is resumed again. The duration of the lighting continues for the second time for 22 hours, and the third time continues to be 18 poems, which is gradually shortened, and is extinguished after 3 hours after the 7th lighting. At this time, if a few drops of water are injected, the LED lights up again, and 1^0 continues to light for 22 hours. As described above, the lighting time of the LED is gradually shortened, and the lighting continues until the sixth time. In the future, the LED will be re-ignited when the LED is extinguished, and the illumination time of the % LED can be up to 250 hours. In the power generating apparatus of Example 2 of the present invention, it was confirmed that there was almost the same tendency, and the lighting time was about 2/3 of the first example of the present invention. [Industrial Applicability] As described above, the water power generation device using the water-generating alloy of the present invention can generate electricity over a long period of time by being in contact with water. Therefore, it is not only a substitute for dry batteries for various home electric appliances, but also for disaster areas. It is also useful for the operation of equipment or machines, or for the search for mountain accidents or shipwrecks by installing them on life jackets or transmitters. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a plan view showing a Mil relating to a power generating device according to an embodiment of the present invention. Fig. 2 is a view showing the manufacturing process of the power generating device of the present invention (Fig. 3A is a view showing the manufacturing process of the power generating device of the present invention (the -23-) 0 200810206 (21) 2). 3B is a view showing a manufacturing process of the power generating device of the present invention (part 3). FIG. 4 is a view showing a manufacturing process of the power generating device of the present invention (4). FIG. 5 is a view showing a manufacturing process of the power generating device of the present invention. Figure 5 is a diagram showing the manufacturing process of the power generating device of the present invention (6). Figure 7 is a view showing the manufacturing process of the power generating device of the present invention (7). Figure 8 is a view A schematic view showing the configuration of a power generating device according to another embodiment of the present invention. [Description of main component symbols] 2 : Positive terminal 4 : Current collector 6 : Separator 8 : Negative electrode 1 〇 : Power generator 1 2 : Positive charge - 24