JP5342152B2 - ガリウムナイトライド系エピタキシャル結晶及びその製造方法 - Google Patents
ガリウムナイトライド系エピタキシャル結晶及びその製造方法 Download PDFInfo
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- 239000013078 crystal Substances 0.000 title claims description 119
- 229910002601 GaN Inorganic materials 0.000 title claims description 97
- JMASRVWKEDWRBT-UHFFFAOYSA-N Gallium nitride Chemical compound [Ga]#N JMASRVWKEDWRBT-UHFFFAOYSA-N 0.000 title claims description 80
- 238000004519 manufacturing process Methods 0.000 title claims description 14
- 239000000758 substrate Substances 0.000 claims description 53
- 238000000034 method Methods 0.000 claims description 49
- 239000004065 semiconductor Substances 0.000 claims description 36
- 230000005669 field effect Effects 0.000 claims description 29
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical group [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 12
- 239000002019 doping agent Substances 0.000 claims description 12
- 229910052749 magnesium Inorganic materials 0.000 claims description 12
- 239000011777 magnesium Substances 0.000 claims description 12
- 229910052581 Si3N4 Inorganic materials 0.000 claims description 9
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 4
- 239000000463 material Substances 0.000 description 20
- 238000000605 extraction Methods 0.000 description 11
- 239000002994 raw material Substances 0.000 description 9
- RNQKDQAVIXDKAG-UHFFFAOYSA-N aluminum gallium Chemical compound [Al].[Ga] RNQKDQAVIXDKAG-UHFFFAOYSA-N 0.000 description 8
- 238000002488 metal-organic chemical vapour deposition Methods 0.000 description 8
- 230000015556 catabolic process Effects 0.000 description 7
- PMHQVHHXPFUNSP-UHFFFAOYSA-M copper(1+);methylsulfanylmethane;bromide Chemical compound Br[Cu].CSC PMHQVHHXPFUNSP-UHFFFAOYSA-M 0.000 description 6
- 238000002248 hydride vapour-phase epitaxy Methods 0.000 description 5
- 238000002955 isolation Methods 0.000 description 5
- 238000001451 molecular beam epitaxy Methods 0.000 description 5
- 239000012535 impurity Substances 0.000 description 4
- 238000001459 lithography Methods 0.000 description 4
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 4
- 229910010271 silicon carbide Inorganic materials 0.000 description 4
- AUCDRFABNLOFRE-UHFFFAOYSA-N alumane;indium Chemical compound [AlH3].[In] AUCDRFABNLOFRE-UHFFFAOYSA-N 0.000 description 3
- 239000000969 carrier Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 238000007740 vapor deposition Methods 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 230000005684 electric field Effects 0.000 description 2
- 239000012299 nitrogen atmosphere Substances 0.000 description 2
- 238000005036 potential barrier Methods 0.000 description 2
- JBRZTFJDHDCESZ-UHFFFAOYSA-N AsGa Chemical compound [As]#[Ga] JBRZTFJDHDCESZ-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 229910001218 Gallium arsenide Inorganic materials 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000005229 chemical vapour deposition Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001312 dry etching Methods 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 239000012777 electrically insulating material Substances 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000000206 photolithography Methods 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 229910052594 sapphire Inorganic materials 0.000 description 1
- 239000010980 sapphire Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
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- Junction Field-Effect Transistors (AREA)
- Insulated Gate Type Field-Effect Transistor (AREA)
Description
横方向成長法を用いることにより開口部の結晶に存在する転位の伝播を大幅に減らすことができるため、第二の緩衝層以降の結晶の転位密度を低減することができる。特にトランジスタにおいて電子が走行する第一緩衝層の転位密度を1×105 cm-3以下程度にすることができるため高い移動度を有する動作層を形成することができる。したがって、例えば、第一の緩衝層の平均転位密度が、非ガリウムナイトライド系の絶縁層の開口部の上部を除いて、1×105 /cm以下であるとする構成により、高い移動度を有する動作層を形成することができる。
102 緩衝層
103 p伝導型半導体結晶層
104 絶縁層
104A 開口部
105 接続層
106 第2の緩衝層
107 第1の緩衝層
108 ゲート層
109、209 ソース電極
110、210 ドレイン電極
111、211 ゲート電極
112、212 正孔引き抜き電極
113、213 素子分離溝
201 シリコンカーバイド下地基板
202 アルミナイトライド緩衝層
203 p伝導型ガリウムナイトライド結晶層
204 シリコンナイトライド絶縁層
204A 開口部
205 p伝導型ガリウムナイトライド接続層
206 i伝導型ガリウムナイト横方向成長層
207 i伝導型ガリウムナイトライドチャネル層
208 i伝導型アルミガリウムナイトライド電子供給層
Claims (15)
- 下地基板上にエピタキシャル成長により形成された電界効果トランジスタ用のガリウムナイトライド系エピタキシャル結晶であって、
ゲート層と、
前記ゲート層の前記下地基板側界面に接するチャネル層を含み、i型もしくはp型である第1の緩衝層と、
該第1の緩衝層の前記下地基板側に配されている第2の緩衝層と、
該第2の緩衝層の前記下地基板側に配されており、その一部に開口部を有する非ガリウムナイトライド系の絶縁層と、
該絶縁層の前記下地基板側に配されているp伝導型半導体結晶層と
を有しており、
前記第1の緩衝層を前記p伝導型半導体結晶層に電気的に接続するためのガリウムナイトライド系結晶から成る接続層が前記非ガリウムナイトライド系の絶縁層の前記開口部に配されていることを特徴とするガリウムナイトライド系エピタキシャル結晶。 - 前記接続層がp伝導型結晶である請求項1に記載のガリウムナイトライド系エピタキシャル結晶。
- 前記接続層が前記第1の緩衝層に向かって延びる端部を有しており、該端部は前記第1の緩衝層を超えて延びていない請求項1又は2に記載のガリウムナイトライド系エピタキシャル結晶。
- 前記接続層が、前記非ガリウムナイトライド系の絶縁層の前記開口部に露出された前記p伝導型半導体結晶層上への選択成長により形成された結晶層である請求項1、2又は3に記載のガリウムナイトライド系エピタキシャル結晶。
- 前記第1の緩衝層の平均転位密度が、前記非ガリウムナイトライド系の絶縁層の前記開口部の上部を除いて、1×105/cm以下である請求項1、2、3、又は4に記載のガリウムナイトライド系エピタキシャル結晶。
- 前記第2の緩衝層の少なくとも一部が、前記開口部に配されたガリウムナイトライド系結晶を基点として選択横方向成長法により形成された結晶層である請求項1、2、3、4又は5に記載のガリウムナイトライド系エピタキシャル結晶。
- 前記絶縁層が酸化シリコン又は窒化シリコンである請求項1、2、3、4、5又は6に記載のガリウムナイトライド系エピタキシャル結晶。
- 請求項1、2、3、4、5、6又は7に記載のガリウムナイトライド系エピタキシャル結晶を用いて形成された電界効果トランジスタであって、
前記ゲート層の上部に形成されたゲート電極と、
前記ゲート電極の両側に配置され、前記ゲート層とオーミック接続されたソース電極及びドレイン電極とを備えており、
前記開口部或いは前記開口部に形成された接続層が、ソース電極下部、又は前記ゲート電極のソース側端と前記ソース電極の間の領域に配されており、
前記p伝導型半導体結晶層が正孔引抜き用電極に接続されていることを特徴とする電界効果トランジスタ。 - 前記第2の緩衝層が、横方向成長法により成長された結晶層である請求項8に記載の電界効果トランジスタ。
- 前記第1の緩衝層と前記ゲート層との界面が半導体ヘテロ接合界面で構成されている請求項8に記載の電界効果トランジスタ。
- 請求項1に記載のガリウムナイトライド系エピタキシャル結晶の製造方法において、
前記下地基板の上に前記p伝導型半導体結晶層をエピタキシャル成長させるステップと、
前記p伝導型半導体結晶層の上に前記絶縁層を形成するステップと、
前記絶縁層に開口部を設けるステップと、
前記絶縁層をマスクとして前記開口部にガリウムナイトライド系結晶を選択成長させて前記p伝導型半導体結晶層を前記第1の緩衝層に電気的に接続するための接続層を形成するステップと
を有することを特徴とするガリウムナイトライド系エピタキシャル結晶の製造方法。 - 前記接続層を形成した後、前記絶縁層上に、前記開口部に形成されているガリウムナイトライド系結晶を基点として選択横方向成長法により結晶層を形成するステップをさらに有する請求項11に記載のガリウムナイトライド系エピタキシャル結晶の製造方法。
- p伝導型の層においてp伝導型を与えるドーパントがマグネシウムである請求項1、2、3、4、5、6又は7に記載のガリウムナイトライド系エピタキシャル結晶。
- p伝導型の層においてp伝導型を与えるドーパントがマグネシウムである請求項8、9又は10に記載の電界効果トランジスタ。
- p伝導型の層においてp伝導型を与えるドーパントがマグネシウムである請求項11又は12に記載のガリウムナイトライド系エピタキシャル結晶の製造方法。
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US (1) | US8350292B2 (ja) |
JP (1) | JP5342152B2 (ja) |
KR (1) | KR20090119849A (ja) |
CN (1) | CN101611479B (ja) |
DE (1) | DE112008000410T5 (ja) |
GB (1) | GB2460197A (ja) |
TW (1) | TWI445182B (ja) |
WO (1) | WO2008099901A1 (ja) |
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JP4677499B2 (ja) * | 2008-12-15 | 2011-04-27 | Dowaエレクトロニクス株式会社 | 電子デバイス用エピタキシャル基板およびその製造方法 |
EP2432005A4 (en) * | 2009-05-11 | 2015-05-27 | Dowa Electronics Materials Co Ltd | EPITACTICAL SUBSTRATE FOR ELECTRONIC EQUIPMENT AND METHOD FOR THE PRODUCTION THEREOF |
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JP3139445B2 (ja) | 1997-03-13 | 2001-02-26 | 日本電気株式会社 | GaN系半導体の成長方法およびGaN系半導体膜 |
JPH11135770A (ja) | 1997-09-01 | 1999-05-21 | Sumitomo Chem Co Ltd | 3−5族化合物半導体とその製造方法および半導体素子 |
JP3129298B2 (ja) * | 1998-11-11 | 2001-01-29 | 日本電気株式会社 | 電界効果トランジスタ及びその製造方法 |
JP2001168111A (ja) | 1999-12-07 | 2001-06-22 | Nippon Telegr & Teleph Corp <Ntt> | GaN電界効果トランジスタ |
JP3869662B2 (ja) * | 2001-02-02 | 2007-01-17 | 三洋電機株式会社 | 半導体層の形成方法 |
JP2004014674A (ja) * | 2002-06-05 | 2004-01-15 | Nippon Telegr & Teleph Corp <Ntt> | 半導体構造 |
JP4746825B2 (ja) | 2003-05-15 | 2011-08-10 | 富士通株式会社 | 化合物半導体装置 |
JP4199599B2 (ja) * | 2003-06-03 | 2008-12-17 | 住友化学株式会社 | 3−5族化合物半導体の製造方法 |
JP4974454B2 (ja) * | 2004-11-15 | 2012-07-11 | 株式会社豊田中央研究所 | 半導体装置 |
JP4446869B2 (ja) * | 2004-11-24 | 2010-04-07 | トヨタ自動車株式会社 | へテロ接合型のiii−v族化合物半導体装置とその製造方法 |
JP4542912B2 (ja) * | 2005-02-02 | 2010-09-15 | 株式会社東芝 | 窒素化合物半導体素子 |
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DE112008000410T5 (de) | 2009-12-24 |
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KR20090119849A (ko) | 2009-11-20 |
US8350292B2 (en) | 2013-01-08 |
US20100117094A1 (en) | 2010-05-13 |
WO2008099901A1 (ja) | 2008-08-21 |
GB2460197A (en) | 2009-11-25 |
CN101611479A (zh) | 2009-12-23 |
GB0915202D0 (en) | 2009-10-07 |
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