JP5230426B2 - 多中心シャトリング剤(multi−centeredshuttlingagent)によるポリマー構造および分子量分布の制御 - Google Patents
多中心シャトリング剤(multi−centeredshuttlingagent)によるポリマー構造および分子量分布の制御 Download PDFInfo
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- JP5230426B2 JP5230426B2 JP2008531358A JP2008531358A JP5230426B2 JP 5230426 B2 JP5230426 B2 JP 5230426B2 JP 2008531358 A JP2008531358 A JP 2008531358A JP 2008531358 A JP2008531358 A JP 2008531358A JP 5230426 B2 JP5230426 B2 JP 5230426B2
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- 0 C1CC*CC1 Chemical compound C1CC*CC1 0.000 description 6
- XDTMQSROBMDMFD-UHFFFAOYSA-N C1CCCCC1 Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
- C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
- C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
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- C—CHEMISTRY; METALLURGY
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
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- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/01—Additive used together with the catalyst, excluding compounds containing Al or B
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
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- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
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- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
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- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C—CHEMISTRY; METALLURGY
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2308/00—Chemical blending or stepwise polymerisation process with the same catalyst
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- C—CHEMISTRY; METALLURGY
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2314/00—Polymer mixtures characterised by way of preparation
- C08L2314/06—Metallocene or single site catalysts
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Graft Or Block Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US71754305P | 2005-09-15 | 2005-09-15 | |
| US60/717,543 | 2005-09-15 | ||
| PCT/US2006/036049 WO2007035493A2 (en) | 2005-09-15 | 2006-09-14 | Control of polymer architecture and molecular weight distribution via multi-centered shuttling agent |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2009509003A JP2009509003A (ja) | 2009-03-05 |
| JP2009509003A5 JP2009509003A5 (https=) | 2011-12-08 |
| JP5230426B2 true JP5230426B2 (ja) | 2013-07-10 |
Family
ID=37763831
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2008531358A Active JP5230426B2 (ja) | 2005-09-15 | 2006-09-14 | 多中心シャトリング剤(multi−centeredshuttlingagent)によるポリマー構造および分子量分布の制御 |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US7947787B2 (https=) |
| EP (2) | EP1940897B1 (https=) |
| JP (1) | JP5230426B2 (https=) |
| KR (1) | KR20080055838A (https=) |
| CN (1) | CN101331164B (https=) |
| AR (1) | AR058448A1 (https=) |
| BR (2) | BRPI0617041B1 (https=) |
| CA (1) | CA2622599A1 (https=) |
| ES (2) | ES2483591T3 (https=) |
| RU (1) | RU2008114492A (https=) |
| SG (1) | SG165384A1 (https=) |
| TW (1) | TWI417304B (https=) |
| WO (1) | WO2007035493A2 (https=) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2768987A1 (en) | 2009-07-29 | 2011-02-03 | Dow Global Technologies Llc | Multifunctional chain shuttling agents |
| WO2011016992A2 (en) | 2009-07-29 | 2011-02-10 | Dow Global Technologies Inc. | Polymeric chain transfer/shuttling agents |
| JP5726873B2 (ja) | 2009-07-29 | 2015-06-03 | ダウ グローバル テクノロジーズ エルエルシー | 二頭又は多頭連鎖シャトリング剤、及びブロックコポリマーの調製のためのそれらの使用 |
| US20110054122A1 (en) | 2009-08-31 | 2011-03-03 | Jerzy Klosin | Catalyst and process for polymerizing an olefin and polyolefin prepared thereby |
| US8202954B2 (en) | 2010-02-19 | 2012-06-19 | Dow Global Technologies Llc | Metal-ligand complexes and catalysts |
| ES2874670T3 (es) | 2010-02-19 | 2021-11-05 | Dow Global Technologies Llc | Proceso para polimerizar un monómero de olefina y catalizador para el mismo |
| US8609794B2 (en) | 2010-05-17 | 2013-12-17 | Dow Global Technologies, Llc. | Process for selectively polymerizing ethylene and catalyst therefor |
| WO2012061706A1 (en) | 2010-11-04 | 2012-05-10 | Dow Global Technologies Llc | Double shuttling of polyolefin polymeryl chains |
| WO2012103080A1 (en) | 2011-01-26 | 2012-08-02 | Dow Global Technologies Llc | Process for making a polyolefin-polysiloxane block copolymer |
| WO2012155022A1 (en) | 2011-05-12 | 2012-11-15 | Dow Global Technologies Llc | Non-cyclopentadienyl-based chromium catalysts for olefin polymerization |
| ES2895162T3 (es) * | 2011-06-30 | 2022-02-17 | Dow Global Technologies Llc | Películas multicapa a base de poliolefina que tienen un rendimiento integrado de lámina posterior y encapsulación que comprenden una capa que comprende material compuesto de copolímero de bloque cristalino |
| JP2018525507A (ja) * | 2015-08-31 | 2018-09-06 | エクソンモービル・ケミカル・パテンツ・インク | ビニル連鎖移動剤の使用によって製造されたポリマー |
| WO2017058910A1 (en) | 2015-09-30 | 2017-04-06 | Dow Global Technologies Llc | Multi- or dual-headed compositions useful for chain shuttling and process to prepare the same |
| KR102413982B1 (ko) * | 2016-07-29 | 2022-06-30 | 다우 글로벌 테크놀로지스 엘엘씨 | 다중모드 엘라스토머 생산용 혼합 촉매 시스템 |
| EP4435013A3 (en) | 2016-09-30 | 2024-12-25 | Dow Global Technologies LLC | Process for preparing multi- or dual-headed compositions useful for chain shuttling |
| CN112074549B (zh) * | 2018-03-30 | 2023-06-23 | 陶氏环球技术有限责任公司 | 烯烃聚合活化剂 |
| KR102729476B1 (ko) | 2018-03-30 | 2024-11-14 | 다우 글로벌 테크놀로지스 엘엘씨 | 올레핀 중합 활성화제 |
| EP3774934A1 (en) | 2018-03-30 | 2021-02-17 | Dow Global Technologies LLC | Highly soluble bis-borate as binuclear co-catalysts for olefin polymerizations |
| SG11202008667SA (en) | 2018-03-30 | 2020-10-29 | Dow Global Technologies Llc | Binuclear olefin polymerization activators |
| KR102787419B1 (ko) | 2018-03-30 | 2025-03-27 | 다우 글로벌 테크놀로지스 엘엘씨 | 올레핀 중합을 위한 공-촉매로서 고도 가용성 알킬 치환된 카르베늄 보레이트 |
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| TW200714613A (en) | 2007-04-16 |
| CA2622599A1 (en) | 2007-03-29 |
| KR20080055838A (ko) | 2008-06-19 |
| EP2392601A3 (en) | 2012-04-04 |
| BRPI0617041B1 (pt) | 2018-01-30 |
| BRPI0617041A2 (pt) | 2011-07-12 |
| US7947787B2 (en) | 2011-05-24 |
| WO2007035493A3 (en) | 2007-05-10 |
| CN101331164A (zh) | 2008-12-24 |
| JP2009509003A (ja) | 2009-03-05 |
| BR122017016853B1 (pt) | 2018-05-15 |
| CN101331164B (zh) | 2011-03-23 |
| TWI417304B (zh) | 2013-12-01 |
| AR058448A1 (es) | 2008-02-06 |
| ES2483591T3 (es) | 2014-08-06 |
| US20080275189A1 (en) | 2008-11-06 |
| EP2392601B1 (en) | 2015-10-28 |
| EP1940897A2 (en) | 2008-07-09 |
| RU2008114492A (ru) | 2009-10-20 |
| EP1940897B1 (en) | 2014-05-07 |
| SG165384A1 (en) | 2010-10-28 |
| EP2392601A2 (en) | 2011-12-07 |
| ES2558316T3 (es) | 2016-02-03 |
| WO2007035493A2 (en) | 2007-03-29 |
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