JP5210382B2 - 分散ナノ粒子および無機ナノプレートレットを含むポリマーナノ複合体 - Google Patents
分散ナノ粒子および無機ナノプレートレットを含むポリマーナノ複合体 Download PDFInfo
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- JP5210382B2 JP5210382B2 JP2010518207A JP2010518207A JP5210382B2 JP 5210382 B2 JP5210382 B2 JP 5210382B2 JP 2010518207 A JP2010518207 A JP 2010518207A JP 2010518207 A JP2010518207 A JP 2010518207A JP 5210382 B2 JP5210382 B2 JP 5210382B2
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/005—Reinforced macromolecular compounds with nanosized materials, e.g. nanoparticles, nanofibres, nanotubes, nanowires, nanorods or nanolayered materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y20/00—Nanooptics, e.g. quantum optics or photonic crystals
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2363/00—Characterised by the use of epoxy resins; Derivatives of epoxy resins
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/880,820 US8344054B2 (en) | 2007-07-24 | 2007-07-24 | Polymer nanocomposites including dispersed nanoparticles and inorganic nanoplatelets |
| US11/880,820 | 2007-07-24 | ||
| PCT/US2008/008880 WO2009014685A1 (en) | 2007-07-24 | 2008-07-22 | Polymer nanocomposites including dispersed nanoparticles and inorganic nanoplatelets |
Publications (3)
| Publication Number | Publication Date |
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| JP2010534267A JP2010534267A (ja) | 2010-11-04 |
| JP2010534267A5 JP2010534267A5 (enExample) | 2011-09-01 |
| JP5210382B2 true JP5210382B2 (ja) | 2013-06-12 |
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| JP2010518207A Expired - Fee Related JP5210382B2 (ja) | 2007-07-24 | 2008-07-22 | 分散ナノ粒子および無機ナノプレートレットを含むポリマーナノ複合体 |
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| Country | Link |
|---|---|
| US (1) | US8344054B2 (enExample) |
| JP (1) | JP5210382B2 (enExample) |
| WO (1) | WO2009014685A1 (enExample) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| DE102008048874A1 (de) * | 2008-09-25 | 2010-04-08 | Siemens Aktiengesellschaft | Beschichtungen für elektronische Schaltungen |
| JP5281969B2 (ja) * | 2009-06-30 | 2013-09-04 | 三菱エンジニアリングプラスチックス株式会社 | 芳香族ポリカーボネート樹脂組成物及びそれを使用する成形品 |
| US9517424B2 (en) * | 2011-04-14 | 2016-12-13 | University Of Florida Research Foundation, Inc | Method for removing hydrogen phosphate from an aqueous solution using alpha zirconium phosphate |
| US9228149B2 (en) | 2012-07-02 | 2016-01-05 | Exxonmobil Research And Engineering Company | Enhanced durability performance of lubricants using functionalized metal phosphate nanoplatelets |
| US9321919B2 (en) | 2013-01-04 | 2016-04-26 | The Texas A&M University System | Surface-modified, exfoliated nanoplatelets as mesomorphic structures in solutions and polymeric matrices |
| KR101619438B1 (ko) * | 2013-06-14 | 2016-05-10 | 주식회사 엘지화학 | 금속 나노플레이트, 이의 제조 방법, 이를 포함하는 도전성 잉크 조성물 및 전도성 필름 |
| US10542918B2 (en) | 2013-10-23 | 2020-01-28 | Verily Life Sciences Llc | Modulation of a response signal to distinguish between analyte and background signals |
| US9504405B2 (en) | 2013-10-23 | 2016-11-29 | Verily Life Sciences Llc | Spatial modulation of magnetic particles in vasculature by external magnetic field |
| US10259948B2 (en) | 2014-03-25 | 2019-04-16 | Kaneka Corporation | Coating compositions and coating products made therefrom |
| US9861710B1 (en) | 2015-01-16 | 2018-01-09 | Verily Life Sciences Llc | Composite particles, methods, and in vivo diagnostic system |
Family Cites Families (76)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4053577A (en) * | 1972-02-18 | 1977-10-11 | Tioxide Group Limited | Process for the gaseous phase production of metal oxide particles |
| IT1161200B (it) * | 1983-02-25 | 1987-03-18 | Montedison Spa | Processo e apparecchio per la preparazione di particelle di ossidi metallici monodisperse, sferiche, non aggregate e di dimensione inferiore al micron |
| JPS61122106A (ja) * | 1984-11-19 | 1986-06-10 | Ube Ind Ltd | 微粉末状マグネシウム酸化物の製造方法 |
| EP0214308B1 (en) * | 1985-03-05 | 1993-07-28 | Idemitsu Kosan Company Limited | Method for preparing super-fine spherical particles of metal oxide |
| US4575522A (en) * | 1985-03-07 | 1986-03-11 | Hydril Company | Rubber composition for geothermal application |
| EP0234816B1 (en) * | 1986-02-12 | 1993-08-11 | Catalysts & Chemicals Industries Co., Ltd. | Processes for preparing mono-dispersed particles |
| US4778671A (en) * | 1986-07-14 | 1988-10-18 | Corning Glass Works | Preparation of unagglomerated metal oxide particles with uniform particle size |
| EP0280673B1 (en) * | 1987-02-25 | 1991-07-31 | Nippon Shokubai Kagaku Kogyo Co., Ltd | Method for production of inorganic minute globular particles |
| US4764357A (en) * | 1987-03-09 | 1988-08-16 | Akzo America Inc. | Process for producing finely divided powdery metal oxide compositions |
| US4871790A (en) * | 1987-11-25 | 1989-10-03 | Minnesota Mining And Manufacturing Company | Colloidal metals in monomers or polymers |
| US4931427A (en) * | 1988-01-15 | 1990-06-05 | Academy Of Applied Science, Inc. | Process for producing metal oxide superconductor-polymer composites and composites thereby formed |
| US5047174A (en) * | 1988-11-21 | 1991-09-10 | Akzo America Inc. | Production of stable metal oxide sols |
| US5207973A (en) * | 1989-11-27 | 1993-05-04 | Martin Marietta Energy Systems, Inc. | Method and apparatus for the production of metal oxide powder |
| JP3047110B2 (ja) * | 1990-06-15 | 2000-05-29 | 株式会社東北テクノアーチ | 金属酸化物微粒子の製造方法 |
| US5409683A (en) * | 1990-08-23 | 1995-04-25 | Regents Of The University Of California | Method for producing metal oxide aerogels |
| DE4033417A1 (de) * | 1990-10-20 | 1992-04-23 | Basf Ag | Verfahren zur herstellung von mit metalloxiden dotierten zinkoxidpigmenten |
| JPH04357114A (ja) | 1991-05-31 | 1992-12-10 | Mitsubishi Materials Corp | 超微粒子酸化亜鉛粉末の製造方法 |
| JP3292414B2 (ja) | 1992-11-26 | 2002-06-17 | 住友ゴム工業株式会社 | タイヤトレッドゴム組成物 |
| EP0599643B1 (en) | 1992-11-26 | 1996-05-15 | Sumitomo Rubber Industries Ltd. | Rubber compositions of tyre tread |
| CA2113501C (en) * | 1993-02-08 | 2007-09-18 | James P. Mason | Transparent polycarbonate pet blends |
| EP0698275A4 (en) * | 1993-04-28 | 1996-09-04 | Mark Mitchnick | CONDUCTIVE POLYMERS |
| JP3733599B2 (ja) * | 1993-08-11 | 2006-01-11 | 住友化学株式会社 | 金属酸化物粉末およびその製造方法 |
| JPH07218463A (ja) * | 1994-02-04 | 1995-08-18 | Figaro Eng Inc | 金属酸化物表面へのシリカマスクの調製方法 |
| US6200680B1 (en) * | 1994-06-06 | 2001-03-13 | Nippon Shokubai Co., Ltd. | Fine zinc oxide particles, process for producing the same, and use thereof |
| FR2721615A1 (fr) * | 1994-06-24 | 1995-12-29 | Rhone Poulenc Chimie | Procédé de préparation de particules d'oxyde métallique organophiles. |
| BR9508246A (pt) * | 1994-07-07 | 1997-09-30 | Chiron Diagnostics Corp | Particulas de óxido de metal magnético altamente dispersas processos para a preparação das mesmas e uso das mesmas |
| JP3229174B2 (ja) * | 1995-08-21 | 2001-11-12 | 日本アエロジル株式会社 | 表面改質金属酸化物微粉末およびその製造方法 |
| US5753373A (en) * | 1995-12-21 | 1998-05-19 | Minnesota Mining And Manufacturing Company | Coating composition having anti-reflective and anti-fogging properties |
| US5856254A (en) * | 1996-02-15 | 1999-01-05 | Vaw Silizium Gmbh | Spherical metal-oxide powder particles and process for their manufacture |
| US5637258A (en) * | 1996-03-18 | 1997-06-10 | Nanocrystals Technology L.P. | Method for producing rare earth activited metal oxide nanocrystals |
| US6169119B1 (en) * | 1997-02-14 | 2001-01-02 | Reliance Electric Technologies, Llc | Metal oxide sols and process for making the same |
| US5780525A (en) * | 1997-02-14 | 1998-07-14 | Reliance Electric Industrial Company | Photocurable composition for electrical insulation |
| US5928723A (en) * | 1997-04-09 | 1999-07-27 | Cabot Corporation | Progress for producing surface modified metal oxide compositions |
| US6071486A (en) * | 1997-04-09 | 2000-06-06 | Cabot Corporation | Process for producing metal oxide and organo-metal oxide compositions |
| US6235270B1 (en) * | 1997-04-18 | 2001-05-22 | Showa Denko K.K. | Cosmetics, silica-coated metal oxide powder and production method therefor |
| US6139816A (en) * | 1997-06-09 | 2000-10-31 | Merck Kanto Advanced Chemical Ltd | Process for the preparation of ultra-fine powders of metal oxides |
| US6599631B2 (en) * | 2001-01-26 | 2003-07-29 | Nanogram Corporation | Polymer-inorganic particle composites |
| US5777001A (en) * | 1997-08-04 | 1998-07-07 | Kerr Mcgee Chemical Corp. | Graft polymerized metal oxide compositions and methods |
| JP4184487B2 (ja) * | 1997-08-15 | 2008-11-19 | 昭和電工株式会社 | 二酸化チタン微粒子の製造方法 |
| AU751756B2 (en) * | 1997-11-18 | 2002-08-29 | Shiseido Company Ltd. | Ultraviolet-screening zinc oxide excellent in transparency and composition containing the same |
| JPH11209695A (ja) * | 1998-01-27 | 1999-08-03 | Jsr Corp | コーティング用組成物および硬化体 |
| JPH11217511A (ja) | 1998-02-04 | 1999-08-10 | Toppan Printing Co Ltd | 高分子と無機化合物からなる複合体およびその製造方法 |
| KR100265202B1 (ko) * | 1998-02-05 | 2000-09-15 | 김순택 | 유기-무기컴포지트의 제조방법 |
| EP1708038B1 (en) * | 1998-05-11 | 2009-02-18 | Nippon Aerosil Co., Ltd. | Method for producing fine powder of hydrophobic metal oxide for electrophotography |
| AUPP355798A0 (en) * | 1998-05-15 | 1998-06-11 | University Of Western Australia, The | Process for the production of ultrafine powders |
| JP3953649B2 (ja) * | 1998-07-17 | 2007-08-08 | オリヱント化学工業株式会社 | 有機−無機ハイブリッド成分傾斜高分子材料、及びその製造方法 |
| US6036886A (en) * | 1998-07-29 | 2000-03-14 | Nanocrystals Technology L.P. | Microemulsion method for producing activated metal oxide nanocrystals |
| US6329058B1 (en) * | 1998-07-30 | 2001-12-11 | 3M Innovative Properties Company | Nanosize metal oxide particles for producing transparent metal oxide colloids and ceramers |
| US6527825B1 (en) * | 1998-08-19 | 2003-03-04 | Dow Global Technologies Inc. | Process for preparing nanosize metal oxide powders |
| DE19907704A1 (de) | 1999-02-23 | 2000-08-24 | Bayer Ag | Nanopartikuläres, redispergierbares Fällungszinkoxid |
| JP4214203B2 (ja) * | 1999-05-18 | 2009-01-28 | オリヱント化学工業株式会社 | 有機−無機複合材料およびその製造方法 |
| JP4473364B2 (ja) * | 1999-06-03 | 2010-06-02 | Jsr株式会社 | 光硬化性樹脂組成物及び光学部材 |
| US6797760B1 (en) * | 1999-10-15 | 2004-09-28 | Alphagary Corporation | Non-dripping, flame retardant, fluoroelastomer insulative compositions for telecommunication cables |
| CN1276015C (zh) * | 2000-05-30 | 2006-09-20 | 南卡罗来纳州大学研究基金会 | 包含基质聚合物和层状粘土材料的、可萃取物质水平改进的聚合物纳米复合材料 |
| BR0105083A (pt) * | 2000-11-17 | 2002-06-25 | Goodyear Tire & Rubber | Composição de borracha leve contendo argila |
| US6710114B2 (en) * | 2000-12-21 | 2004-03-23 | Acushnet Company | Golf balls including solution blended polymeric composite and method of making same |
| US6586096B2 (en) * | 2000-12-22 | 2003-07-01 | Eastman Kodak Company | Polymethylmethacrylate nanocomposite optical article and method of making same |
| JP2003147090A (ja) | 2001-11-14 | 2003-05-21 | Mitsubishi Chemicals Corp | ナノ粒子含有熱可塑性樹脂組成物成形体及びその製造方法 |
| US6919395B2 (en) * | 2002-01-04 | 2005-07-19 | Acushnet Company | Golf ball compositions comprising nanoparticulates |
| US20050215718A1 (en) * | 2002-01-04 | 2005-09-29 | Murali Rajagopalan | Nanocomposite ethylene copolymer compositions for golf balls |
| US20030176551A1 (en) * | 2002-03-06 | 2003-09-18 | Rediske James E. | Stabilized pigmented polymer compositions |
| DE10212121A1 (de) * | 2002-03-15 | 2003-09-25 | Bayer Ag | Verfahren zur Herstellung von nano-Zinkoxid-Dispersionen stabilisiert durch hydroxylgruppenhaltige anorganische Polymere |
| US6759446B2 (en) * | 2002-05-02 | 2004-07-06 | The Ohio State University Research Foundation | Polymer nanocomposite foams |
| US6860924B2 (en) * | 2002-06-07 | 2005-03-01 | Nanoscale Materials, Inc. | Air-stable metal oxide nanoparticles |
| JP2004292282A (ja) | 2003-03-28 | 2004-10-21 | Mitsubishi Chemicals Corp | 酸化亜鉛ナノ粒子及びその製造方法、並びに、その酸化亜鉛ナノ粒子含有組成物及びそれを用いた積層体 |
| US7342065B2 (en) | 2003-09-18 | 2008-03-11 | The Goodyear Tire & Rubber Company | Preparation of nanocomposite of elastomer and exfoliated clay platelets, rubber compositions comprised of said nanocomposite and articles of manufacture, including tires |
| SG136949A1 (en) * | 2004-04-15 | 2007-11-29 | Agency Science Tech & Res | A biomimetic approach to low-cost fabrication of complex nanostructures of metal oxides by natural oxidation at low-temperature |
| US20060194910A1 (en) | 2004-05-19 | 2006-08-31 | Nobuo Miyatake | Stabilization of polymers with zinc oxide nanoparticles |
| US7482382B2 (en) * | 2004-05-19 | 2009-01-27 | The Texas A&M University System | Process for preparing nano-sized metal oxide particles |
| US8052918B2 (en) | 2004-07-21 | 2011-11-08 | Nissin Kogyo Co., Ltd. | Carbon-based material and method of producing the same, and composite material and method of producing the same |
| US7119140B2 (en) * | 2004-07-22 | 2006-10-10 | Ronald Basham | Transparent films, compositions, and method of manufacture thereof |
| KR20060056772A (ko) | 2004-11-22 | 2006-05-25 | 대우전자부품(주) | 편향요크의 수평편향코일의 고정구조 |
| KR100598454B1 (ko) * | 2004-12-31 | 2006-07-10 | 제일모직주식회사 | 열안정성이 우수한 암모늄계 나노클레이 및 이를 이용한투명한 열가소성 수지 나노 복합체 |
| WO2007023919A1 (ja) | 2005-08-24 | 2007-03-01 | Kaneka Corporation | 合成樹脂用安定化剤組成物 |
| US8163830B2 (en) * | 2006-03-31 | 2012-04-24 | Intel Corporation | Nanoclays in polymer compositions, articles containing same, processes of making same, and systems containing same |
| US7498381B1 (en) * | 2006-08-02 | 2009-03-03 | Exxonmobil Chemical Patents Inc. | Low permeability elastomeric-metal phosphate nanocomposites |
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| Publication number | Publication date |
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| WO2009014685A1 (en) | 2009-01-29 |
| US8344054B2 (en) | 2013-01-01 |
| JP2010534267A (ja) | 2010-11-04 |
| US20090029167A1 (en) | 2009-01-29 |
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