JP5194876B2 - 酸化ニッケル粉末及びその製造方法 - Google Patents
酸化ニッケル粉末及びその製造方法 Download PDFInfo
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- JP5194876B2 JP5194876B2 JP2008042682A JP2008042682A JP5194876B2 JP 5194876 B2 JP5194876 B2 JP 5194876B2 JP 2008042682 A JP2008042682 A JP 2008042682A JP 2008042682 A JP2008042682 A JP 2008042682A JP 5194876 B2 JP5194876 B2 JP 5194876B2
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- Prior art keywords
- nickel oxide
- oxide powder
- nickel
- producing
- quality
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 229910000480 nickel oxide Inorganic materials 0.000 title claims description 116
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 title claims description 116
- 239000000843 powder Substances 0.000 title claims description 101
- 238000004519 manufacturing process Methods 0.000 title claims description 35
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 51
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 45
- 239000000460 chlorine Substances 0.000 claims description 45
- 229910052801 chlorine Inorganic materials 0.000 claims description 45
- 239000007864 aqueous solution Substances 0.000 claims description 40
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 34
- 238000004140 cleaning Methods 0.000 claims description 34
- 239000011593 sulfur Substances 0.000 claims description 34
- 229910052717 sulfur Inorganic materials 0.000 claims description 34
- 238000005406 washing Methods 0.000 claims description 33
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 30
- BFDHFSHZJLFAMC-UHFFFAOYSA-L nickel(ii) hydroxide Chemical compound [OH-].[OH-].[Ni+2] BFDHFSHZJLFAMC-UHFFFAOYSA-L 0.000 claims description 28
- 150000007524 organic acids Chemical class 0.000 claims description 20
- 229910021586 Nickel(II) chloride Inorganic materials 0.000 claims description 15
- 238000010438 heat treatment Methods 0.000 claims description 15
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 claims description 15
- 239000000243 solution Substances 0.000 claims description 14
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 11
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 11
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 10
- 239000003513 alkali Substances 0.000 claims description 10
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 8
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 6
- 239000011777 magnesium Substances 0.000 claims description 6
- 229910052749 magnesium Inorganic materials 0.000 claims description 6
- 230000003472 neutralizing effect Effects 0.000 claims description 5
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 claims description 4
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 claims description 4
- 229960005070 ascorbic acid Drugs 0.000 claims description 4
- 235000010323 ascorbic acid Nutrition 0.000 claims description 4
- 239000011668 ascorbic acid Substances 0.000 claims description 4
- 235000013922 glutamic acid Nutrition 0.000 claims description 4
- 239000004220 glutamic acid Substances 0.000 claims description 4
- 238000000790 scattering method Methods 0.000 claims description 4
- 235000015165 citric acid Nutrition 0.000 claims description 3
- 239000012670 alkaline solution Substances 0.000 claims 1
- 238000000034 method Methods 0.000 description 37
- 239000002245 particle Substances 0.000 description 32
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- 239000007788 liquid Substances 0.000 description 13
- 230000000694 effects Effects 0.000 description 12
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical group [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 11
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 10
- 239000012535 impurity Substances 0.000 description 10
- 239000000463 material Substances 0.000 description 10
- 229910052726 zirconium Inorganic materials 0.000 description 10
- 238000006243 chemical reaction Methods 0.000 description 8
- 238000002156 mixing Methods 0.000 description 8
- 239000002994 raw material Substances 0.000 description 8
- 239000012065 filter cake Substances 0.000 description 7
- 229910001233 yttria-stabilized zirconia Inorganic materials 0.000 description 7
- 229910000859 α-Fe Inorganic materials 0.000 description 7
- 239000002002 slurry Substances 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 238000001914 filtration Methods 0.000 description 5
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 description 5
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 description 5
- 238000010304 firing Methods 0.000 description 4
- 238000006386 neutralization reaction Methods 0.000 description 4
- 229910052759 nickel Inorganic materials 0.000 description 4
- 238000004364 calculation method Methods 0.000 description 3
- 238000011109 contamination Methods 0.000 description 3
- 238000009295 crossflow filtration Methods 0.000 description 3
- 230000001186 cumulative effect Effects 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 230000001590 oxidative effect Effects 0.000 description 3
- 208000005156 Dehydration Diseases 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000011324 bead Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 230000018044 dehydration Effects 0.000 description 2
- 238000006297 dehydration reaction Methods 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 238000010907 mechanical stirring Methods 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 150000002815 nickel Chemical class 0.000 description 2
- 229910017604 nitric acid Inorganic materials 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 238000010298 pulverizing process Methods 0.000 description 2
- 238000004062 sedimentation Methods 0.000 description 2
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 238000004438 BET method Methods 0.000 description 1
- 229910021607 Silver chloride Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 238000011088 calibration curve Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000012776 electronic material Substances 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910000008 nickel(II) carbonate Inorganic materials 0.000 description 1
- ZULUUIKRFGGGTL-UHFFFAOYSA-L nickel(ii) carbonate Chemical compound [Ni+2].[O-]C([O-])=O ZULUUIKRFGGGTL-UHFFFAOYSA-L 0.000 description 1
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 1
- 229920002742 polystyrene-block-poly(ethylene/propylene) -block-polystyrene Polymers 0.000 description 1
- 239000011164 primary particle Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
- 229910001961 silver nitrate Inorganic materials 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Landscapes
- Inorganic Compounds Of Heavy Metals (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2008042682A JP5194876B2 (ja) | 2008-02-25 | 2008-02-25 | 酸化ニッケル粉末及びその製造方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2008042682A JP5194876B2 (ja) | 2008-02-25 | 2008-02-25 | 酸化ニッケル粉末及びその製造方法 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2009196870A JP2009196870A (ja) | 2009-09-03 |
| JP2009196870A5 JP2009196870A5 (enrdf_load_stackoverflow) | 2011-03-03 |
| JP5194876B2 true JP5194876B2 (ja) | 2013-05-08 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2008042682A Expired - Fee Related JP5194876B2 (ja) | 2008-02-25 | 2008-02-25 | 酸化ニッケル粉末及びその製造方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP5194876B2 (enrdf_load_stackoverflow) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5168070B2 (ja) * | 2008-10-08 | 2013-03-21 | 住友金属鉱山株式会社 | 酸化ニッケル粉末及びその製造方法 |
| JP5621268B2 (ja) * | 2010-02-03 | 2014-11-12 | 住友金属鉱山株式会社 | 酸化ニッケル微粉末及びその製造方法 |
| WO2011136036A1 (ja) * | 2010-04-27 | 2011-11-03 | 住友化学株式会社 | 遷移金属水酸化物の製造方法 |
| JP5733101B2 (ja) * | 2011-08-11 | 2015-06-10 | 住友金属鉱山株式会社 | 酸化ニッケル粉末の製造方法 |
| JP5942659B2 (ja) * | 2012-07-20 | 2016-06-29 | 住友金属鉱山株式会社 | 酸化ニッケル微粉末の製造方法及び該酸化ニッケル微粉末製造原料用の水酸化ニッケル粉末の製造方法 |
| CN102887550B (zh) * | 2012-10-09 | 2014-07-16 | 四川大学 | 生产介孔氧化镍的方法 |
| JP6135479B2 (ja) * | 2013-11-28 | 2017-05-31 | 住友金属鉱山株式会社 | ニッケル粉の製造方法 |
| JP6565803B2 (ja) * | 2016-06-24 | 2019-08-28 | 住友金属鉱山株式会社 | 酸化ニッケルの製造方法、流動焙焼炉 |
| CN108178197A (zh) * | 2017-12-14 | 2018-06-19 | 金川集团股份有限公司 | 一种电子级氧化亚镍的制备方法 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0710544A (ja) * | 1993-06-23 | 1995-01-13 | Tdk Corp | 酸化ニッケル粉末の製造方法 |
| JP3477831B2 (ja) * | 1994-07-19 | 2003-12-10 | 戸田工業株式会社 | 磁気カード用バリウムフェライト粒子粉末の製造法 |
| JPH1179752A (ja) * | 1997-09-01 | 1999-03-23 | Toda Kogyo Corp | 酸化ニッケル粒子およびその製造方法 |
| JP2000212609A (ja) * | 1999-01-22 | 2000-08-02 | Sumitomo Metal Mining Co Ltd | 積層セラミックコンデンサ―内部電極用ニッケル粉およびその製造方法 |
| JP2004315273A (ja) * | 2003-04-15 | 2004-11-11 | Sumitomo Metal Mining Co Ltd | 高比表面積で焼結性に優れる酸化ニッケル粉末及びその製造方法 |
| JP4978785B2 (ja) * | 2007-07-17 | 2012-07-18 | 住友金属鉱山株式会社 | ニッケル粉の製造方法 |
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- 2008-02-25 JP JP2008042682A patent/JP5194876B2/ja not_active Expired - Fee Related
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| Publication number | Publication date |
|---|---|
| JP2009196870A (ja) | 2009-09-03 |
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