JP5191733B2 - ブロックドイソシアネート及びその塗料組成物における使用 - Google Patents
ブロックドイソシアネート及びその塗料組成物における使用 Download PDFInfo
- Publication number
- JP5191733B2 JP5191733B2 JP2007530472A JP2007530472A JP5191733B2 JP 5191733 B2 JP5191733 B2 JP 5191733B2 JP 2007530472 A JP2007530472 A JP 2007530472A JP 2007530472 A JP2007530472 A JP 2007530472A JP 5191733 B2 JP5191733 B2 JP 5191733B2
- Authority
- JP
- Japan
- Prior art keywords
- cyclohexane
- bis
- isocyanotomethyl
- isocyanurate
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
- C08G18/751—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring
- C08G18/752—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group
- C08G18/757—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing at least two isocyanate or isothiocyanate groups linked to the cycloaliphatic ring by means of an aliphatic group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
- C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
- C08G18/792—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/80—Masked polyisocyanates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/80—Masked polyisocyanates
- C08G18/8061—Masked polyisocyanates masked with compounds having only one group containing active hydrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/80—Masked polyisocyanates
- C08G18/8061—Masked polyisocyanates masked with compounds having only one group containing active hydrogen
- C08G18/807—Masked polyisocyanates masked with compounds having only one group containing active hydrogen with nitrogen containing compounds
- C08G18/8074—Lactams
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Polyurethanes Or Polyureas (AREA)
- Paints Or Removers (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US60710704P | 2004-09-03 | 2004-09-03 | |
| US60/607,107 | 2004-09-03 | ||
| PCT/US2005/031685 WO2006029141A1 (en) | 2004-09-03 | 2005-09-02 | Blocked isocyanates and their use in coating compositions |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2012219599A Division JP5778647B2 (ja) | 2004-09-03 | 2012-10-01 | ブロックドイソシアネート及びその塗料組成物における使用 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2008512520A JP2008512520A (ja) | 2008-04-24 |
| JP5191733B2 true JP5191733B2 (ja) | 2013-05-08 |
Family
ID=35355819
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2007530472A Expired - Lifetime JP5191733B2 (ja) | 2004-09-03 | 2005-09-02 | ブロックドイソシアネート及びその塗料組成物における使用 |
| JP2012219599A Expired - Lifetime JP5778647B2 (ja) | 2004-09-03 | 2012-10-01 | ブロックドイソシアネート及びその塗料組成物における使用 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2012219599A Expired - Lifetime JP5778647B2 (ja) | 2004-09-03 | 2012-10-01 | ブロックドイソシアネート及びその塗料組成物における使用 |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US20080033086A1 (enExample) |
| EP (1) | EP1789466B1 (enExample) |
| JP (2) | JP5191733B2 (enExample) |
| KR (1) | KR101250703B1 (enExample) |
| CN (1) | CN101072806B (enExample) |
| AT (1) | ATE532808T1 (enExample) |
| AU (1) | AU2005282549A1 (enExample) |
| BR (1) | BRPI0515235B1 (enExample) |
| CA (1) | CA2577785C (enExample) |
| MX (1) | MX2007002611A (enExample) |
| WO (1) | WO2006029141A1 (enExample) |
| ZA (1) | ZA200701641B (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11421135B2 (en) | 2016-05-20 | 2022-08-23 | Mitsui Chemicals, Inc. | Curable composition, coating material, solar cell coating material, solar cell back sheet coating material, adhesive, solar cell adhesive, solar cell back sheet adhesive, producing method of sheet, and curing agent |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5543915B2 (ja) * | 2007-05-21 | 2014-07-09 | ルブリゾル アドバンスド マテリアルズ, インコーポレイテッド | ポリウレタンポリマー |
| EP2036937A1 (en) * | 2007-09-13 | 2009-03-18 | Stichting Dutch Polymer Institute | Polycarbonate and process for producing the same |
| CN101469259B (zh) * | 2007-12-27 | 2012-09-19 | 上海轻工业研究所有限公司 | 聚氨酯反应性热熔结构胶 |
| FR2927631B1 (fr) * | 2008-02-15 | 2010-03-05 | Arkema France | Utilisation d'un promoteur d'adherence dans une solution de nettoyage de la surface d'un substrat a base de tpe et/ou de pa, pour augmenter l'adherence dudit substrat avec les joints de colle aqueux. |
| JP5566360B2 (ja) * | 2010-11-22 | 2014-08-06 | ローム アンド ハース カンパニー | ビス(イソシアナトメチル)シクロヘキサンからのイソシアヌラート組成物および第三級アミン触媒を含むポリウレタンコーティング組成物 |
| CN102477251B (zh) | 2010-11-22 | 2015-05-13 | 罗门哈斯公司 | 包含源自二(异氰酸根合甲基)环己烷和源自脂族二异氰酸酯的异氰尿酸酯组合物的双组分聚氨酯涂料组合物 |
| JP6247492B2 (ja) | 2012-11-06 | 2017-12-13 | ダウ グローバル テクノロジーズ エルエルシー | 水性皮革コーティング組成物および皮革をコーティングするための方法 |
| CA2929608C (en) * | 2013-11-18 | 2021-02-02 | E.I. Du Pont De Nemours And Company | Composites and ballistic resistant armor articles containing the composites |
| CN109890865B (zh) * | 2016-10-18 | 2021-12-07 | 科思创德国股份有限公司 | 通过封闭型多异氰酸酯的催化交联制造塑料 |
| CA3110222A1 (en) * | 2018-08-21 | 2020-02-27 | The Secant Group, Llc | Controlled-release urethane-elastomers for use in implantable products |
| EP3800213A1 (en) | 2019-10-01 | 2021-04-07 | Cromogenia Units, S.A. | Blocked isocyanate polyurethane compositions using a new blocking agent, method of manufacture and uses thereof |
| CN110804146B (zh) * | 2019-12-06 | 2021-09-07 | 万华化学集团股份有限公司 | 一种存储稳定的封闭型异氰酸酯组合物及其制备方法和应用 |
| CN111647382B (zh) * | 2020-06-30 | 2022-03-25 | 浙江华峰热塑性聚氨酯有限公司 | 一种tpu粘合剂的制备方法及其用途 |
| CN112266464B (zh) * | 2020-11-06 | 2022-05-03 | 广东也乐新材料制造有限公司 | 一种高耐性封闭型水性聚异氰酸酯的制备方法及其应用 |
| CN112557582B (zh) * | 2020-12-17 | 2022-11-01 | 南通恒华粘合材料科技有限公司 | 一种聚酯多元醇羟值测定的方法 |
| CN115925581B (zh) * | 2021-08-09 | 2024-12-03 | 万华化学集团股份有限公司 | 一种制备异氰酸酯的方法 |
| EP4163314B1 (de) * | 2021-10-05 | 2023-12-06 | Evonik Operations GmbH | Verfahren zur herstellung fester polyurethanhärter |
| CN114276520B (zh) * | 2021-12-08 | 2023-09-19 | 万华化学集团股份有限公司 | 一种封闭多异氰酸酯组合物及其制备方法与应用 |
| CN114736350B (zh) * | 2022-05-25 | 2023-12-19 | 安徽科瑞达新材料有限公司 | 一种脂肪族二异氰酸酯的二聚体加成产物的制备方法 |
| IT202300016509A1 (it) * | 2023-08-03 | 2025-02-03 | Maflon S P A | Composizione di poliisocianati bloccati, uso di detta composizione, e metodo di preparazione |
Family Cites Families (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2105777C3 (de) * | 1971-02-08 | 1976-02-05 | Veba Chemie Ag | Pulverförmige Überzugsmasse |
| DE2215080C3 (de) * | 1972-03-28 | 1978-10-12 | Bayer Ag, 5090 Leverkusen | Pulverförmige Überzugsmittel |
| DE2707656C2 (de) * | 1977-02-23 | 1986-04-17 | Bayer Ag, 5090 Leverkusen | Pulverförmige Überzugsmittel |
| DE2916201A1 (de) * | 1979-04-21 | 1980-10-30 | Huels Chemische Werke Ag | Verfahren zur trimerisierung von diisocyanaten |
| JPS5698136A (en) * | 1980-01-08 | 1981-08-07 | Kanegafuchi Chem Ind Co Ltd | Continuous manufacture of laminated substance |
| JPS579773A (en) * | 1980-06-23 | 1982-01-19 | Takeda Chem Ind Ltd | Production of polyisocyanate |
| DE3046409A1 (de) * | 1980-12-10 | 1982-07-15 | Bayer Ag, 5090 Leverkusen | Beschichtungsmittel und ein verfahren zur herstellung von ueberzuegen |
| US4395529A (en) * | 1981-07-20 | 1983-07-26 | Cargill, Incorporated | Coating powders for protective films based on epsilon-caprolactam blocked isocyanates |
| US4491663A (en) * | 1982-04-14 | 1985-01-01 | Ford Motor Company | Trifunctional blocked isocyanate containing an isocyanurate ring |
| US5246557A (en) * | 1984-02-29 | 1993-09-21 | The Baxenden Chemical Co. | Blocked isocyanates |
| CA1334848C (en) * | 1988-08-05 | 1995-03-21 | William E. Slack | Process for the production of polyisocyanates which contain isocyanurate groups |
| US4973646A (en) * | 1990-04-09 | 1990-11-27 | Eastman Kodak Company | Powder coating compositions |
| JP3056280B2 (ja) * | 1990-05-24 | 2000-06-26 | 三井化学株式会社 | ポリイソシアナト−イソシアヌレート及びその製造方法、ならびにこれらの用途 |
| US5159045A (en) * | 1990-05-24 | 1992-10-27 | Mitsui Toatsu Chemicals, Inc. | Polyisocyanato-isocyanurate, and preparation process and use of the same |
| US5232988A (en) * | 1992-02-25 | 1993-08-03 | Miles Inc. | Blocked polyisocyanates prepared from partially trimerized cyclic organic diisocyanates having (cyclo)aliphatically bound isocyanate groups and their use for the production of coatings |
| DE4213361A1 (de) | 1992-04-23 | 1993-10-28 | Bayer Ag | Verfahren zur Herstellung von Isocyanatpräpolymeren und ihre Verwendung zur Herstellung von Beschichtungsmitteln |
| US5817732A (en) * | 1993-02-12 | 1998-10-06 | Asahi Kasei Kogyo Kabushiki Kaisha | Blocked polyisocyanate and coating composition |
| CA2116167C (en) * | 1993-03-15 | 2007-05-15 | Myron W. Shaffer | One-component coating compositions containing oxime- or lactam-blocked polyisocyanates which have improved resistance to yellowing |
| US5510443A (en) * | 1993-03-15 | 1996-04-23 | Bayer Corporation | Process for preparing a coating with improved resistance to yellowing and the resulting coating |
| JP3712295B2 (ja) | 1996-04-12 | 2005-11-02 | 旭化成ケミカルズ株式会社 | ブロックポリイソシアネート組成物及びそれを用いた一液性熱硬化組成物 |
| US5939547A (en) * | 1997-12-22 | 1999-08-17 | Bayer Corporation | Formation of blocked isocyanurate group-containing polyisocyanates from partially blocked isocyanates |
| JPH11240936A (ja) * | 1998-02-26 | 1999-09-07 | Mitsubishi Gas Chem Co Inc | ポリイソシアネートオリゴマーおよび該ポリイソシアネートオリゴマーを用いたポリウレタン塗料 |
| US6355761B1 (en) * | 1999-05-12 | 2002-03-12 | Basf Coatings Ag | Coating composition |
| DE19860049A1 (de) * | 1998-12-23 | 2000-06-29 | Basf Ag | Härtbare Zubereitungen |
| JP2000290493A (ja) * | 1999-04-09 | 2000-10-17 | Asahi Chem Ind Co Ltd | ブロックポリイソシアネート組成物 |
| US6252121B1 (en) * | 1999-07-27 | 2001-06-26 | Union Carbide Chemicals & Plastics Technology Corporation | Metal-ligand complex catalyzed processes |
| US6660385B2 (en) * | 2000-10-11 | 2003-12-09 | Kansai Paint Co., Ltd. | Cationic paint composition |
| DE10123419A1 (de) * | 2001-05-14 | 2002-11-21 | Bayer Ag | Verfahren zur Herstellung von aliphatischen Polyisocyanaten mit Uretdion-Isocyanurat- sowie Iminooxadiazindionstruktur |
| WO2004041890A1 (en) * | 2002-10-31 | 2004-05-21 | Dow Global Technologies Inc. | Polyurethane dispersion and articles prepared therefrom |
| US20040087754A1 (en) * | 2002-10-31 | 2004-05-06 | Paul Foley | Polyurethane compounds and articles prepared therefrom |
| JP4467563B2 (ja) * | 2003-02-28 | 2010-05-26 | ダウ グローバル テクノロジーズ インコーポレイティド | イソシアヌレート基を含有するポリイソシアネート混合物の製造 |
-
2005
- 2005-09-02 MX MX2007002611A patent/MX2007002611A/es unknown
- 2005-09-02 KR KR1020077007528A patent/KR101250703B1/ko not_active Expired - Lifetime
- 2005-09-02 US US11/660,774 patent/US20080033086A1/en not_active Abandoned
- 2005-09-02 CN CN2005800372164A patent/CN101072806B/zh not_active Expired - Lifetime
- 2005-09-02 JP JP2007530472A patent/JP5191733B2/ja not_active Expired - Lifetime
- 2005-09-02 EP EP05795032A patent/EP1789466B1/en not_active Expired - Lifetime
- 2005-09-02 BR BRPI0515235A patent/BRPI0515235B1/pt active IP Right Grant
- 2005-09-02 AT AT05795032T patent/ATE532808T1/de active
- 2005-09-02 CA CA2577785A patent/CA2577785C/en not_active Expired - Lifetime
- 2005-09-02 WO PCT/US2005/031685 patent/WO2006029141A1/en not_active Ceased
- 2005-09-02 AU AU2005282549A patent/AU2005282549A1/en not_active Abandoned
-
2007
- 2007-02-23 ZA ZA200701641A patent/ZA200701641B/xx unknown
-
2012
- 2012-10-01 JP JP2012219599A patent/JP5778647B2/ja not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11421135B2 (en) | 2016-05-20 | 2022-08-23 | Mitsui Chemicals, Inc. | Curable composition, coating material, solar cell coating material, solar cell back sheet coating material, adhesive, solar cell adhesive, solar cell back sheet adhesive, producing method of sheet, and curing agent |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2006029141A1 (en) | 2006-03-16 |
| US20080033086A1 (en) | 2008-02-07 |
| ZA200701641B (en) | 2008-08-27 |
| CA2577785C (en) | 2014-10-28 |
| KR101250703B1 (ko) | 2013-04-03 |
| CN101072806A (zh) | 2007-11-14 |
| CN101072806B (zh) | 2012-09-05 |
| JP2013067800A (ja) | 2013-04-18 |
| KR20070049684A (ko) | 2007-05-11 |
| JP5778647B2 (ja) | 2015-09-16 |
| AU2005282549A1 (en) | 2006-03-16 |
| BRPI0515235A (pt) | 2008-07-15 |
| MX2007002611A (es) | 2007-04-27 |
| EP1789466A1 (en) | 2007-05-30 |
| CA2577785A1 (en) | 2006-03-16 |
| BRPI0515235B1 (pt) | 2016-09-27 |
| EP1789466B1 (en) | 2011-11-09 |
| ATE532808T1 (de) | 2011-11-15 |
| JP2008512520A (ja) | 2008-04-24 |
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