JP5172526B2 - 防錆処理された金属部材およびコート塗料 - Google Patents
防錆処理された金属部材およびコート塗料 Download PDFInfo
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- JP5172526B2 JP5172526B2 JP2008203010A JP2008203010A JP5172526B2 JP 5172526 B2 JP5172526 B2 JP 5172526B2 JP 2008203010 A JP2008203010 A JP 2008203010A JP 2008203010 A JP2008203010 A JP 2008203010A JP 5172526 B2 JP5172526 B2 JP 5172526B2
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- 229910052751 metal Inorganic materials 0.000 title claims description 273
- 239000002184 metal Substances 0.000 title claims description 273
- 239000003973 paint Substances 0.000 title claims description 58
- 239000000049 pigment Substances 0.000 claims description 247
- 239000000463 material Substances 0.000 claims description 239
- 239000011248 coating agent Substances 0.000 claims description 153
- 238000000576 coating method Methods 0.000 claims description 153
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims description 117
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 113
- 239000011247 coating layer Substances 0.000 claims description 111
- 239000004606 Fillers/Extenders Substances 0.000 claims description 94
- 229920005989 resin Polymers 0.000 claims description 85
- 239000011347 resin Substances 0.000 claims description 85
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 80
- 239000011701 zinc Substances 0.000 claims description 73
- 229910052725 zinc Inorganic materials 0.000 claims description 73
- 239000010410 layer Substances 0.000 claims description 72
- 230000003449 preventive effect Effects 0.000 claims description 61
- 239000002131 composite material Substances 0.000 claims description 46
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 claims description 44
- 239000000391 magnesium silicate Substances 0.000 claims description 44
- 229910052919 magnesium silicate Inorganic materials 0.000 claims description 44
- 235000019792 magnesium silicate Nutrition 0.000 claims description 44
- 239000003960 organic solvent Substances 0.000 claims description 43
- 230000002265 prevention Effects 0.000 claims description 41
- 239000002245 particle Substances 0.000 claims description 38
- 239000003822 epoxy resin Substances 0.000 claims description 37
- 229920000647 polyepoxide Polymers 0.000 claims description 37
- 239000005011 phenolic resin Substances 0.000 claims description 36
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical group [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 claims description 28
- 229910000165 zinc phosphate Inorganic materials 0.000 claims description 28
- 229920000388 Polyphosphate Polymers 0.000 claims description 20
- 239000001205 polyphosphate Substances 0.000 claims description 20
- 235000011176 polyphosphates Nutrition 0.000 claims description 20
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 16
- 239000002904 solvent Substances 0.000 claims description 13
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 9
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 claims description 9
- 239000000454 talc Substances 0.000 claims description 9
- 229910052623 talc Inorganic materials 0.000 claims description 9
- 239000004132 Calcium polyphosphate Substances 0.000 claims description 8
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 8
- 239000004111 Potassium silicate Substances 0.000 claims description 8
- 239000004115 Sodium Silicate Substances 0.000 claims description 8
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 claims description 8
- HJJOHHHEKFECQI-UHFFFAOYSA-N aluminum;phosphite Chemical compound [Al+3].[O-]P([O-])[O-] HJJOHHHEKFECQI-UHFFFAOYSA-N 0.000 claims description 8
- 239000001506 calcium phosphate Substances 0.000 claims description 8
- 229910000389 calcium phosphate Inorganic materials 0.000 claims description 8
- 235000011010 calcium phosphates Nutrition 0.000 claims description 8
- 235000019827 calcium polyphosphate Nutrition 0.000 claims description 8
- 239000011777 magnesium Substances 0.000 claims description 8
- 229910052749 magnesium Inorganic materials 0.000 claims description 8
- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 claims description 8
- 235000019353 potassium silicate Nutrition 0.000 claims description 8
- 229910052913 potassium silicate Inorganic materials 0.000 claims description 8
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 8
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 8
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 claims description 8
- XWKBMOUUGHARTI-UHFFFAOYSA-N tricalcium;diphosphite Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])[O-].[O-]P([O-])[O-] XWKBMOUUGHARTI-UHFFFAOYSA-N 0.000 claims description 8
- AUTOISGCBLBLBA-UHFFFAOYSA-N trizinc;diphosphite Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])[O-].[O-]P([O-])[O-] AUTOISGCBLBLBA-UHFFFAOYSA-N 0.000 claims description 8
- 239000011230 binding agent Substances 0.000 claims description 7
- 238000009826 distribution Methods 0.000 claims description 7
- PAZHGORSDKKUPI-UHFFFAOYSA-N lithium metasilicate Chemical compound [Li+].[Li+].[O-][Si]([O-])=O PAZHGORSDKKUPI-UHFFFAOYSA-N 0.000 claims description 7
- 229910052912 lithium silicate Inorganic materials 0.000 claims description 7
- 235000001055 magnesium Nutrition 0.000 claims description 7
- GVALZJMUIHGIMD-UHFFFAOYSA-H magnesium phosphate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O GVALZJMUIHGIMD-UHFFFAOYSA-H 0.000 claims description 7
- 239000004137 magnesium phosphate Substances 0.000 claims description 7
- 229910000157 magnesium phosphate Inorganic materials 0.000 claims description 7
- 229960002261 magnesium phosphate Drugs 0.000 claims description 7
- 235000010994 magnesium phosphates Nutrition 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- VMFOHNMEJNFJAE-UHFFFAOYSA-N trimagnesium;diphosphite Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]P([O-])[O-].[O-]P([O-])[O-] VMFOHNMEJNFJAE-UHFFFAOYSA-N 0.000 claims description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 claims description 6
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 6
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 6
- 230000001186 cumulative effect Effects 0.000 claims description 6
- 238000000691 measurement method Methods 0.000 claims description 6
- 239000003849 aromatic solvent Substances 0.000 claims description 4
- 150000002576 ketones Chemical class 0.000 claims description 4
- QQZOPKMRPOGIEB-UHFFFAOYSA-N 2-Oxohexane Chemical compound CCCCC(C)=O QQZOPKMRPOGIEB-UHFFFAOYSA-N 0.000 claims description 3
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 3
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 3
- 239000008096 xylene Substances 0.000 claims description 3
- 239000004925 Acrylic resin Substances 0.000 claims description 2
- 229920000178 Acrylic resin Polymers 0.000 claims description 2
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 claims 3
- 238000012360 testing method Methods 0.000 description 304
- 239000000203 mixture Substances 0.000 description 61
- 239000000843 powder Substances 0.000 description 47
- 238000003756 stirring Methods 0.000 description 39
- 238000004040 coloring Methods 0.000 description 38
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 36
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 36
- 238000002156 mixing Methods 0.000 description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 18
- 239000011324 bead Substances 0.000 description 13
- 238000011156 evaluation Methods 0.000 description 13
- 229910019142 PO4 Inorganic materials 0.000 description 12
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 12
- 235000021317 phosphate Nutrition 0.000 description 12
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 11
- 239000010452 phosphate Substances 0.000 description 10
- 238000013329 compounding Methods 0.000 description 9
- 230000007547 defect Effects 0.000 description 9
- 239000008199 coating composition Substances 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 235000019441 ethanol Nutrition 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- BULVZWIRKLYCBC-UHFFFAOYSA-N phorate Chemical compound CCOP(=S)(OCC)SCSCC BULVZWIRKLYCBC-UHFFFAOYSA-N 0.000 description 4
- 238000005260 corrosion Methods 0.000 description 3
- 235000019794 sodium silicate Nutrition 0.000 description 3
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 238000007542 hardness measurement Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 230000000149 penetrating effect Effects 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- -1 silicate ions Chemical class 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- 101000856234 Clostridium acetobutylicum (strain ATCC 824 / DSM 792 / JCM 1419 / LMG 5710 / VKM B-1787) Butyrate-acetoacetate CoA-transferase subunit A Proteins 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 240000007930 Oxalis acetosella Species 0.000 description 1
- 235000008098 Oxalis acetosella Nutrition 0.000 description 1
- HYOUHSBOGJQFMZ-UHFFFAOYSA-L P(=O)([O-])([O-])[O-].[PH4+].[Mg+2] Chemical compound P(=O)([O-])([O-])[O-].[PH4+].[Mg+2] HYOUHSBOGJQFMZ-UHFFFAOYSA-L 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- PXGXIMYFYPBSIL-UHFFFAOYSA-N [Mg].OP(O)O Chemical compound [Mg].OP(O)O PXGXIMYFYPBSIL-UHFFFAOYSA-N 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000005489 elastic deformation Effects 0.000 description 1
- 238000005485 electric heating Methods 0.000 description 1
- 238000010828 elution Methods 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 238000005480 shot peening Methods 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Images
Landscapes
- Paints Or Removers (AREA)
- Chemical Treatment Of Metals (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Laminated Bodies (AREA)
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2008203010A JP5172526B2 (ja) | 2007-09-07 | 2008-08-06 | 防錆処理された金属部材およびコート塗料 |
| CN2008102134471A CN101381875B (zh) | 2007-09-07 | 2008-09-04 | 防锈处理过的金属部件和涂布涂料 |
| EP08163773A EP2033995B1 (en) | 2007-09-07 | 2008-09-05 | Metallic member being subjected to rust-preventive treatment and coating composition for the same |
| US12/230,863 US8007923B2 (en) | 2007-09-07 | 2008-09-05 | Metallic member being subjected to rust-preventive treatment |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2007232772 | 2007-09-07 | ||
| JP2007232772 | 2007-09-07 | ||
| JP2008203010A JP5172526B2 (ja) | 2007-09-07 | 2008-08-06 | 防錆処理された金属部材およびコート塗料 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2009078263A JP2009078263A (ja) | 2009-04-16 |
| JP2009078263A5 JP2009078263A5 (cg-RX-API-DMAC7.html) | 2011-09-08 |
| JP5172526B2 true JP5172526B2 (ja) | 2013-03-27 |
Family
ID=40461921
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2008203010A Active JP5172526B2 (ja) | 2007-09-07 | 2008-08-06 | 防錆処理された金属部材およびコート塗料 |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JP5172526B2 (cg-RX-API-DMAC7.html) |
| CN (1) | CN101381875B (cg-RX-API-DMAC7.html) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5829799B2 (ja) * | 2010-01-21 | 2015-12-09 | 日新製鋼株式会社 | 耐食性および耐アルカリ性に優れた塗装鋼板 |
| CN103097576B (zh) * | 2010-06-30 | 2015-11-25 | 日新制钢株式会社 | 耐腐蚀性及耐碱性优异的涂层钢板 |
| CN104018147A (zh) * | 2014-06-13 | 2014-09-03 | 苏州汉力新材料有限公司 | 合金金属基底防腐剂 |
| JP6800856B2 (ja) * | 2015-01-16 | 2020-12-16 | トーマス・アンド・ベッツ・インターナショナル・エルエルシー | 自己修復材料で形成された電気系統で用いられる電気装置及び電気部品 |
| KR101646454B1 (ko) * | 2015-03-20 | 2016-08-05 | 현대자동차주식회사 | 호스 클립 및 호스 클립 제조 공정 |
| CN105964511A (zh) * | 2016-05-17 | 2016-09-28 | 哈尔滨电机厂有限责任公司 | 精加工金属件采用无溶剂去除防锈材料包装的工艺方法 |
| KR102156906B1 (ko) * | 2017-12-26 | 2020-09-16 | 주식회사 포스코 | 방청 피막 |
| CN108410563A (zh) * | 2018-05-11 | 2018-08-17 | 铜陵康达铝合金制品有限责任公司 | 一种铝合金切削液的制备方法 |
| EP3722374B1 (en) * | 2019-04-08 | 2024-09-04 | Hamilton Sundstrand Corporation | Low temperature-cured corrosion inhibition coating |
| JP7745859B1 (ja) * | 2024-10-15 | 2025-09-30 | 日本ペイント株式会社 | 防錆塗料組成物、塗装物品ならびに塗装物品の製造方法 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU746271B2 (en) * | 1998-02-18 | 2002-04-18 | Nippon Paint Co., Ltd. | Anticorrosive coating material and method of rust prevention |
| JP4245705B2 (ja) * | 1998-10-29 | 2009-04-02 | 日本ペイント株式会社 | アルミダイキャスト部品用防錆プライマー塗料 |
| JP2003165948A (ja) * | 2001-11-29 | 2003-06-10 | Kansai Paint Co Ltd | 下塗塗料組成物及びこれを用いた補修塗装方法 |
| JP2003194288A (ja) * | 2001-12-26 | 2003-07-09 | Maruyasu Industries Co Ltd | 金属管の表面処理構造および表面処理方法 |
| JP2003313492A (ja) * | 2002-02-21 | 2003-11-06 | Toshiba Corp | 熱硬化型塗料、その塗装方法およびその塗装物 |
| JP2004359818A (ja) * | 2003-06-04 | 2004-12-24 | Toshiba Corp | 防錆塗料およびその塗装物 |
| JP4534528B2 (ja) * | 2004-03-04 | 2010-09-01 | Ｊｆｅスチール株式会社 | 耐食性、耐湿性、加工性及び耐塗膜剥離性に優れた環境調和型プレコート鋼板 |
| JP2006083464A (ja) * | 2004-08-16 | 2006-03-30 | Togo Seisakusho Corp | 防錆金属部品及びその製造方法 |
-
2008
- 2008-08-06 JP JP2008203010A patent/JP5172526B2/ja active Active
- 2008-09-04 CN CN2008102134471A patent/CN101381875B/zh active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN101381875B (zh) | 2011-12-07 |
| CN101381875A (zh) | 2009-03-11 |
| JP2009078263A (ja) | 2009-04-16 |
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