JP5099618B2 - 繊維複合材料及びその製造方法 - Google Patents
繊維複合材料及びその製造方法 Download PDFInfo
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- JP5099618B2 JP5099618B2 JP2006196935A JP2006196935A JP5099618B2 JP 5099618 B2 JP5099618 B2 JP 5099618B2 JP 2006196935 A JP2006196935 A JP 2006196935A JP 2006196935 A JP2006196935 A JP 2006196935A JP 5099618 B2 JP5099618 B2 JP 5099618B2
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- fiber composite
- fiber assembly
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- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/26—Agents rendering paper transparent or translucent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/10—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of paper or cardboard
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
- Y10T428/269—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension including synthetic resin or polymer layer or component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/608—Including strand or fiber material which is of specific structural definition
- Y10T442/614—Strand or fiber material specified as having microdimensions [i.e., microfiber]
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Laminated Bodies (AREA)
- Reinforced Plastic Materials (AREA)
- Paper (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Description
<測定装置>
日立ハイテクノロジーズ社製「UV−4100形分光度計」(固体試料測定システム)を使用。
<測定条件>
・6mm×6mmの光源マスク使用
・測定サンプルを積分球開口より22cm離れた位置において測光した。サンプルをこの位置に置くことで、拡散透過光は除去され、積分球内部の受光部に直線透過光のみが届く。
・リファレンスサンプルなし。リファレンス(試料と空気との屈折率差によって生じる反射。フレネル反射が生じる場合は、直線透過率100%ということはあり得ない。)がないため、フレネル反射による透過率のロスが生じている。
・スキャンスピード:300nm/min
・光源:タングステンランプ、重水素ランプ
・光源切り替え:340nm
<計算方法>
50μm厚可視光透過率は、50μm厚換算における波長400〜700nmでの光線透過率の平均値より求めた。
<試料の調製及び測定条件>
各試料に、金蒸着(蒸着膜厚:数nm)を行い、下記条件で電子顕微鏡観察を行った。
測定装置:JEOL6700F(日本電子株式会社製)
加速電圧:1.5kV
倍率:10000倍
ワーキングディスタンス:8mm
コントラストの調整:AUTO
各セルロース繊維の平均繊維径は各試料のSEM画像から求めた。
20℃において、サンプルの単位体積当りの質量を測定して密度を求め、次式により空隙率を求めた。なお、本実施例で用いた繊維はセルロースであり、繊維の密度は1.5g/cm3である。
セイコーインスツルメンツ製「TMA/SS6100」を用い、ASTM D 696に規定された方法に従って下記の測定条件で測定した。
<測定条件>
昇温速度:5℃/min
雰囲気:N2中
加熱温度:20〜150℃
荷重:3g
測定回数:3回
試料長:4×15mm
試料厚さ:試料により異なる
モード:引っ張りモード
<測定装置・条件>
各試料について、下記条件で原子間力顕微鏡(AFM)を用いて評価した。
測定装置:SII製SPA−400
測定領域:5μm×5μm
原料としてパルプ由来のミクロフィブリル化セルロース:MFC(高圧ホモジナイザー処理で、針葉樹クラフトパルプ(NBKP)をミクロフィブリル化したもの、平均繊維径1μm)を水に十分に撹拌し、1重量%濃度の水懸濁液を7kg調製し、グラインダー(栗田機械作成所製「ピュアファインミルKMG1−10」)にて、この水懸濁液を、ほぼ接触させた状態の1200rpmで回転するディスク間を、中央から外に向かって通過させる操作を10回行った。
上述した製造例1において、原料としてコットン(脱脂綿)を用いたこと以外は同様にして、厚さ40〜45μm、密度1.4g/cm3、空隙率7%のコットンシートを得た。
上述した製造例1と同様の方法で製造したパルプシートを、含水状態のままt-ブチルアルコールコールへ浸し、水をすべて置換した。これを凍結乾燥機(EYELA製、FDU−2100、DRC−1000)を用いて凍結乾燥を行い、完全に脱水した。得られた乾燥パルプシートをプレスし、厚さ50μm、密度0.9g/cm3、空隙率40%の高空隙率パルプシートを得た。
製造例1で得られたパルプシートの両面にセロハンテープ(屈折率1.5)を貼り付けラミネートした。
製造例2で得られたコットンシートの両面へアクリル樹脂A(エトキシ化ビスフェノールAジアクリレート、屈折率1.54)をスピンコートし樹脂を硬化した。スピンコート条件は、1000rpm10秒、2000rpm3秒、5000rpm45秒である。スピンコーターは、ミカサ株式会社製の1H−D7を使用した。樹脂の硬化は、ベルトコンベアー型UV照射装置(フュージョンシステムズ製、Fusion F300、LCBベンチトップコンベア)を用い、20J/cm2の紫外線を照射して樹脂を硬化させた。
実施例2において、アクリル樹脂としてアクリル樹脂B(トリシクロデカンジメタクリレート(TCDDMA)、屈折率1.53)を用いたこと以外は同様にして、コットンシートの両面へアクリル樹脂Bをスピンコートして樹脂を硬化させた。
製造例2で得られたコットンシートの両面へプラズマCVD装置によってそれぞれ300nmのSiN層(屈折率1.92)を成膜した。このSiN層上からコットンシートの両面へ実施例2と同様の方法でアクリル樹脂Aをスピンコートして樹脂を硬化させた。
製造例2で得られたコットンシートをアクリル樹脂Aに減圧下(0.08MPa)で12時間浸漬処理し含浸させた後、取り出したシートを実施例2と同様のベルトコンベアー型UV照射装置を用い、20J/cm2の紫外線を照射して樹脂を硬化させた。
比較例1において、アクリル樹脂としてアクリル樹脂Bを用いたこと以外は同様にして、コットンシートへアクリル樹脂Bを含浸させ硬化させた。
製造例3で得られたパルプシートの両面へアクリル樹脂Aを実施例2と同様の方法によってスピンコートし樹脂を硬化させた。
製造例3で得られたパルプシートの両面にセロハンテープを貼り付けラミネートした。
Claims (17)
- 平均繊維径が4〜200nm、50μm厚可視光透過率が3%以上、空隙率が35%以下である繊維集合体と、前記繊維集合体表面をコートし平滑化するコート層とを備え、50μm厚可視光透過率が60%以上であることを特徴とする繊維複合材料。
- 請求項1において、前記繊維集合体がセルロース繊維で構成されることを特徴とする繊維複合材料。
- 請求項2において、前記セルロース繊維が植物繊維から分離した繊維であることを特徴とする繊維複合材料。
- 請求項3において、前記セルロース繊維が前記植物繊維から分離した繊維を解繊処理したものであることを特徴とする繊維複合材料。
- 請求項4において、前記解繊処理は磨砕処理を含むことを特徴とする繊維複合材料。
- 請求項2から5のいずれか1項において、前記セルロース繊維が化学修飾及び/又は物理修飾されていることを特徴とする繊維複合材料。
- 請求項1から6のいずれか1項において、前記コート層が、有機高分子材料、無機高分子材料、及び有機高分子と無機高分子とのハイブリッド高分子材料のうち少なくとも1種又は2種以上の組み合せであることを特徴とする繊維複合材料。
- 請求項7において、前記コート層が結晶化度10%以下で、ガラス転移温度が110℃以上の合成高分子材料であることを特徴とする繊維複合材料。
- 請求項7又は8において、前記コート層が無機材料をさらに含むことを特徴とする繊維複合材料。
- 請求項1から9のいずれか1項において、前記コート層の屈折率が1.4〜1.7であることを特徴とする繊維複合材料。
- 請求項1から10のいずれか1項において、前記コート層の50μm厚可視光透過率が60%以上であることを特徴とする繊維複合材料。
- 請求項1から11のいずれか1項において、前記繊維集合体表面の全面が前記コート層によってコートされることを特徴とする繊維複合材料。
- 請求項1から11のいずれか1項において、前記繊維集合体表面のうち前記コート層がコートされない部分に、前記コート層の材料とは異なる耐水性被覆材料が被覆されることを特徴とする繊維複合材料。
- 請求項1から13のいずれか1項において、線熱膨張係数が0.05×10−5〜5×10−5K−1であることを特徴とする繊維複合材料。
- 請求項1から14のいずれか1項に記載の繊維複合材料を製造する方法であって、前記コート層を形成し得るコート用液状物を、前記繊維集合体の表面に塗布し、次いで前記コート用液状物を硬化させることを特徴とする繊維複合材料の製造方法。
- 請求項15において、前記コート用液状物は、流動状のコート材料、流動状のコート材料の原料、コート材料を流動化させた流動化物、コート材料の原料を流動化させた流動化物、コート材料の溶液、及びコート材料の原料の溶液から選ばれる1種又は2種以上の組み合せであることを特徴とする繊維複合材料の製造方法。
- 請求項1から14のいずれか1項に記載の繊維複合材料を製造する方法であって、前記コート層を形成し得るコート用ラミネート材料を、前記繊維集合体の表面に貼り付けることを特徴とする繊維複合材料の製造方法。
Priority Applications (7)
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JP2006196935A JP5099618B2 (ja) | 2006-07-19 | 2006-07-19 | 繊維複合材料及びその製造方法 |
CNA2007800273098A CN101489783A (zh) | 2006-07-19 | 2007-07-12 | 纤维复合材料及其制备方法 |
EP20070790699 EP2042300B1 (en) | 2006-07-19 | 2007-07-12 | Fiber composite material and process for producing the same |
KR1020097003082A KR101049650B1 (ko) | 2006-07-19 | 2007-07-12 | 섬유 복합 재료 및 그의 제조방법 |
PCT/JP2007/063905 WO2008010449A1 (fr) | 2006-07-19 | 2007-07-12 | matériau composite fibreux ET SON PROCÉDÉ DE FABRICATION |
US12/309,402 US8372764B2 (en) | 2006-07-19 | 2007-07-12 | Fiber composite material and method for manufacturing the same |
TW96126026A TW200827392A (en) | 2006-07-19 | 2007-07-17 | Fiber composite material and method for producing the same |
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JP2006196935A JP5099618B2 (ja) | 2006-07-19 | 2006-07-19 | 繊維複合材料及びその製造方法 |
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JP5099618B2 true JP5099618B2 (ja) | 2012-12-19 |
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US (1) | US8372764B2 (ja) |
EP (1) | EP2042300B1 (ja) |
JP (1) | JP5099618B2 (ja) |
KR (1) | KR101049650B1 (ja) |
CN (1) | CN101489783A (ja) |
TW (1) | TW200827392A (ja) |
WO (1) | WO2008010449A1 (ja) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2021241409A1 (ja) | 2020-05-25 | 2021-12-02 | 富士フイルム株式会社 | 組成物、シート状成形体、人工皮革およびシート状成形体の製造方法 |
Families Citing this family (42)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101932416B (zh) * | 2007-12-21 | 2013-12-04 | 三菱化学株式会社 | 纤维复合体 |
JP5150295B2 (ja) * | 2008-02-12 | 2013-02-20 | ローム株式会社 | フレキシブル基板及びその製造方法 |
JP5386866B2 (ja) * | 2008-06-30 | 2014-01-15 | 国立大学法人京都大学 | ナノファイバーシート |
EP2308907B1 (en) * | 2008-07-31 | 2014-01-01 | Kyoto University | Molding material containing unsaturated polyester resin and microfibrillated plant fiber |
WO2010074340A1 (ja) * | 2008-12-26 | 2010-07-01 | 花王株式会社 | ガスバリア用材料及びガスバリア性成形体とその製造方法 |
FI124724B (fi) * | 2009-02-13 | 2014-12-31 | Upm Kymmene Oyj | Menetelmä muokatun selluloosan valmistamiseksi |
US20110206928A1 (en) * | 2009-08-24 | 2011-08-25 | Maranchi Jeffrey P | Reinforced Fibers and Related Processes |
US20110294925A1 (en) * | 2009-11-23 | 2011-12-01 | Shaler Stephen M | Composite from hemicellulose extracted wood with improved performance and reduced emissions |
JP2011246592A (ja) * | 2010-05-26 | 2011-12-08 | Panasonic Electric Works Co Ltd | 成形材料及び成形体 |
JP5910504B2 (ja) * | 2010-11-16 | 2016-04-27 | 王子ホールディングス株式会社 | セルロース繊維集合体およびその製造方法、解繊セルロース繊維およびその製造方法、並びにセルロース繊維複合体 |
BRPI1106315B1 (pt) * | 2011-01-28 | 2020-12-22 | Universidade Estadual Paulista Júlio De Mesquita Filho | compósitos opticamente transparentes baseados em celulose bacteriana e boehmita, siloxano e/ou sistema boehmita, siloxano e processo de obtenção dos compósitos |
JP5798504B2 (ja) * | 2011-11-18 | 2015-10-21 | 王子ホールディングス株式会社 | 微細繊維状セルロースの製造方法、不織布の製造方法、微細繊維状セルロース、微細繊維状セルロース含有スラリー、不織布、および複合体 |
FI125237B (en) * | 2011-12-22 | 2015-07-31 | Upm Kymmene Corp | The abstracting agent |
TWI577737B (zh) * | 2012-07-27 | 2017-04-11 | Lg化學股份有限公司 | 可固化組成物 |
JP6079039B2 (ja) * | 2012-08-10 | 2017-02-15 | 王子ホールディングス株式会社 | 微細繊維状セルロース及びその製造方法 |
US9505915B2 (en) * | 2012-11-05 | 2016-11-29 | Kyoto Municipal Institute Of Industrial Technology And Culture | Fastening component and method for manufacturing the fastening component |
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JP6127697B2 (ja) * | 2013-03-14 | 2017-05-17 | 王子ホールディングス株式会社 | 微細繊維状セルロース含有シートの製造方法 |
CA2912520C (en) * | 2013-05-16 | 2021-12-14 | Oji Holdings Corporation | Phosphoric acid-esterified fine cellulose fiber and method for producing the same |
KR102269729B1 (ko) | 2013-06-03 | 2021-06-25 | 오지 홀딩스 가부시키가이샤 | 미세 섬유 함유 시트의 제조 방법 |
US10532545B2 (en) | 2014-04-22 | 2020-01-14 | Oji Holdings Corporation | Composite and method for producing the same |
CN103952820A (zh) * | 2014-05-21 | 2014-07-30 | 张家港市玮美纺织有限公司 | 一种耐高温短纤维纱线 |
CN103952913A (zh) * | 2014-05-21 | 2014-07-30 | 张家港市玮美纺织有限公司 | 一种防紫外线短纤维纱线 |
US20170182737A1 (en) * | 2014-07-31 | 2017-06-29 | Hewlett-Packard Development Company, L.P. | Opaque-plastic film on a fiber surface |
JP6021877B2 (ja) * | 2014-10-22 | 2016-11-09 | 国立大学法人京都大学 | ゴム組成物及びゴム組成物の製造方法 |
CN104388017B (zh) * | 2014-12-12 | 2016-10-05 | 江苏天宇纤维有限公司 | 一种新型玻璃纤维网栅格及其定型胶 |
KR101675093B1 (ko) * | 2015-04-16 | 2016-11-11 | 울산과학기술원 | 유연성 투명기판의 제조방법 및 이에 의한 유연성 투명기판 |
US20180169698A1 (en) * | 2015-06-01 | 2018-06-21 | Zverse ,Inc. | Process for sealing, reinforcing and cosmetically coating cast or 3-d printed gypsum articles |
KR102196197B1 (ko) * | 2015-09-18 | 2020-12-29 | 오지 홀딩스 가부시키가이샤 | 적층체 |
JP6639203B2 (ja) * | 2015-11-26 | 2020-02-05 | 旭化成株式会社 | セルロース繊維層を含むシート |
EP3385443A4 (en) | 2015-11-30 | 2019-05-29 | Oji Holdings Corporation | SHEET AND METHOD FOR MANUFACTURING SHEET |
US11426763B2 (en) | 2016-01-20 | 2022-08-30 | Oji Holdings Corporation | Laminate and method for producing laminate |
EP3411449A4 (en) * | 2016-02-04 | 2019-10-09 | University of Maryland, College Park | TRANSPARENT WOOD COMPOSITE, SYSTEMS AND METHOD OF MANUFACTURE |
CA3050730A1 (en) * | 2016-03-31 | 2017-10-05 | Oji Holdings Corporation | Method for producing fibrous cellulose, and fibrous cellulose |
KR101989901B1 (ko) | 2016-06-02 | 2019-06-17 | 주식회사 아모그린텍 | 필터여재, 이의 제조방법 및 이를 포함하는 필터모듈 |
CN109476856B (zh) * | 2016-07-08 | 2021-11-09 | 王子控股株式会社 | 片材 |
JP6213641B2 (ja) * | 2016-09-07 | 2017-10-18 | 王子ホールディングス株式会社 | 微細繊維状セルロース |
JP6404382B2 (ja) * | 2017-02-28 | 2018-10-10 | 大王製紙株式会社 | セルロース微細繊維及びその製造方法 |
CN107221586B (zh) * | 2017-05-25 | 2019-09-20 | 青岛海信电器股份有限公司 | 柔性基板及制备方法、qled器件、柔性显示设备 |
GB201709925D0 (en) * | 2017-06-21 | 2017-08-02 | Royal College Of Art | Composite structure |
US10865317B2 (en) | 2017-08-31 | 2020-12-15 | Kimberly-Clark Worldwide, Inc. | Low-fluorine compositions with cellulose for generating superhydrophobic surfaces |
JP6989200B1 (ja) * | 2021-10-07 | 2022-01-05 | 都インキ株式会社 | (半)透明クリアファイル |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3855047A (en) * | 1970-07-08 | 1974-12-17 | Minnesota Mining & Mfg | Sheet-like nonwoven web and flexible article of polyester and aromatic polyamide staple fibers |
JPH07156279A (ja) | 1993-12-09 | 1995-06-20 | Asahi Chem Ind Co Ltd | 透明なガラス繊維強化樹脂の成形法 |
JPH08120597A (ja) * | 1994-10-20 | 1996-05-14 | Mitsubishi Paper Mills Ltd | リサイクル可能な耐水性透明紙および窓開き封筒用フィルム |
FR2739383B1 (fr) * | 1995-09-29 | 1997-12-26 | Rhodia Ag Rhone Poulenc | Microfibrilles de cellulose a surface modifiee - procede de fabrication et utilisation comme charge dans les materiaux composites |
JPH09207234A (ja) | 1996-02-07 | 1997-08-12 | Sogo Resin Kogyo Kk | 透明部を有する繊維強化樹脂製品とその製造方法 |
WO2002059192A1 (fr) * | 2001-01-25 | 2002-08-01 | Fuji Photo Film Co., Ltd. | Film d'acylate de cellulose, film d'acylate de cellulose avec couche mince fonctionnelle et procede de preparation de ceux-ci |
CN1832985B (zh) | 2003-07-31 | 2010-10-20 | 国立大学法人京都大学 | 纤维增强复合材料及其制备方法和应用 |
JP4724814B2 (ja) * | 2003-07-31 | 2011-07-13 | 国立大学法人京都大学 | 繊維強化複合材料及びその製造方法並びに配線基板 |
WO2006001527A1 (en) * | 2004-06-29 | 2006-01-05 | Fujifilm Corporation | Optical cellulose acylate film, polarizing plate and liquid crystal display |
JP2006123222A (ja) * | 2004-10-26 | 2006-05-18 | Sekisui Film Kk | 金属調化粧シート及び化粧金属板 |
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US8372764B2 (en) | 2013-02-12 |
EP2042300A1 (en) | 2009-04-01 |
KR101049650B1 (ko) | 2011-07-14 |
EP2042300B1 (en) | 2013-09-11 |
JP2008024778A (ja) | 2008-02-07 |
KR20090029845A (ko) | 2009-03-23 |
US20090305033A1 (en) | 2009-12-10 |
WO2008010449A1 (fr) | 2008-01-24 |
TW200827392A (en) | 2008-07-01 |
CN101489783A (zh) | 2009-07-22 |
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