JP5021159B2 - 熱硬化性の非ポリマー被覆組成物及び前記組成物を用いた被覆法 - Google Patents
熱硬化性の非ポリマー被覆組成物及び前記組成物を用いた被覆法 Download PDFInfo
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- JP5021159B2 JP5021159B2 JP2004354342A JP2004354342A JP5021159B2 JP 5021159 B2 JP5021159 B2 JP 5021159B2 JP 2004354342 A JP2004354342 A JP 2004354342A JP 2004354342 A JP2004354342 A JP 2004354342A JP 5021159 B2 JP5021159 B2 JP 5021159B2
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- carbamate
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- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- VSKFADHADUWCCL-UHFFFAOYSA-N carbamoperoxoic acid Chemical compound NC(=O)OO VSKFADHADUWCCL-UHFFFAOYSA-N 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical class [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- 238000011437 continuous method Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 1
- 239000006184 cosolvent Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000007766 curtain coating Methods 0.000 description 1
- 125000000392 cycloalkenyl group Chemical group 0.000 description 1
- AYOHIQLKSOJJQH-UHFFFAOYSA-N dibutyltin Chemical compound CCCC[Sn]CCCC AYOHIQLKSOJJQH-UHFFFAOYSA-N 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- XJUNRGGMKUAPAP-UHFFFAOYSA-N dioxido(dioxo)molybdenum;lead(2+) Chemical compound [Pb+2].[O-][Mo]([O-])(=O)=O XJUNRGGMKUAPAP-UHFFFAOYSA-N 0.000 description 1
- 238000003618 dip coating Methods 0.000 description 1
- 230000008034 disappearance Effects 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 229940060296 dodecylbenzenesulfonic acid Drugs 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- HQMYMLYUCNJLLU-UHFFFAOYSA-N ethenol;ethylurea Chemical compound OC=C.CCNC(N)=O HQMYMLYUCNJLLU-UHFFFAOYSA-N 0.000 description 1
- WUDNUHPRLBTKOJ-UHFFFAOYSA-N ethyl isocyanate Chemical compound CCN=C=O WUDNUHPRLBTKOJ-UHFFFAOYSA-N 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical compound O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 description 1
- 239000008397 galvanized steel Substances 0.000 description 1
- 229910052595 hematite Inorganic materials 0.000 description 1
- 239000011019 hematite Substances 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- DCYOBGZUOMKFPA-UHFFFAOYSA-N iron(2+);iron(3+);octadecacyanide Chemical compound [Fe+2].[Fe+2].[Fe+2].[Fe+3].[Fe+3].[Fe+3].[Fe+3].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] DCYOBGZUOMKFPA-UHFFFAOYSA-N 0.000 description 1
- WTFXARWRTYJXII-UHFFFAOYSA-N iron(2+);iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[Fe+2].[Fe+3].[Fe+3] WTFXARWRTYJXII-UHFFFAOYSA-N 0.000 description 1
- LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 description 1
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 1
- YOBAEOGBNPPUQV-UHFFFAOYSA-N iron;trihydrate Chemical compound O.O.O.[Fe].[Fe] YOBAEOGBNPPUQV-UHFFFAOYSA-N 0.000 description 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 1
- ZBKFYXZXZJPWNQ-UHFFFAOYSA-N isothiocyanate group Chemical group [N-]=C=S ZBKFYXZXZJPWNQ-UHFFFAOYSA-N 0.000 description 1
- 150000002540 isothiocyanates Chemical class 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- MOUPNEIJQCETIW-UHFFFAOYSA-N lead chromate Chemical compound [Pb+2].[O-][Cr]([O-])(=O)=O MOUPNEIJQCETIW-UHFFFAOYSA-N 0.000 description 1
- 150000007517 lewis acids Chemical class 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 150000007974 melamines Chemical class 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- QQWAKSKPSOFJFF-UHFFFAOYSA-N oxiran-2-ylmethyl 2,2-dimethyloctanoate Chemical compound CCCCCCC(C)(C)C(=O)OCC1CO1 QQWAKSKPSOFJFF-UHFFFAOYSA-N 0.000 description 1
- FIWHJQPAGLNURC-UHFFFAOYSA-N oxiran-2-ylmethyl 7,7-dimethyloctanoate Chemical compound CC(C)(C)CCCCCC(=O)OCC1CO1 FIWHJQPAGLNURC-UHFFFAOYSA-N 0.000 description 1
- 150000002924 oxiranes Chemical class 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- ZZSIDSMUTXFKNS-UHFFFAOYSA-N perylene red Chemical compound CC(C)C1=CC=CC(C(C)C)=C1N(C(=O)C=1C2=C3C4=C(OC=5C=CC=CC=5)C=1)C(=O)C2=CC(OC=1C=CC=CC=1)=C3C(C(OC=1C=CC=CC=1)=CC1=C2C(C(N(C=3C(=CC=CC=3C(C)C)C(C)C)C1=O)=O)=C1)=C2C4=C1OC1=CC=CC=C1 ZZSIDSMUTXFKNS-UHFFFAOYSA-N 0.000 description 1
- CMPQUABWPXYYSH-UHFFFAOYSA-N phenyl phosphate Chemical compound OP(O)(=O)OC1=CC=CC=C1 CMPQUABWPXYYSH-UHFFFAOYSA-N 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 239000000088 plastic resin Substances 0.000 description 1
- 239000003495 polar organic solvent Substances 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920005906 polyester polyol Polymers 0.000 description 1
- ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical class O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 description 1
- 229960003351 prussian blue Drugs 0.000 description 1
- 239000013225 prussian blue Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- AZLXCBPKSXFMET-UHFFFAOYSA-M sodium 4-[(4-sulfophenyl)diazenyl]naphthalen-1-olate Chemical compound [Na+].C12=CC=CC=C2C(O)=CC=C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 AZLXCBPKSXFMET-UHFFFAOYSA-M 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000007592 spray painting technique Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- NVKTUNLPFJHLCG-UHFFFAOYSA-N strontium chromate Chemical compound [Sr+2].[O-][Cr]([O-])(=O)=O NVKTUNLPFJHLCG-UHFFFAOYSA-N 0.000 description 1
- 150000003462 sulfoxides Chemical class 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- YARHBRUWMYJLHY-UHFFFAOYSA-Q triazanium;iron(3+);hexacyanide Chemical compound [NH4+].[NH4+].[NH4+].[Fe+3].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] YARHBRUWMYJLHY-UHFFFAOYSA-Q 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
- QEDNBHNWMHJNAB-UHFFFAOYSA-N tris(8-methylnonyl) phosphite Chemical compound CC(C)CCCCCCCOP(OCCCCCCCC(C)C)OCCCCCCCC(C)C QEDNBHNWMHJNAB-UHFFFAOYSA-N 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 description 1
- 229910000165 zinc phosphate Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/02—Polyureas
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/2805—Compounds having only one group containing active hydrogen
- C08G18/285—Nitrogen containing compounds
- C08G18/2865—Compounds having only one primary or secondary amino group; Ammonia
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/46—Polycondensates having carboxylic or carbonic ester groups in the main chain having heteroatoms other than oxygen
- C08G18/4615—Polycondensates having carboxylic or carbonic ester groups in the main chain having heteroatoms other than oxygen containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D201/00—Coating compositions based on unspecified macromolecular compounds
- C09D201/02—Coating compositions based on unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups
- C09D201/025—Coating compositions based on unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups containing nitrogen atoms
Description
Rは、H又はアルキルであり、有利に、RはH又は1〜約8個の炭素原子を有するアルキルであり、更に有利に、RはH又は1〜約4個の炭素原子を有するアルキルであり、更に有利に、RはHである]
を有する基を指す。RがHである場合、カルバメート基は、ここでは1級カルバメート基を指す。本発明に関して使用される”末端尿素基”という用語は、以下の構造式
R’’及びR’’’は、それぞれ独立して、H又はアルキルであるか、又は、R’’及びR’’’は一緒になって複素環を形成する]
を有する基を指す。有利に、R’’及びR’’’はそれぞれ独立して、又は一緒になって、エチレン架橋を形成し、更に有利に、R’’及びR’’’はそれぞれHである(1級末端尿素)。
ペンタエリトリトール136g(1モル)を、120℃で、キシレン100g中で、無水ヘキサヒドロフタル酸508g(3.3モル)と反応させた。反応は120℃を上回る発熱を伴って開始し、125℃未満に制御するように留意した。反応の終了を、IR(1860及び1780cm−1での無水物のピークの消失)により、及び酸価滴定によりモニターした。IRによる無水物ピークが存在せず、かつ酸価が286〜289mgKOH/不揮発性物質gである時に、反応が100%完了した。このポリエステル酸に、グリシジルネオデカノエート(Resolution Performance ProductsからのCardura E10)792g(3.3当量)を、温度が上昇して130℃を上回ることのないような速度で添加した。添加後、滴定された酸価が3mgKOH/不揮発性物質g未満であり、かつ、IRが845〜910cm−1でエポキシドピークを示さなくなるまで、反応混合物を130〜135℃で保持した。このように形成されたポリエステルポリオールは、滴定の通り、約156mgKOH/不揮発性物質gのヒドロキシル価を有していた。
3リットルの反応器に、樹脂調製物Aのカルバメート−官能性樹脂(不揮発性物質含分70%)2293質量部、ベンジルアミン56質量部及びアロマチック(Aromatic)100 25質量部を装入した。反応器の内容物を高度の撹拌下に(約200rpm)撹拌し、10℃に冷却した。ヘキサメチレンジイソシアネート44質量部とアロマチック100 57.5質量部との混合物を2時間に亘り添加し、温度を15℃又はそれ未満に保持した。反応器に添加したアロマチック100 25質量部で供給管を洗浄した。その後、反応器の内容物を室温に温めた。生成物は、1ミクロンより大きな粒子を含まない不揮発性物質69質量%の固体含分を有していた。分散液生成物の滴定では、遊離イソシアネートは示されなかった。
ロータ−ステータを備えた9000rpmが可能なT25 S1ドライブと流動室DK25.11とを備えたウルトラツラックス(Ultra-Turrax)(IKAから入手したもの)を、第二の反応物を反応室中へと同軸方向でポンプ輸送することができるように改良した。従って、チャネル入口を流動室中に挿入し、流動室の中心領域を通過して、反応室中へと第二の反応物が排出されるようにした。実施例1で使用したカルバメート−官能性樹脂2293質量部、ベンジルアミン56質量部、及びアロマチック100 25質量部を用いて第一の混合物を製造し、10℃未満に冷却した。ヘキサメチレンジイソシアネート44質量部及びアロマチック100 57.5質量部を用いて、第二の混合物を製造した。9000rpmで運転しているTS−25ドライブを用いて、第一の混合物を流動室の入口ポート中へとポンプ輸送し、第二の混合物を、追加されたチャンネル入口を通して流動室中へとポンプ輸送した。第一の混合物及び第二の混合物の添加が同時に、開始と終了が一緒になるように調節された速度で、両混合物をポンプ輸送した。カルバメート−官能性樹脂中のジウレア結晶の分散液を、流動室の出口で捕集した。分散液生成物に添加したアロマチック100 25質量部で流動室を洗浄した。
以下の表に示した材料と質量部との組合せにより、被覆組成物を製造した。
Claims (14)
- 熱硬化性の非ポリマー被覆組成物において、
・ カルバメート基、末端尿素基、カルボン酸基、メルカプト基、1級アミン基、2級アミン基、1級アミンのアミド、およびこれらの組み合わせからなる群から選択される、複数の活性水素基を有する少なくとも1種のモノマー材料、
・ 少なくとも1種のモノマー材料と反応する少なくとも1種の架橋剤、及び
・ アミンとイソシアネートとの結晶質反応生成物を含有することを特徴とする、熱硬化性の非ポリマー被覆組成物。 - 活性水素基が、カルバメート基、末端尿素基、カルボン酸基、及びこれらの組合せからなる群から選択されている、請求項1記載の熱硬化性の非ポリマー被覆組成物。
- 架橋剤が結晶質反応生成物と反応する、請求項1または2記載の熱硬化性の非ポリマー被覆組成物。
- 複数の活性水素基を有する少なくとも1種のモノマー材料が、カルバメート−官能性モノマー材料又は末端尿素−官能性モノマー材料を含有し、このカルバメート−官能性モノマー材料又は末端尿素−官能性モノマー材料は、少なくとも2個の官能基を含有し、この少なくとも2個の官能基の少なくとも一方はカルバメート基又は末端尿素基であり、このカルバメート基又は末端尿素基は、(1)エポキシ基を有する化合物と有機酸基を有する化合物との間の開環反応の結果である第一の化合物のヒドロキシル基と(2)シアン酸、又は、カルバメート基又は尿素基含有化合物との反応生成物である、請求項1から3までのいずれか1項記載の熱硬化性の非ポリマー被覆組成物。
- 複数の活性水素基を有する少なくとも1種のモノマー材料が、カルバメート−官能性材料又は末端尿素−官能性材料を含有し、このカルバメート−官能性材料又は末端尿素−官能性材料は、(1)カルバメート基又は末端尿素基と、ラクトン又はヒドロキシカルボン酸と反応する活性水素基とを含有する化合物と、(2)ラクトン又はヒドロキシカルボン酸との反応生成物である、請求項1から3までのいずれか1項記載の熱硬化性の非ポリマー被覆組成物。
- 複数の活性水素基を有する少なくとも1種のモノマー材料が、カルバメート−官能性材料又は末端尿素−官能性材料を含有し、このカルバメート−官能性材料又は末端尿素−官能性材料は、(1)1級カルバメート基又は末端尿素基とヒドロキシル基とを含有する化合物と(2)ラクトン又はヒドロキシカルボン酸との反応により製造された第一の材料(A)と、化合物(1)の複数の分子のヒドロキシル基とは反応するが、化合物(1)のカルバメート基又は尿素基とは反応しない、第二の材料(B)との反応生成物である、請求項1から3までのいずれか1項記載の熱硬化性の非ポリマー被覆組成物。
- 複数の活性水素基を有する少なくとも1種のモノマー材料が、カルバメート−官能性材料又は末端尿素−官能性材料を含有し、このカルバメート−官能性材料又は末端尿素−官能性材料は、(1)少なくとも1種のポリイソシアネートと活性水素含有連鎖延長剤とを含む混合物の反応生成物である第一の材料と(2)前記の第一の材料と反応する基と、カルバメート基又は末端尿素基、又はカルバメート基又は末端尿素基へと変換することができる基とを含有する化合物との反応生成物である、請求項1から3までのいずれか1項記載の熱硬化性の非ポリマー被覆組成物。
- 複数の活性水素基を有する少なくとも1種のモノマー材料が、少なくとも2個のカルバメート基と24〜72個の炭素原子を有する炭化水素部分とを有するカルバメート−官能性材料を有する、請求項1から7までのいずれか1項記載の熱硬化性の非ポリマー被覆組成物。
- アミンが1級モノアミンである、請求項1から8までのいずれか1項記載の熱硬化性の非ポリマー被覆組成物。
- アミンが、ベンジルアミン、エチルアミン、プロピルアミン、ブチルアミン、ペンチルアミン、ヘキシルアミン、メチルブチルアミン、エチルプロピルアミン、エチルブチルアミン及びこれらの組合せから成る群から選択されている、請求項1から9までのいずれか1項記載の熱硬化性の非ポリマー被覆組成物。
- イソシアネートが1,6−ヘキサメチレンジイソシアネートを含有する、請求項1から10までのいずれか1項記載の熱硬化性の非ポリマー被覆組成物。
- ヒュームドシリカを含有する、請求項1から11までのいずれか1項記載の熱硬化性の非ポリマー被覆組成物。
- 被覆組成物を用いて下地を被覆する方法において、以下の工程:
請求項1から12までのいずれか1項記載の熱硬化性の非ポリマー被覆組成物の層を下地に施与する工程;
及び
施与された層を硬化して、下地上に硬化された被覆層を生じさせる工程
を有することを特徴とする、被覆組成物を用いて下地を被覆する方法。 - 熱硬化性の非ポリマー被覆組成物を、クリヤコートとして、予め施与されたベースコート被覆層上に施与する、請求項13記載の方法。
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US10/732,850 US8686090B2 (en) | 2003-12-10 | 2003-12-10 | Use of urea crystals for non-polymeric coatings |
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JP2005171252A JP2005171252A (ja) | 2005-06-30 |
JP5021159B2 true JP5021159B2 (ja) | 2012-09-05 |
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US (1) | US8686090B2 (ja) |
EP (1) | EP1541639B1 (ja) |
JP (1) | JP5021159B2 (ja) |
AT (1) | ATE498663T1 (ja) |
BR (1) | BRPI0412559A (ja) |
CA (1) | CA2513978A1 (ja) |
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2003
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- 2004-11-23 AT AT04027726T patent/ATE498663T1/de not_active IP Right Cessation
- 2004-11-23 DE DE602004031402T patent/DE602004031402D1/de active Active
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US8686090B2 (en) | 2014-04-01 |
EP1541639A1 (en) | 2005-06-15 |
WO2005061632A1 (en) | 2005-07-07 |
DE602004031402D1 (de) | 2011-03-31 |
ATE498663T1 (de) | 2011-03-15 |
CA2513978A1 (en) | 2005-07-07 |
US20050131134A1 (en) | 2005-06-16 |
JP2005171252A (ja) | 2005-06-30 |
BRPI0412559A (pt) | 2006-09-19 |
EP1541639B1 (en) | 2011-02-16 |
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