JP4987857B2 - 重合体分散物及び電気触媒インク - Google Patents
重合体分散物及び電気触媒インク Download PDFInfo
- Publication number
- JP4987857B2 JP4987857B2 JP2008511801A JP2008511801A JP4987857B2 JP 4987857 B2 JP4987857 B2 JP 4987857B2 JP 2008511801 A JP2008511801 A JP 2008511801A JP 2008511801 A JP2008511801 A JP 2008511801A JP 4987857 B2 JP4987857 B2 JP 4987857B2
- Authority
- JP
- Japan
- Prior art keywords
- electrocatalyst
- ink
- acid
- polymer
- polymer dispersion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000010411 electrocatalyst Substances 0.000 title claims description 89
- 239000004815 dispersion polymer Substances 0.000 title claims description 35
- 239000000463 material Substances 0.000 claims description 46
- 229920001940 conductive polymer Polymers 0.000 claims description 40
- 239000012528 membrane Substances 0.000 claims description 39
- 239000002253 acid Substances 0.000 claims description 33
- 239000002322 conducting polymer Substances 0.000 claims description 29
- 238000009792 diffusion process Methods 0.000 claims description 26
- 239000007788 liquid Substances 0.000 claims description 26
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 18
- 230000002378 acidificating effect Effects 0.000 claims description 18
- 229910017604 nitric acid Inorganic materials 0.000 claims description 18
- 229920000642 polymer Polymers 0.000 claims description 11
- 230000003197 catalytic effect Effects 0.000 claims description 8
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 6
- 239000004020 conductor Substances 0.000 claims description 3
- UQSQSQZYBQSBJZ-UHFFFAOYSA-N fluorosulfonic acid Chemical compound OS(F)(=O)=O UQSQSQZYBQSBJZ-UHFFFAOYSA-N 0.000 claims description 3
- 239000000976 ink Substances 0.000 description 100
- 239000006185 dispersion Substances 0.000 description 38
- 229920000557 Nafion® Polymers 0.000 description 27
- 239000007789 gas Substances 0.000 description 24
- 230000000052 comparative effect Effects 0.000 description 19
- 239000002609 medium Substances 0.000 description 18
- 239000003054 catalyst Substances 0.000 description 17
- 239000006228 supernatant Substances 0.000 description 17
- 238000000034 method Methods 0.000 description 16
- 101000575041 Homo sapiens Male-enhanced antigen 1 Proteins 0.000 description 15
- 102100025532 Male-enhanced antigen 1 Human genes 0.000 description 15
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 14
- 238000004519 manufacturing process Methods 0.000 description 12
- 238000002474 experimental method Methods 0.000 description 10
- 239000007787 solid Substances 0.000 description 10
- 239000000243 solution Substances 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 238000001595 flow curve Methods 0.000 description 8
- 239000000446 fuel Substances 0.000 description 8
- 229910052697 platinum Inorganic materials 0.000 description 7
- 238000007639 printing Methods 0.000 description 7
- 238000012546 transfer Methods 0.000 description 6
- 238000002156 mixing Methods 0.000 description 5
- 239000003960 organic solvent Substances 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- 239000000758 substrate Substances 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 238000005507 spraying Methods 0.000 description 4
- 229920003935 Flemion® Polymers 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 238000000429 assembly Methods 0.000 description 3
- 230000000712 assembly Effects 0.000 description 3
- 238000005266 casting Methods 0.000 description 3
- 238000005119 centrifugation Methods 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000003487 electrochemical reaction Methods 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 239000005518 polymer electrolyte Substances 0.000 description 3
- 239000002861 polymer material Substances 0.000 description 3
- 229920005597 polymer membrane Polymers 0.000 description 3
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 3
- 238000001771 vacuum deposition Methods 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 239000012736 aqueous medium Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 238000011068 loading method Methods 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 229920003934 Aciplex® Polymers 0.000 description 1
- 239000007848 Bronsted acid Substances 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 239000010953 base metal Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 229920001600 hydrophobic polymer Polymers 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 230000032258 transport Effects 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/52—Electrically conductive inks
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/28—Nitrogen-containing compounds
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/8647—Inert electrodes with catalytic activity, e.g. for fuel cells consisting of more than one material, e.g. consisting of composites
- H01M4/8652—Inert electrodes with catalytic activity, e.g. for fuel cells consisting of more than one material, e.g. consisting of composites as mixture
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/8663—Selection of inactive substances as ingredients for catalytic active masses, e.g. binders, fillers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
- H01M4/8803—Supports for the deposition of the catalytic active composition
- H01M4/881—Electrolytic membranes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
- H01M4/8825—Methods for deposition of the catalytic active composition
- H01M4/8828—Coating with slurry or ink
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1004—Fuel cells with solid electrolytes characterised by membrane-electrode assemblies [MEA]
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
- H01M8/1023—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon, e.g. polyarylenes, polystyrenes or polybutadiene-styrenes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/1039—Polymeric electrolyte materials halogenated, e.g. sulfonated polyvinylidene fluorides
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
- H01M8/1081—Polymeric electrolyte materials characterised by the manufacturing processes starting from solutions, dispersions or slurries exclusively of polymers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Composite Materials (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Inert Electrodes (AREA)
- Catalysts (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB0510119.1 | 2005-05-18 | ||
| GBGB0510119.1A GB0510119D0 (en) | 2005-05-18 | 2005-05-18 | Polymer dispersion and electrocatalyst ink |
| PCT/GB2006/050112 WO2006123187A1 (en) | 2005-05-18 | 2006-05-16 | Polymer dispersion and electrocatalyst ink |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2008540793A JP2008540793A (ja) | 2008-11-20 |
| JP2008540793A5 JP2008540793A5 (enExample) | 2009-07-02 |
| JP4987857B2 true JP4987857B2 (ja) | 2012-07-25 |
Family
ID=34708361
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2008511801A Expired - Fee Related JP4987857B2 (ja) | 2005-05-18 | 2006-05-16 | 重合体分散物及び電気触媒インク |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US9127182B2 (enExample) |
| EP (1) | EP1882020B1 (enExample) |
| JP (1) | JP4987857B2 (enExample) |
| KR (1) | KR101270857B1 (enExample) |
| CN (1) | CN101223253B (enExample) |
| CA (1) | CA2608299A1 (enExample) |
| GB (1) | GB0510119D0 (enExample) |
| WO (1) | WO2006123187A1 (enExample) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB0614909D0 (en) * | 2006-07-27 | 2006-09-06 | Johnson Matthey Plc | Catalyst |
| EP2467889A1 (de) * | 2009-08-21 | 2012-06-27 | Basf Se | Anorganische und/oder organische säure enthaltende katalysatortinte und deren verwendung in der herstellung von elektroden, katalysatorbeschichteten membranen, gasdiffusionselektroden und membran-elektroden-einheiten |
| CN104115318A (zh) * | 2012-02-23 | 2014-10-22 | 凸版印刷株式会社 | 固体高分子型燃料电池用膜电极接合体及其制造方法、固体高分子型燃料电池 |
| US9865883B2 (en) * | 2014-02-14 | 2018-01-09 | Nissan North America, Inc. | Fuel cell electrodes using high density support material |
| JP6206371B2 (ja) | 2014-10-14 | 2017-10-04 | トヨタ自動車株式会社 | 燃料電池用電極触媒層の製造方法 |
| CN108884578B (zh) | 2016-04-04 | 2020-05-05 | 二氧化碳材料公司 | 催化剂层和电解装置 |
| CN112744972B (zh) * | 2020-12-31 | 2022-02-22 | 中国科学院生态环境研究中心 | 电芬顿-膜蒸馏协同水处理的装置及方法 |
| GB2607883A (en) | 2021-06-11 | 2022-12-21 | Johnson Matthey Hydrogen Technologies Ltd | Electrocatalyst ink |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4043933A (en) * | 1976-06-15 | 1977-08-23 | United Technologies Corporation | Method of fabricating a fuel cell electrode |
| JPS58165266A (ja) * | 1982-03-26 | 1983-09-30 | Hitachi Ltd | 燃料電池 |
| US4849253A (en) * | 1987-05-29 | 1989-07-18 | International Fuel Cell Corporation | Method of making an electrochemical cell electrode |
| GB9504713D0 (en) | 1995-03-09 | 1995-04-26 | Johnson Matthey Plc | Improved electrocatalytic material |
| US5672439A (en) * | 1995-12-18 | 1997-09-30 | Ballard Power Systems, Inc. | Method and apparatus for reducing reactant crossover in an electrochemical fuel cell |
| DE19611510A1 (de) * | 1996-03-23 | 1997-09-25 | Degussa | Gasdiffusionselektrode für Membranbrennstoffzellen und Verfahren zu ihrer Herstellung |
| JP3873387B2 (ja) | 1997-07-25 | 2007-01-24 | 株式会社ジーエス・ユアサコーポレーション | 高分子電解質膜−反応部接合体の製造方法 |
| US6277512B1 (en) * | 1999-06-18 | 2001-08-21 | 3M Innovative Properties Company | Polymer electrolyte membranes from mixed dispersions |
| JP2002280003A (ja) * | 2001-03-21 | 2002-09-27 | Matsushita Electric Ind Co Ltd | 高分子電解質型燃料電池用電極と電解質膜電極接合体の製造方法 |
| GB0200253D0 (en) * | 2002-01-08 | 2002-02-20 | Johnson Matthey Plc | Improved material for electrode manufacture |
| JP3941515B2 (ja) * | 2002-01-15 | 2007-07-04 | トヨタ自動車株式会社 | 燃料電池電極用触媒層の製造方法及び燃料電池電極用触媒層製造用インクの製造方法 |
| DE10318398B4 (de) | 2002-04-24 | 2008-05-21 | Honda Giken Kogyo K.K. | Verfahren zum Herstellen einer Elektrolytmembran-Verbundelektrode und eine Lackzusammensetzung, die darin verwendet wird |
| JP4123272B2 (ja) * | 2002-06-17 | 2008-07-23 | ダイキン工業株式会社 | 含フッ素ポリマー分散体及び含フッ素ポリマー分散体製造方法 |
| JP2005123106A (ja) * | 2003-10-20 | 2005-05-12 | Toyota Motor Corp | 燃料電池用膜・電極接合体の製造方法 |
| CN1256783C (zh) * | 2004-05-14 | 2006-05-17 | 武汉理工大学 | 一种高温质子交换膜燃料电池膜电极及制备方法 |
| KR100601984B1 (ko) * | 2005-01-20 | 2006-07-18 | 삼성에스디아이 주식회사 | 담지 촉매 및 그 제조방법 |
-
2005
- 2005-05-18 GB GBGB0510119.1A patent/GB0510119D0/en not_active Ceased
-
2006
- 2006-05-16 CN CN200680025965XA patent/CN101223253B/zh not_active Expired - Fee Related
- 2006-05-16 JP JP2008511801A patent/JP4987857B2/ja not_active Expired - Fee Related
- 2006-05-16 KR KR1020077029407A patent/KR101270857B1/ko not_active Expired - Fee Related
- 2006-05-16 CA CA002608299A patent/CA2608299A1/en not_active Abandoned
- 2006-05-16 EP EP06744314.3A patent/EP1882020B1/en active Active
- 2006-05-16 WO PCT/GB2006/050112 patent/WO2006123187A1/en not_active Ceased
- 2006-05-17 US US11/914,696 patent/US9127182B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JP2008540793A (ja) | 2008-11-20 |
| EP1882020A1 (en) | 2008-01-30 |
| KR20080023300A (ko) | 2008-03-13 |
| CN101223253B (zh) | 2011-03-09 |
| KR101270857B1 (ko) | 2013-06-07 |
| GB0510119D0 (en) | 2005-06-22 |
| CA2608299A1 (en) | 2006-11-23 |
| US20080292943A1 (en) | 2008-11-27 |
| US9127182B2 (en) | 2015-09-08 |
| EP1882020B1 (en) | 2013-07-10 |
| CN101223253A (zh) | 2008-07-16 |
| WO2006123187A1 (en) | 2006-11-23 |
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