JP4987202B2 - 熱硬化性ポリマー分散液 - Google Patents
熱硬化性ポリマー分散液 Download PDFInfo
- Publication number
- JP4987202B2 JP4987202B2 JP2001530381A JP2001530381A JP4987202B2 JP 4987202 B2 JP4987202 B2 JP 4987202B2 JP 2001530381 A JP2001530381 A JP 2001530381A JP 2001530381 A JP2001530381 A JP 2001530381A JP 4987202 B2 JP4987202 B2 JP 4987202B2
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- JP
- Japan
- Prior art keywords
- polymer
- dispersion
- ethylenically unsaturated
- weight
- alkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- 239000006185 dispersion Substances 0.000 title claims description 36
- 229920001187 thermosetting polymer Polymers 0.000 title description 9
- 239000004634 thermosetting polymer Substances 0.000 title description 3
- 239000004815 dispersion polymer Substances 0.000 claims abstract description 41
- 239000000758 substrate Substances 0.000 claims abstract description 20
- 238000004519 manufacturing process Methods 0.000 claims abstract description 8
- 229920000642 polymer Polymers 0.000 claims description 130
- 239000000203 mixture Substances 0.000 claims description 102
- 239000011230 binding agent Substances 0.000 claims description 84
- 239000000178 monomer Substances 0.000 claims description 42
- 238000006243 chemical reaction Methods 0.000 claims description 34
- 150000001412 amines Chemical class 0.000 claims description 32
- 239000000463 material Substances 0.000 claims description 21
- 125000000217 alkyl group Chemical group 0.000 claims description 20
- 239000003431 cross linking reagent Substances 0.000 claims description 20
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 20
- 239000007864 aqueous solution Substances 0.000 claims description 18
- 239000007787 solid Substances 0.000 claims description 18
- 239000002245 particle Substances 0.000 claims description 17
- 238000006116 polymerization reaction Methods 0.000 claims description 16
- 125000003342 alkenyl group Chemical group 0.000 claims description 14
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 13
- 150000001875 compounds Chemical class 0.000 claims description 12
- 150000002763 monocarboxylic acids Chemical class 0.000 claims description 12
- 125000002947 alkylene group Chemical group 0.000 claims description 11
- 238000007720 emulsion polymerization reaction Methods 0.000 claims description 11
- 150000001991 dicarboxylic acids Chemical class 0.000 claims description 10
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 9
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 claims description 9
- 150000003973 alkyl amines Chemical class 0.000 claims description 8
- 150000005690 diesters Chemical class 0.000 claims description 8
- 239000001257 hydrogen Substances 0.000 claims description 8
- 229910052739 hydrogen Inorganic materials 0.000 claims description 8
- 150000003254 radicals Chemical class 0.000 claims description 8
- 239000004971 Cross linker Substances 0.000 claims description 6
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical class C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 5
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- 150000001408 amides Chemical class 0.000 claims description 2
- 150000003018 phosphorus compounds Chemical group 0.000 claims description 2
- 238000005304 joining Methods 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 64
- 239000000835 fiber Substances 0.000 description 52
- -1 vinyl halides Chemical class 0.000 description 40
- 239000002253 acid Substances 0.000 description 26
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 24
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 24
- 238000001723 curing Methods 0.000 description 22
- 239000008367 deionised water Substances 0.000 description 22
- 229910021641 deionized water Inorganic materials 0.000 description 22
- 238000002360 preparation method Methods 0.000 description 19
- 238000000034 method Methods 0.000 description 18
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 18
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 17
- 239000007799 cork Substances 0.000 description 15
- 150000002148 esters Chemical class 0.000 description 15
- 238000012360 testing method Methods 0.000 description 15
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 13
- 239000003795 chemical substances by application Substances 0.000 description 12
- 239000003365 glass fiber Substances 0.000 description 12
- 239000004816 latex Substances 0.000 description 12
- 229920000126 latex Polymers 0.000 description 12
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 11
- 239000011248 coating agent Substances 0.000 description 11
- 239000000243 solution Substances 0.000 description 11
- 238000001035 drying Methods 0.000 description 10
- 239000011094 fiberboard Substances 0.000 description 10
- 239000002023 wood Substances 0.000 description 10
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 9
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 9
- 150000007513 acids Chemical class 0.000 description 9
- 239000011521 glass Substances 0.000 description 9
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 9
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 8
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 229920002522 Wood fibre Polymers 0.000 description 8
- 230000002378 acidificating effect Effects 0.000 description 8
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 8
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 8
- 239000002025 wood fiber Substances 0.000 description 8
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 7
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 7
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 7
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 7
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 7
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 7
- 238000000576 coating method Methods 0.000 description 7
- 229920001577 copolymer Polymers 0.000 description 7
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 7
- GRVDJDISBSALJP-UHFFFAOYSA-N methyloxidanyl Chemical compound [O]C GRVDJDISBSALJP-UHFFFAOYSA-N 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- 229920002554 vinyl polymer Polymers 0.000 description 7
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 239000000654 additive Substances 0.000 description 6
- 239000011976 maleic acid Substances 0.000 description 6
- 150000003077 polyols Chemical group 0.000 description 6
- 230000008569 process Effects 0.000 description 6
- 239000011541 reaction mixture Substances 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 6
- QGLWBTPVKHMVHM-KTKRTIGZSA-N (z)-octadec-9-en-1-amine Chemical class CCCCCCCC\C=C/CCCCCCCCN QGLWBTPVKHMVHM-KTKRTIGZSA-N 0.000 description 5
- AZUYLZMQTIKGSC-UHFFFAOYSA-N 1-[6-[4-(5-chloro-6-methyl-1H-indazol-4-yl)-5-methyl-3-(1-methylindazol-5-yl)pyrazol-1-yl]-2-azaspiro[3.3]heptan-2-yl]prop-2-en-1-one Chemical compound ClC=1C(=C2C=NNC2=CC=1C)C=1C(=NN(C=1C)C1CC2(CN(C2)C(C=C)=O)C1)C=1C=C2C=NN(C2=CC=1)C AZUYLZMQTIKGSC-UHFFFAOYSA-N 0.000 description 5
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 5
- 150000001298 alcohols Chemical class 0.000 description 5
- 239000011093 chipboard Substances 0.000 description 5
- 238000005886 esterification reaction Methods 0.000 description 5
- 238000007046 ethoxylation reaction Methods 0.000 description 5
- 230000009477 glass transition Effects 0.000 description 5
- 238000005470 impregnation Methods 0.000 description 5
- 239000002557 mineral fiber Substances 0.000 description 5
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 4
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 4
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 4
- 230000001070 adhesive effect Effects 0.000 description 4
- 150000008064 anhydrides Chemical class 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 230000032050 esterification Effects 0.000 description 4
- 239000001530 fumaric acid Substances 0.000 description 4
- 239000003999 initiator Substances 0.000 description 4
- 239000012784 inorganic fiber Substances 0.000 description 4
- 238000009413 insulation Methods 0.000 description 4
- 239000010410 layer Substances 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 4
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 4
- 229920005862 polyol Polymers 0.000 description 4
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 239000004576 sand Substances 0.000 description 4
- 230000008961 swelling Effects 0.000 description 4
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 4
- 229960004418 trolamine Drugs 0.000 description 4
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 description 3
- 244000198134 Agave sisalana Species 0.000 description 3
- 241000218236 Cannabis Species 0.000 description 3
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical class NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 3
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 3
- 229910003827 NRaRb Inorganic materials 0.000 description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 3
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 3
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
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- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
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- LEJBBGNFPAFPKQ-UHFFFAOYSA-N 2-(2-prop-2-enoyloxyethoxy)ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOC(=O)C=C LEJBBGNFPAFPKQ-UHFFFAOYSA-N 0.000 description 2
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- INQDDHNZXOAFFD-UHFFFAOYSA-N 2-[2-(2-prop-2-enoyloxyethoxy)ethoxy]ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOCCOC(=O)C=C INQDDHNZXOAFFD-UHFFFAOYSA-N 0.000 description 2
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 2
- KUDUQBURMYMBIJ-UHFFFAOYSA-N 2-prop-2-enoyloxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC(=O)C=C KUDUQBURMYMBIJ-UHFFFAOYSA-N 0.000 description 2
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- 125000000113 cyclohexyl group Chemical class [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 2
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- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- OPQYOFWUFGEMRZ-UHFFFAOYSA-N tert-butyl 2,2-dimethylpropaneperoxoate Chemical compound CC(C)(C)OOC(=O)C(C)(C)C OPQYOFWUFGEMRZ-UHFFFAOYSA-N 0.000 description 1
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- WMXCDAVJEZZYLT-UHFFFAOYSA-N tert-butylthiol Chemical compound CC(C)(C)S WMXCDAVJEZZYLT-UHFFFAOYSA-N 0.000 description 1
- UFHILTCGAOPTOV-UHFFFAOYSA-N tetrakis(ethenyl)silane Chemical compound C=C[Si](C=C)(C=C)C=C UFHILTCGAOPTOV-UHFFFAOYSA-N 0.000 description 1
- AKRQMTFHUVDMIL-UHFFFAOYSA-N tetrakis(prop-2-enyl)silane Chemical compound C=CC[Si](CC=C)(CC=C)CC=C AKRQMTFHUVDMIL-UHFFFAOYSA-N 0.000 description 1
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- 235000010215 titanium dioxide Nutrition 0.000 description 1
- 150000003918 triazines Chemical class 0.000 description 1
- YNJBWRMUSHSURL-UHFFFAOYSA-N trichloroacetic acid Chemical compound OC(=O)C(Cl)(Cl)Cl YNJBWRMUSHSURL-UHFFFAOYSA-N 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea group Chemical group NC(=O)N XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
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Classifications
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- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
- D04H1/593—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives to layered webs
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/02—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of acids, salts or anhydrides
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F267/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated polycarboxylic acids or derivatives thereof as defined in group C08F22/00
- C08F267/02—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated polycarboxylic acids or derivatives thereof as defined in group C08F22/00 on to polymers of acids or salts
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
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- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
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- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
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- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
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- D04H1/587—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives characterised by the bonding agents used
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- D—TEXTILES; PAPER
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- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
- D04H1/64—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives the bonding agent being applied in wet state, e.g. chemical agents in dispersions or solutions
- D04H1/645—Impregnation followed by a solidification process
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
- C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Polymerisation Methods In General (AREA)
- Graft Or Block Polymers (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Polyurethanes Or Polyureas (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19949592A DE19949592A1 (de) | 1999-10-14 | 1999-10-14 | Thermisch härtbare Polymerdipersion |
| DE19949592.0 | 1999-10-14 | ||
| PCT/EP2000/010108 WO2001027163A1 (de) | 1999-10-14 | 2000-10-13 | Thermisch härtbare polymerdispersion |
Publications (3)
| Publication Number | Publication Date |
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| JP2003511520A JP2003511520A (ja) | 2003-03-25 |
| JP2003511520A5 JP2003511520A5 (enExample) | 2011-10-13 |
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| JP2001530381A Expired - Fee Related JP4987202B2 (ja) | 1999-10-14 | 2000-10-13 | 熱硬化性ポリマー分散液 |
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| EP (1) | EP1240205B1 (enExample) |
| JP (1) | JP4987202B2 (enExample) |
| KR (1) | KR100747905B1 (enExample) |
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| BR (1) | BR0014703B1 (enExample) |
| DE (2) | DE19949592A1 (enExample) |
| ES (1) | ES2231273T3 (enExample) |
| MX (1) | MX225920B (enExample) |
| WO (1) | WO2001027163A1 (enExample) |
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| DE10125139A1 (de) * | 2001-05-22 | 2002-12-05 | Basf Ag | Thermisch härtbare Bindemittel |
| DE10151569A1 (de) | 2001-10-23 | 2003-04-30 | Basf Ag | Thermisch härtbare Bindemittel |
| DE10208361A1 (de) * | 2002-02-27 | 2003-09-04 | Basf Ag | Verfahren zur Herstellung einer wässrigen thermisch härtbaren Polymerdispersion |
| PT1554323E (pt) | 2002-10-14 | 2015-07-31 | Bollig & Kemper Gmbh & Co Kg | Dispersão de microgel com ácido fosfónico modificado |
| DE10247847A1 (de) * | 2002-10-14 | 2004-04-22 | Bollig & Kemper Gmbh & Co. Kg | Phosphonsäuremodifizierte Mikrogeldispersion |
| DE10304958A1 (de) * | 2003-02-06 | 2004-08-19 | Basf Ag | Verwendung von wäßrigen Bindemitteln bei der Herstellung von Schleifmaterialien |
| DE10310882A1 (de) * | 2003-03-11 | 2004-09-23 | Basf Ag | Verwendung von wäßrigen Bindemitteln bei der Herstellung von Filtermaterialien |
| US7399818B2 (en) | 2004-03-16 | 2008-07-15 | Rohm And Haas Company | Curable composition and use thereof |
| DE102004013390A1 (de) * | 2004-03-17 | 2005-10-06 | Basf Ag | Dachbahnen |
| DE102004016646A1 (de) * | 2004-03-31 | 2005-10-27 | Basf Ag | Verfahren zur Herstellung von Halbzeug und Formteilen |
| DE102004061144A1 (de) * | 2004-12-16 | 2006-06-22 | Basf Ag | Verwendung formaldehydfreier wässriger Bindemittel für Substrate |
| DE102005005205A1 (de) | 2005-02-03 | 2006-08-10 | Basf Ag | Verwendung einer wässrigen Polymerdispersion als Bindemittel für cellulosische Fasern sowie zur Herstellung von Filtermaterialien |
| EP1739106A1 (en) * | 2005-07-01 | 2007-01-03 | Rohm and Haas Company | Method for preparing curable composition |
| TW200710153A (en) * | 2005-07-01 | 2007-03-16 | Rohm & Haas | Curable composition |
| DE102005037113A1 (de) * | 2005-08-03 | 2007-02-08 | Basf Ag | Verwendung einer thermisch härtbaren wässrigen Zusammensetzung als Bindemittel für Substrate |
| DE102006019184A1 (de) * | 2006-04-21 | 2007-10-25 | Basf Ag | Verwendung einer wässrigen Polymerzusammensetzung als Bindemittel für faserförmige oder körnige Substrate |
| US8299153B2 (en) * | 2006-12-22 | 2012-10-30 | Rohm And Haas Company | Curable aqueous compositions |
| EP1942141A1 (en) * | 2006-12-22 | 2008-07-09 | Rohm and Haas France SAS | Curable composition |
| US7888407B2 (en) | 2007-10-26 | 2011-02-15 | Conocophillips Company | Disperse non-polyalphaolefin drag reducing polymers |
| US7842738B2 (en) * | 2007-10-26 | 2010-11-30 | Conocophillips Company | High polymer content hybrid drag reducers |
| US20100056717A1 (en) * | 2007-11-02 | 2010-03-04 | Mallard Creek Polymers | One Component Thermoset Latex Composition |
| PL2093318T3 (pl) | 2008-02-22 | 2013-05-31 | Isowood Holding Gmbh | Elastyczny materiał kompozytowy, sposób jego wytwarzania oraz jego zastosowanie |
| US20100040832A1 (en) * | 2008-08-13 | 2010-02-18 | Saint-Gobain Technical Fabrics America, Inc. | Formaldehyde free woven and non-woven fabrics having improved hot wet tensile strength and binder formulations for same |
| US8816016B2 (en) * | 2008-09-09 | 2014-08-26 | Rohm And Haas Company | Reduced corrosion curable composition |
| EP2172333A1 (de) * | 2008-09-19 | 2010-04-07 | Basf Se | Mehrschichtige lignucellulosehaltige Formkörper mit geringer Formaldehydemission |
| US20100197185A1 (en) * | 2009-01-30 | 2010-08-05 | Saint-Gobain Technical Fabrics America, Inc. | Low and ultra-low formaldehyde emission binders for non-woven glass mat |
| MX2012000638A (es) * | 2009-07-14 | 2012-04-30 | Sherwin Williams Co | Polimeros hibridos de almidon. |
| ES2542742T3 (es) | 2009-09-09 | 2015-08-11 | Basf Se | Procedimiento para la preparación de una dispersión acuosa de aglutinante |
| CN102040794B (zh) * | 2009-10-21 | 2014-10-08 | 罗门哈斯公司 | 可固化水性组合物 |
| US8623501B2 (en) * | 2010-03-04 | 2014-01-07 | Basf Se | Lignocellulose materials having good mechanical properties |
| US8920923B2 (en) * | 2010-03-04 | 2014-12-30 | Basf Se | Lignocellulose materials having good mechanical properties |
| DE102011005638A1 (de) | 2010-03-19 | 2011-12-15 | Basf Se | Verfahren zur Herstellung eines Formkörpers aus körnigen und/oder faserförmigen Substraten |
| EP2614117B1 (de) | 2010-09-10 | 2016-08-17 | Basf Se | Mehrschichtige lignocellulosehaltige formkörper mit geringer formaldehydemission |
| WO2012080338A1 (de) | 2010-12-17 | 2012-06-21 | Basf Se | Mehrschichtige lignocellulosehaltige formkörper mit geringer formaldehydemission |
| JP5443526B2 (ja) * | 2011-03-01 | 2014-03-19 | ローム アンド ハース カンパニー | エポキシ樹脂吸収ポリマー粒子 |
| DE102012105425B4 (de) | 2012-06-22 | 2017-05-04 | Carcoustics Techconsult Gmbh | Halbzeug und Formteil aus flächenförmigen Fasergebilden und Bindemitteln sowie Verfahren zu deren Herstellung |
| AU2014323535B2 (en) | 2013-09-18 | 2018-05-10 | Holcim Technology Ltd | Peel and stick roofing membranes with cured pressure-sensitive adhesives |
| JP6162562B2 (ja) * | 2013-09-26 | 2017-07-12 | 株式会社日本触媒 | 新規結合剤 |
| CA2936607C (en) | 2014-01-13 | 2023-01-03 | Basf Se | Method for the production of lignocellulose materials |
| CA2941239C (en) | 2014-03-07 | 2022-12-06 | Firestone Building Products Co., LLC | Roofing membranes with pre-applied, cured, pressure-sensitive seam adhesives |
| EP3126432B1 (de) | 2014-04-04 | 2018-01-10 | Basf Se | Verfahren zur herstellung von formkörpern |
| LT3274143T (lt) | 2015-03-27 | 2019-12-10 | Basf Se | Medienos medžiagų gamybos būdas |
| WO2016156053A1 (de) | 2015-03-27 | 2016-10-06 | Basf Se | Verfahren zur herstellung von ein- oder mehrschichtigen lignocellulosewerkstoffen unter verwendung von trialkylphosphat |
| PL3416988T3 (pl) | 2016-02-15 | 2020-11-16 | Basf Se | Kompozyt polimer/włókno termoformowalny |
| US20200299967A1 (en) | 2016-03-25 | 2020-09-24 | Firestone Building Products Company, Llc | Method of reroofing |
| US12006692B2 (en) | 2016-03-25 | 2024-06-11 | Holcim Technology Ltd | Fully-adhered roof system adhered and seamed with a common adhesive |
| WO2017165870A1 (en) | 2016-03-25 | 2017-09-28 | Firestone Building Products Co., LLC | Fabric-backed roofing membrane composite |
| CA3018752C (en) | 2016-03-25 | 2022-06-07 | Firestone Building Products Company, Llc | Fully-adhered roof system adhered and seamed with a common adhesive |
| CA3037076A1 (en) | 2016-09-23 | 2018-03-29 | Basf Se | Method for producing lignocellulose materials |
| CN113015756B (zh) | 2018-10-10 | 2024-08-02 | 罗门哈斯公司 | 包含多阶段胶乳聚合物颗粒的水性组合物 |
| KR102269775B1 (ko) * | 2020-09-15 | 2021-06-28 | 윤미라 | 저온경화 가능한 난연성 유·무기 바인더 및 그 제조방법 |
| WO2023117394A1 (de) | 2021-12-20 | 2023-06-29 | Basf Se | Verfahren zur herstellung eines thermoverformbaren polymer/faser-komposits |
| EP4594421A1 (en) | 2022-09-27 | 2025-08-06 | Basf Se | Binder system for an aqueous stoving paint |
| WO2025190757A1 (en) | 2024-03-11 | 2025-09-18 | Basf Se | Coating composition for container glass |
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| JPH047378A (ja) * | 1990-04-05 | 1992-01-10 | Ppg Ind Inc | 外部架橋剤を用いることなく塗装するための分散体 |
| JPH09291105A (ja) * | 1996-01-08 | 1997-11-11 | Basf Ag | 水不溶性ポリマーの製造法およびポリマー分散液 |
| WO1999002591A1 (de) * | 1997-07-08 | 1999-01-21 | Basf Aktiengesellschaft | Thermisch härtbare, wässrige zusammensetzungen |
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| GB1366081A (en) | 1971-03-25 | 1974-09-11 | Ethylene Plastique Sa | Process for the treatment of the surface of a substrate with ethylene -maleic anhydride copolymer particles |
| CA1076297A (en) | 1974-03-25 | 1980-04-22 | Graham Swift | Method for curing polymers containing one or more carboxy or anhydride functions |
| US4670505A (en) | 1985-08-23 | 1987-06-02 | Hercules Incorporated | Polyacrylate dispersions |
| CA1318426C (en) | 1986-08-22 | 1993-05-25 | Johnsondiversey Inc. | Resin-fortified emulsion polymers and methods of preparing the same |
| US4868016A (en) | 1988-02-23 | 1989-09-19 | Rohm And Haas Company | Method of treating substrates |
| ATE113307T1 (de) | 1990-03-03 | 1994-11-15 | Basf Ag | Formkörper. |
| US5314943A (en) | 1990-11-30 | 1994-05-24 | Rohm And Haax Company | Low viscosity high strength acid binder |
| US5143582A (en) | 1991-05-06 | 1992-09-01 | Rohm And Haas Company | Heat-resistant nonwoven fabrics |
| EP0537910A2 (en) | 1991-10-18 | 1993-04-21 | Rohm And Haas Company | Solvent resistant latex paint |
| EP0576128A1 (en) | 1992-06-23 | 1993-12-29 | Rohm And Haas Company | Polymer blend containing an acid-rich polymer |
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| JP3040267B2 (ja) | 1992-10-23 | 2000-05-15 | 日本カーバイド工業株式会社 | 再帰反射性シートの製造方法 |
| US5427587A (en) | 1993-10-22 | 1995-06-27 | Rohm And Haas Company | Method for strengthening cellulosic substrates |
| JP2764554B2 (ja) * | 1995-03-31 | 1998-06-11 | 三洋化成工業株式会社 | 共役ジエン系樹脂ラテックス |
| DE19900460A1 (de) | 1999-01-08 | 2000-07-13 | Basf Ag | Polymerdispersionen |
| DE19900459A1 (de) | 1999-01-08 | 2000-07-13 | Basf Ag | Polymerdispersion |
-
1999
- 1999-10-14 DE DE19949592A patent/DE19949592A1/de not_active Withdrawn
-
2000
- 2000-10-13 KR KR1020027004775A patent/KR100747905B1/ko not_active Expired - Fee Related
- 2000-10-13 US US10/110,106 patent/US6841608B1/en not_active Expired - Lifetime
- 2000-10-13 MX MXPA02003692 patent/MX225920B/es active IP Right Grant
- 2000-10-13 DE DE50005625T patent/DE50005625D1/de not_active Expired - Lifetime
- 2000-10-13 WO PCT/EP2000/010108 patent/WO2001027163A1/de not_active Ceased
- 2000-10-13 AT AT00967867T patent/ATE261456T1/de active
- 2000-10-13 EP EP00967867A patent/EP1240205B1/de not_active Expired - Lifetime
- 2000-10-13 ES ES00967867T patent/ES2231273T3/es not_active Expired - Lifetime
- 2000-10-13 JP JP2001530381A patent/JP4987202B2/ja not_active Expired - Fee Related
- 2000-10-13 BR BRPI0014703-6A patent/BR0014703B1/pt not_active IP Right Cessation
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH047378A (ja) * | 1990-04-05 | 1992-01-10 | Ppg Ind Inc | 外部架橋剤を用いることなく塗装するための分散体 |
| JPH09291105A (ja) * | 1996-01-08 | 1997-11-11 | Basf Ag | 水不溶性ポリマーの製造法およびポリマー分散液 |
| WO1999002591A1 (de) * | 1997-07-08 | 1999-01-21 | Basf Aktiengesellschaft | Thermisch härtbare, wässrige zusammensetzungen |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2003511520A (ja) | 2003-03-25 |
| DE50005625D1 (en) | 2004-04-15 |
| EP1240205A1 (de) | 2002-09-18 |
| DE19949592A1 (de) | 2001-04-19 |
| KR100747905B1 (ko) | 2007-08-08 |
| ATE261456T1 (de) | 2004-03-15 |
| US6841608B1 (en) | 2005-01-11 |
| EP1240205B1 (de) | 2004-03-10 |
| BR0014703A (pt) | 2002-06-18 |
| KR20020041457A (ko) | 2002-06-01 |
| WO2001027163A1 (de) | 2001-04-19 |
| ES2231273T3 (es) | 2005-05-16 |
| MXPA02003692A (es) | 2002-08-30 |
| MX225920B (es) | 2005-01-31 |
| BR0014703B1 (pt) | 2011-10-18 |
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