JP4955073B2 - 積層体の製造方法及び該方法で製造された積層体 - Google Patents
積層体の製造方法及び該方法で製造された積層体 Download PDFInfo
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- JP4955073B2 JP4955073B2 JP2009553861A JP2009553861A JP4955073B2 JP 4955073 B2 JP4955073 B2 JP 4955073B2 JP 2009553861 A JP2009553861 A JP 2009553861A JP 2009553861 A JP2009553861 A JP 2009553861A JP 4955073 B2 JP4955073 B2 JP 4955073B2
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- 239000011256 inorganic filler Substances 0.000 claims description 2
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- VVBLNCFGVYUYGU-UHFFFAOYSA-N 4,4'-Bis(dimethylamino)benzophenone Chemical compound C1=CC(N(C)C)=CC=C1C(=O)C1=CC=C(N(C)C)C=C1 VVBLNCFGVYUYGU-UHFFFAOYSA-N 0.000 description 2
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- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
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- 239000011229 interlayer Substances 0.000 description 2
- 239000005453 ketone based solvent Substances 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- 229920001228 polyisocyanate Polymers 0.000 description 2
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- PIZHFBODNLEQBL-UHFFFAOYSA-N 2,2-diethoxy-1-phenylethanone Chemical compound CCOC(OCC)C(=O)C1=CC=CC=C1 PIZHFBODNLEQBL-UHFFFAOYSA-N 0.000 description 1
- BTJPUDCSZVCXFQ-UHFFFAOYSA-N 2,4-diethylthioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC(CC)=CC(CC)=C3SC2=C1 BTJPUDCSZVCXFQ-UHFFFAOYSA-N 0.000 description 1
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- ZCDADJXRUCOCJE-UHFFFAOYSA-N 2-chlorothioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC(Cl)=CC=C3SC2=C1 ZCDADJXRUCOCJE-UHFFFAOYSA-N 0.000 description 1
- KMNCBSZOIQAUFX-UHFFFAOYSA-N 2-ethoxy-1,2-diphenylethanone Chemical compound C=1C=CC=CC=1C(OCC)C(=O)C1=CC=CC=C1 KMNCBSZOIQAUFX-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- MPIAGWXWVAHQBB-UHFFFAOYSA-N [3-prop-2-enoyloxy-2-[[3-prop-2-enoyloxy-2,2-bis(prop-2-enoyloxymethyl)propoxy]methyl]-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(COC(=O)C=C)(COC(=O)C=C)COCC(COC(=O)C=C)(COC(=O)C=C)COC(=O)C=C MPIAGWXWVAHQBB-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
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- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- VSWIZZORKUCUDZ-UHFFFAOYSA-N bis(6-hydroxy-6-methylcyclohexa-2,4-dien-1-yl)methanone Chemical compound CC1(O)C=CC=CC1C(=O)C1C(O)(C)C=CC=C1 VSWIZZORKUCUDZ-UHFFFAOYSA-N 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- BMFYCFSWWDXEPB-UHFFFAOYSA-N cyclohexyl(phenyl)methanone Chemical compound C=1C=CC=CC=1C(=O)C1CCCCC1 BMFYCFSWWDXEPB-UHFFFAOYSA-N 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000006356 dehydrogenation reaction Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 239000003759 ester based solvent Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000004210 ether based solvent Substances 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 230000005251 gamma ray Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000007756 gravure coating Methods 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-M hexanoate Chemical compound CCCCCC([O-])=O FUZZWVXGSFPDMH-UHFFFAOYSA-M 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000006224 matting agent Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 229910001507 metal halide Inorganic materials 0.000 description 1
- 150000005309 metal halides Chemical class 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 238000007645 offset printing Methods 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000012766 organic filler Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
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- 239000004094 surface-active agent Substances 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/50—Multilayers
- B05D7/52—Two layers
- B05D7/54—No clear coat specified
- B05D7/544—No clear coat specified the first layer is let to dry at least partially before applying the second layer
Description
(1)アートレジンAH−51M40・・・根上工業株式会社製タックフリー型ウレタンアクリレート。
(2)紫光UV1700B・・・日本合成化学株式会社製(液状)ウレタンアクリレート。
(3)ダイヤナールBR85・・・三菱レーヨン株式会社製アクリル樹脂(Tg約100℃)。
(4)アロニックスM−402・・・東亜合成株式会社製ジペンタエリスリトールヘキサアクリレート。
(5)アクリディックA−814・・・DIC株式会社製アクリルポリオール。
(6)デスモジュール L−75・・・住友バイエルウレタン株式会社製ポリイソシアネート。
(7)パラロイドB−72・・・ロームアンドハース製アクリル樹脂(Tg約40℃)。(8)イルガキュア184・・・チバ・スペシャリティー・ケミカルズ株式会社製光重合開始剤。
(9)サイロイド7000・・・グレースジャパン株式会社製シリカ(平均粒径約5μm)。
1層目をバーコーターにて原反全面に塗工し、100℃、約60秒乾燥し溶剤を揮発させた。2層目は1層目の上に実施例1、2、比較例1,2の場合は全面に、実施例3、比較例4,5の場合は部分的にバーコーターにて塗工し、100℃、約60秒乾燥し溶剤を揮発させた。表1及び表2に記載の硬化条件にて塗膜全体を硬化させた。硬化条件は、UV:高圧水銀灯 120W/cm 1灯 10m/分 1パス照射した。熱硬化を行う場合は60℃で3日間静置した。
タックフリー性・・・100℃、約60秒の熱乾燥後、指触にてタックを評価する。
耐ブロッキング性・・・PETフィルム(東洋坊製え5101、25μm)を塗工物上に設置し、100g/cm2、40℃、24時間放置し、PETフィルムへの裏移りの状態を評価する。
折り曲げ性・・・塗工物を180°折り曲げ、塗膜の割れの状態を評価する。
MEKラビング・・・脱脂綿にMEKを含ませ、塗工物表面を100回ダブルラビングした時の塗膜状態を評価する。
Claims (3)
- (1)紙又はプラスチックフィルム基材上に、(a)主骨格にウレタン結合を有し、(b)軟化点が40−150℃で、(c)重量平均分子量が5,000−1,000,000で、(d)有機溶剤に可溶の活性エネルギー線硬化性樹脂及び有機溶剤を含有する活性エネルギー線硬化性組成物を塗布する工程、(2)活性エネルギー線照射を伴わない乾燥工程、(3)熱可塑性組成物、熱硬化性組成物及び活性エネルギー線硬化性組成物からなる群から選ばれる1種以上を含有する組成物を全面あるいは部分的に重ね塗布する工程、(4)活性エネルギー線を照射する硬化工程をこの順に有することを特徴とする積層体の製造方法。
- 前記した、(a)主骨格にウレタン結合を有し、(b)軟化点が40−150℃で、(c)重量平均分子量が5,000−1,000,000で、(d)有機溶剤に可溶の活性エネルギー線硬化性樹脂及び有機溶剤を含有する活性エネルギー線硬化性組成物が、平均粒径20μm以下の無機系フィラーを含有する請求項1に記載の積層体の製造方法。
- 紙又はプラスチックフィルム基材上に、活性エネルギー線硬化性組成物の硬化層及び、熱可塑性組成物、熱硬化性組成物及び活性エネルギー線硬化性組成物からなる群から選ばれる1種以上を含有する組成物の硬化層とを有する積層体であって、
(1)紙又はプラスチックフィルム基材上に、(a)主骨格にウレタン結合を有し、(b)軟化点が40−150℃で、(c)重量平均分子量が5,000−1,000,000で、(d)有機溶剤に可溶の活性エネルギー線硬化性樹脂及び有機溶剤を含有する活性エネルギー線硬化性組成物を塗布する工程、(2)活性エネルギー線照射を伴わない乾燥工程、(3)熱可塑性組成物、熱硬化性組成物及び活性エネルギー線硬化性組成物からなる群から選ばれる1種以上を含有する組成物を全面あるいは部分的に重ね塗布する工程、(4)活性エネルギー線を照射する硬化工程によって製造されることを特徴とする積層体。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2009553861A JP4955073B2 (ja) | 2008-06-13 | 2009-06-02 | 積層体の製造方法及び該方法で製造された積層体 |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
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JP2008155239 | 2008-06-13 | ||
JP2008155239 | 2008-06-13 | ||
PCT/JP2009/060014 WO2009150954A1 (ja) | 2008-06-13 | 2009-06-02 | 積層体の製造方法及び該方法で製造された積層体 |
JP2009553861A JP4955073B2 (ja) | 2008-06-13 | 2009-06-02 | 積層体の製造方法及び該方法で製造された積層体 |
Publications (2)
Publication Number | Publication Date |
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JPWO2009150954A1 JPWO2009150954A1 (ja) | 2011-11-10 |
JP4955073B2 true JP4955073B2 (ja) | 2012-06-20 |
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JP2009553861A Active JP4955073B2 (ja) | 2008-06-13 | 2009-06-02 | 積層体の製造方法及び該方法で製造された積層体 |
Country Status (3)
Country | Link |
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JP (1) | JP4955073B2 (ja) |
TW (1) | TWI461291B (ja) |
WO (1) | WO2009150954A1 (ja) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
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EP3053739A4 (en) * | 2013-09-30 | 2017-05-03 | Dai Nippon Printing Co., Ltd. | Decorative sheet, decorative resin molded article, and manufacturing method for decorative resin molded article |
JP6549937B2 (ja) * | 2014-09-26 | 2019-07-24 | セーレン株式会社 | 積層シートおよび成形体、並びにそれらの製造方法 |
JP6492878B2 (ja) * | 2015-03-30 | 2019-04-03 | 大日本印刷株式会社 | 化粧シート及びその製造方法 |
JP6658847B2 (ja) * | 2018-11-19 | 2020-03-04 | 大日本印刷株式会社 | 化粧シート及びその製造方法 |
Family Cites Families (2)
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JP4948850B2 (ja) * | 2006-03-02 | 2012-06-06 | 中国塗料株式会社 | 多層塗膜、該多層塗膜を備える基材、およびこれらの製造方法 |
JP2007276212A (ja) * | 2006-04-04 | 2007-10-25 | Mitsubishi Chemicals Corp | 積層体 |
-
2009
- 2009-06-02 JP JP2009553861A patent/JP4955073B2/ja active Active
- 2009-06-02 WO PCT/JP2009/060014 patent/WO2009150954A1/ja active Application Filing
- 2009-06-12 TW TW098119645A patent/TWI461291B/zh active
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Publication number | Publication date |
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TWI461291B (zh) | 2014-11-21 |
JPWO2009150954A1 (ja) | 2011-11-10 |
TW201002518A (en) | 2010-01-16 |
WO2009150954A1 (ja) | 2009-12-17 |
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