JP4918129B2 - 繊維、生地及び肌着 - Google Patents
繊維、生地及び肌着 Download PDFInfo
- Publication number
- JP4918129B2 JP4918129B2 JP2009274382A JP2009274382A JP4918129B2 JP 4918129 B2 JP4918129 B2 JP 4918129B2 JP 2009274382 A JP2009274382 A JP 2009274382A JP 2009274382 A JP2009274382 A JP 2009274382A JP 4918129 B2 JP4918129 B2 JP 4918129B2
- Authority
- JP
- Japan
- Prior art keywords
- weight
- parts
- manufactured
- fiber
- ciba japan
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000004744 fabric Substances 0.000 title claims description 47
- 239000004753 textile Substances 0.000 title description 3
- 239000000835 fiber Substances 0.000 claims description 131
- 229920002614 Polyether block amide Polymers 0.000 claims description 71
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 64
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 62
- 239000003963 antioxidant agent Substances 0.000 claims description 42
- 230000003078 antioxidant effect Effects 0.000 claims description 42
- 229910052698 phosphorus Inorganic materials 0.000 claims description 33
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 32
- 239000011574 phosphorus Substances 0.000 claims description 32
- PYSRRFNXTXNWCD-UHFFFAOYSA-N 3-(2-phenylethenyl)furan-2,5-dione Chemical compound O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 PYSRRFNXTXNWCD-UHFFFAOYSA-N 0.000 claims description 28
- 229920000147 Styrene maleic anhydride Polymers 0.000 claims description 28
- 229920002725 thermoplastic elastomer Polymers 0.000 claims description 24
- 229920001971 elastomer Polymers 0.000 claims description 22
- 239000000806 elastomer Substances 0.000 claims description 22
- 150000007513 acids Chemical class 0.000 claims description 17
- 150000008065 acid anhydrides Chemical class 0.000 claims description 9
- 229920002647 polyamide Polymers 0.000 claims description 9
- 229920005989 resin Polymers 0.000 description 115
- 239000011347 resin Substances 0.000 description 115
- 239000008188 pellet Substances 0.000 description 91
- 239000004611 light stabiliser Substances 0.000 description 44
- 239000000126 substance Substances 0.000 description 35
- 238000009987 spinning Methods 0.000 description 34
- 238000003801 milling Methods 0.000 description 32
- OLFNXLXEGXRUOI-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4,6-bis(2-phenylpropan-2-yl)phenol Chemical compound C=1C(N2N=C3C=CC=CC3=N2)=C(O)C(C(C)(C)C=2C=CC=CC=2)=CC=1C(C)(C)C1=CC=CC=C1 OLFNXLXEGXRUOI-UHFFFAOYSA-N 0.000 description 29
- 239000006096 absorbing agent Substances 0.000 description 27
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 24
- 238000004383 yellowing Methods 0.000 description 23
- 238000002074 melt spinning Methods 0.000 description 22
- FLPKSBDJMLUTEX-UHFFFAOYSA-N bis(1,2,2,6,6-pentamethylpiperidin-4-yl) 2-butyl-2-[(3,5-ditert-butyl-4-hydroxyphenyl)methyl]propanedioate Chemical compound C1C(C)(C)N(C)C(C)(C)CC1OC(=O)C(C(=O)OC1CC(C)(C)N(C)C(C)(C)C1)(CCCC)CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 FLPKSBDJMLUTEX-UHFFFAOYSA-N 0.000 description 21
- 239000000203 mixture Substances 0.000 description 21
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 18
- 230000000052 comparative effect Effects 0.000 description 17
- 238000000034 method Methods 0.000 description 17
- 238000012360 testing method Methods 0.000 description 17
- 229920006345 thermoplastic polyamide Polymers 0.000 description 13
- 229920010774 Pebax® MV 1074 SA 01 Polymers 0.000 description 12
- 229910021529 ammonia Inorganic materials 0.000 description 12
- 229920011934 Pebax® 6333 SA 01 Polymers 0.000 description 10
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 10
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 10
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 10
- 239000002131 composite material Substances 0.000 description 10
- 230000000694 effects Effects 0.000 description 9
- 238000001816 cooling Methods 0.000 description 8
- 239000012321 sodium triacetoxyborohydride Substances 0.000 description 8
- 238000004332 deodorization Methods 0.000 description 7
- 230000001877 deodorizing effect Effects 0.000 description 7
- 210000004243 sweat Anatomy 0.000 description 7
- 229920002292 Nylon 6 Polymers 0.000 description 6
- 238000009826 distribution Methods 0.000 description 6
- 239000011521 glass Substances 0.000 description 6
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 6
- 239000004677 Nylon Substances 0.000 description 5
- 239000004952 Polyamide Substances 0.000 description 5
- -1 nitrogen oxide compound Chemical class 0.000 description 5
- 229920001778 nylon Polymers 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- AIBRSVLEQRWAEG-UHFFFAOYSA-N 3,9-bis(2,4-ditert-butylphenoxy)-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP1OCC2(COP(OC=3C(=CC(=CC=3)C(C)(C)C)C(C)(C)C)OC2)CO1 AIBRSVLEQRWAEG-UHFFFAOYSA-N 0.000 description 4
- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 description 4
- 229920000299 Nylon 12 Polymers 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 4
- 230000009471 action Effects 0.000 description 4
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 4
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 4
- 230000000704 physical effect Effects 0.000 description 4
- 229920006122 polyamide resin Polymers 0.000 description 4
- 229920006346 thermoplastic polyester elastomer Polymers 0.000 description 4
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 3
- 229920000571 Nylon 11 Polymers 0.000 description 3
- 238000002845 discoloration Methods 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 230000006870 function Effects 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 230000001953 sensory effect Effects 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 2
- 239000004959 Rilsan Substances 0.000 description 2
- 229920003734 UBESTA® Polymers 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 230000036760 body temperature Effects 0.000 description 2
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 230000035597 cooling sensation Effects 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 230000035807 sensation Effects 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- QAEDZJGFFMLHHQ-UHFFFAOYSA-N trifluoroacetic anhydride Chemical compound FC(F)(F)C(=O)OC(=O)C(F)(F)F QAEDZJGFFMLHHQ-UHFFFAOYSA-N 0.000 description 2
- KMOUUZVZFBCRAM-OLQVQODUSA-N (3as,7ar)-3a,4,7,7a-tetrahydro-2-benzofuran-1,3-dione Chemical compound C1C=CC[C@@H]2C(=O)OC(=O)[C@@H]21 KMOUUZVZFBCRAM-OLQVQODUSA-N 0.000 description 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- NOGFHTGYPKWWRX-UHFFFAOYSA-N 2,2,6,6-tetramethyloxan-4-one Chemical compound CC1(C)CC(=O)CC(C)(C)O1 NOGFHTGYPKWWRX-UHFFFAOYSA-N 0.000 description 1
- SPSPIUSUWPLVKD-UHFFFAOYSA-N 2,3-dibutyl-6-methylphenol Chemical compound CCCCC1=CC=C(C)C(O)=C1CCCC SPSPIUSUWPLVKD-UHFFFAOYSA-N 0.000 description 1
- YAGPRJYCDKGWJR-UHFFFAOYSA-N 2-(2,4,8,10-tetratert-butylbenzo[d][1,3,2]benzodioxaphosphepin-6-yl)oxy-n,n-bis[2-(2,4,8,10-tetratert-butylbenzo[d][1,3,2]benzodioxaphosphepin-6-yl)oxyethyl]ethanamine Chemical compound O1C2=C(C(C)(C)C)C=C(C(C)(C)C)C=C2C2=CC(C(C)(C)C)=CC(C(C)(C)C)=C2OP1OCCN(CCOP1OC2=C(C=C(C=C2C=2C=C(C=C(C=2O1)C(C)(C)C)C(C)(C)C)C(C)(C)C)C(C)(C)C)CCOP(OC1=C(C=C(C=C11)C(C)(C)C)C(C)(C)C)OC2=C1C=C(C(C)(C)C)C=C2C(C)(C)C YAGPRJYCDKGWJR-UHFFFAOYSA-N 0.000 description 1
- FALRKNHUBBKYCC-UHFFFAOYSA-N 2-(chloromethyl)pyridine-3-carbonitrile Chemical compound ClCC1=NC=CC=C1C#N FALRKNHUBBKYCC-UHFFFAOYSA-N 0.000 description 1
- MSXXDBCLAKQJQT-UHFFFAOYSA-N 2-tert-butyl-6-methyl-4-[3-(2,4,8,10-tetratert-butylbenzo[d][1,3,2]benzodioxaphosphepin-6-yl)oxypropyl]phenol Chemical compound CC(C)(C)C1=C(O)C(C)=CC(CCCOP2OC3=C(C=C(C=C3C=3C=C(C=C(C=3O2)C(C)(C)C)C(C)(C)C)C(C)(C)C)C(C)(C)C)=C1 MSXXDBCLAKQJQT-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 206010016326 Feeling cold Diseases 0.000 description 1
- 229920003620 Grilon® Polymers 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- FRCLQKLLFQYUJJ-UHFFFAOYSA-N P(O)(O)O.P(O)(O)O.C(C)(C)(C)C1=C(C(=CC(=C1)C)C(C)(C)C)C(O)(C(CO)(CO)CO)C1=C(C=C(C=C1C(C)(C)C)C)C(C)(C)C Chemical compound P(O)(O)O.P(O)(O)O.C(C)(C)(C)C1=C(C(=CC(=C1)C)C(C)(C)C)C(O)(C(CO)(CO)CO)C1=C(C=C(C=C1C(C)(C)C)C)C(C)(C)C FRCLQKLLFQYUJJ-UHFFFAOYSA-N 0.000 description 1
- GIATZHZBSIMOEE-UHFFFAOYSA-N P(O)(O)O.P(O)(O)O.C(C)(C)(C)C1=C(C=CC(=C1)C(C)(C)C)C(O)(C(CO)(CO)CO)C1=C(C=C(C=C1)C(C)(C)C)C(C)(C)C Chemical compound P(O)(O)O.P(O)(O)O.C(C)(C)(C)C1=C(C=CC(=C1)C(C)(C)C)C(O)(C(CO)(CO)CO)C1=C(C=C(C=C1)C(C)(C)C)C(C)(C)C GIATZHZBSIMOEE-UHFFFAOYSA-N 0.000 description 1
- RRFWWSOELBTKEK-UHFFFAOYSA-N P(O)(O)O.P(O)(O)O.C(CCCCCCCCCCCCCCCCC)C(O)(C(CO)(CO)CO)CCCCCCCCCCCCCCCCCC Chemical compound P(O)(O)O.P(O)(O)O.C(CCCCCCCCCCCCCCCCC)C(O)(C(CO)(CO)CO)CCCCCCCCCCCCCCCCCC RRFWWSOELBTKEK-UHFFFAOYSA-N 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- BEIOEBMXPVYLRY-UHFFFAOYSA-N [4-[4-bis(2,4-ditert-butylphenoxy)phosphanylphenyl]phenyl]-bis(2,4-ditert-butylphenoxy)phosphane Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(C=1C=CC(=CC=1)C=1C=CC(=CC=1)P(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C BEIOEBMXPVYLRY-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 125000000732 arylene group Chemical group 0.000 description 1
- 229920005601 base polymer Polymers 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004737 colorimetric analysis Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- VGGRCVDNFAQIKO-UHFFFAOYSA-N formic anhydride Chemical compound O=COC=O VGGRCVDNFAQIKO-UHFFFAOYSA-N 0.000 description 1
- VANNPISTIUFMLH-UHFFFAOYSA-N glutaric anhydride Chemical compound O=C1CCCC(=O)O1 VANNPISTIUFMLH-UHFFFAOYSA-N 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000005338 heat storage Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 239000002530 phenolic antioxidant Substances 0.000 description 1
- 125000004437 phosphorous atom Chemical group 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920006149 polyester-amide block copolymer Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- WYVAMUWZEOHJOQ-UHFFFAOYSA-N propionic anhydride Chemical compound CCC(=O)OC(=O)CC WYVAMUWZEOHJOQ-UHFFFAOYSA-N 0.000 description 1
- VPODXHOUBDCEHN-UHFFFAOYSA-N pyridine-3-carbonyl pyridine-3-carboxylate Chemical compound C=1C=CN=CC=1C(=O)OC(=O)C1=CC=CN=C1 VPODXHOUBDCEHN-UHFFFAOYSA-N 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229940014800 succinic anhydride Drugs 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000035900 sweating Effects 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 1
- LENZDBCJOHFCAS-UHFFFAOYSA-N tris Chemical compound OCC(N)(CO)CO LENZDBCJOHFCAS-UHFFFAOYSA-N 0.000 description 1
- WGKLOLBTFWFKOD-UHFFFAOYSA-N tris(2-nonylphenyl) phosphite Chemical compound CCCCCCCCCC1=CC=CC=C1OP(OC=1C(=CC=CC=1)CCCCCCCCC)OC1=CC=CC=C1CCCCCCCCC WGKLOLBTFWFKOD-UHFFFAOYSA-N 0.000 description 1
- 210000002700 urine Anatomy 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
- 238000004394 yellowing prevention Methods 0.000 description 1
Landscapes
- Artificial Filaments (AREA)
Description
また、特許文献4には、紡糸時に酸性の液状混合物を混合する方法が開示されている。
以下に本発明を詳述する。
本発明の繊維は、熱可塑性エラストマーを含有する。
上記熱可塑性エラストマーを含有する繊維は、着用時に直接肌に接したときにヒヤリとした感覚を惹起し、清涼感を与えることができる。
上記熱可塑性エラストマーは、ポリアミド系エラストマーであることが好ましい。
本発明に用いる酸化チタンとしては、ルチル型酸化チタンが好ましい。
本発明の繊維は、酸性化合物を含有し、上記酸性化合物は、スチレン−無水マレイン酸共重合体、又は、酸無水物である。
本発明では、このような酸性化合物を用いることで、繊維の耐黄変性、耐赤変性を大幅に向上させることができる。
本発明の繊維は、リン系酸化防止剤を含有する。上記リン系酸化防止剤を含有することで、特に耐赤変性を大幅に向上させることができる。
本発明の繊維は、qmax値が0.2J/sec/cm2以上であることが好ましい。
熱伝導率(W/cm/℃)=W・D/A/ΔT (2)
W:熱流量(J/sec)
D:試料の厚さ(cm)
A:熱板面積(cm2)
ΔT:試料台と熱板との温度差(℃)
本発明の繊維を用いてなる生地もまた、本発明の1つである。
本明細書において生地には、編物、織物、不織布等が含まれる。
本発明の繊維、又は本発明の生地を用いてなる肌着もまた、本発明の1つである。
(実施例1)
(実施例2)
(実施例3)
(実施例4)
(実施例5)
(実施例6)
(実施例7)
(実施例8)
(実施例9)
(実施例10)
(実施例11)
得られたコンジュゲート繊維を用いて編み立てを行い、フライス生地を作製した。
(実施例12)
得られたコンジュゲート繊維を用いて編み立てを行い、フライス生地を作製した。
(実施例13)
得られたコンジュゲート繊維を用いて編み立てを行い、フライス生地を作製した。
(実施例14)
得られたコンジュゲート繊維を用いて編み立てを行い、フライス生地を作製した。
(実施例15)
得られたコンジュゲート繊維を用いて編み立てを行い、フライス生地を作製した。
(実施例16)
得られたコンジュゲート繊維を用いて編み立てを行い、フライス生地を作製した。
(比較例1)
(比較例2)
(比較例3)
(比較例4)
(比較例5)
(比較例6)
(比較例7)
(比較例8)
(比較例9)
(比較例10)
(比較例11)
得られたコンジュゲート繊維を用いて編み立てを行い、フライス生地を作製した。
(比較例12)
得られたコンジュゲート繊維を用いて編み立てを行い、フライス生地を作製した。
(比較例13)
得られたコンジュゲート繊維を用いて編み立てを行い、フライス生地を作製した。
(比較例14)
得られたコンジュゲート繊維を用いて編み立てを行い、フライス生地を作製した。
(比較例15)
得られたコンジュゲート繊維を用いて編み立てを行い、フライス生地を作製した。
(比較例16)
得られたコンジュゲート繊維を用いて編み立てを行い、フライス生地を作製した。
(評価)
実施例及び比較例で用いた熱可塑性エラストマー及び得られた生地について、以下の方法により評価を行った。結果を表1〜4に示した。
(1)コートルズ黄変試験
(2)NOx黄変試験
Δb*値=(試験後のb*値)−(試験前のb*値)
(3)ファンヒータ赤変試験
Δa*値=(試験後のa*値)−(試験前のa*値)
(4)汗耐光試験
(5)アンモニア防臭試験
(6)qmax値の測定
Claims (5)
- 熱可塑性エラストマー、酸化チタン、酸性化合物及びリン系酸化防止剤を含有する繊維であって、
前記酸化チタンは、ルチル型酸化チタンであり、
前記酸性化合物は、スチレン−無水マレイン酸共重合体、又は、酸無水物であり、
前記熱可塑性エラストマー100重量部に対して、前記酸化チタン3重量部以上と、前記酸性化合物を0.1重量部以上含有する
ことを特徴とする繊維。 - 熱可塑性エラストマーは、ポリアミド系エラストマーであることを特徴とする請求項1記載の繊維。
- 熱可塑性エラストマーは、ポリエーテルブロックアミド共重合体であることを特徴とする請求項1又は2記載の繊維。
- 請求項1、2又は3記載の繊維を用いてなることを特徴とする生地。
- 請求項1、2又は3記載の繊維又は請求項4記載の生地を用いてなることを特徴とする肌着。
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2009274382A JP4918129B2 (ja) | 2009-12-02 | 2009-12-02 | 繊維、生地及び肌着 |
TW99105391A TW201120261A (en) | 2009-12-02 | 2010-02-25 | Fiber, cloth, and underwear. |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2009274382A JP4918129B2 (ja) | 2009-12-02 | 2009-12-02 | 繊維、生地及び肌着 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2011117092A JP2011117092A (ja) | 2011-06-16 |
JP4918129B2 true JP4918129B2 (ja) | 2012-04-18 |
Family
ID=44282732
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2009274382A Active JP4918129B2 (ja) | 2009-12-02 | 2009-12-02 | 繊維、生地及び肌着 |
Country Status (2)
Country | Link |
---|---|
JP (1) | JP4918129B2 (ja) |
TW (1) | TW201120261A (ja) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5666987B2 (ja) | 2011-05-25 | 2015-02-12 | 株式会社デンソー | 移動物体検出装置 |
CN114015228B (zh) * | 2021-12-07 | 2023-09-19 | 上海彩艳实业有限公司 | 抗光、热黄变聚酰胺母粒及纤维 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH01229810A (ja) * | 1988-03-07 | 1989-09-13 | Kanebo Ltd | 所望のアミノ基量を有するポリアミド繊維の製造方法 |
JPH0616929A (ja) * | 1992-06-30 | 1994-01-25 | Kanebo Ltd | ポリアミド組成物 |
JP3113745B2 (ja) * | 1992-09-21 | 2000-12-04 | 株式会社クラレ | ポリエステル繊維または成形品の製造方法 |
JPH0820680A (ja) * | 1994-07-06 | 1996-01-23 | Dainippon Ink & Chem Inc | 添加剤含有樹脂組成物及びその製造法 |
JPH10130497A (ja) * | 1996-11-01 | 1998-05-19 | Mitsubishi Gas Chem Co Inc | ポリアミド樹脂組成物 |
JP2001002781A (ja) * | 1999-06-16 | 2001-01-09 | Toray Ind Inc | ポリアミドペレットの製造方法、繊維および成形品 |
CN102517773B (zh) * | 2005-04-18 | 2014-02-19 | 郡是株式会社 | 接触冷感优异的衣料和接触冷感优异的汗衫 |
JP5384916B2 (ja) * | 2008-09-30 | 2014-01-08 | グンゼ株式会社 | 繊維、生地及び肌着 |
-
2009
- 2009-12-02 JP JP2009274382A patent/JP4918129B2/ja active Active
-
2010
- 2010-02-25 TW TW99105391A patent/TW201120261A/zh unknown
Also Published As
Publication number | Publication date |
---|---|
TW201120261A (en) | 2011-06-16 |
JP2011117092A (ja) | 2011-06-16 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5384916B2 (ja) | 繊維、生地及び肌着 | |
JP2008507632A (ja) | 湿潤性ポリエステル繊維及び布 | |
JP4918129B2 (ja) | 繊維、生地及び肌着 | |
EP3350361A1 (en) | Polyamide fiber with improved comfort management, process thereof and article made therefrom | |
KR20100127077A (ko) | 내구 흡한속건성 난연 폴리에스테르 섬유 및 그 제조방법 | |
JP2012214919A (ja) | 繊維、生地及び衣料 | |
US20150017439A1 (en) | Bio-based polymer blends and methods of making fibers | |
JP2013163885A (ja) | ポリウレタン弾性繊維およびその製造方法 | |
JP5133546B2 (ja) | 吸放湿性ポリエステル繊維 | |
JP4704197B2 (ja) | ポリエステル繊維 | |
US20180030620A1 (en) | Polyester fiber for artificial hair, process for producing same, and hair ornament product including same | |
JP6296059B2 (ja) | 吸湿性ポリエステル繊維及びその製造方法 | |
EP3767017A1 (en) | Highly hygroscopic sea-island type composite fiber, fiber structure, and polyester composition | |
JP6443127B2 (ja) | 吸放湿性ポリエステル繊維の製造方法 | |
JP4834858B2 (ja) | ポリウレタン糸およびその製造方法 | |
JP2009185401A (ja) | 原着糸の製造方法 | |
JP2012214920A (ja) | 繊維、生地及び衣料 | |
JP2012207318A (ja) | 人工毛髪用ポリエステル繊維およびその製造方法 | |
JP7344273B2 (ja) | 人工毛髪用繊維 | |
JP5663271B2 (ja) | 生地、ストレッチ衣料及び肌着 | |
JP6054623B2 (ja) | ポリエステル複合繊維 | |
JPH11269724A (ja) | 芯鞘型複合繊維および混繊糸 | |
JP2004060129A (ja) | 高吸放湿ポリアミド繊維およびその製造方法 | |
JP2016113732A (ja) | ポリペンタメチレンアジパミド繊維 | |
JP2004238770A (ja) | クリーンルームウェア用耐加水分解性ポリエステル繊維 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20111004 |
|
A871 | Explanation of circumstances concerning accelerated examination |
Free format text: JAPANESE INTERMEDIATE CODE: A871 Effective date: 20111004 |
|
RD02 | Notification of acceptance of power of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7422 Effective date: 20111004 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20120112 |
|
TRDD | Decision of grant or rejection written | ||
A975 | Report on accelerated examination |
Free format text: JAPANESE INTERMEDIATE CODE: A971005 Effective date: 20120117 |
|
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20120124 |
|
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20120127 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20150203 Year of fee payment: 3 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 4918129 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20150203 Year of fee payment: 3 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |