CN114015228B - 抗光、热黄变聚酰胺母粒及纤维 - Google Patents
抗光、热黄变聚酰胺母粒及纤维 Download PDFInfo
- Publication number
- CN114015228B CN114015228B CN202111482845.5A CN202111482845A CN114015228B CN 114015228 B CN114015228 B CN 114015228B CN 202111482845 A CN202111482845 A CN 202111482845A CN 114015228 B CN114015228 B CN 114015228B
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- polyamide
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- master batch
- fiber
- light
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000004952 Polyamide Substances 0.000 title claims abstract description 83
- 229920002647 polyamide Polymers 0.000 title claims abstract description 83
- 239000000835 fiber Substances 0.000 title claims abstract description 72
- 239000004594 Masterbatch (MB) Substances 0.000 title claims abstract description 71
- 238000004383 yellowing Methods 0.000 title claims abstract description 49
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 42
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 27
- 239000012792 core layer Substances 0.000 claims abstract description 15
- 238000002360 preparation method Methods 0.000 claims abstract description 10
- 238000009987 spinning Methods 0.000 claims abstract description 6
- 239000000306 component Substances 0.000 claims description 46
- 230000003078 antioxidant effect Effects 0.000 claims description 35
- 239000004611 light stabiliser Substances 0.000 claims description 32
- 239000006097 ultraviolet radiation absorber Substances 0.000 claims description 29
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 16
- 239000000314 lubricant Substances 0.000 claims description 13
- 229940124543 ultraviolet light absorber Drugs 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 12
- 230000009471 action Effects 0.000 claims description 9
- 239000010410 layer Substances 0.000 claims description 9
- 150000001412 amines Chemical class 0.000 claims description 7
- 238000010008 shearing Methods 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- 230000002209 hydrophobic effect Effects 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 229920002292 Nylon 6 Polymers 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 5
- 239000000377 silicon dioxide Substances 0.000 claims description 5
- 229920002302 Nylon 6,6 Polymers 0.000 claims description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 3
- 238000009998 heat setting Methods 0.000 claims description 3
- 238000004804 winding Methods 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 2
- 239000008358 core component Substances 0.000 claims description 2
- BSZXAFXFTLXUFV-UHFFFAOYSA-N 1-phenylethylbenzene Chemical group C=1C=CC=CC=1C(C)C1=CC=CC=C1 BSZXAFXFTLXUFV-UHFFFAOYSA-N 0.000 claims 1
- 238000007664 blowing Methods 0.000 claims 1
- 239000002131 composite material Substances 0.000 claims 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims 1
- 239000000654 additive Substances 0.000 abstract description 17
- 230000000996 additive effect Effects 0.000 abstract description 8
- 238000012216 screening Methods 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 5
- 238000006243 chemical reaction Methods 0.000 abstract description 2
- 238000011031 large-scale manufacturing process Methods 0.000 abstract description 2
- 230000002195 synergetic effect Effects 0.000 abstract description 2
- 238000009792 diffusion process Methods 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- 239000002250 absorbent Substances 0.000 description 4
- 230000002745 absorbent Effects 0.000 description 4
- 238000001914 filtration Methods 0.000 description 4
- 229910021485 fumed silica Inorganic materials 0.000 description 4
- 239000004753 textile Substances 0.000 description 4
- 230000006750 UV protection Effects 0.000 description 3
- 239000006096 absorbing agent Substances 0.000 description 3
- 238000006731 degradation reaction Methods 0.000 description 3
- 230000004907 flux Effects 0.000 description 3
- 230000005012 migration Effects 0.000 description 3
- 238000013508 migration Methods 0.000 description 3
- 238000010525 oxidative degradation reaction Methods 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 235000012239 silicon dioxide Nutrition 0.000 description 3
- VETPHHXZEJAYOB-UHFFFAOYSA-N 1-n,4-n-dinaphthalen-2-ylbenzene-1,4-diamine Chemical compound C1=CC=CC2=CC(NC=3C=CC(NC=4C=C5C=CC=CC5=CC=4)=CC=3)=CC=C21 VETPHHXZEJAYOB-UHFFFAOYSA-N 0.000 description 2
- 239000004262 Ethyl gallate Substances 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 230000002401 inhibitory effect Effects 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 229920002994 synthetic fiber Polymers 0.000 description 2
- 239000012209 synthetic fiber Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 238000005303 weighing Methods 0.000 description 2
- 229910002012 Aerosil® Inorganic materials 0.000 description 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 150000001408 amides Chemical group 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000010044 bi-component spinning Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 125000006297 carbonyl amino group Chemical group [H]N([*:2])C([*:1])=O 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000013538 functional additive Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 150000002605 large molecules Chemical class 0.000 description 1
- 230000031700 light absorption Effects 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000010128 melt processing Methods 0.000 description 1
- 238000002074 melt spinning Methods 0.000 description 1
- FTWUXYZHDFCGSV-UHFFFAOYSA-N n,n'-diphenyloxamide Chemical compound C=1C=CC=CC=1NC(=O)C(=O)NC1=CC=CC=C1 FTWUXYZHDFCGSV-UHFFFAOYSA-N 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 150000008301 phosphite esters Chemical class 0.000 description 1
- 238000001782 photodegradation Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920005594 polymer fiber Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000004224 protection Effects 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
- C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/28—Formation of filaments, threads, or the like while mixing different spinning solutions or melts during the spinning operation; Spinnerette packs therefor
- D01D5/30—Conjugate filaments; Spinnerette packs therefor
- D01D5/34—Core-skin structure; Spinnerette packs therefor
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
- D01F1/106—Radiation shielding agents, e.g. absorbing, reflecting agents
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/12—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyamide as constituent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2377/00—Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2477/00—Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Artificial Filaments (AREA)
Abstract
Description
Claims (4)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202111482845.5A CN114015228B (zh) | 2021-12-07 | 2021-12-07 | 抗光、热黄变聚酰胺母粒及纤维 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202111482845.5A CN114015228B (zh) | 2021-12-07 | 2021-12-07 | 抗光、热黄变聚酰胺母粒及纤维 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN114015228A CN114015228A (zh) | 2022-02-08 |
CN114015228B true CN114015228B (zh) | 2023-09-19 |
Family
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Family Applications (1)
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CN202111482845.5A Active CN114015228B (zh) | 2021-12-07 | 2021-12-07 | 抗光、热黄变聚酰胺母粒及纤维 |
Country Status (1)
Country | Link |
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CN (1) | CN114015228B (zh) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN115652466B (zh) * | 2022-12-12 | 2023-03-31 | 烟台新秀新材料有限公司 | 用于聚酰胺材料的协同复配酰胺化光稳定剂 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2005226176A (ja) * | 2004-02-10 | 2005-08-25 | Toray Ind Inc | 光触媒機能を有するポリアミド繊維およびその製造方法 |
JP2011117092A (ja) * | 2009-12-02 | 2011-06-16 | Gunze Ltd | 繊維、生地及び肌着 |
CN103409843A (zh) * | 2013-09-02 | 2013-11-27 | 江苏红豆实业股份有限公司 | 具有抗紫外线功能的锦纶纤维的制备方法 |
CN109852014A (zh) * | 2019-01-11 | 2019-06-07 | 深圳市金志成塑胶科技有限公司 | 一种bopet抗uv母粒材料及其制备工艺 |
CN111621147A (zh) * | 2019-02-28 | 2020-09-04 | 艾曼斯(苏州)工程塑料有限公司 | 聚酰胺组合物及其制备方法和应用 |
CN113444267A (zh) * | 2021-07-20 | 2021-09-28 | 佛山市塑派科技有限公司 | 一种功能纤维母粒及其制备方法和功能纤维 |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10428189B2 (en) * | 2014-07-18 | 2019-10-01 | Chroma Color Corporation | Process and composition for well dispersed, highly loaded color masterbatch |
-
2021
- 2021-12-07 CN CN202111482845.5A patent/CN114015228B/zh active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2005226176A (ja) * | 2004-02-10 | 2005-08-25 | Toray Ind Inc | 光触媒機能を有するポリアミド繊維およびその製造方法 |
JP2011117092A (ja) * | 2009-12-02 | 2011-06-16 | Gunze Ltd | 繊維、生地及び肌着 |
CN103409843A (zh) * | 2013-09-02 | 2013-11-27 | 江苏红豆实业股份有限公司 | 具有抗紫外线功能的锦纶纤维的制备方法 |
CN109852014A (zh) * | 2019-01-11 | 2019-06-07 | 深圳市金志成塑胶科技有限公司 | 一种bopet抗uv母粒材料及其制备工艺 |
CN111621147A (zh) * | 2019-02-28 | 2020-09-04 | 艾曼斯(苏州)工程塑料有限公司 | 聚酰胺组合物及其制备方法和应用 |
CN113444267A (zh) * | 2021-07-20 | 2021-09-28 | 佛山市塑派科技有限公司 | 一种功能纤维母粒及其制备方法和功能纤维 |
Non-Patent Citations (2)
Title |
---|
刘吉平等.《纺织科学中的纳米技术》.中国纺织出版社,2003,(2003年5月第1版),187-190. * |
赵万金等."受阻胺抗氧剂对PA6工业丝热氧老化性能的影响".《合成纤维工业》.2011,第34卷(第1期),1-4. * |
Also Published As
Publication number | Publication date |
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CN114015228A (zh) | 2022-02-08 |
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Effective date of registration: 20240204 Address after: 201500 Building 2, No. 11, Wangwei West Road, Fengjing town, Jinshan District, Shanghai Patentee after: SHANGHAI CAIYAN INDUSTRY Co.,Ltd. Country or region after: China Address before: 201500 Building 2, No. 11, Wangwei West Road, Fengjing town, Jinshan District, Shanghai Patentee before: SHANGHAI CAIYAN INDUSTRY Co.,Ltd. Country or region before: China Patentee before: JIAXING University |
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