JP4768619B2 - マイクロチャネル技術を用いる酸化方法およびそのために有用な新規触媒 - Google Patents
マイクロチャネル技術を用いる酸化方法およびそのために有用な新規触媒 Download PDFInfo
- Publication number
- JP4768619B2 JP4768619B2 JP2006532382A JP2006532382A JP4768619B2 JP 4768619 B2 JP4768619 B2 JP 4768619B2 JP 2006532382 A JP2006532382 A JP 2006532382A JP 2006532382 A JP2006532382 A JP 2006532382A JP 4768619 B2 JP4768619 B2 JP 4768619B2
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- fin
- heat exchange
- process microchannel
- microchannel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000000034 method Methods 0.000 title claims abstract description 199
- 239000003054 catalyst Substances 0.000 title claims abstract description 165
- 230000008569 process Effects 0.000 title claims abstract description 105
- 238000007254 oxidation reaction Methods 0.000 title claims description 59
- 230000003647 oxidation Effects 0.000 title claims description 48
- 238000005516 engineering process Methods 0.000 title description 2
- 239000000203 mixture Substances 0.000 claims description 107
- 238000006243 chemical reaction Methods 0.000 claims description 88
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical group C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 79
- 150000002430 hydrocarbons Chemical class 0.000 claims description 67
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 65
- 239000000047 product Substances 0.000 claims description 60
- 229930195733 hydrocarbon Natural products 0.000 claims description 58
- 239000010948 rhodium Substances 0.000 claims description 57
- 239000004215 Carbon black (E152) Substances 0.000 claims description 54
- 239000000376 reactant Substances 0.000 claims description 52
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 51
- 238000002485 combustion reaction Methods 0.000 claims description 51
- 239000001301 oxygen Substances 0.000 claims description 51
- 229910052760 oxygen Inorganic materials 0.000 claims description 51
- 125000004432 carbon atom Chemical group C* 0.000 claims description 48
- 239000012530 fluid Substances 0.000 claims description 45
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 36
- 229910052703 rhodium Inorganic materials 0.000 claims description 36
- 239000007789 gas Substances 0.000 claims description 30
- 229910052759 nickel Inorganic materials 0.000 claims description 26
- 239000002002 slurry Substances 0.000 claims description 26
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 25
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 23
- 239000000463 material Substances 0.000 claims description 21
- 239000011651 chromium Substances 0.000 claims description 20
- 229910052751 metal Inorganic materials 0.000 claims description 20
- 239000002184 metal Substances 0.000 claims description 20
- 229910052697 platinum Inorganic materials 0.000 claims description 19
- 229910052804 chromium Inorganic materials 0.000 claims description 17
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 16
- 229920000642 polymer Polymers 0.000 claims description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
- 229910045601 alloy Inorganic materials 0.000 claims description 15
- 239000000956 alloy Substances 0.000 claims description 15
- 229910052746 lanthanum Inorganic materials 0.000 claims description 15
- 239000003921 oil Substances 0.000 claims description 15
- KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium Substances [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 15
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 14
- 238000000576 coating method Methods 0.000 claims description 14
- 239000007788 liquid Substances 0.000 claims description 14
- -1 ethylene, propylene, butane Chemical group 0.000 claims description 13
- 229910052763 palladium Inorganic materials 0.000 claims description 13
- 239000006260 foam Substances 0.000 claims description 12
- 229910052739 hydrogen Inorganic materials 0.000 claims description 12
- 229910052742 iron Inorganic materials 0.000 claims description 12
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims description 12
- 229910052707 ruthenium Inorganic materials 0.000 claims description 12
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 11
- 238000010304 firing Methods 0.000 claims description 11
- 239000011148 porous material Substances 0.000 claims description 11
- 229910052782 aluminium Inorganic materials 0.000 claims description 10
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 10
- 239000000919 ceramic Substances 0.000 claims description 10
- 239000011248 coating agent Substances 0.000 claims description 10
- 229910052749 magnesium Inorganic materials 0.000 claims description 10
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 9
- 239000001569 carbon dioxide Substances 0.000 claims description 9
- 229910000831 Steel Inorganic materials 0.000 claims description 8
- 150000007824 aliphatic compounds Chemical class 0.000 claims description 8
- 229910052791 calcium Inorganic materials 0.000 claims description 8
- 239000002131 composite material Substances 0.000 claims description 8
- 229910052802 copper Inorganic materials 0.000 claims description 8
- 239000010949 copper Substances 0.000 claims description 8
- 239000010959 steel Substances 0.000 claims description 8
- 229910001369 Brass Inorganic materials 0.000 claims description 7
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 7
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 7
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 7
- 150000001491 aromatic compounds Chemical class 0.000 claims description 7
- 229910052788 barium Inorganic materials 0.000 claims description 7
- 239000010951 brass Substances 0.000 claims description 7
- 239000011152 fibreglass Substances 0.000 claims description 7
- 239000011521 glass Substances 0.000 claims description 7
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 7
- 229910052757 nitrogen Inorganic materials 0.000 claims description 7
- 239000010453 quartz Substances 0.000 claims description 7
- 229910052710 silicon Inorganic materials 0.000 claims description 7
- 239000010703 silicon Substances 0.000 claims description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 7
- 239000007787 solid Substances 0.000 claims description 7
- 239000003381 stabilizer Substances 0.000 claims description 7
- 229910052719 titanium Inorganic materials 0.000 claims description 7
- 239000010936 titanium Substances 0.000 claims description 7
- 229910052726 zirconium Inorganic materials 0.000 claims description 7
- 229910052684 Cerium Inorganic materials 0.000 claims description 6
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 6
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 claims description 6
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims description 6
- 229910002651 NO3 Inorganic materials 0.000 claims description 6
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 6
- 229910052771 Terbium Inorganic materials 0.000 claims description 6
- 125000002947 alkylene group Chemical group 0.000 claims description 6
- 230000008859 change Effects 0.000 claims description 6
- 229910001026 inconel Inorganic materials 0.000 claims description 6
- 150000002739 metals Chemical class 0.000 claims description 6
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 claims description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 5
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical group CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 5
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims description 5
- 239000000835 fiber Substances 0.000 claims description 5
- 239000001257 hydrogen Substances 0.000 claims description 5
- 239000000758 substrate Substances 0.000 claims description 5
- BFIMMTCNYPIMRN-UHFFFAOYSA-N 1,2,3,5-tetramethylbenzene Chemical compound CC1=CC(C)=C(C)C(C)=C1 BFIMMTCNYPIMRN-UHFFFAOYSA-N 0.000 claims description 4
- GWHJZXXIDMPWGX-UHFFFAOYSA-N 1,2,4-trimethylbenzene Chemical compound CC1=CC=C(C)C(C)=C1 GWHJZXXIDMPWGX-UHFFFAOYSA-N 0.000 claims description 4
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N 1-Heptene Chemical compound CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 claims description 4
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 claims description 4
- JRZJOMJEPLMPRA-UHFFFAOYSA-N 1-nonene Chemical compound CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 4
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 claims description 4
- WGLLSSPDPJPLOR-UHFFFAOYSA-N 2,3-dimethylbut-2-ene Chemical compound CC(C)=C(C)C WGLLSSPDPJPLOR-UHFFFAOYSA-N 0.000 claims description 4
- SDJHPPZKZZWAKF-UHFFFAOYSA-N 2,3-dimethylbuta-1,3-diene Chemical compound CC(=C)C(C)=C SDJHPPZKZZWAKF-UHFFFAOYSA-N 0.000 claims description 4
- BKOOMYPCSUNDGP-UHFFFAOYSA-N 2-methylbut-2-ene Chemical compound CC=C(C)C BKOOMYPCSUNDGP-UHFFFAOYSA-N 0.000 claims description 4
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 4
- 229910000792 Monel Inorganic materials 0.000 claims description 4
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 claims description 4
- URLKBWYHVLBVBO-UHFFFAOYSA-N Para-Xylene Chemical group CC1=CC=C(C)C=C1 URLKBWYHVLBVBO-UHFFFAOYSA-N 0.000 claims description 4
- 229910052777 Praseodymium Inorganic materials 0.000 claims description 4
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- IAQRGUVFOMOMEM-UHFFFAOYSA-N but-2-ene Chemical compound CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 claims description 4
- OCKPCBLVNKHBMX-UHFFFAOYSA-N butylbenzene Chemical compound CCCCC1=CC=CC=C1 OCKPCBLVNKHBMX-UHFFFAOYSA-N 0.000 claims description 4
- 238000001246 colloidal dispersion Methods 0.000 claims description 4
- RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 claims description 4
- SQNZJJAZBFDUTD-UHFFFAOYSA-N durene Chemical compound CC1=CC(C)=C(C)C=C1C SQNZJJAZBFDUTD-UHFFFAOYSA-N 0.000 claims description 4
- 239000011261 inert gas Substances 0.000 claims description 4
- 239000013067 intermediate product Substances 0.000 claims description 4
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 claims description 4
- IVSZLXZYQVIEFR-UHFFFAOYSA-N m-xylene Chemical group CC1=CC=CC(C)=C1 IVSZLXZYQVIEFR-UHFFFAOYSA-N 0.000 claims description 4
- BKIMMITUMNQMOS-UHFFFAOYSA-N nonane Chemical compound CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 claims description 4
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims description 4
- HFPZCAJZSCWRBC-UHFFFAOYSA-N p-cymene Chemical compound CC(C)C1=CC=C(C)C=C1 HFPZCAJZSCWRBC-UHFFFAOYSA-N 0.000 claims description 4
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 claims description 4
- QMMOXUPEWRXHJS-UHFFFAOYSA-N pentene-2 Natural products CCC=CC QMMOXUPEWRXHJS-UHFFFAOYSA-N 0.000 claims description 4
- ODLMAHJVESYWTB-UHFFFAOYSA-N propylbenzene Chemical compound CCCC1=CC=CC=C1 ODLMAHJVESYWTB-UHFFFAOYSA-N 0.000 claims description 4
- YTZKOQUCBOVLHL-UHFFFAOYSA-N tert-butylbenzene Chemical compound CC(C)(C)C1=CC=CC=C1 YTZKOQUCBOVLHL-UHFFFAOYSA-N 0.000 claims description 4
- 229910017414 LaAl Inorganic materials 0.000 claims description 3
- 150000001336 alkenes Chemical class 0.000 claims description 3
- 239000001307 helium Substances 0.000 claims description 3
- 229910052734 helium Inorganic materials 0.000 claims description 3
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 claims description 3
- 229910052741 iridium Inorganic materials 0.000 claims description 3
- 229910052762 osmium Inorganic materials 0.000 claims description 3
- 150000004291 polyenes Chemical class 0.000 claims description 3
- 229910052727 yttrium Inorganic materials 0.000 claims description 3
- APPOKADJQUIAHP-GGWOSOGESA-N (2e,4e)-hexa-2,4-diene Chemical compound C\C=C\C=C\C APPOKADJQUIAHP-GGWOSOGESA-N 0.000 claims description 2
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical compound C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 claims description 2
- PRBHEGAFLDMLAL-UHFFFAOYSA-N 1,5-Hexadiene Natural products CC=CCC=C PRBHEGAFLDMLAL-UHFFFAOYSA-N 0.000 claims description 2
- YHQXBTXEYZIYOV-UHFFFAOYSA-N 3-methylbut-1-ene Chemical compound CC(C)C=C YHQXBTXEYZIYOV-UHFFFAOYSA-N 0.000 claims description 2
- 235000004977 Brassica sinapistrum Nutrition 0.000 claims description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical group O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 2
- 241000196324 Embryophyta Species 0.000 claims description 2
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims description 2
- IYABWNGZIDDRAK-UHFFFAOYSA-N allene Chemical compound C=C=C IYABWNGZIDDRAK-UHFFFAOYSA-N 0.000 claims description 2
- 150000004645 aluminates Chemical class 0.000 claims description 2
- 238000001354 calcination Methods 0.000 claims description 2
- 239000003245 coal Substances 0.000 claims description 2
- DIOQZVSQGTUSAI-NJFSPNSNSA-N decane Chemical compound CCCCCCCCC[14CH3] DIOQZVSQGTUSAI-NJFSPNSNSA-N 0.000 claims description 2
- 239000002283 diesel fuel Substances 0.000 claims description 2
- XNMQEEKYCVKGBD-UHFFFAOYSA-N dimethylacetylene Natural products CC#CC XNMQEEKYCVKGBD-UHFFFAOYSA-N 0.000 claims description 2
- 229910001882 dioxygen Inorganic materials 0.000 claims description 2
- 239000012467 final product Substances 0.000 claims description 2
- 239000000295 fuel oil Substances 0.000 claims description 2
- 239000003502 gasoline Substances 0.000 claims description 2
- PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical compound C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 claims description 2
- YUWFEBAXEOLKSG-UHFFFAOYSA-N hexamethylbenzene Chemical compound CC1=C(C)C(C)=C(C)C(C)=C1C YUWFEBAXEOLKSG-UHFFFAOYSA-N 0.000 claims description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 2
- 239000001282 iso-butane Substances 0.000 claims description 2
- KXUHSQYYJYAXGZ-UHFFFAOYSA-N isobutylbenzene Chemical compound CC(C)CC1=CC=CC=C1 KXUHSQYYJYAXGZ-UHFFFAOYSA-N 0.000 claims description 2
- 229910052748 manganese Inorganic materials 0.000 claims description 2
- 239000011572 manganese Substances 0.000 claims description 2
- AUHZEENZYGFFBQ-UHFFFAOYSA-N mesitylene Substances CC1=CC(C)=CC(C)=C1 AUHZEENZYGFFBQ-UHFFFAOYSA-N 0.000 claims description 2
- 125000001827 mesitylenyl group Chemical group [H]C1=C(C(*)=C(C([H])=C1C([H])([H])[H])C([H])([H])[H])C([H])([H])[H] 0.000 claims description 2
- 229910001092 metal group alloy Inorganic materials 0.000 claims description 2
- 239000011707 mineral Substances 0.000 claims description 2
- DIOQZVSQGTUSAI-UHFFFAOYSA-N n-butylhexane Natural products CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 claims description 2
- 229910000510 noble metal Inorganic materials 0.000 claims description 2
- 229940078552 o-xylene Drugs 0.000 claims description 2
- QYZLKGVUSQXAMU-UHFFFAOYSA-N penta-1,4-diene Chemical compound C=CCC=C QYZLKGVUSQXAMU-UHFFFAOYSA-N 0.000 claims description 2
- BEZDDPMMPIDMGJ-UHFFFAOYSA-N pentamethylbenzene Chemical compound CC1=CC(C)=C(C)C(C)=C1C BEZDDPMMPIDMGJ-UHFFFAOYSA-N 0.000 claims description 2
- 150000002978 peroxides Chemical class 0.000 claims description 2
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- ZJMWRROPUADPEA-UHFFFAOYSA-N sec-butylbenzene Chemical compound CCC(C)C1=CC=CC=C1 ZJMWRROPUADPEA-UHFFFAOYSA-N 0.000 claims description 2
- 239000011275 tar sand Substances 0.000 claims description 2
- 239000003570 air Substances 0.000 claims 3
- 239000003426 co-catalyst Substances 0.000 claims 2
- 239000000243 solution Substances 0.000 claims 2
- 241001133760 Acoelorraphe Species 0.000 claims 1
- 240000002791 Brassica napus Species 0.000 claims 1
- 244000068988 Glycine max Species 0.000 claims 1
- 235000010469 Glycine max Nutrition 0.000 claims 1
- 230000000712 assembly Effects 0.000 claims 1
- 238000000429 assembly Methods 0.000 claims 1
- 239000007809 chemical reaction catalyst Substances 0.000 claims 1
- 239000007795 chemical reaction product Substances 0.000 claims 1
- 239000012895 dilution Substances 0.000 claims 1
- 238000010790 dilution Methods 0.000 claims 1
- 239000003350 kerosene Substances 0.000 claims 1
- 239000003345 natural gas Substances 0.000 claims 1
- 238000007740 vapor deposition Methods 0.000 claims 1
- 238000001179 sorption measurement Methods 0.000 abstract 1
- 239000008188 pellet Substances 0.000 description 36
- 238000001816 cooling Methods 0.000 description 31
- 238000010438 heat treatment Methods 0.000 description 24
- 238000001035 drying Methods 0.000 description 16
- 238000011068 loading method Methods 0.000 description 14
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 12
- 235000019198 oils Nutrition 0.000 description 12
- 238000000527 sonication Methods 0.000 description 12
- 238000007598 dipping method Methods 0.000 description 11
- 239000000446 fuel Substances 0.000 description 11
- 239000000843 powder Substances 0.000 description 11
- 229910021193 La 2 O 3 Inorganic materials 0.000 description 10
- 229910052799 carbon Inorganic materials 0.000 description 10
- 238000003756 stirring Methods 0.000 description 10
- 230000008901 benefit Effects 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- 238000012546 transfer Methods 0.000 description 8
- 229910002543 FeCrAlY Inorganic materials 0.000 description 7
- 230000003197 catalytic effect Effects 0.000 description 7
- 239000011777 magnesium Substances 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 6
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- 239000008367 deionised water Substances 0.000 description 6
- 229910021641 deionized water Inorganic materials 0.000 description 6
- 230000006870 function Effects 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- 229910010413 TiO 2 Inorganic materials 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 239000011575 calcium Substances 0.000 description 5
- 238000010586 diagram Methods 0.000 description 5
- 239000003085 diluting agent Substances 0.000 description 5
- 230000001965 increasing effect Effects 0.000 description 5
- 238000000746 purification Methods 0.000 description 5
- 238000011084 recovery Methods 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 4
- 230000002378 acidificating effect Effects 0.000 description 4
- 239000011324 bead Substances 0.000 description 4
- 239000006227 byproduct Substances 0.000 description 4
- 230000017525 heat dissipation Effects 0.000 description 4
- 238000005470 impregnation Methods 0.000 description 4
- 229910044991 metal oxide Inorganic materials 0.000 description 4
- 150000004706 metal oxides Chemical class 0.000 description 4
- 229910017604 nitric acid Inorganic materials 0.000 description 4
- 239000011253 protective coating Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 229920001187 thermosetting polymer Polymers 0.000 description 4
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 3
- 229910002422 La(NO3)3·6H2O Inorganic materials 0.000 description 3
- 229910004298 SiO 2 Inorganic materials 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 230000004907 flux Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 3
- 238000006213 oxygenation reaction Methods 0.000 description 3
- 239000001294 propane Substances 0.000 description 3
- 229910002076 stabilized zirconia Inorganic materials 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- 229910000975 Carbon steel Inorganic materials 0.000 description 2
- 229910004631 Ce(NO3)3.6H2O Inorganic materials 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- GEIAQOFPUVMAGM-UHFFFAOYSA-N ZrO Inorganic materials [Zr]=O GEIAQOFPUVMAGM-UHFFFAOYSA-N 0.000 description 2
- 150000001334 alicyclic compounds Chemical class 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 125000006267 biphenyl group Chemical group 0.000 description 2
- 239000010962 carbon steel Substances 0.000 description 2
- 239000000109 continuous material Substances 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- IIEWJVIFRVWJOD-UHFFFAOYSA-N ethylcyclohexane Chemical compound CCC1CCCCC1 IIEWJVIFRVWJOD-UHFFFAOYSA-N 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 150000001247 metal acetylides Chemical class 0.000 description 2
- 239000006262 metallic foam Substances 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 150000004767 nitrides Chemical class 0.000 description 2
- 150000002825 nitriles Chemical class 0.000 description 2
- 238000000197 pyrolysis Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 229910052596 spinel Inorganic materials 0.000 description 2
- 239000011029 spinel Substances 0.000 description 2
- 230000001052 transient effect Effects 0.000 description 2
- WOZZOSDBXABUFO-UHFFFAOYSA-N tri(butan-2-yloxy)alumane Chemical compound [Al+3].CCC(C)[O-].CCC(C)[O-].CCC(C)[O-] WOZZOSDBXABUFO-UHFFFAOYSA-N 0.000 description 2
- MHCVCKDNQYMGEX-UHFFFAOYSA-N 1,1'-biphenyl;phenoxybenzene Chemical compound C1=CC=CC=C1C1=CC=CC=C1.C=1C=CC=CC=1OC1=CC=CC=C1 MHCVCKDNQYMGEX-UHFFFAOYSA-N 0.000 description 1
- 244000188595 Brassica sinapistrum Species 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 1
- 239000005751 Copper oxide Substances 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229910020068 MgAl Inorganic materials 0.000 description 1
- 229910002645 Ni-Rh Inorganic materials 0.000 description 1
- 229910018487 Ni—Cr Inorganic materials 0.000 description 1
- 206010070834 Sensitisation Diseases 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001361 allenes Chemical class 0.000 description 1
- JNDMLEXHDPKVFC-UHFFFAOYSA-N aluminum;oxygen(2-);yttrium(3+) Chemical compound [O-2].[O-2].[O-2].[Al+3].[Y+3] JNDMLEXHDPKVFC-UHFFFAOYSA-N 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- 229910002090 carbon oxide Inorganic materials 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 238000003889 chemical engineering Methods 0.000 description 1
- 238000005229 chemical vapour deposition Methods 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- 229910000428 cobalt oxide Inorganic materials 0.000 description 1
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 1
- 229910000431 copper oxide Inorganic materials 0.000 description 1
- 229910052878 cordierite Inorganic materials 0.000 description 1
- 150000001924 cycloalkanes Chemical class 0.000 description 1
- 125000002993 cycloalkylene group Chemical group 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 238000006356 dehydrogenation reaction Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical compound [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000006266 etherification reaction Methods 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 229910001701 hydrotalcite Inorganic materials 0.000 description 1
- 229960001545 hydrotalcite Drugs 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical group [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- 239000010699 lard oil Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 239000012982 microporous membrane Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 229910000476 molybdenum oxide Inorganic materials 0.000 description 1
- 125000002950 monocyclic group Chemical group 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 229910000480 nickel oxide Inorganic materials 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- QGLKJKCYBOYXKC-UHFFFAOYSA-N nonaoxidotritungsten Chemical compound O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1 QGLKJKCYBOYXKC-UHFFFAOYSA-N 0.000 description 1
- 239000010742 number 1 fuel oil Substances 0.000 description 1
- 238000005839 oxidative dehydrogenation reaction Methods 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 description 1
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 238000005240 physical vapour deposition Methods 0.000 description 1
- 229920013639 polyalphaolefin Polymers 0.000 description 1
- 125000003367 polycyclic group Chemical group 0.000 description 1
- 229920006389 polyphenyl polymer Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 230000008313 sensitization Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000003079 shale oil Substances 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 238000007581 slurry coating method Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 150000005671 trienes Chemical class 0.000 description 1
- 229910001930 tungsten oxide Inorganic materials 0.000 description 1
- 229910001935 vanadium oxide Inorganic materials 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 229910019901 yttrium aluminum garnet Inorganic materials 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 229910000166 zirconium phosphate Inorganic materials 0.000 description 1
- LEHFSLREWWMLPU-UHFFFAOYSA-B zirconium(4+);tetraphosphate Chemical compound [Zr+4].[Zr+4].[Zr+4].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LEHFSLREWWMLPU-UHFFFAOYSA-B 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/386—Catalytic partial combustion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/0407—Constructional details of adsorbing systems
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/0407—Constructional details of adsorbing systems
- B01D53/0446—Means for feeding or distributing gases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/0093—Microreactors, e.g. miniaturised or microfabricated reactors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/63—Platinum group metals with rare earths or actinides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0215—Coating
- B01J37/0225—Coating of metal substrates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/024—Multiple impregnation or coating
- B01J37/0244—Coatings comprising several layers
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/384—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts the catalyst being continuously externally heated
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/45—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by condensation
- C07C45/46—Friedel-Crafts reactions
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F3/00—Plate-like or laminated elements; Assemblies of plate-like or laminated elements
- F28F3/02—Elements or assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with recesses, with corrugations
- F28F3/04—Elements or assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with recesses, with corrugations the means being integral with the element
- F28F3/048—Elements or assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with recesses, with corrugations the means being integral with the element in the form of ribs integral with the element or local variations in thickness of the element, e.g. grooves, microchannels
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/112—Metals or metal compounds not provided for in B01D2253/104 or B01D2253/106
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/25—Coated, impregnated or composite adsorbents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/30—Physical properties of adsorbents
- B01D2253/302—Dimensions
- B01D2253/306—Surface area, e.g. BET-specific surface
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/30—Physical properties of adsorbents
- B01D2253/34—Specific shapes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00781—Aspects relating to microreactors
- B01J2219/00819—Materials of construction
- B01J2219/00822—Metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00781—Aspects relating to microreactors
- B01J2219/00819—Materials of construction
- B01J2219/00831—Glass
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00781—Aspects relating to microreactors
- B01J2219/00819—Materials of construction
- B01J2219/00833—Plastic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00781—Aspects relating to microreactors
- B01J2219/00819—Materials of construction
- B01J2219/00835—Comprising catalytically active material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00781—Aspects relating to microreactors
- B01J2219/00851—Additional features
- B01J2219/00858—Aspects relating to the size of the reactor
- B01J2219/00862—Dimensions of the reaction cavity itself
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00781—Aspects relating to microreactors
- B01J2219/00873—Heat exchange
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00781—Aspects relating to microreactors
- B01J2219/00889—Mixing
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
- C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
- C01B2203/0261—Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a catalytic partial oxidation step [CPO]
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/08—Methods of heating or cooling
- C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
- C01B2203/0838—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel
- C01B2203/0844—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel the non-combustive exothermic reaction being another reforming reaction as defined in groups C01B2203/02 - C01B2203/0294
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/08—Methods of heating or cooling
- C01B2203/0872—Methods of cooling
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/08—Methods of heating or cooling
- C01B2203/0872—Methods of cooling
- C01B2203/0883—Methods of cooling by indirect heat exchange
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/08—Methods of heating or cooling
- C01B2203/0872—Methods of cooling
- C01B2203/0888—Methods of cooling by evaporation of a fluid
- C01B2203/0894—Generation of steam
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1005—Arrangement or shape of catalyst
- C01B2203/1011—Packed bed of catalytic structures, e.g. particles, packing elements
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1005—Arrangement or shape of catalyst
- C01B2203/1023—Catalysts in the form of a monolith or honeycomb
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1005—Arrangement or shape of catalyst
- C01B2203/1029—Catalysts in the form of a foam
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1005—Arrangement or shape of catalyst
- C01B2203/1035—Catalyst coated on equipment surfaces, e.g. reactor walls
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1047—Group VIII metal catalysts
- C01B2203/1052—Nickel or cobalt catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1047—Group VIII metal catalysts
- C01B2203/1064—Platinum group metal catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1082—Composition of support materials
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1094—Promotors or activators
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
- C01B2203/1235—Hydrocarbons
- C01B2203/1241—Natural gas or methane
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
- C01B2203/1235—Hydrocarbons
- C01B2203/1247—Higher hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/141—At least two reforming, decomposition or partial oxidation steps in parallel
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/16—Controlling the process
- C01B2203/1628—Controlling the pressure
- C01B2203/1633—Measuring the pressure
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/80—Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
- C01B2203/82—Several process steps of C01B2203/02 - C01B2203/08 integrated into a single apparatus
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F21/00—Constructions of heat-exchange apparatus characterised by the selection of particular materials
- F28F21/06—Constructions of heat-exchange apparatus characterised by the selection of particular materials of plastics material
- F28F21/065—Constructions of heat-exchange apparatus characterised by the selection of particular materials of plastics material the heat-exchange apparatus employing plate-like or laminated conduits
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F2255/00—Heat exchanger elements made of materials having special features or resulting from particular manufacturing processes
- F28F2255/06—Heat exchanger elements made of materials having special features or resulting from particular manufacturing processes composite, e.g. polymers with fillers or fibres
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F2260/00—Heat exchangers or heat exchange elements having special size, e.g. microstructures
- F28F2260/02—Heat exchangers or heat exchange elements having special size, e.g. microstructures having microchannels
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/20—Capture or disposal of greenhouse gases of methane
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Combustion & Propulsion (AREA)
- Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- General Health & Medical Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- General Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Thermal Sciences (AREA)
- Physics & Mathematics (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Description
(A)炭化水素反応物および酸素または酸素源を含む反応組成物をマイクロチャネル反応器に流し、反応条件下で触媒に接触させて流し生成物を形成するステップを含み、マイクロチャネル反応器が少なくとも1つのプロセスマイクロチャネルを含み、触媒がプロセスマイクロチャネル内に配置され、炭化水素反応物がメタンを含み、プロセスマイクロチャネル内の反応組成物の接触時間は約500ミリ秒以下であり、プロセスマイクロチャネル内の反応組成物と生成物の温度は約1150℃以下であり、炭化水素反応物の変換は少なくとも約50%である方法に関する。
(B)ステップ(A)で形成された中間生成物を、マイクロチャネル反応器を通して流して反応条件下で燃焼触媒に接触させてCO2とH2Oを含む最終生成物を形成する。
M1 aM2 bM3 cAldOx
(式中、M1はRh、Ni、Pd、Pt、Ru、Co、またはその2種以上の混合物であり、
M2はCe、Pr、Tb、またはその2種以上の混合物であり、
M3はLa、Ba、Zr、Mg、Ca、またはその2種以上の混合物であり、
aは約0.0001〜約1の範囲の数字であり、
bは0〜約0.9999の範囲の数字であり、
cは約0.0001〜約0.9999の範囲の数字であり、
dは約0.0001〜約0.9999の範囲の数字であり、
xは存在する元素の要求する原子価を満足するのに必要な酸素の数である)
(A)Al2O3の層を少なくとも担体構造の一部に塗工するステップと、
(B)ステップ(A)で形成した被処理担体構造を焼成するステップと、
(C)ステップ(B)で形成した焼成担体構造の表面に助触媒または安定剤を加えるステップであって、助触媒または安定剤がLa、Ba、Zr、Mg、Ca、またはその酸化物もしくは硝酸塩、あるいその2種以上の混合物を含むステップと、
(D)ステップ(C)で形成した被処理担体構造を焼成するステップと、
(E)ステップ(D)で形成した焼成担体構造の表面に触媒金属またはその酸化物もしくは硝酸塩を塗工するステップであって、触媒金属がRh、Ni、Pd、Pt、Ru、Co、またはその2種以上の混合物を含むステップと、
(F)ステップ(E)で形成した被処理担体構造を焼成して担持触媒を形成するステップとを含む、担持触媒の製造方法に関する。
(1)純粋な炭化水素化合物:すなわち、脂肪族化合物(例えばアルカンまたはアルキレン)、脂環式化合物(例えばシクロアルカン、シクロアルキレン)、芳香族化合物、脂肪族および脂環式化合物で置換した芳香族化合物、芳香族で置換した脂肪族化合物、芳香族で置換した脂環式化合物等。例には、メタン、エタン、エチレン、プロパン、プロピレン、エチルシクロヘキサン、トルエン、キシレン、エチルベンゼン、スチレン等が含まれる。
(2)置換した炭化水素化合物:すなわち、化合物の炭化水素特性を大きく変化させない非炭化水素置換基を含む炭化水素化合物。非炭化水素置換基の例には、ヒドロキシ、アシル、ニトロ等が含まれる。
(3)ヘテロ置換炭化水素化合物:すなわち、特性では主として炭化水素であるが、鎖または環中に炭素以外の原子を含み、他は炭素原子からなる炭化水素化合物。適切なヘテロ原子には、例えば、窒素、酸素、硫黄が含まれる。
M1 aM2 bM3 cAldOx (I)
で表される組成物を含むことができ、
式(I)中、M1はRh、Ni、Pd、Pt、Ru、Co、またはその2種以上の混合物であり、M2はCe、Pr、Tb、またはその2種以上の混合物であり、M3はLa、Ba、Zr、Mg、Ca、またはその2種以上の混合物であり、aは約0.0001〜約1の範囲の数字であり、一実施形態において0.01〜約1であり、bは0〜約0.9999の範囲の数字であり、一実施形態において0〜約0.2であり、cは約0.0001〜約0.9999の範囲の数字であり、一実施形態において約0.01〜約0.2であり、dは約0.0001〜約0.9999の範囲の数字であり、一実施形態において約0.1〜約0.9であり、xは存在する元素の要求する原子価を満足するのに必要な酸素の数であり、触媒は基材上に被覆され、または発泡体、フェルト、ワッドもしくはフィン上に担持される一実施形態においてM1はRhまたはNiであり、一実施形態においてそれはRhである。一実施形態においてM3はLaまたはMgであり、一実施形態においてそれはLaである。一実施形態において触媒は式Rh/LaAl11O18またはRh/LaAlO3によって表すことができる。
(A)Al2O3の層を天然の酸化物層に塗工して被処理担体構造を形成するステップと、
(B)ステップ(A)で形成した被処理担体構造を焼成するステップと、
(C)ステップ(B)で形成した焼成され担体構造の表面に助触媒または安定剤を塗工するステップであって、助触媒または安定剤がLa、Ba、Zr、Mg、Ca、またはその酸化物もしくは硝酸塩、あるいはその2種以上の混合物を含むステップと、
(D)ステップ(C)で形成した被処理担体構造を焼成するステップと、
(E)ステップ(D)で形成した焼成担体構造の表面に触媒金属またはその酸化物もしくは硝酸塩を塗工するステップであって、触媒金属がRh、Ni、Pd、Pt、Ru、Co、またはその2種以上の混合物を含むステップと、
(F)ステップ(E)で形成した被処理担体構造を焼成して担体構造を形成するステップとを含む。一実施形態において、ステップ(F)で形成された触媒は水素中で還元することができる。
CH4変換(%)=(VCH4,in−VCH4,out)/(VCH4,in)×100
H2選択性(%)=(VH2,out測定値)/(VH2,out理論値)×100
CO選択性(%)=(VCO,out)/(VCO2,out+VCO2,out)×100
CH4変換(%)=(VCH4,in−VCH4,out)/(VCH4,in)×100
で計算される。燃焼触媒については、メタン変換は平均温度862℃で30.6%である。このデバイスでは、平均9.3W/cm2がSMR反応へ伝達される。燃焼チャネル中の圧力降下は2.5〜5.0psiである。
Claims (41)
- 少なくとも一つのプロセスマイクロチャネルと該少なくとも一つのマイクロチャネル内の少なくとも一つの部分酸化反応触媒からなるマイクロチャネル反応器内で炭化水素反応物をCOとH2とからなる部分酸化反応生成物に変換する方法であって、
(A)該炭化水素反応物および酸素または酸素源からなる反応組成物を該少なくとも一つのマイクロチャネル内で混合し、その混合物を該少なくとも一つのマイクロチャネル内を流して部分酸化反応条件下で該少なくとも一つの部分酸化反応触媒に接触させて該生成物を形成するステップを含み、該炭化水素反応物がメタンを含み、該少なくとも一つのプロセスマイクロチャネル内の該反応組成物の接触時間が500ミリ秒以下であり、該少なくとも一つのプロセスマイクロチャネル内の該反応組成物と生成物の温度が1150℃以下であり、該炭化水素反応物の変換が少なくとも50%である方法。 - 請求項1に記載の方法において、前記ステップ(A)における前記触媒は部分酸化触媒であり、ステップ(A)で形成された前記生成物は中間生成物であり、さらにステップ(A)に続く以下の追加のステップ、
(B)上記ステップ(A)で形成された該中間生成物をマイクロチャネル反応器に流し、反応条件下で燃焼触媒に接触させてCO2とH2Oからなる最終生成物を形成するステップからなる方法。 - 請求項1に記載の方法において、前記反応組成物がさらにH2Oを含んでおり、前記生成物がH2、COおよびCO2からなる方法。
- 請求項1から3のいずれか1つに記載の方法において、前記反応組成物が前記ステップ(A)の前に予備加熱される方法。
- 請求項1から4のいずれか1つに記載の方法において、前記反応組成物と酸素または酸素源が前記ステップ(A)の間に混合される方法。
- 請求項1から5のいずれか1つに記載の方法において、前記マイクロチャネル反応器は、前記触媒を含む複数のプロセスマイクロチャネルと、流体を該プロセスマイクロチャネルへ流入させる流路を提供するヘッダと、流体を該プロセスマイクロチャネルから流出させる流路を提供するフッタとからなる方法。
- 請求項1から6のいずれか1つに記載の方法において、前記プロセスマイクロチャネルは、0.05〜10mmの幅と高さの内部寸法を有し、前記プロセスマイクロチャネルは、アルミニウム、チタン、ニッケル、銅、2種以上の該金属の合金、鋼、モネル、インコネル、真鍮、ポリマー、セラミック、ガラス、ポリマーとファイバーグラスからなる複合材、石英、シリコン、またはその2種以上の組合せからなる材料から作製される方法。
- 請求項1から7のいずれか1つに記載の方法において、前記プロセスマイクロチャネルは、入口と、出口と、該入口と該出口の間に展延する伸張部分からなり、前記プロセスマイクロチャネルはさらに該伸張部分の長さに沿う複数のエントリーポイントを備え、前記酸素または酸素源が前記複数のエントリーポイントを通じて前記プロセスマイクロチャネルへ流入する方法。
- 請求項1から8のいずれか1つに記載の方法において、前記マイクロチャネル反応器がさらに前記プロセスマイクロチャネルに熱的に接触している少なくとも1つの熱交換チャネルからなる方法。
- 請求項9に記載の方法において、前記熱交換チャネルが0.05〜10mmの幅と高さの内部寸法を有し、前記熱交換チャネルは、アルミニウム、チタン、ニッケル、銅、2種以上の該金属の合金、鋼、モネル、インコネル、真鍮、ポリマー、セラミック、ガラス、ポリマーとファイバーグラスからなる複合材、石英、シリコン、またはその2種以上の組合せからなる材料から作製される方法。
- 請求項1から10のいずれか1つに記載の方法において、前記炭化水素反応物がさらに脂肪族化合物、芳香族化合物、アルキル基またはアルキレン基で置換された芳香族化合物、分子当たり2〜20個の炭素原子を含むアルカン、2〜20個の炭素原子を含むアルケン、3〜20個の炭素原子を含むポリエン、またはその2種以上の混合物からなる方法。
- 請求項1から11のいずれか1つに記載の方法において、前記炭化水素反応物が、エチレン、プロピレン、ブタン、イソブタン、ペンタン、ヘキサン、ヘプタン、オクタン、ノナン、デカン、エチレン、プロピレン、1−ブテン、2−ブテン、イソブチレン、1−ペンテン、2−ペンテン、3−メチル−1−ブテン、2−メチル−2−ブテン、1−ヘキサン、2,3−ジメチル−2−ブテン、1−へプテン、1−オクテン、1−ノネン、1−デセン、1,2−プロパジエン、1,3−ブタジエン、2−メチル−1,3−ブタジエン、1,3−ペンタジエン、1,4−ペンタジエン、1,5−ヘキサジエン、2,4−ヘキサジエン、2,3−ジメチル−1,3−ブタジエン、トルエン、o−キシレン、m−キシレン、p−キシレン、ヘミメリテン、プソイドクメン、メシチレン、プレーニテン、イソジュレン、ジュレン、ペンタメチルベンゼン、ヘキサメチルベンゼン、エチルベンゼン、n−プロピルベンゼン、クメン、n−ブチルベンゼン、イソブチルベンゼン、sec−ブチルベンゼン、tert−ブチルベンゼン、p−シメン、スチレン、天然油、合成油、ナフサ、ディーゼル燃料、燃料油、ケロセン、ガソリン、植物原料から誘導される炭化水素、鉱物原料から誘導される炭化水素、大豆、菜種、ヤシ、頁岩、石炭、タール砂から誘導される炭化水素、またはその2種以上の混合物からなる方法。
- 請求項1から12のいずれか1つに記載の方法において、前記炭化水素反応物が天然ガスを含む方法。
- 請求項1から13のいずれか1つに記載の方法において、前記酸素源が分子酸素、空気、窒素酸化物、一酸化炭素、二酸化炭素、過酸化物、酸素と空気の気体混合物、不活性ガスもしくは希釈ガスとの混合物である方法。
- 請求項1から14のいずれか1つに記載の方法において、前記反応組成物がさらに窒素、ヘリウム、二酸化炭素、液体水、蒸気、またはこれら2種以上の混合物である方法。
- 請求項1から15のいずれか1つに記載の方法において、前記プロセスマイクロチャネルが熱交換チャネル内の熱交換流体と熱を交換し、該熱交換流体が前記熱交換チャネル内で相変化を起こす方法。
- 請求項1から16のいずれか1つに記載の方法において、前記プロセスマイクロチャネルが前記熱交換チャネル中で行われる吸熱化学反応によって冷却され、該熱交換チャネルは前記プロセスマイクロチャネルと熱接触する方法。
- 請求項1から17のいずれか1つに記載の方法において、前記反応組成物が前記プロセスマイクロチャネルを第1方向に流れ熱交換流体が熱交換チャネルを第2方向に流れ、該熱交換チャネルが該プロセスマイクロチャネルと熱接触しており該第2方向が該第1方向に対して直交流、該第1方向に対して並流または該第1方向に対して向流である方法。
- 請求項1から18のいずれか1つに記載の方法において、熱交換流体が熱交換チャネル中にあり、該熱交換チャネルは前記プロセスマイクロチャネルと熱接触しており、前記熱交換流体が空気、蒸気、液体水、二酸化炭素、気体窒素、液体窒素、不活性ガス、一酸化炭素、溶融塩、油、気体炭化水素、液体炭化水素、炭化水素反応物、酸素または酸素源、またはこれら2種以上の混合物である方法。
- 請求項1から19のいずれか1つに記載の方法において、前記触媒が粒子状固体の形、または基板にウォッシュコートした形態を取る、あるいは側流構成、貫通流構成、蛇行構成、隣接する間隙を備える側流構成、隣接する間隙を備える発泡体構成、間隙を備えるフィン構成、流動用の間隙を備える金網構成を有する担体構造、または発泡体、フェルト、ワッド、フィンまたはその2種以上の組合わせの構成を有する担体構造によって担持される方法。
- 請求項1から20のいずれか1つに記載の方法において、前記触媒が、Ni、Cr、Feからなる合金、またはFe、Cr、Al、Yからなる合金からなる材料から作られた担体構造によって担持される方法。
- 請求項1から21のいずれか1つに記載の方法において、前記触媒が少なくとも1個のフィンからなるフィン組立体の形の担体構造に担持されており、該フィン組立体が平行な間隔を置いた複数のフィンからなる方法。
- 請求項22に記載の方法において、前記フィンが外部表面を有し多孔質材料が前記フィンの該外部表面の少なくとも一部を被覆していて前記触媒が該多孔質材料によって担持されると共に該多孔質材料がコーティング、繊維、発泡体またはフェルトから成り、あるいは複数の繊維または突起が前記フィンの該外部表面の少なくとも一部から展延していて前記触媒が該突起によって担持される方法。
- 請求項22に記載の方法において、前記フィンが外部表面を有し、前記触媒が前記フィンの該外部表面の少なくとも一部上にウォッシュコートされるか、前記フィンの該外部表面の少なくとも一部上に溶液から成長するか、あるいは前記フィンの該外部表面の少なくとも一部上に蒸着を用いて堆積される方法。
- 請求項22に記載の方法において、前記フィン組立体が平行な間隔を置いた複数のフィンからなり、該フィンの少なくとも1個が他の該フィンの長さとは異なる長さを有する、または該フィンの少なくとも1個が他の該フィンの高さとは異なる高さを有する方法。
- 請求項22に記載の方法において、前記フィンが正方形、矩形または台形の形状の断面を有し、前記フィンがアルミニウム、チタン、鉄、ニッケル、白金、ロジウム、銅、クロム、2種以上の該金属の合金、鋼、真鍮、ポリマー、セラミック、ガラス、ポリマーとファイバーグラスからなる複合材、石英、シリコン、またはその2種以上の組合せからなる材料から作製される方法。
- 請求項1から26のいずれか1つに記載の方法において、前記触媒がRh、Pt、Ni、Cr、Ru、Pd、Os、Ir、またはその酸化物、あるいはその2種以上の混合物からなる方法。
- 請求項1から27のいずれか1つに記載の方法において、前記触媒が下記式で表される組成物を含む方法。
M 1 a M 2 b M 3 c Al d O x
(式中、M 1 はRh、Ni、Pd、Pt、Ru、Co、またはその2種以上の混合物であり、
M 2 はCe、Pr、Tb、またはその2種以上の混合物であり、
M 3 はLa、Ba、Zr、Mg、Ca、またはその2種以上の混合物であり、
aは0.0001〜1の範囲の数字であり、
bは0〜0.9999の範囲の数字であり、
cは0.0001〜0.9999の範囲の数字であり、
dは0.0001〜0.9999の範囲の数字であり、
xは該存在する元素の要求する原子価を満足するのに必要な酸素の数である。) - 請求項2に記載の方法において、前記燃焼触媒が貴金属またはその酸化物、ペロブスカイトあるいはアルミン酸塩からなる方法。
- 請求項29に記載の方法において、前記燃焼触媒がさらにCe、Tb、もしくはPrまたはその酸化物、あるいはその2種以上の混合物からなる方法。
- 請求項2に記載の方法において、前記燃焼触媒がPt、Rh、Pd、Co、Mn、Fe、Niまたはその酸化物、あるいはその2種以上の混合物からなる方法。
- 請求項1から31のいずれか1つに記載の方法において、前記反応組成物および/または生成物と前記触媒との接触時間が0.1ミリ秒〜100秒であり、または前記プロセスマイクロチャネルに流入する前記反応組成物の温度が200℃〜1000℃の範囲であり、または前記プロセスマイクロチャネルに流入する前記反応組成物の圧力が0.1〜100気圧の範囲であり、または前記プロセスマイクロチャネルを流れる前記反応組成物および生成物の空間速度が少なくとも100hr −1 であり、または前記プロセスマイクロチャネルを流れる前記反応組成物および生成物の圧力降下が前記プロセスマイクロチャネルの長さ1メートル当たり2気圧以下である方法。
- 請求項1から32のいずれか1つに記載の方法において、熱交換流体が熱交換チャネル中にあり、該熱交換チャネルは前記プロセスマイクロチャネルと熱接触しており、前記熱交換チャネルを流れる該熱交換流体の全圧力降下が10気圧以下である方法。
- 下記式で表わされる組成物からなる、請求項1記載の方法に用いられる触媒であって、基板上にコーティングされるか、あるいは発泡体、フェルト、ワッドまたはフィン上に担持される触媒。
M 1 a M 2 b M 3 c Al d O x
(式中、M 1 はRh、Ni、Pd、Pt、Ru、Co、またはその2種以上の混合物であり、
M 2 はCe、Pr、Tb、またはその2種以上の混合物であり、
M 3 はLa、Ba、Zr、Mg、Ca、またはその2種以上の混合物であり、
aは0.0001〜1の範囲の数字であり、
bは0〜0.9999の範囲の数字であり、
cは0.0001〜0.9999の範囲の数字であり、
dは0.0001〜0.9999の範囲の数字であり、
xは該存在する元素の要求する原子価を満足するのに必要な酸素の数である。) - 請求項1記載の方法に用いられる担持触媒の形成方法であって、下記のステップ(A)〜(F)からなる方法。
(A)Al 2 O 3 の層を担体構造の少なくとも一部に塗工するステップ、
(B)上記ステップ(A)で形成した被処理担体構造を焼成するステップ、
(C)上記ステップ(B)で形成した焼成担体構造の表面に助触媒または安定剤を塗工して被処理担体構造を形成するステップであって、該助触媒または安定剤がLa、Ba、Zr、Mg、Ca、またはその酸化物もしくは硝酸塩、あるいはその2種以上の混合物であるステップ、
(D)上記ステップ(C)で形成した被処理担体構造を焼成するステップ、
(E)上記ステップ(D)で形成した焼成担体構造の表面に触媒金属またはその酸化物もしくは硝酸塩を塗工して、被処理担体構造を形成するステップであって、該触媒金属がRh、Ni、Pd、Pt、Ru、Coまたはその2種以上の混合物であるステップ、
(F)上記ステップ(E)で形成した被処理担体構造を焼成して担持触媒を形成するステップ。 - 請求項35に記載の方法において、前記ステップ(F)で形成された担持触媒が水素中で還元される方法。
- 請求項35または36に記載の方法において、前記担体構造が、アルミニウム、チタン、鉄、ニッケル、白金、ロジウム、銅、クロム、2種以上の該金属の合金、鋼、真鍮、ポリマー、セラミック、ガラス、ポリマーとファイバーグラスからなる複合材、石英、シリコン、Fe、Cr、Al、Yからなる合金から作られ、これら天然酸化物層がAl 2 O 3 、またはNi、Cr、Feからなる合金から作られこれら天然酸化物層がCr 2 O 3 、またはこれら2種以上の組合せからなる方法。
- 請求項35から37のいずれか1つに記載の方法において、前記ステップ(A)の前に、前記担体構造が300℃〜1400℃の範囲の温度で0.1〜1000時間加熱され、または前記ステップ(B)の間に、前記被処理担体構造が150℃〜1200℃の範囲の温度で0.1〜1000時間焼成され、または前記ステップ(C)の間に、La(NO 3 ) 3 からなる溶液が前記焼成担体構造の前記表面に塗工され、または前記ステップ(D)の間に、前記被処理担体構造が150℃〜1200℃の範囲の温度で0.1〜1000時間焼成され、または前記ステップ(E)の間に、Rh(NO 3 ) 3 からなる組成物が前記焼成担体構造の前記表面に塗工され、または前記ステップ(F)の間に、前記被処理担体構造が150℃〜1200℃の範囲の温度で0.1〜1000時間焼成される方法。
- 請求項35から38のいずれか1つに記載の方法において、前記ステップ(A)の間に、Al 2 O 3 からなるスラリーまたはコロイド分散液が前記天然酸化物層の上に塗工される方法。
- 請求項1から33または35から39のいずれか1つに記載の方法において、前記触媒が式Rh/LaAl 11 O 18 またはRh/LaAlO 3 で表される方法。
- 請求項34に記載の触媒において、前記触媒が式Rh/LaAl 11 O 18 またはRh/LaAlO 3 で表される触媒。
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/440,053 | 2003-05-16 | ||
US10/440,053 US7220390B2 (en) | 2003-05-16 | 2003-05-16 | Microchannel with internal fin support for catalyst or sorption medium |
US10/449,913 | 2003-05-30 | ||
US10/449,913 US7226574B2 (en) | 2003-05-16 | 2003-05-30 | Oxidation process using microchannel technology and novel catalyst useful in same |
PCT/US2004/010611 WO2004103549A2 (en) | 2003-05-16 | 2004-04-08 | Oxidation process using microchannel technology and novel catalyst useful in same |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2007515362A JP2007515362A (ja) | 2007-06-14 |
JP4768619B2 true JP4768619B2 (ja) | 2011-09-07 |
Family
ID=33417967
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2006532390A Expired - Fee Related JP5087276B2 (ja) | 2003-05-16 | 2004-04-08 | 触媒または吸着媒体用内部フィン担体を備えるマイクロチャネル |
JP2006532382A Expired - Fee Related JP4768619B2 (ja) | 2003-05-16 | 2004-04-08 | マイクロチャネル技術を用いる酸化方法およびそのために有用な新規触媒 |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2006532390A Expired - Fee Related JP5087276B2 (ja) | 2003-05-16 | 2004-04-08 | 触媒または吸着媒体用内部フィン担体を備えるマイクロチャネル |
Country Status (8)
Country | Link |
---|---|
US (3) | US7220390B2 (ja) |
EP (2) | EP1631376A1 (ja) |
JP (2) | JP5087276B2 (ja) |
CN (2) | CN100531890C (ja) |
AU (1) | AU2004241943B2 (ja) |
CA (2) | CA2525733C (ja) |
RU (1) | RU2005139413A (ja) |
WO (1) | WO2004103550A1 (ja) |
Families Citing this family (155)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU779487B2 (en) * | 1999-08-17 | 2005-01-27 | Battelle Memorial Institute | Chemical reactor and method for catalytic gas phase reactions |
US6488838B1 (en) * | 1999-08-17 | 2002-12-03 | Battelle Memorial Institute | Chemical reactor and method for gas phase reactant catalytic reactions |
US6746657B2 (en) * | 2002-03-12 | 2004-06-08 | Precision Combustion, Inc. | Method for reduced methanation |
US7014835B2 (en) * | 2002-08-15 | 2006-03-21 | Velocys, Inc. | Multi-stream microchannel device |
US8580211B2 (en) * | 2003-05-16 | 2013-11-12 | Velocys, Inc. | Microchannel with internal fin support for catalyst or sorption medium |
US7220390B2 (en) * | 2003-05-16 | 2007-05-22 | Velocys, Inc. | Microchannel with internal fin support for catalyst or sorption medium |
JP4587016B2 (ja) * | 2003-05-30 | 2010-11-24 | ソニー株式会社 | 反応装置とその製造方法、改質装置、電源供給システム |
US20050207953A1 (en) * | 2003-07-22 | 2005-09-22 | The Regents Of The University Of California | High aspect ratio chemical microreactor |
WO2005015658A2 (en) * | 2003-08-07 | 2005-02-17 | Cbh2 Technologies, Inc. | Hypergolic hydrogen generation system for fuel cell power plants |
US8066955B2 (en) * | 2003-10-17 | 2011-11-29 | James M. Pinchot | Processing apparatus fabrication |
GB2410449B (en) * | 2004-01-28 | 2008-05-21 | Statoil Asa | Fischer-Tropsch catalysts |
US7084180B2 (en) * | 2004-01-28 | 2006-08-01 | Velocys, Inc. | Fischer-tropsch synthesis using microchannel technology and novel catalyst and microchannel reactor |
US7520917B2 (en) * | 2004-02-18 | 2009-04-21 | Battelle Memorial Institute | Devices with extended area structures for mass transfer processing of fluids |
US8062623B2 (en) * | 2004-10-15 | 2011-11-22 | Velocys | Stable, catalyzed, high temperature combustion in microchannel, integrated combustion reactors |
JP4971975B2 (ja) * | 2004-03-23 | 2012-07-11 | ヴェロシス インコーポレイテッド | 熱成長アルミナに直接適用される触媒材料を有する触媒、及びこれを用いる触媒作用法;改善された酸化的脱水素方法 |
US7744830B2 (en) * | 2004-04-29 | 2010-06-29 | Lawrence Livermore National Security, Llc | Catalyst for microelectromechanical systems microreactors |
WO2006052296A1 (en) * | 2004-07-07 | 2006-05-18 | Cbh2 Technologies, Inc. | Methods of improving thermal transfer within a hydrocarbon reforming system |
WO2006020709A1 (en) * | 2004-08-12 | 2006-02-23 | Velocys Inc. | Process for converting ethylene to ethylene oxide using microchannel process technology |
EP1791783A1 (en) * | 2004-09-20 | 2007-06-06 | Shell Internationale Research Maatschappij B.V. | A process for the catalytic partial oxidation of a liquid hydrocarbonaceous fuel |
JP5643474B2 (ja) | 2004-10-01 | 2014-12-17 | ヴェロシス,インク. | マイクロチャネルプロセス技術を用いる多相混合プロセス |
DE102004050506A1 (de) * | 2004-10-15 | 2006-04-20 | Degussa Ag | Verfahren zur Herstellung von Olefinoxiden und Peroxiden, Reaktor und dessen Verwendung |
EP1817102A1 (en) * | 2004-11-12 | 2007-08-15 | Velocys, Inc. | Process using microchannel technology for conducting alkylation or acylation reaction |
US8383872B2 (en) | 2004-11-16 | 2013-02-26 | Velocys, Inc. | Multiphase reaction process using microchannel technology |
JP4991102B2 (ja) * | 2004-12-22 | 2012-08-01 | パナソニック株式会社 | マイクロリアクタ |
DE102005004075B4 (de) * | 2005-01-28 | 2008-04-03 | Umicore Ag & Co. Kg | Keramischer Mikroreaktor |
US7507274B2 (en) * | 2005-03-02 | 2009-03-24 | Velocys, Inc. | Separation process using microchannel technology |
US8122909B2 (en) * | 2005-03-23 | 2012-02-28 | Velocys | Surface features in microprocess technology |
EP1890802A2 (en) * | 2005-05-25 | 2008-02-27 | Velocys, Inc. | Support for use in microchannel processing |
US20070004810A1 (en) * | 2005-06-30 | 2007-01-04 | Yong Wang | Novel catalyst and fischer-tropsch synthesis process using same |
ES2925730T3 (es) * | 2005-07-08 | 2022-10-19 | Velocys Inc | Proceso de reacción catalítica usando la tecnología de microcanales |
GT200600392A (es) * | 2005-08-31 | 2007-09-25 | Produccion por auto-oxidacion de peroxido de hidrogeno a traves de hidrogenacion en un microreactor | |
WO2007027785A2 (en) * | 2005-08-31 | 2007-03-08 | Fmc Corporation | Auto-oxidation production of hydrogen peroxide via oxidation in a microreactor |
JP5345750B2 (ja) * | 2005-09-30 | 2013-11-20 | 富士フイルム株式会社 | 流体デバイス |
JP2007105668A (ja) * | 2005-10-14 | 2007-04-26 | Mitsubishi Chemicals Corp | 気液反応方法及びそのための装置 |
US7788073B2 (en) * | 2005-12-13 | 2010-08-31 | Linde Aktiengesellschaft | Processes for determining the strength of a plate-type exchanger, for producing a plate-type heat exchanger, and for producing a process engineering system |
EP2397457A3 (en) * | 2006-03-23 | 2013-11-20 | Velocys Inc. | Process for making styrene using microchannel process technology |
JP5239125B2 (ja) * | 2006-04-10 | 2013-07-17 | 株式会社豊田中央研究所 | 反応器 |
JP4963372B2 (ja) * | 2006-04-10 | 2012-06-27 | 株式会社豊田中央研究所 | 反応器、反応器の製造方法、及び反応器用単位部材 |
JP5362552B2 (ja) | 2006-04-20 | 2013-12-11 | ヴェロシス,インク. | マイクロチャネルプロセス技術を用いて非ニュートン流体を処理し、および/または形成させるためのプロセス |
WO2007144446A1 (en) * | 2006-06-15 | 2007-12-21 | Ecocat Oy | Coating for particulate filters |
JP5278641B2 (ja) * | 2006-06-23 | 2013-09-04 | 日産自動車株式会社 | メタル基材の製造方法 |
EP1939136A3 (en) * | 2006-12-29 | 2013-03-27 | Corning Incorporated | High throughput pressure resistant microfluidic devices |
US7829602B2 (en) * | 2007-01-19 | 2010-11-09 | Velocys, Inc. | Process and apparatus for converting natural gas to higher molecular weight hydrocarbons using microchannel process technology |
US20080173533A1 (en) * | 2007-01-22 | 2008-07-24 | John Carlton Mankins | Process and method of making space-solar fuels and other chemicals |
US7923592B2 (en) | 2007-02-02 | 2011-04-12 | Velocys, Inc. | Process for making unsaturated hydrocarbons using microchannel process technology |
JP5374702B2 (ja) * | 2007-03-09 | 2013-12-25 | 国立大学法人横浜国立大学 | 水素生成方法 |
US8603407B2 (en) | 2007-03-21 | 2013-12-10 | Precision Combustion, Inc. | Catalytic isobutane alkylation |
KR101472767B1 (ko) * | 2007-05-24 | 2014-12-24 | 에어 워터 가부시키가이샤 | 일산화탄소 가스 발생 장치 및 방법 |
US20090043141A1 (en) * | 2007-05-30 | 2009-02-12 | Terry Mazanec | Oxidative coupling of methane |
US20090075156A1 (en) * | 2007-09-13 | 2009-03-19 | Velocys Inc. | Porous Electrolessly Deposited Coatings |
CN101234324B (zh) * | 2007-11-21 | 2010-06-09 | 清华大学 | 一种微接触混合器 |
US8092558B2 (en) * | 2008-01-22 | 2012-01-10 | Asemblon, Inc. | Microchannel reactor module for hydrogen release |
JP5148308B2 (ja) * | 2008-02-01 | 2013-02-20 | 三井造船株式会社 | 廃食油の改質反応器 |
US8071836B2 (en) * | 2008-03-13 | 2011-12-06 | Fina Technology, Inc. | Process for toluene and methane coupling in a microreactor |
US8076527B2 (en) * | 2008-03-13 | 2011-12-13 | Fina Technology, Inc. | Process for production of ethylbenzene from toluene and methane |
US7745667B2 (en) * | 2008-04-07 | 2010-06-29 | Velocys | Microchannel apparatus comprising structured walls, chemical processes, methods of making formaldehyde |
EP2282828A2 (en) * | 2008-04-09 | 2011-02-16 | Velocys, Inc. | Process for converting a carbonaceous material to methane, methanol and/or dimethyl ether using microchannel process technology |
US8100996B2 (en) * | 2008-04-09 | 2012-01-24 | Velocys, Inc. | Process for upgrading a carbonaceous material using microchannel process technology |
CA2719382C (en) * | 2008-04-09 | 2019-02-26 | Velocys Inc. | Process for upgrading a carbonaceous material using microchannel process technology |
CN102099346A (zh) * | 2008-07-14 | 2011-06-15 | 巴斯夫欧洲公司 | 制备环氧乙烷的方法 |
EP2346964A2 (en) | 2008-10-10 | 2011-07-27 | Velocys, Inc. | Process and apparatus employing microchannel process technology |
US20110311417A1 (en) * | 2008-11-06 | 2011-12-22 | Agency For Science, Technology And Research | Apparatus for Biopolymer Synthesis |
JP5722804B2 (ja) * | 2009-03-02 | 2015-05-27 | クラリアント コーポレイション | 活性化された酸化ジルコニウム触媒支持体 |
US8278363B2 (en) * | 2009-03-23 | 2012-10-02 | Thomas Charles Holcombe | Fischer-tropsch reactions using heat transfer tubes with a catalyst layer on the outside surfaces |
US8906266B2 (en) * | 2009-04-22 | 2014-12-09 | Shell Oil Company | Process for the preparation of hydrogen and carbon monoxide containing gas |
WO2010141629A1 (en) | 2009-06-02 | 2010-12-09 | Thermochem Recovery International, Inc. | Gasifier having integrated fuel cell power generation system |
US8524927B2 (en) * | 2009-07-13 | 2013-09-03 | Velocys, Inc. | Process for making ethylene oxide using microchannel process technology |
GB2473071B (en) | 2009-09-01 | 2013-09-11 | Gtl F1 Ag | Fischer-tropsch catalysts |
CA2777183A1 (en) * | 2009-10-09 | 2011-04-14 | Velocys Inc. | Process for treating heavy oil |
CA2779826C (en) * | 2009-11-06 | 2016-12-13 | Auburn University | Microfibrous media for optimizing and controlling highly exothermic and highly endothermic reactions/processes |
GB2475492B (en) | 2009-11-18 | 2014-12-31 | Gtl F1 Ag | Fischer-Tropsch synthesis |
EP2519718A4 (en) * | 2009-12-31 | 2013-09-11 | Nanostellar Inc | WITH BISMUT OR MANGAN DOTED ENGINE GAS CATALYST |
JP2011000586A (ja) * | 2010-07-28 | 2011-01-06 | Casio Computer Co Ltd | 反応装置 |
PL2603316T3 (pl) | 2010-08-09 | 2018-02-28 | Gtl. F1 Ag | Katalizatory fischer-tropsch |
RU2013114747A (ru) * | 2010-10-18 | 2014-11-27 | Велосис Инк. | Микроканальное технологическое устройство |
DE112011103504T5 (de) | 2010-10-18 | 2013-11-14 | Velocys Corporation | Laminierte, lecksichere, chemische Prozessoren, Herstellungsverfahren und Betriebsverfahren |
AU2011323198B2 (en) | 2010-11-05 | 2015-06-18 | Thermochem Recovery International, Inc. | Solids circulation system and method for capture and conversion of reactive solids |
FR2970070A1 (fr) * | 2011-01-04 | 2012-07-06 | Commissariat Energie Atomique | Echangeur de chaleur en materiaux polymeres et composites |
DE112012003041T5 (de) * | 2011-07-19 | 2014-04-17 | Velocys, Inc. | Mikrokanalreaktoren und Herstellungsverfahren |
CN103958398B (zh) | 2011-09-27 | 2016-01-06 | 国际热化学恢复股份有限公司 | 合成气净化系统和方法 |
CN103055956B (zh) * | 2011-10-18 | 2015-09-23 | 中国石油化工股份有限公司 | 加氢催化剂的浸渍液及其制备方法和加氢催化剂及其制备方法 |
SG11201401659TA (en) * | 2011-11-02 | 2014-05-29 | Univ Singapore | A heat sink assembly apparatus |
US9238284B2 (en) * | 2011-12-20 | 2016-01-19 | Unison Industries, Llc | Methods for forming a heat exchanger and portions thereof |
US9295960B2 (en) | 2012-03-23 | 2016-03-29 | United Technologies Corporation | Catalytic reaction in confined flow channel |
US9599410B2 (en) * | 2012-07-27 | 2017-03-21 | General Electric Company | Plate-like air-cooled engine surface cooler with fluid channel and varying fin geometry |
CN102836695B (zh) * | 2012-08-07 | 2015-01-07 | 李晓澎 | 一种净化乙炔、丙烷、液化石油气、fcc汽油的净化剂及净化方法 |
PL229084B1 (pl) * | 2012-11-07 | 2018-06-29 | Politechnika Lodzka | Wielowarstwowy kompozyt do rewersyjnej sorpcji rtęci oraz sposób sorpcji i desorpcji rtęci z fazy gazowej |
JP6408754B2 (ja) * | 2013-02-06 | 2018-10-17 | 株式会社Ihi | リアクタ |
WO2014159555A1 (en) | 2013-03-12 | 2014-10-02 | Battelle Memorial Institute | Reactor incorporating a heat exchanger |
US9676623B2 (en) | 2013-03-14 | 2017-06-13 | Velocys, Inc. | Process and apparatus for conducting simultaneous endothermic and exothermic reactions |
JPWO2014208444A1 (ja) * | 2013-06-26 | 2017-02-23 | 株式会社Ihi | 触媒構造体、リアクタ、および、触媒構造体の製造方法 |
EP3015164B1 (en) * | 2013-06-27 | 2022-02-23 | IHI Corporation | Reactor with corrugated catalyst structure |
CN103418387B (zh) * | 2013-08-27 | 2014-12-17 | 山西洁泰达煤化工工程有限公司 | 一种多孔结构的镍锆甲烷化催化剂的制备方法 |
JP6376131B2 (ja) * | 2013-09-13 | 2018-08-22 | 株式会社Ihi | リアクタ |
CN103638986A (zh) * | 2013-11-29 | 2014-03-19 | 宁波科森净化器制造有限公司 | 一种使用翼片提高反应接触面积的催化剂载体 |
US20150225315A1 (en) * | 2014-02-10 | 2015-08-13 | Honeywell International Inc. | Reactor design for liquid phase fluorination |
AU2015225534B2 (en) * | 2014-03-04 | 2019-03-14 | Conocophillips Company | Heat exchanger for a liquefied natural gas facility |
WO2015135968A1 (de) * | 2014-03-14 | 2015-09-17 | Basf Se | Yttriumhaltiger katalysator zur hochtemperatur kohlendioxidhydrierung, kombinierten hochtemperatur kohlendioxidhydrierung und reformierung und/oder reformierung sowie ein verfahren zur hochtemperatur kohlendioxidhydrierung, kombinierten hochtemperatur kohlendioxidhydrierung und reformierung und/oder reformierung |
CN105214583B (zh) * | 2014-06-20 | 2017-05-17 | 中国科学院大连化学物理研究所 | 一种用于甲醇无氧脱氢反应的微反应器及其制备和应用 |
US10076739B1 (en) | 2014-07-22 | 2018-09-18 | Precision Combustion, Inc. | Chemical reactor for use with overly reactive chemicals |
US10710043B2 (en) | 2014-09-24 | 2020-07-14 | Raven Sr, Llc | Compact and maintainable waste reformation apparatus |
CN104327227B (zh) * | 2014-11-18 | 2016-04-13 | 西安元创化工科技股份有限公司 | 一种酚醛树脂的合成方法 |
KR101963059B1 (ko) * | 2014-12-11 | 2019-03-27 | 다나카 기킨조쿠 고교 가부시키가이샤 | 과산화수소 분해용 촉매 및 그 제조 방법 그리고 그 촉매를 사용한 과산화수소를 분해하는 방법 |
DE102015201065A1 (de) * | 2015-01-22 | 2016-07-28 | Bayerische Motoren Werke Aktiengesellschaft | Verfahren zur Energieversorgung mit einem Reaktor zur Freisetzung von Wasserstoff aus flüssigen Verbindungen |
JP6355106B2 (ja) * | 2015-03-24 | 2018-07-11 | 三菱重工業株式会社 | 燃料改質機構、流体改質機構、燃料改質機構を備えるジェットエンジン、燃料改質機構の製造方法 |
KR20180004251A (ko) | 2015-06-08 | 2018-01-10 | 가부시키가이샤 아이에이치아이 | 리액터 |
EP3313794B1 (en) | 2015-06-26 | 2022-01-26 | Corning Incorporated | Colorless copper-containing material |
CN106391044A (zh) * | 2015-07-28 | 2017-02-15 | 江苏吉华化工有限公司 | 一种催化剂 |
CN105032447B (zh) * | 2015-07-29 | 2017-07-25 | 中国科学院山西煤炭化学研究所 | 一种费托合成油驰放气催化燃烧催化剂及制法和应用 |
CN105003417A (zh) * | 2015-08-10 | 2015-10-28 | 安徽万瑞冷电科技有限公司 | 一种新型低温泵冷伞及其制备方法 |
EP3334508A4 (en) | 2015-08-13 | 2019-04-10 | Waters Technologies Corporation | NICKEL-COBALT ALLOY MATERIAL DEVICES AND COMPONENTS |
CN106622057B (zh) * | 2015-10-30 | 2019-02-01 | 中国石油化工股份有限公司 | 一种费托合成微反应器和费托合成方法 |
CN106622056B (zh) * | 2015-10-30 | 2019-02-01 | 中国石油化工股份有限公司 | 费托合成反应系统和费托合成方法 |
CN106622058B (zh) * | 2015-10-30 | 2019-04-16 | 中国石油化工股份有限公司 | 一种费托合成反应装置和费托合成方法 |
US10208621B2 (en) | 2015-12-07 | 2019-02-19 | General Electric Company | Surface cooler and an associated method thereof |
WO2017142515A1 (en) | 2016-02-16 | 2017-08-24 | Thermochem Recovery International, Inc., | Two-stage energy-integrated product gas generation system and method |
JP6728751B2 (ja) | 2016-02-23 | 2020-07-22 | 株式会社Ihi | 反応装置及び反応システム |
DE102016105492A1 (de) | 2016-03-23 | 2017-09-28 | Karlsruher Institut für Technologie | Reaktor zur Herstellung von Synthesegas |
US10286431B1 (en) | 2016-03-25 | 2019-05-14 | Thermochem Recovery International, Inc. | Three-stage energy-integrated product gas generation method |
CN107266321B (zh) * | 2016-04-06 | 2019-10-25 | 中国科学院大连化学物理研究所 | 一种三氟甲氧基苯硝化的方法 |
CN106237939A (zh) * | 2016-08-29 | 2016-12-21 | 成都赛普瑞兴科技有限公司 | 反应装置及反应设备 |
US10197015B2 (en) | 2016-08-30 | 2019-02-05 | Thermochem Recovery International, Inc. | Feedstock delivery system having carbonaceous feedstock splitter and gas mixing |
US10197014B2 (en) | 2016-08-30 | 2019-02-05 | Thermochem Recovery International, Inc. | Feed zone delivery system having carbonaceous feedstock density reduction and gas mixing |
US10364398B2 (en) | 2016-08-30 | 2019-07-30 | Thermochem Recovery International, Inc. | Method of producing product gas from multiple carbonaceous feedstock streams mixed with a reduced-pressure mixing gas |
KR101877124B1 (ko) * | 2016-09-07 | 2018-07-10 | 서강대학교산학협력단 | 균일하게 구조규칙적인 메조동공 TiO2-B 합성 방법 및 이의 광화학적 광촉매 물성 |
JP6919274B2 (ja) * | 2017-03-31 | 2021-08-18 | 株式会社Ihi | 触媒反応器 |
US10329506B2 (en) | 2017-04-10 | 2019-06-25 | Thermochem Recovery International, Inc. | Gas-solids separation system having a partitioned solids transfer conduit |
US10717102B2 (en) | 2017-05-31 | 2020-07-21 | Thermochem Recovery International, Inc. | Pressure-based method and system for measuring the density and height of a fluidized bed |
US9920926B1 (en) | 2017-07-10 | 2018-03-20 | Thermochem Recovery International, Inc. | Pulse combustion heat exchanger system and method |
AU2018344730B2 (en) * | 2017-10-05 | 2021-08-05 | Rasa Industries, Ltd. | Heat source device and method for using silver zeolite |
US10099200B1 (en) | 2017-10-24 | 2018-10-16 | Thermochem Recovery International, Inc. | Liquid fuel production system having parallel product gas generation |
FR3074067B1 (fr) * | 2017-11-28 | 2019-12-20 | Commissariat A L'energie Atomique Et Aux Energies Alternatives | Reacteur echangeur comportant un systeme de distribution etagee de reactifs |
CN108212150B (zh) * | 2017-12-27 | 2020-12-29 | 南京工业大学 | 一种负载铑液体金属溶液催化剂及其制备和应用 |
CN108889057B (zh) * | 2018-08-10 | 2021-05-07 | 中国恩菲工程技术有限公司 | 烟气净化装置及方法、烟气净化吸附剂及其应用 |
CN109225234B (zh) * | 2018-09-19 | 2021-07-20 | 石河子大学 | 一种用于碳催化加氢制甲烷的组合物 |
US11497468B2 (en) * | 2018-12-21 | 2022-11-15 | Fujifilm Sonosite, Inc. | Ultrasound probe |
CN109634321B (zh) * | 2018-12-31 | 2021-02-05 | 西安优耐特容器制造有限公司 | 适用于微反应实验的精确控温系统及方法 |
CN109876847B (zh) * | 2019-03-05 | 2020-04-14 | 大连理工大学 | 一种应用于烯烃氢甲酰化的分子筛封装铑的非均相核壳式催化剂及其催化方法 |
US11204204B2 (en) * | 2019-03-08 | 2021-12-21 | Toyota Motor Engineering & Manufacturing North America, Inc. | Acoustic absorber with integrated heat sink |
KR20200118539A (ko) * | 2019-04-08 | 2020-10-16 | 현대자동차주식회사 | 튜브-핀 어셈블리 |
CN110280246A (zh) * | 2019-06-28 | 2019-09-27 | 中南民族大学 | 一种Co/C-N催化剂的制备方法及其在CO2加氢合成甲醇反应中的应用 |
CN110592610B (zh) * | 2019-09-29 | 2021-02-05 | 肯特催化材料股份有限公司 | 一种季铵盐模板剂的制备方法和应用 |
US11555157B2 (en) | 2020-03-10 | 2023-01-17 | Thermochem Recovery International, Inc. | System and method for liquid fuel production from carbonaceous materials using recycled conditioned syngas |
WO2022024309A1 (ja) * | 2020-07-30 | 2022-02-03 | 株式会社Ihi | 熱交換構造 |
US11466223B2 (en) | 2020-09-04 | 2022-10-11 | Thermochem Recovery International, Inc. | Two-stage syngas production with separate char and product gas inputs into the second stage |
CN114752234A (zh) * | 2021-01-08 | 2022-07-15 | 杭州三花研究院有限公司 | 复合材料及其制备方法、换热器及热管理系统 |
JP2022172990A (ja) * | 2021-05-07 | 2022-11-17 | 株式会社クリーンプラネット | 発熱装置 |
CN113600118A (zh) * | 2021-07-07 | 2021-11-05 | 上海试四赫维化工有限公司 | 利用板翅结构反应器制备三-(2-氯乙基)亚磷酸酯的方法 |
CN114965618B (zh) * | 2022-06-13 | 2023-10-17 | 潍坊学院 | 双模式生物传感器及其在dna甲基转移酶活性检测中的应用 |
CN115557467B (zh) * | 2022-11-23 | 2023-04-25 | 浙江百能科技有限公司 | 煤炭分级利用废水制氢反应系统及方法 |
CN115770607B (zh) * | 2022-12-01 | 2024-06-04 | 中国科学院上海高等研究院 | 一种包覆型单原子金基催化剂、制备方法及其在烯烃氢甲酰化反应中的应用 |
US12012558B1 (en) | 2022-12-14 | 2024-06-18 | Saudi Arabian Oil Company | Microchannel reactors for catalytic oxidation of hydrocarbon fuels |
CN115869960B (zh) * | 2022-12-16 | 2024-07-12 | 南京红宝丽醇胺化学有限公司 | 一种Ni-Co-Ce-Cr催化剂及其制备方法与应用 |
CN117504540B (zh) * | 2023-11-08 | 2024-05-07 | 南京华瑞微集成电路有限公司 | 一种cvd尾气处理设备 |
CN117582995B (zh) * | 2023-11-15 | 2024-04-19 | 山东鑫鼎化工科技有限公司 | 一种用于甲基丙烯腈合成的催化剂及其制备方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0840703A (ja) * | 1994-05-23 | 1996-02-13 | Ngk Insulators Ltd | 水素製造装置 |
US20020009406A1 (en) * | 2000-02-18 | 2002-01-24 | Kostantinos Kourtakis | Chromium-rare earth based catalysts and process for converting hydrocarbons to synthesis gas |
JP2003507288A (ja) * | 1999-08-17 | 2003-02-25 | バッテル・メモリアル・インスティチュート | 気相反応物質触媒反応用化学反応器及び方法 |
US20050119355A1 (en) * | 2001-06-21 | 2005-06-02 | Cuong Pham-Huu | Method for obtaining synthesis gas by partial catalytic oxidation |
Family Cites Families (152)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4450A (en) * | 1846-04-11 | Spring-lancet | ||
US12624A (en) * | 1855-04-03 | Island | ||
DE246257C (ja) | ||||
US115730A (en) * | 1871-06-06 | Improvement in machines for making sheet-lead | ||
US3972837A (en) * | 1973-07-03 | 1976-08-03 | Johnson Matthey & Co., Limited | Catalyst for purifying automotive exhaust gases |
US4089810A (en) * | 1973-08-20 | 1978-05-16 | Johnson, Matthey & Co., Limited | Catalyst |
GB1531134A (en) | 1975-08-20 | 1978-11-01 | Atomic Energy Authority Uk | Methods of fabricating bodies and to bodies so fabricated |
GB1568391A (en) * | 1976-04-14 | 1980-05-29 | Atomic Energy Authority Uk | Catalysts having metallic substrates |
US4289652A (en) * | 1978-02-10 | 1981-09-15 | Johnson Matthey Inc. | Catalyst comprising a metal substrate |
US4392362A (en) | 1979-03-23 | 1983-07-12 | The Board Of Trustees Of The Leland Stanford Junior University | Micro miniature refrigerators |
US4388277A (en) | 1980-06-06 | 1983-06-14 | United Kingdom Atomic Energy Authority | Catalyst device and method |
US4516632A (en) | 1982-08-31 | 1985-05-14 | The United States Of America As Represented By The United States Deparment Of Energy | Microchannel crossflow fluid heat exchanger and method for its fabrication |
US4844837A (en) * | 1982-09-30 | 1989-07-04 | Engelhard Corporation | Catalytic partial oxidation process |
DE3926466C2 (de) | 1989-08-10 | 1996-12-19 | Christoph Dipl Ing Caesar | Mikroreaktor zur Durchführung chemischer Reaktionen von zwei chemischen Stoffen mit starker Wärmetönung |
US5093299A (en) | 1990-01-09 | 1992-03-03 | The Standard Oil Company | Catalyst for process for the manufacture of acrylonitrile and methacrylonitrile |
US5248251A (en) * | 1990-11-26 | 1993-09-28 | Catalytica, Inc. | Graded palladium-containing partial combustion catalyst and a process for using it |
GB9122788D0 (en) | 1991-10-26 | 1991-12-11 | Johnson Matthey Plc | Catalyst |
US5198580A (en) | 1991-11-18 | 1993-03-30 | The Standard Oil Company | Process for oxidation of propane |
US5317805A (en) | 1992-04-28 | 1994-06-07 | Minnesota Mining And Manufacturing Company | Method of making microchanneled heat exchangers utilizing sacrificial cores |
US5258543A (en) | 1992-06-26 | 1993-11-02 | The Standard Oil Company | Method for ammoxidation of olefins |
EP0584887B1 (en) | 1992-08-28 | 1999-10-06 | Union Carbide Chemicals & Plastics Technology Corporation | Catalysts for treating exhaust gases from internal combustion and stationary source engines |
US5309637A (en) | 1992-10-13 | 1994-05-10 | Rockwell International Corporation | Method of manufacturing a micro-passage plate fin heat exchanger |
US5399537A (en) * | 1992-12-21 | 1995-03-21 | Amoco Corporation | Method for preparing synthesis gas using nickel catalysts |
JP3512186B2 (ja) | 1993-03-19 | 2004-03-29 | イー・アイ・デユポン・ドウ・ヌムール・アンド・カンパニー | 化学処理及び製造のための一体構造及び方法、並びにその使用方法及び製造方法 |
US5648582A (en) * | 1993-08-20 | 1997-07-15 | Regents Of The University Of Minnesota | Stable, ultra-low residence time partial oxidation |
US5727618A (en) | 1993-08-23 | 1998-03-17 | Sdl Inc | Modular microchannel heat exchanger |
EP0640561B1 (en) | 1993-08-24 | 1998-11-11 | Shell Internationale Researchmaatschappij B.V. | Process for the catalytic partial oxidation of hydrocarbons |
JPH07251983A (ja) * | 1994-03-11 | 1995-10-03 | Canon Aptecs Kk | プリント媒体供給装置、該装置を具えたプリンタおよびプリント媒体巻取り装置 |
KR100247524B1 (ko) | 1994-05-31 | 2000-03-15 | 겐지 아이다 | 아크릴산 제조용 촉매 및 이 촉매를 이용한 아크릴산의 제조방법 |
TW349033B (en) | 1994-05-31 | 1999-01-01 | Nippon Catalytic Chem Ind | Catalyst for production of methacrylic acid and method for production of methacrylic acid by the use of the catalysta catalyst for the production of methacrylic acid by the vapor-phase catalytic oxidation and/or oxidative dehydrogenation of at least one compound |
US6126723A (en) | 1994-07-29 | 2000-10-03 | Battelle Memorial Institute | Microcomponent assembly for efficient contacting of fluid |
US5611214A (en) | 1994-07-29 | 1997-03-18 | Battelle Memorial Institute | Microcomponent sheet architecture |
US6129973A (en) | 1994-07-29 | 2000-10-10 | Battelle Memorial Institute | Microchannel laminated mass exchanger and method of making |
US5811062A (en) * | 1994-07-29 | 1998-09-22 | Battelle Memorial Institute | Microcomponent chemical process sheet architecture |
IT1273491B (it) | 1995-02-03 | 1997-07-08 | Snam Progetti | Materiale avente struttura a strati tipo idrotalcite e relativi usi |
GR1002714B (el) | 1995-05-03 | 1997-06-10 | Zhang Zhaolong | Καταλυτες για τη μερικη οξειδωση ελαφρων υδρογονανθρακων προς αεριο συνθεσης. |
DE69628016T2 (de) | 1995-06-16 | 2004-04-01 | University Of Washington, Seattle | Miniaturisierte differentielle extraktionsvorrichtung und verfahren |
US5727616A (en) * | 1995-10-27 | 1998-03-17 | Edentec | Elastomeric heat exchanger bed |
DE19608824A1 (de) | 1996-03-07 | 1997-09-18 | Inst Mikrotechnik Mainz Gmbh | Verfahren zur Herstellung von Mikrowärmetauschern |
US5858314A (en) | 1996-04-12 | 1999-01-12 | Ztek Corporation | Thermally enhanced compact reformer |
DE19622331A1 (de) | 1996-06-04 | 1997-12-11 | Basf Ag | Verfahren der heterogen katalysierten Gasphasenoxidation von Propan zu Acrolein |
US5828314A (en) * | 1996-10-16 | 1998-10-27 | Seiko Communication Systems | Pager with adaptable alarm |
GB9626516D0 (en) | 1996-12-20 | 1997-02-05 | Ici Plc | Ammonia oxidation |
FR2760008A1 (fr) | 1997-02-27 | 1998-08-28 | Atochem Elf Sa | Procede de fabrication d'acroleine a partir du propylene par reaction redox et utilisation d'une composition solide d'oxydes mixtes comme systeme redox dans ladite reaction |
GB2322633A (en) | 1997-02-28 | 1998-09-02 | Norske Stats Oljeselskap | Fischer-Tropsch reactor |
ATE292779T1 (de) | 1997-06-03 | 2005-04-15 | Chart Heat Exchangers Ltd Part | Wärmetauscher und/oder vorrichtung zur mischung von fluiden |
US6200536B1 (en) | 1997-06-26 | 2001-03-13 | Battelle Memorial Institute | Active microchannel heat exchanger |
US6437193B1 (en) | 1997-07-15 | 2002-08-20 | E. I. Du Pont De Nemours And Company | Vapor phase oxidation of propylene to acrolein |
US6907921B2 (en) | 1998-06-18 | 2005-06-21 | 3M Innovative Properties Company | Microchanneled active fluid heat exchanger |
GB9723260D0 (en) | 1997-11-05 | 1998-01-07 | British Nuclear Fuels Plc | A method of performing a chemical reaction |
US6127571A (en) | 1997-11-11 | 2000-10-03 | Uop Llc | Controlled reactant injection with permeable plates |
US6030920A (en) | 1997-12-24 | 2000-02-29 | Saudi Basic Industries Corporation | Catalysts for producing acetic acid from ethane oxidation, processes of making same and method of using same |
DE19801374C1 (de) | 1998-01-16 | 1999-03-11 | Dbb Fuel Cell Engines Gmbh | Verfahren zum Löten von metallischen mikrostrukturierten Blechen |
JP3749391B2 (ja) | 1998-03-04 | 2006-02-22 | トヨタ自動車株式会社 | 排ガス浄化用触媒及びその製造方法 |
GB9806199D0 (en) | 1998-03-24 | 1998-05-20 | Johnson Matthey Plc | Catalytic generation of hydrogen |
US6028221A (en) | 1998-06-29 | 2000-02-22 | Saudi Basic Industries Corporation | Catalyst systems for the one step gas phase production of acetic acid from ethylene and methods of making and using the same |
US6540975B2 (en) | 1998-07-27 | 2003-04-01 | Battelle Memorial Institute | Method and apparatus for obtaining enhanced production rate of thermal chemical reactions |
US6616909B1 (en) | 1998-07-27 | 2003-09-09 | Battelle Memorial Institute | Method and apparatus for obtaining enhanced production rate of thermal chemical reactions |
US6440895B1 (en) * | 1998-07-27 | 2002-08-27 | Battelle Memorial Institute | Catalyst, method of making, and reactions using the catalyst |
US6479428B1 (en) | 1998-07-27 | 2002-11-12 | Battelle Memorial Institute | Long life hydrocarbon conversion catalyst and method of making |
DE19837518A1 (de) | 1998-08-19 | 2000-02-24 | Basf Ag | Verfahren zur Herstellung von Acrolein und/oder Acrylsäure aus Propan |
DE19837519A1 (de) | 1998-08-19 | 2000-02-24 | Basf Ag | Verfahren zur Herstellung von Acrolein und/oder Acrylsäure aus Propan |
DE19837517A1 (de) | 1998-08-19 | 2000-02-24 | Basf Ag | Verfahren zur Herstellung von Acrolein und/oder Acrylsäure aus Propan |
US6100436A (en) | 1998-09-08 | 2000-08-08 | Uop Llc | Process and apparatus for controlling reaction temperatures with heating arrangement in series flow |
US6632772B2 (en) | 1998-09-23 | 2003-10-14 | Lg Chemical, Ltd. | Method of coating a catalyst to a support for use in acrolein oxidation |
US6381646B2 (en) * | 1998-11-03 | 2002-04-30 | Cisco Technology, Inc. | Multiple network connections from a single PPP link with partial network address translation |
US6268529B1 (en) | 1998-12-08 | 2001-07-31 | The Standard Oil Company | Method for the manufacture of acrylic acid |
US6310240B1 (en) | 1998-12-23 | 2001-10-30 | E. I. Du Pont De Nemours And Company | Vapor phase oxidation of acrolein to acrylic acid |
US6749814B1 (en) | 1999-03-03 | 2004-06-15 | Symyx Technologies, Inc. | Chemical processing microsystems comprising parallel flow microreactors and methods for using same |
US6192596B1 (en) * | 1999-03-08 | 2001-02-27 | Battelle Memorial Institute | Active microchannel fluid processing unit and method of making |
DE19910508A1 (de) | 1999-03-10 | 2000-09-21 | Basf Ag | Verfahren der katalytischen Gasphasenoxidation von Acrolein zu Acrylsäure |
MY121141A (en) | 1999-03-10 | 2005-12-30 | Basf Ag | Method for the catalytic gas-phase oxidation of propene into acrolein |
GB9907704D0 (en) | 1999-04-01 | 1999-05-26 | Bp Chem Int Ltd | Catalyst and process utilising the catalyst |
KR100315225B1 (ko) * | 1999-05-11 | 2001-11-26 | 김순택 | 저전압용 분홍색 형광체 |
US6143921A (en) | 1999-05-14 | 2000-11-07 | Saudi Basic Industries Corporation | Method for producing vinyl acetate monomer from ethane or ethylene oxidation |
JP4185217B2 (ja) | 1999-05-25 | 2008-11-26 | 株式会社日本触媒 | 複合酸化物触媒、並びに(メタ)アクロレインおよび(メタ)アクリル酸の製造方法 |
US6675875B1 (en) | 1999-08-06 | 2004-01-13 | The Ohio State University | Multi-layered micro-channel heat sink, devices and systems incorporating same |
GB9918586D0 (en) | 1999-08-07 | 1999-10-06 | British Gas Plc | Compact reactor |
US6746651B1 (en) | 1999-08-10 | 2004-06-08 | Aerojet-General Corporation | Axial flow catalyst pack |
AU779487B2 (en) * | 1999-08-17 | 2005-01-27 | Battelle Memorial Institute | Chemical reactor and method for catalytic gas phase reactions |
US6969506B2 (en) | 1999-08-17 | 2005-11-29 | Battelle Memorial Institute | Methods of conducting simultaneous exothermic and endothermic reactions |
US6216343B1 (en) | 1999-09-02 | 2001-04-17 | The United States Of America As Represented By The Secretary Of The Air Force | Method of making micro channel heat pipe having corrugated fin elements |
KR100336969B1 (ko) | 1999-09-30 | 2002-05-17 | 김충섭 | 코아-쉘 구조를 갖는 고체촉매를 이용한 아크롤레인의 제조방법 |
US6409940B1 (en) * | 1999-10-18 | 2002-06-25 | Conoco Inc. | Nickel-rhodium based catalysts and process for preparing synthesis gas |
US6313393B1 (en) | 1999-10-21 | 2001-11-06 | Battelle Memorial Institute | Heat transfer and electric-power-generating component containing a thermoelectric device |
DE19955969A1 (de) | 1999-11-19 | 2001-05-31 | Inst Mikrotechnik Mainz Gmbh | Verwendung von Polyimid für Haftschichten und lithographisches Verfahren zur Herstellung von Mikrobauteilen |
WO2001037988A1 (fr) | 1999-11-25 | 2001-05-31 | Kawasaki Jukogyo Kabushiki Kaisha | Catalyseur pour la reaction exothermique ou endothermique, catalyseur pour la reaction de conversion et catalyseur pour l'oxydation selective de monoxyde de carbone et reformeur du type a echange de chaleur a ailette en plaques |
US6770245B2 (en) | 1999-12-15 | 2004-08-03 | Uop Llc | Multiple parallel processing assembly |
US6341577B1 (en) * | 1999-12-21 | 2002-01-29 | H. Kenneth Holyoak | Apparatus and method for feeding frogs cultivated in captivity |
US20020012624A1 (en) | 2000-01-07 | 2002-01-31 | Figueroa Juan C. | Bulk nickel alloy catalysts and process for production of syngas |
AU3648701A (en) | 2000-01-21 | 2001-07-31 | Conoco Inc. | Thermal shock resistant catalysts for synthesis gas production |
US6415860B1 (en) | 2000-02-09 | 2002-07-09 | Board Of Supervisors Of Louisiana State University And Agricultural And Mechanical College | Crossflow micro heat exchanger |
DE10007764A1 (de) | 2000-02-20 | 2001-08-23 | Gen Motors Corp | Brennerelement |
US6486091B1 (en) | 2000-03-14 | 2002-11-26 | Saudi Basic Industries Corporation | Process for making highly active and selective catalysts for the production of unsaturated nitriles |
US6561208B1 (en) | 2000-04-14 | 2003-05-13 | Nanostream, Inc. | Fluidic impedances in microfluidic system |
US6746658B2 (en) | 2000-04-20 | 2004-06-08 | Conocophillips Company | Rhodium cloth catalyst for partial oxidation of hydrocarbons |
US7125540B1 (en) | 2000-06-06 | 2006-10-24 | Battelle Memorial Institute | Microsystem process networks |
US6441227B1 (en) | 2000-06-23 | 2002-08-27 | Saudi Basic Industries Corporation | Two stage process for the production of unsaturated carboxylic acids by oxidation of lower unsaturated hydrocarbons |
DE10036602A1 (de) | 2000-07-27 | 2002-02-14 | Cpc Cellular Process Chemistry | Mikroreaktor für Reaktionen zwischen Gasen und Flüssigkeiten |
DE60123817T2 (de) * | 2000-07-28 | 2007-05-16 | Honda Giken Kogyo K.K. | Mehrzweck-mikrobauteil mit mikrokanälen |
AU2001283076A1 (en) | 2000-08-14 | 2002-02-25 | Chevron U.S.A. Inc. | Use of microchannel reactors in combinatorial chemistry |
DE10040209A1 (de) * | 2000-08-17 | 2002-02-28 | Linde Ag | Reaktor zur Durchführung einer stark wärmegetönten katalytischen Reaktion |
DE10041823C2 (de) | 2000-08-25 | 2002-12-19 | Inst Mikrotechnik Mainz Gmbh | Verfahren und statischer Mikrovermischer zum Mischen mindestens zweier Fluide |
ATE368001T1 (de) | 2000-09-05 | 2007-08-15 | Conocophillips Co | Verfahren zur herstellung von synthesegas mit lanthanid-dotierter rhodiumkatalysatoren |
US7081312B1 (en) * | 2000-09-26 | 2006-07-25 | General Motors Corporation | Multiple stage combustion process to maintain a controllable reformation temperature profile |
SE0004297D0 (sv) | 2000-11-23 | 2000-11-23 | Gyros Ab | Device for thermal cycling |
US6773684B2 (en) | 2001-01-26 | 2004-08-10 | Utc Fuel Cells, Llc | Compact fuel gas reformer assemblage |
US6681788B2 (en) | 2001-01-29 | 2004-01-27 | Caliper Technologies Corp. | Non-mechanical valves for fluidic systems |
WO2002066403A1 (en) | 2001-02-16 | 2002-08-29 | Conoco Inc. | Supported rhodium-spinel catalysts and process for producing synthesis gas |
DE10108716A1 (de) | 2001-02-23 | 2002-09-19 | Clariant Gmbh | Verfahren und Vorrichtung zur kontinuierlichen Redox-Regelung bei Azokupplungen |
WO2002083291A1 (de) | 2001-04-12 | 2002-10-24 | Mir-Chem Gmbh | Vorrichtung und verfahren zum katalytischen reformieren von kohlenwasserstoffen oder alkoholen |
US6508862B1 (en) | 2001-04-30 | 2003-01-21 | Battelle Memorial Institute | Apparatus and methods for separation/purification utilizing rapidly cycled thermal swing sorption |
DE10123093A1 (de) | 2001-05-07 | 2002-11-21 | Inst Mikrotechnik Mainz Gmbh | Verfahren und statischer Mikrovermischer zum Mischen mindestens zweier Fluide |
EP1389271B1 (en) | 2001-05-23 | 2006-07-12 | Svenska Rymdaktiebolaget | Reactor for decomposition of ammonium dinitramide-based liquid monopropellants and process for the decomposition |
US6756515B2 (en) | 2001-06-22 | 2004-06-29 | Uop Llc | Dehydrogenation process using layered catalyst composition |
DE10146545A1 (de) | 2001-09-21 | 2003-04-10 | Merck Patent Gmbh | Mikrokomponente |
FR2830206B1 (fr) | 2001-09-28 | 2004-07-23 | Corning Inc | Dispositif microfluidique et sa fabrication |
CA2478333C (en) * | 2002-03-11 | 2013-10-15 | Battelle Memorial Institute | Microchannel reactors with temperature control |
US6756340B2 (en) | 2002-04-08 | 2004-06-29 | Uop Llc | Dehydrogenation catalyst composition |
US7402719B2 (en) | 2002-06-13 | 2008-07-22 | Velocys | Catalytic oxidative dehydrogenation, and microchannel reactors for catalytic oxidative dehydrogenation |
JP2004041867A (ja) | 2002-07-09 | 2004-02-12 | Daihatsu Motor Co Ltd | 排ガス浄化用触媒 |
US7097787B2 (en) | 2002-07-19 | 2006-08-29 | Conocophillips Company | Utilization of micro-channel gas distributor to distribute unreacted feed gas into reactors |
EP1525154A2 (en) | 2002-07-30 | 2005-04-27 | Hyradix Inc. | Feedforward control processes for variable output hydrogen generators |
AU2003298540A1 (en) | 2002-08-02 | 2004-05-25 | Avery Dennison Corporation | Process and apparatus for microreplication |
US6969505B2 (en) | 2002-08-15 | 2005-11-29 | Velocys, Inc. | Process for conducting an equilibrium limited chemical reaction in a single stage process channel |
US20040032036A1 (en) | 2002-08-19 | 2004-02-19 | Anandaraman Subramaniam | Process for the preparation of flavor or fragrance microcapsules |
WO2004035194A2 (en) | 2002-10-16 | 2004-04-29 | Conocophillips Company | High hydrothermal stability catalyst support |
US7404936B2 (en) * | 2002-10-22 | 2008-07-29 | Velocys | Catalysts, in microchannel apparatus, and reactions using same |
EP1415706B1 (en) | 2002-10-29 | 2017-07-12 | Corning Incorporated | Coated microstructure and method of manufacture |
EP1562742A4 (en) | 2002-10-31 | 2008-08-06 | Georgia Tech Res Inst | MICROSTRUCTURES AND MANUFACTURING METHOD THEREFOR |
US6986382B2 (en) | 2002-11-01 | 2006-01-17 | Cooligy Inc. | Interwoven manifolds for pressure drop reduction in microchannel heat exchangers |
US7276540B2 (en) | 2002-11-11 | 2007-10-02 | Conocophillips Company | Supports for high surface area catalysts |
EP1567254A2 (en) | 2002-11-11 | 2005-08-31 | Conocophillips Company | Novel syngas catalysts and their method of use |
DE10253519A1 (de) | 2002-11-16 | 2004-06-03 | Ehrfeld Mikrotechnik Ag | Verfahren zur Ermittlung optimaler Reaktionswege und Prozessbedingungen zur Synthese chemischer Verbindungen in Mikroreaktionssystemen und zur Durchführung der Synthese |
DE60307885T3 (de) | 2002-12-02 | 2010-12-16 | Compactgtl Plc, Abingdon | Katalytisches verfahren |
US6802889B2 (en) | 2002-12-05 | 2004-10-12 | Air Products And Chemicals, Inc. | Pressure swing adsorption system for gas separation |
US7141217B2 (en) | 2002-12-05 | 2006-11-28 | Uop Llc | Elevated pressure apparatus and method for generating a plurality of isolated effluents |
JP4527384B2 (ja) | 2002-12-06 | 2010-08-18 | 綜研化学株式会社 | マイクロチャンネルを用いた着色球状粒子の製造方法、およびその製造方法に用いるマイクロチャンネル式製造装置 |
DE20218972U1 (de) | 2002-12-07 | 2003-02-13 | Ehrfeld Mikrotechnik AG, 55234 Wendelsheim | Statischer Laminationsmikrovermischer |
GB0229348D0 (en) | 2002-12-17 | 2003-01-22 | Glaxo Group Ltd | A mixing apparatus and method |
US20040131517A1 (en) | 2003-01-03 | 2004-07-08 | Akporiaye Duncan E. | Material heat treatment system and method |
US20040132209A1 (en) | 2003-01-03 | 2004-07-08 | Alexanian Ara J. | Multi-chamber treatment apparatus and method |
US7267987B2 (en) | 2003-01-06 | 2007-09-11 | Uop Llc | Process and assembly for simultaneously evaluating a plurality of catalysts |
US20060133957A1 (en) | 2003-01-17 | 2006-06-22 | Knapp Merrill A | Device and method for fragmenting material by hydrodynamic shear |
DE10301874A1 (de) | 2003-01-17 | 2004-07-29 | Celanese Emulsions Gmbh | Verfahren und Vorrichtung zur Herstellung von Emulsionspolymerisaten |
US20040141893A1 (en) | 2003-01-21 | 2004-07-22 | Martin Jerry L. | Chemical reactor with enhanced heat exchange |
DE10303581A1 (de) | 2003-01-30 | 2004-08-12 | Clariant Gmbh | Acetoacetylierung von Alkoholen, Thiolen und Aminen im Mikroreaktor |
EP1594798B1 (en) | 2003-01-30 | 2018-12-19 | Gyros Patent Ab | Inner walls of microfluidic devices |
US7220390B2 (en) * | 2003-05-16 | 2007-05-22 | Velocys, Inc. | Microchannel with internal fin support for catalyst or sorption medium |
WO2005032693A2 (en) * | 2003-08-29 | 2005-04-14 | Velocys Inc. | Process for separating nitrogen from methane using microchannel process technology |
US20050269069A1 (en) * | 2004-06-04 | 2005-12-08 | American Standard International, Inc. | Heat transfer apparatus with enhanced micro-channel heat transfer tubing |
US7507274B2 (en) * | 2005-03-02 | 2009-03-24 | Velocys, Inc. | Separation process using microchannel technology |
-
2003
- 2003-05-16 US US10/440,053 patent/US7220390B2/en not_active Expired - Fee Related
- 2003-05-30 US US10/449,913 patent/US7226574B2/en not_active Expired - Fee Related
-
2004
- 2004-04-08 WO PCT/US2004/010945 patent/WO2004103550A1/en active Application Filing
- 2004-04-08 EP EP04749913A patent/EP1631376A1/en not_active Withdrawn
- 2004-04-08 CA CA2525733A patent/CA2525733C/en not_active Expired - Fee Related
- 2004-04-08 AU AU2004241943A patent/AU2004241943B2/en not_active Ceased
- 2004-04-08 JP JP2006532390A patent/JP5087276B2/ja not_active Expired - Fee Related
- 2004-04-08 CA CA2829163A patent/CA2829163C/en not_active Expired - Fee Related
- 2004-04-08 CN CNB200480019997XA patent/CN100531890C/zh not_active Expired - Fee Related
- 2004-04-08 EP EP12158836A patent/EP2463024A1/en not_active Withdrawn
- 2004-04-08 JP JP2006532382A patent/JP4768619B2/ja not_active Expired - Fee Related
- 2004-04-08 CN CNB2004800203373A patent/CN100423826C/zh not_active Expired - Fee Related
- 2004-04-08 RU RU2005139413/15A patent/RU2005139413A/ru not_active Application Discontinuation
-
2006
- 2006-12-28 US US11/617,158 patent/US7896935B2/en not_active Expired - Fee Related
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0840703A (ja) * | 1994-05-23 | 1996-02-13 | Ngk Insulators Ltd | 水素製造装置 |
JP2003507288A (ja) * | 1999-08-17 | 2003-02-25 | バッテル・メモリアル・インスティチュート | 気相反応物質触媒反応用化学反応器及び方法 |
US20020009406A1 (en) * | 2000-02-18 | 2002-01-24 | Kostantinos Kourtakis | Chromium-rare earth based catalysts and process for converting hydrocarbons to synthesis gas |
US20050119355A1 (en) * | 2001-06-21 | 2005-06-02 | Cuong Pham-Huu | Method for obtaining synthesis gas by partial catalytic oxidation |
Also Published As
Publication number | Publication date |
---|---|
CA2829163C (en) | 2016-01-19 |
CN100423826C (zh) | 2008-10-08 |
WO2004103550A1 (en) | 2004-12-02 |
US7226574B2 (en) | 2007-06-05 |
US20040229752A1 (en) | 2004-11-18 |
CA2525733A1 (en) | 2004-12-02 |
RU2005139413A (ru) | 2006-05-10 |
JP5087276B2 (ja) | 2012-12-05 |
JP2007534457A (ja) | 2007-11-29 |
US7220390B2 (en) | 2007-05-22 |
EP2463024A1 (en) | 2012-06-13 |
CN1835795A (zh) | 2006-09-20 |
US20040228781A1 (en) | 2004-11-18 |
JP2007515362A (ja) | 2007-06-14 |
CA2829163A1 (en) | 2004-12-02 |
AU2004241943A1 (en) | 2004-12-02 |
CA2525733C (en) | 2015-06-23 |
EP1631376A1 (en) | 2006-03-08 |
US7896935B2 (en) | 2011-03-01 |
AU2004241943B2 (en) | 2010-05-13 |
US20070140955A1 (en) | 2007-06-21 |
CN100531890C (zh) | 2009-08-26 |
CN1822898A (zh) | 2006-08-23 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP4768619B2 (ja) | マイクロチャネル技術を用いる酸化方法およびそのために有用な新規触媒 | |
AU2004241941B2 (en) | Oxidation process using microchannel technology and novel catalyst useful in same | |
US9216402B2 (en) | Reactor and catalyst for converting natural gas to organic compounds | |
US7858667B2 (en) | Alcohol synthesis from CO or CO2 | |
US6616909B1 (en) | Method and apparatus for obtaining enhanced production rate of thermal chemical reactions | |
CA2657485C (en) | Method and apparatus for obtaining enhanced production rate of thermal chemical reactions | |
US9011781B2 (en) | Catalysts having catalytic material applied directly to thermally-grown alumina and catalytic methods using same; improved methods of oxidative dehydrogenation | |
EA034971B1 (ru) | Процесс фишера-тропша | |
CA2438714C (en) | A catalyst and method of steam reforming | |
US8158550B2 (en) | Multilayer catalyst, process for the preparation and use thereof in the partial oxidation of hydrocarbons in gaseous phase | |
WO2019204600A1 (en) | Small channel short fixed bed adiabatic reactor for oxidative coupling of methane | |
US20060083672A1 (en) | Methods of conducting catalytic combustion in a multizone reactor, and a method of making a thermally stable catalyst support | |
AU2013273714A1 (en) | Alcohol synthesis from CO or CO2 | |
RU2248240C1 (ru) | Катализатор, способ его приготовления и способ получения синтез-газа | |
WO2006044819A2 (en) | Stable, catalyzed, high temperature combustion in microchannel, integrated combustion reactors, methods of conducting catalytic combustion in a multizone reactor, and method of making a thermally stable catalyst support | |
ZA200306076B (en) | A catalyst and method of steam reforming. |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20070405 |
|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20070405 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20100615 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20100910 |
|
A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20100917 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20101124 |
|
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20110607 |
|
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20110616 |
|
R150 | Certificate of patent or registration of utility model |
Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20140624 Year of fee payment: 3 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
LAPS | Cancellation because of no payment of annual fees |