JP4751917B2 - 排ガス浄化用触媒 - Google Patents
排ガス浄化用触媒 Download PDFInfo
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- JP4751917B2 JP4751917B2 JP2008170808A JP2008170808A JP4751917B2 JP 4751917 B2 JP4751917 B2 JP 4751917B2 JP 2008170808 A JP2008170808 A JP 2008170808A JP 2008170808 A JP2008170808 A JP 2008170808A JP 4751917 B2 JP4751917 B2 JP 4751917B2
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- Prior art keywords
- catalyst layer
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- 239000003054 catalyst Substances 0.000 title claims description 215
- 238000000746 purification Methods 0.000 title claims description 31
- 239000010410 layer Substances 0.000 claims description 242
- 238000011144 upstream manufacturing Methods 0.000 claims description 31
- 239000000463 material Substances 0.000 claims description 23
- 239000002356 single layer Substances 0.000 claims description 3
- 239000007789 gas Substances 0.000 description 82
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 60
- KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium Substances [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 57
- 239000010948 rhodium Substances 0.000 description 40
- 239000000758 substrate Substances 0.000 description 29
- 239000000843 powder Substances 0.000 description 18
- 239000002002 slurry Substances 0.000 description 17
- 230000000694 effects Effects 0.000 description 14
- 239000002131 composite material Substances 0.000 description 12
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 11
- 239000001301 oxygen Substances 0.000 description 11
- 229910052760 oxygen Inorganic materials 0.000 description 11
- 229910021193 La 2 O 3 Inorganic materials 0.000 description 10
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 9
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 9
- 229910052697 platinum Inorganic materials 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 7
- 230000007423 decrease Effects 0.000 description 6
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 5
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 description 5
- 239000000446 fuel Substances 0.000 description 5
- 229910000510 noble metal Inorganic materials 0.000 description 5
- 229910052703 rhodium Inorganic materials 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 description 4
- 229910052763 palladium Inorganic materials 0.000 description 4
- 230000010718 Oxidation Activity Effects 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 230000003197 catalytic effect Effects 0.000 description 3
- 229910052878 cordierite Inorganic materials 0.000 description 3
- JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical compound [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 description 3
- 239000012153 distilled water Substances 0.000 description 3
- 229910052746 lanthanum Inorganic materials 0.000 description 3
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 3
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- MMKQUGHLEMYQSG-UHFFFAOYSA-N oxygen(2-);praseodymium(3+) Chemical compound [O-2].[O-2].[O-2].[Pr+3].[Pr+3] MMKQUGHLEMYQSG-UHFFFAOYSA-N 0.000 description 3
- 238000005192 partition Methods 0.000 description 3
- 229910003447 praseodymium oxide Inorganic materials 0.000 description 3
- 229920006395 saturated elastomer Polymers 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 229910052727 yttrium Inorganic materials 0.000 description 3
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 3
- 229910002651 NO3 Inorganic materials 0.000 description 2
- 229910017493 Nd 2 O 3 Inorganic materials 0.000 description 2
- 229910052779 Neodymium Inorganic materials 0.000 description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 2
- 230000010757 Reduction Activity Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 239000010970 precious metal Substances 0.000 description 2
- -1 SiC Chemical compound 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000001174 ascending effect Effects 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- PLDDOISOJJCEMH-UHFFFAOYSA-N neodymium oxide Inorganic materials [O-2].[O-2].[O-2].[Nd+3].[Nd+3] PLDDOISOJJCEMH-UHFFFAOYSA-N 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/19—Catalysts containing parts with different compositions
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/9445—Simultaneously removing carbon monoxide, hydrocarbons or nitrogen oxides making use of three-way catalysts [TWC] or four-way-catalysts [FWC]
- B01D53/945—Simultaneously removing carbon monoxide, hydrocarbons or nitrogen oxides making use of three-way catalysts [TWC] or four-way-catalysts [FWC] characterised by a specific catalyst
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- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
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- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/46—Ruthenium, rhodium, osmium or iridium
- B01J23/464—Rhodium
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
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- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/024—Multiple impregnation or coating
- B01J37/0244—Coatings comprising several layers
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- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
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- B01J37/024—Multiple impregnation or coating
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- B01D2258/014—Stoichiometric gasoline engines
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/9459—Removing one or more of nitrogen oxides, carbon monoxide, or hydrocarbons by multiple successive catalytic functions; systems with more than one different function, e.g. zone coated catalysts
- B01D53/9477—Removing one or more of nitrogen oxides, carbon monoxide, or hydrocarbons by multiple successive catalytic functions; systems with more than one different function, e.g. zone coated catalysts with catalysts positioned on separate bricks, e.g. exhaust systems
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
- B01J35/56—Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional monoliths
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/10—Capture or disposal of greenhouse gases of nitrous oxide (N2O)
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/12—Improving ICE efficiencies
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- Biomedical Technology (AREA)
- Environmental & Geological Engineering (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
- Catalysts (AREA)
- Exhaust Gas After Treatment (AREA)
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2008170808A JP4751917B2 (ja) | 2008-06-30 | 2008-06-30 | 排ガス浄化用触媒 |
PCT/IB2009/006122 WO2010001226A1 (fr) | 2008-06-30 | 2009-06-29 | Catalyseur feuilleté de purification des gaz d'échappement comprenant différents métaux nobles |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2008170808A JP4751917B2 (ja) | 2008-06-30 | 2008-06-30 | 排ガス浄化用触媒 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2010005590A JP2010005590A (ja) | 2010-01-14 |
JP4751917B2 true JP4751917B2 (ja) | 2011-08-17 |
Family
ID=41057369
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2008170808A Active JP4751917B2 (ja) | 2008-06-30 | 2008-06-30 | 排ガス浄化用触媒 |
Country Status (2)
Country | Link |
---|---|
JP (1) | JP4751917B2 (fr) |
WO (1) | WO2010001226A1 (fr) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2018016606A1 (fr) | 2016-07-20 | 2018-01-25 | ユミコア日本触媒株式会社 | Catalyseur de purification de gaz d'échappement pour moteur à combustion interne, et procédé de purification de gaz d'échappement utilisant le catalyseur de purification de gaz d'échappement |
EP3662997A1 (fr) | 2016-07-20 | 2020-06-10 | Umicore Shokubai Japan Co., Ltd. | Catalyseur pour la purification de gaz d'échappement d'un moteur à combustion interne, ainsi qu'un procédé de purification de gaz d'échappement en utilisant ledit catalyseur |
Families Citing this family (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPWO2011118047A1 (ja) * | 2010-03-24 | 2013-07-04 | トヨタ自動車株式会社 | 排ガス浄化用触媒 |
US8557204B2 (en) * | 2010-11-22 | 2013-10-15 | Umicore Ag & Co. Kg | Three-way catalyst having an upstream single-layer catalyst |
JP5287884B2 (ja) * | 2011-01-27 | 2013-09-11 | トヨタ自動車株式会社 | 排ガス浄化用触媒 |
WO2012140775A1 (fr) * | 2011-04-15 | 2012-10-18 | トヨタ自動車株式会社 | Epurateur d'échappement pour moteur à combustion interne |
JP5720949B2 (ja) * | 2011-12-08 | 2015-05-20 | トヨタ自動車株式会社 | 排ガス浄化用触媒 |
JP5780247B2 (ja) | 2013-01-23 | 2015-09-16 | トヨタ自動車株式会社 | 触媒コンバーター |
JP5757297B2 (ja) | 2013-01-23 | 2015-07-29 | トヨタ自動車株式会社 | 触媒コンバーター |
JP5888259B2 (ja) | 2013-02-13 | 2016-03-16 | トヨタ自動車株式会社 | 触媒コンバーター |
JP5821887B2 (ja) | 2013-04-03 | 2015-11-24 | トヨタ自動車株式会社 | 触媒コンバーター |
JP6133836B2 (ja) | 2014-12-12 | 2017-05-24 | トヨタ自動車株式会社 | 排ガス浄化触媒 |
JP6133835B2 (ja) * | 2014-12-12 | 2017-05-24 | トヨタ自動車株式会社 | 排ガス浄化触媒 |
JP6034356B2 (ja) * | 2014-12-12 | 2016-11-30 | トヨタ自動車株式会社 | 排ガス浄化触媒 |
CN110785231B (zh) | 2017-04-28 | 2022-09-23 | 优美科触媒日本有限公司 | 废气净化用催化剂及使用其的废气净化方法 |
JP6889252B2 (ja) | 2017-04-28 | 2021-06-18 | ユミコア日本触媒株式会社 | 排気ガス浄化用触媒およびそれを用いた排気ガス浄化方法 |
WO2018199250A1 (fr) | 2017-04-28 | 2018-11-01 | ユミコア日本触媒株式会社 | Catalyseur de purification de gaz d'échappement et procédé de purification de gaz d'échappement l'utilisant |
JP7451402B2 (ja) | 2017-12-08 | 2024-03-18 | ジョンソン マッセイ (シャンハイ) ケミカルズ リミテッド | ガソリンエンジンからの排気ガス処理のための新規多領域twc |
US11110436B2 (en) | 2017-12-28 | 2021-09-07 | Umicore Shokubai Japan Co., Ltd. | Phosphorus compound-containing exhaust gas purifying catalyst |
JP7195995B2 (ja) | 2019-03-27 | 2022-12-26 | 株式会社キャタラー | 排ガス浄化用触媒 |
JP6775052B2 (ja) * | 2019-03-27 | 2020-10-28 | 株式会社キャタラー | 排ガス浄化用触媒 |
BR112022011865A2 (pt) * | 2019-12-19 | 2022-09-06 | Basf Corp | Artigo de catalisador, processos para a preparação de um artigo de catalisador, aparelho para preparar o artigo catalítico, sistema de exaustão, métodos para tratar uma corrente de exaustão e para reduzir os níveis de hidrocarbonetos, monóxido de carbono e óxido de nitrogênio e uso do catalisador |
JP7434489B1 (ja) * | 2022-10-18 | 2024-02-20 | 株式会社キャタラー | 排ガス浄化用触媒およびこれを用いた触媒体 |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6384635A (ja) * | 1986-09-26 | 1988-04-15 | Nissan Motor Co Ltd | 排気ガス浄化用触媒 |
JPS63236541A (ja) * | 1987-03-24 | 1988-10-03 | Nissan Motor Co Ltd | 排ガス浄化用触媒 |
JPH05293384A (ja) * | 1992-04-15 | 1993-11-09 | Nissan Motor Co Ltd | 排ガス浄化用触媒及び排ガス浄化方法 |
US5376610A (en) * | 1992-04-15 | 1994-12-27 | Nissan Motor Co., Ltd. | Catalyst for exhaust gas purification and method for exhaust gas purification |
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JP4350250B2 (ja) * | 2000-01-27 | 2009-10-21 | 株式会社キャタラー | 排気ガス浄化用触媒 |
US20040001781A1 (en) * | 2002-06-27 | 2004-01-01 | Engelhard Corporation | Multi-zone catalytic converter |
JP4238056B2 (ja) * | 2003-03-31 | 2009-03-11 | 三井金属鉱業株式会社 | 排ガス浄化用層状触媒 |
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2008
- 2008-06-30 JP JP2008170808A patent/JP4751917B2/ja active Active
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2009
- 2009-06-29 WO PCT/IB2009/006122 patent/WO2010001226A1/fr active Application Filing
Cited By (5)
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WO2018016606A1 (fr) | 2016-07-20 | 2018-01-25 | ユミコア日本触媒株式会社 | Catalyseur de purification de gaz d'échappement pour moteur à combustion interne, et procédé de purification de gaz d'échappement utilisant le catalyseur de purification de gaz d'échappement |
US10654030B2 (en) | 2016-07-20 | 2020-05-19 | Umicore Shokubai Japan Co., Ltd. | Exhaust gas purification catalyst for internal combustion engine, and exhaust gas purifying method using exhaust gas purification catalyst |
EP3662997A1 (fr) | 2016-07-20 | 2020-06-10 | Umicore Shokubai Japan Co., Ltd. | Catalyseur pour la purification de gaz d'échappement d'un moteur à combustion interne, ainsi qu'un procédé de purification de gaz d'échappement en utilisant ledit catalyseur |
EP3696382A1 (fr) | 2016-07-20 | 2020-08-19 | Umicore Shokubai Japan Co., Ltd. | Catalyseur de purification de gaz d'échappement pour moteur à combustion interne, et procédé de purification de gaz d'échappement utilisant ce catalyseur de purification de gaz d'échappement |
US10967362B2 (en) | 2016-07-20 | 2021-04-06 | Umicore Shokubai Japan Co., Ltd. | Catalyst for purification of exhaust gas from internal combustion engine and method for purification of exhaust gas using the catalyst |
Also Published As
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JP2010005590A (ja) | 2010-01-14 |
WO2010001226A8 (fr) | 2010-03-11 |
WO2010001226A1 (fr) | 2010-01-07 |
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