JP4736393B2 - プライマー層が形成されたガラス基材及び防曇性物品 - Google Patents
プライマー層が形成されたガラス基材及び防曇性物品 Download PDFInfo
- Publication number
- JP4736393B2 JP4736393B2 JP2004300997A JP2004300997A JP4736393B2 JP 4736393 B2 JP4736393 B2 JP 4736393B2 JP 2004300997 A JP2004300997 A JP 2004300997A JP 2004300997 A JP2004300997 A JP 2004300997A JP 4736393 B2 JP4736393 B2 JP 4736393B2
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- JP
- Japan
- Prior art keywords
- compound
- hydrolyzable
- antifogging
- primer layer
- zirconium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- 239000011521 glass Substances 0.000 title claims description 43
- 239000000758 substrate Substances 0.000 title claims description 28
- 238000000034 method Methods 0.000 claims description 35
- 238000004140 cleaning Methods 0.000 claims description 34
- 229920005989 resin Polymers 0.000 claims description 33
- 239000011347 resin Substances 0.000 claims description 33
- 238000000576 coating method Methods 0.000 claims description 24
- 150000003377 silicon compounds Chemical class 0.000 claims description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 23
- 239000000243 solution Substances 0.000 claims description 22
- 239000011248 coating agent Substances 0.000 claims description 21
- 150000003755 zirconium compounds Chemical class 0.000 claims description 20
- 229910052710 silicon Inorganic materials 0.000 claims description 16
- 239000010703 silicon Substances 0.000 claims description 16
- 125000002947 alkylene group Chemical group 0.000 claims description 14
- 150000003609 titanium compounds Chemical class 0.000 claims description 14
- 238000010521 absorption reaction Methods 0.000 claims description 13
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 10
- 229910052719 titanium Inorganic materials 0.000 claims description 10
- 239000010936 titanium Substances 0.000 claims description 10
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 9
- 229910052726 zirconium Inorganic materials 0.000 claims description 9
- 238000006460 hydrolysis reaction Methods 0.000 claims description 8
- 239000012670 alkaline solution Substances 0.000 claims description 7
- 230000001747 exhibiting effect Effects 0.000 claims description 6
- 230000007062 hydrolysis Effects 0.000 claims description 6
- 239000003513 alkali Substances 0.000 description 33
- 238000011156 evaluation Methods 0.000 description 21
- 239000010410 layer Substances 0.000 description 19
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 14
- 229920005862 polyol Polymers 0.000 description 9
- 230000005856 abnormality Effects 0.000 description 8
- 150000003077 polyols Chemical class 0.000 description 8
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
- -1 alkoxide compound Chemical class 0.000 description 6
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 238000006068 polycondensation reaction Methods 0.000 description 5
- 235000019441 ethanol Nutrition 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 239000004925 Acrylic resin Substances 0.000 description 3
- 229920000178 Acrylic resin Polymers 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- XFVGXQSSXWIWIO-UHFFFAOYSA-N chloro hypochlorite;titanium Chemical compound [Ti].ClOCl XFVGXQSSXWIWIO-UHFFFAOYSA-N 0.000 description 3
- 239000003822 epoxy resin Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229920000515 polycarbonate Polymers 0.000 description 3
- 239000004417 polycarbonate Substances 0.000 description 3
- 229920000647 polyepoxide Polymers 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 229920005672 polyolefin resin Polymers 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 description 2
- 229920003043 Cellulose fiber Polymers 0.000 description 2
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- 239000006087 Silane Coupling Agent Substances 0.000 description 2
- 239000012790 adhesive layer Substances 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 238000007611 bar coating method Methods 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- BDWFYHUDXIDTIU-UHFFFAOYSA-N ethanol;propane-1,2,3-triol Chemical compound CCO.OCC(O)CO BDWFYHUDXIDTIU-UHFFFAOYSA-N 0.000 description 2
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- CMOAHYOGLLEOGO-UHFFFAOYSA-N oxozirconium;dihydrochloride Chemical compound Cl.Cl.[Zr]=O CMOAHYOGLLEOGO-UHFFFAOYSA-N 0.000 description 2
- 239000005056 polyisocyanate Substances 0.000 description 2
- 229920001228 polyisocyanate Polymers 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- QDZRBIRIPNZRSG-UHFFFAOYSA-N titanium nitrate Chemical compound [O-][N+](=O)O[Ti](O[N+]([O-])=O)(O[N+]([O-])=O)O[N+]([O-])=O QDZRBIRIPNZRSG-UHFFFAOYSA-N 0.000 description 2
- OERNJTNJEZOPIA-UHFFFAOYSA-N zirconium nitrate Chemical compound [Zr+4].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O OERNJTNJEZOPIA-UHFFFAOYSA-N 0.000 description 2
- DUFCMRCMPHIFTR-UHFFFAOYSA-N 5-(dimethylsulfamoyl)-2-methylfuran-3-carboxylic acid Chemical compound CN(C)S(=O)(=O)C1=CC(C(O)=O)=C(C)O1 DUFCMRCMPHIFTR-UHFFFAOYSA-N 0.000 description 1
- 229910000906 Bronze Inorganic materials 0.000 description 1
- RSYNVVGMAGNQLP-UHFFFAOYSA-N CC[SiH2]O Chemical compound CC[SiH2]O RSYNVVGMAGNQLP-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- FTVZOQPUAHMAIA-UHFFFAOYSA-N O.O.[Zr+4].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O Chemical compound O.O.[Zr+4].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O FTVZOQPUAHMAIA-UHFFFAOYSA-N 0.000 description 1
- 238000006124 Pilkington process Methods 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- INNSZZHSFSFSGS-UHFFFAOYSA-N acetic acid;titanium Chemical compound [Ti].CC(O)=O.CC(O)=O.CC(O)=O.CC(O)=O INNSZZHSFSFSGS-UHFFFAOYSA-N 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 230000003373 anti-fouling effect Effects 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 230000037396 body weight Effects 0.000 description 1
- 239000010974 bronze Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000013626 chemical specie Substances 0.000 description 1
- VZJJZMXEQNFTLL-UHFFFAOYSA-N chloro hypochlorite;zirconium;octahydrate Chemical compound O.O.O.O.O.O.O.O.[Zr].ClOCl VZJJZMXEQNFTLL-UHFFFAOYSA-N 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 1
- WEAFESPXUBTSGL-UHFFFAOYSA-N diethyl(hydroxy)silane Chemical compound CC[SiH](O)CC WEAFESPXUBTSGL-UHFFFAOYSA-N 0.000 description 1
- OLLFKUHHDPMQFR-UHFFFAOYSA-N dihydroxy(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](O)(O)C1=CC=CC=C1 OLLFKUHHDPMQFR-UHFFFAOYSA-N 0.000 description 1
- 239000000539 dimer Substances 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 238000003618 dip coating Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000003670 easy-to-clean Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000005357 flat glass Substances 0.000 description 1
- 239000005329 float glass Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- LWIGVRDDANOFTD-UHFFFAOYSA-N hydroxy(dimethyl)silane Chemical compound C[SiH](C)O LWIGVRDDANOFTD-UHFFFAOYSA-N 0.000 description 1
- RSBFFZXDVVCMFR-UHFFFAOYSA-N hydroxy(dipropyl)silane Chemical compound CCC[SiH](O)CCC RSBFFZXDVVCMFR-UHFFFAOYSA-N 0.000 description 1
- AIPVRBGBHQDAPX-UHFFFAOYSA-N hydroxy(methyl)silane Chemical compound C[SiH2]O AIPVRBGBHQDAPX-UHFFFAOYSA-N 0.000 description 1
- OOLVZOPCFIHCRC-UHFFFAOYSA-N hydroxy(propyl)silane Chemical compound CCC[SiH2]O OOLVZOPCFIHCRC-UHFFFAOYSA-N 0.000 description 1
- IOANYFLVSWZRND-UHFFFAOYSA-N hydroxy(tripropyl)silane Chemical compound CCC[Si](O)(CCC)CCC IOANYFLVSWZRND-UHFFFAOYSA-N 0.000 description 1
- MQNNNLJCDJBERF-UHFFFAOYSA-N hydroxy-tri(propan-2-yl)silane Chemical compound CC(C)[Si](O)(C(C)C)C(C)C MQNNNLJCDJBERF-UHFFFAOYSA-N 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 239000005340 laminated glass Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- KBJFYLLAMSZSOG-UHFFFAOYSA-N n-(3-trimethoxysilylpropyl)aniline Chemical compound CO[Si](OC)(OC)CCCNC1=CC=CC=C1 KBJFYLLAMSZSOG-UHFFFAOYSA-N 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 125000005702 oxyalkylene group Chemical group 0.000 description 1
- 125000006353 oxyethylene group Chemical group 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 229920001610 polycaprolactone Polymers 0.000 description 1
- 239000004632 polycaprolactone Substances 0.000 description 1
- 229920005906 polyester polyol Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000029058 respiratory gaseous exchange Effects 0.000 description 1
- 238000007372 rollout process Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical compound [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 description 1
- SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 238000004528 spin coating Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000005341 toughened glass Substances 0.000 description 1
- WVMSIBFANXCZKT-UHFFFAOYSA-N triethyl(hydroxy)silane Chemical compound CC[Si](O)(CC)CC WVMSIBFANXCZKT-UHFFFAOYSA-N 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- DQZNLOXENNXVAD-UHFFFAOYSA-N trimethoxy-[2-(7-oxabicyclo[4.1.0]heptan-4-yl)ethyl]silane Chemical compound C1C(CC[Si](OC)(OC)OC)CCC2OC21 DQZNLOXENNXVAD-UHFFFAOYSA-N 0.000 description 1
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 1
- AAPLIUHOKVUFCC-UHFFFAOYSA-N trimethylsilanol Chemical compound C[Si](C)(C)O AAPLIUHOKVUFCC-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D185/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/28—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
- C03C17/30—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material with silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/42—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating of an organic material and at least one non-metal coating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/48—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms
- C08G77/58—Metal-containing linkages
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
- Y10T428/31645—Next to addition polymer from unsaturated monomers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31652—Of asbestos
- Y10T428/31663—As siloxane, silicone or silane
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31652—Of asbestos
- Y10T428/31667—Next to addition polymer from unsaturated monomers, or aldehyde or ketone condensation product
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Paints Or Removers (AREA)
- Surface Treatment Of Glass (AREA)
- Laminated Bodies (AREA)
- Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Description
アルキレン基を有する加水分解性ケイ素化合物であるγ−アミノプロピルトリエトキシシラン(LS−3150、信越シリコーン社製)を、90重量%のエタノールと10重量%のイソプロピルアルコールからなる変性アルコール(エキネン F−1、キシダ化学社製)で1重量%となるように調製し、溶液を得た。該溶液に加水分解性ジルコニウム化合物であるオキシ塩化ジルコニウム8水和物を、前記ケイ素化合物のケイ素量に対し、前記ジルコニウム化合物のジルコニウム量が、重量比で0.0008倍量となるように添加し、pH値が1.5であるプライマー層を得るための塗布液を得た。
加水分解性ジルコニウム化合物のジルコニウム量を、アルキレン基を有する加水分解性ケイ素化合物のケイ素量に対して、重量比で0.0002倍量となるようにした以外は、実施例1と同様の手順で防曇性部材を得、実施例1と同様の手順でアルカリ洗浄試験、及びアルカリ洗浄評価後の防曇性評価を行った。結果、アルカリ洗浄試験では、外観異常はなく、防曇性評価においても曇りは発生しなかった。
加水分解性ジルコニウム化合物のジルコニウム量を、アルキレン基を有する加水分解性ケイ素化合物のケイ素量に対して、重量比で0.002倍量となるようにした以外は、実施例1と同様の手順で防曇性部材を得、実施例1と同様の手順でアルカリ洗浄試験、及びアルカリ洗浄評価後の防曇性評価を行った。結果、アルカリ洗浄試験では、外観異常はなく、防曇性評価においても曇りは発生しなかった。
加水分解性ジルコニウム化合物を硝酸ジルコニウム2水和物とした以外は、実施例3と同様の手順で防曇性部材を得、実施例1と同様の手順でアルカリ洗浄試験、及びアルカリ洗浄評価後の防曇性評価を行った。結果、アルカリ洗浄試験では、外観異常はなく、防曇性評価においても曇りは発生しなかった。
樹脂被膜を得るための溶液の調製において、イソシアネート反応性基を有する界面活性剤を有する溶液(商品名「VISGARD」A成分、Film Specialties社製)、ポリカーボネートポリオール(商品名「PC−61」、日本ポリウレタン製)、数平均分子量が1000のポリエチレングリコール、短鎖ポリオールであるグリセリンエトキシド(商品名「GE200」三洋化成製)、及びヘキサメチレンジイソシアネートのビューレットタイプポリイソシアネート(商品名「N3200」住友バイエルウレタン製)を、膜を形成する成分が重量比で、37:10:5:48となるように調整した以外は実施例1と同様の手順で防曇性部材を得た。
加水分解性ジルコニウム化合物の代りに、加水分解性チタニウム化合物であるオキシ塩化チタニウムを、前記ケイ素化合物のケイ素量に対し、前記チタニウム化合物のチタニウム量が、重量比で0.002倍量となるように添加し、塗布液のpH値を1.5とした以外は実施例1と同様の手順で防曇性部材を得、実施例1と同様の手順でアルカリ洗浄試験、及びアルカリ洗浄評価後の防曇性評価を行った。結果、アルカリ洗浄試験では、外観異常はなく、防曇性評価においても曇りは発生しなかった。
ケイ素化合物のケイ素量に対し、チタニウム化合物のチタニウム量が、重量比で0.0005倍量となるように添加し、塗布液のpH値を1.5とした以外は実施例6と同様の手順で防曇性部材を得、実施例1と同様の手順でアルカリ洗浄試験、及びアルカリ洗浄評価後の防曇性評価を行った。結果、アルカリ洗浄試験では、外観異常はなく、防曇性評価においても曇りは発生しなかった。
ケイ素化合物のケイ素量に対し、チタニウム化合物のチタニウム量が、重量比で0.0044倍量となるように添加し、塗布液のpH値を1.5とした以外は実施例6と同様の手順で防曇性部材を得、実施例1と同様の手順でアルカリ洗浄試験、及びアルカリ洗浄評価後の防曇性評価を行った。結果、アルカリ洗浄試験では、外観異常はなく、防曇性評価においても曇りは発生しなかった。
加水分解性ジルコニウム化合物を使用しなかった以外は、実施例1と同様の手順とした。アルカリ洗浄試験を行ったところ、接触時間が8時間で樹脂被膜が剥離した。
加水分解性ジルコニウム化合物のジルコニウム量を、アルキレン基を有する加水分解性ケイ素化合物のケイ素量に対して、重量比で0.0001倍量となるようにした以外は、実施例1と同様の手順で試料を得、実施例1と同様の手順でアルカリ洗浄試験を行ったところ、接触時間が16時間で樹脂被膜が剥離した。
加水分解性チタニウム化合物のチタニウム量を、アルキレン基を有する加水分解性ケイ素化合物のケイ素量に対して、重量比で0.0004倍量となるようにした以外は、実施例6と同様の手順で試料を得、実施例1と同様の手順でアルカリ洗浄試験を行ったところ、接触時間が14時間で樹脂被膜が剥離した。
加水分解性ジルコニウム化合物のジルコニウム量を、アルキレン基を有する加水分解性ケイ素化合物のケイ素量に対して、重量比で0.003倍量となるようにした以外は、実施例1と同様の手順で試料を得、実施例1と同様の手順でアルカリ洗浄試験を行ったところ、接触時間が16時間で樹脂被膜が剥離した。
加水分解性チタニウム化合物のチタニウム量を、アルキレン基を有する加水分解性ケイ素化合物のケイ素量に対して、重量比で0.005倍量となるようにした以外は、実施例1と同様の手順で試料を得、実施例1と同様の手順でアルカリ洗浄試験を行ったところ、接触時間が17時間で樹脂被膜が剥離した。
Claims (3)
- ガラス基材上に、アルキレン基を有する加水分解性ケイ素化合物の加水分解生成物、及び加水分解性ジルコニウム化合物又は加水分解性チタニウム化合物の加水分解生成物からなるプライマー層が形成された防曇性物品であり、ジルコニウムがケイ素に対して、重量比で0.0002倍量以上0.0025倍量以下、又はチタニウムがケイ素に対して重量比で0.0005倍量以上0.0045倍量以下である前記プライマー層上に吸水性及び/又は親水性を呈する樹脂被膜が形成されたことを特徴とする防曇性物品。
- 請求項1に記載の防曇性物品を洗浄する方法において、アルカリ性の溶液を用いることを特徴とする洗浄方法。
- 請求項1に記載の防曇性物品のプライマー層を得るための塗布液であり、アルキレン基を有する加水分解性ケイ素化合物及び/又は加水分解物、及び加水分解性ジルコニウム化合物及び/又は加水分解物、又は加水分解性チタニウム化合物及び/又は加水分解物を有し、pH値が2以下であることを特徴とする塗布液。
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JP2004300997A JP4736393B2 (ja) | 2003-12-10 | 2004-10-15 | プライマー層が形成されたガラス基材及び防曇性物品 |
KR1020067011043A KR100766369B1 (ko) | 2003-12-10 | 2004-11-25 | 프라이머층이 형성된 유리 기판 및 김서림 방지성 물품 |
CN2004800366173A CN1898171B (zh) | 2003-12-10 | 2004-11-25 | 具有在其上形成的底涂层的玻璃基底和防雾制品 |
PCT/JP2004/017446 WO2005056488A1 (ja) | 2003-12-10 | 2004-11-25 | プライマー層が形成されたガラス基材及び防曇性物品 |
EP20040820120 EP1693350B1 (en) | 2003-12-10 | 2004-11-25 | Glass substrate having primer layer formed thereon and anti-fogging article |
US10/582,362 US7638199B2 (en) | 2003-12-10 | 2004-11-25 | Glass substrate having primer layer formed thereon and anti-fogging article |
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US (1) | US7638199B2 (ja) |
EP (1) | EP1693350B1 (ja) |
JP (1) | JP4736393B2 (ja) |
KR (1) | KR100766369B1 (ja) |
CN (1) | CN1898171B (ja) |
WO (1) | WO2005056488A1 (ja) |
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EP1809523B1 (en) | 2004-09-20 | 2016-06-22 | AGC Flat Glass North America, Inc. | Anti-fog refrigeration door and method of making the same |
CN101300394A (zh) * | 2005-09-20 | 2008-11-05 | 北美Agc平板玻璃公司 | 防雾制冷门及其制造方法 |
JP5299260B2 (ja) * | 2009-12-24 | 2013-09-25 | 信越化学工業株式会社 | 固体材料の表面処理方法 |
US9188585B2 (en) * | 2010-05-13 | 2015-11-17 | Robert Bosch Gmbh | Device and method for indirect modulation of detection environment |
US9346242B2 (en) * | 2011-12-13 | 2016-05-24 | Samsung Electronics Co., Ltd. | Multi-layer thin film assembly and barrier film for electronic device including the same |
DE102013206369A1 (de) | 2013-04-11 | 2014-10-16 | Tesa Se | Silan-Primer zur Verbesserung der Adhäsion von Klebebändern auf hydrophilen Oberflächen, insbesondere Glasoberflächen |
DE102013206376A1 (de) | 2013-04-11 | 2014-10-16 | Tesa Se | Schwarzer Silan-Primer zur Verbesserung der Adhäsion von Klebebändern auf Glasoberflächen |
JP6163983B2 (ja) * | 2013-09-04 | 2017-07-19 | 株式会社リコー | 液体吐出ヘッド及び画像形成装置 |
DE102014208814A1 (de) | 2014-05-09 | 2015-11-12 | Tesa Se | Primer zur Verbesserung der Adhäsion von Klebebändern auf hydrophilen Oberflächen |
US9099376B1 (en) | 2014-06-06 | 2015-08-04 | Nano And Advanced Materials Institute Limited | Laser direct patterning of reduced-graphene oxide transparent circuit |
JP6270767B2 (ja) * | 2015-03-30 | 2018-01-31 | ニチハ株式会社 | 建材 |
GB201507330D0 (en) * | 2015-04-29 | 2015-06-10 | Pilkington Group Ltd | Splash screen |
KR101827064B1 (ko) | 2015-12-14 | 2018-03-22 | 현대자동차주식회사 | 유리 비산 방지용 코팅제 및 이를 이용한 유리 파손시 비산 방지 기능을 갖는 강화유리와 그 제조방법 |
US20170298230A1 (en) | 2016-04-13 | 2017-10-19 | Tesa Se | Pigmentable Primer |
DE102016210536A1 (de) | 2016-04-13 | 2017-10-19 | Tesa Se | Einfärbbarer Primer |
JP7149962B2 (ja) * | 2017-05-04 | 2022-10-07 | エージーシー グラス ユーロップ | 被覆基板 |
JP7310254B2 (ja) * | 2019-04-19 | 2023-07-19 | 凸版印刷株式会社 | 化粧シート及び化粧部材 |
TWI738082B (zh) * | 2019-10-09 | 2021-09-01 | 才將科技股份有限公司 | 一種連接金屬和樹脂之接著劑、接著層及其應用 |
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- 2004-10-15 JP JP2004300997A patent/JP4736393B2/ja not_active Expired - Fee Related
- 2004-11-25 WO PCT/JP2004/017446 patent/WO2005056488A1/ja active Application Filing
- 2004-11-25 EP EP20040820120 patent/EP1693350B1/en not_active Expired - Fee Related
- 2004-11-25 KR KR1020067011043A patent/KR100766369B1/ko not_active IP Right Cessation
- 2004-11-25 CN CN2004800366173A patent/CN1898171B/zh not_active Expired - Fee Related
- 2004-11-25 US US10/582,362 patent/US7638199B2/en not_active Expired - Fee Related
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Also Published As
Publication number | Publication date |
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US7638199B2 (en) | 2009-12-29 |
WO2005056488A1 (ja) | 2005-06-23 |
KR100766369B1 (ko) | 2007-10-12 |
CN1898171B (zh) | 2010-08-18 |
EP1693350A4 (en) | 2009-03-25 |
JP2005194170A (ja) | 2005-07-21 |
KR20060093132A (ko) | 2006-08-23 |
EP1693350B1 (en) | 2012-05-02 |
CN1898171A (zh) | 2007-01-17 |
US20070099000A1 (en) | 2007-05-03 |
EP1693350A1 (en) | 2006-08-23 |
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