JP4727806B2 - 容易に除去し得るニトロキシルラジカルを用いるアルコールの選択的酸化方法 - Google Patents

容易に除去し得るニトロキシルラジカルを用いるアルコールの選択的酸化方法 Download PDF

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Publication number
JP4727806B2
JP4727806B2 JP2000346074A JP2000346074A JP4727806B2 JP 4727806 B2 JP4727806 B2 JP 4727806B2 JP 2000346074 A JP2000346074 A JP 2000346074A JP 2000346074 A JP2000346074 A JP 2000346074A JP 4727806 B2 JP4727806 B2 JP 4727806B2
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Japan
Prior art keywords
oxy
alcohols
oxyl
reaction
oxidation
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JP2000346074A
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Japanese (ja)
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JP2001199923A (ja
JP2001199923A5 (enExample
Inventor
ラインハルト ゾンマーラーデ
ハンスイェルク グリュッツマッハー
スワド ブールマーズ
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BASF Schweiz AG
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Ciba Holding AG
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G79/00—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule
    • C08G79/02—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule a linkage containing phosphorus
    • C08G79/025—Polyphosphazenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/30—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with halogen containing compounds, e.g. hypohalogenation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
    • C07F9/576—Six-membered rings
    • C07F9/59—Hydrogenated pyridine rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6581—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and nitrogen atoms with or without oxygen or sulfur atoms, as ring hetero atoms
    • C07F9/65812—Cyclic phosphazenes [P=N-]n, n>=3
    • C07F9/65815—Cyclic phosphazenes [P=N-]n, n>=3 n = 3
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Biochemistry (AREA)
  • Molecular Biology (AREA)
  • General Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Heterocyclic Compounds That Contain Two Or More Ring Oxygen Atoms (AREA)
  • Pyrane Compounds (AREA)
  • Catalysts (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Polyethers (AREA)
JP2000346074A 1999-11-19 2000-11-14 容易に除去し得るニトロキシルラジカルを用いるアルコールの選択的酸化方法 Expired - Fee Related JP4727806B2 (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH211399 1999-11-19
CH19992113/99 1999-11-19

Publications (3)

Publication Number Publication Date
JP2001199923A JP2001199923A (ja) 2001-07-24
JP2001199923A5 JP2001199923A5 (enExample) 2007-12-27
JP4727806B2 true JP4727806B2 (ja) 2011-07-20

Family

ID=4226187

Family Applications (1)

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JP2000346074A Expired - Fee Related JP4727806B2 (ja) 1999-11-19 2000-11-14 容易に除去し得るニトロキシルラジカルを用いるアルコールの選択的酸化方法

Country Status (11)

Country Link
US (2) US6441243B1 (enExample)
EP (1) EP1103537B1 (enExample)
JP (1) JP4727806B2 (enExample)
KR (1) KR100707839B1 (enExample)
CN (1) CN1173913C (enExample)
AT (1) ATE240285T1 (enExample)
CA (1) CA2326304A1 (enExample)
CZ (1) CZ20004299A3 (enExample)
DE (1) DE50002160D1 (enExample)
SK (1) SK284566B6 (enExample)
TW (1) TWI266763B (enExample)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002058844A1 (en) * 2001-01-23 2002-08-01 Ciba Specialty Chemicals Holding Inc. Stable free nitroxyl radicals as oxidation catalysts and process for oxidation
EP1302456B1 (de) 2001-10-11 2004-01-02 Consortium für elektrochemische Industrie GmbH Verfahren zur Oxidation von Alkoholen unter Katalyse von Nitroxylverbindungen
KR101029863B1 (ko) 2001-12-21 2011-04-18 시바 홀딩 인코포레이티드 신규한 난연제 화합물
JP4369240B2 (ja) 2002-01-29 2009-11-18 フイルメニツヒ ソシエテ アノニム 不飽和アルコールの酸化法
WO2003080575A1 (en) * 2002-03-26 2003-10-02 Koei Chemical Co., Ltd. Process for producing heterocyclic aldehyde
CN1642892A (zh) * 2002-04-05 2005-07-20 西巴特殊化学品控股有限公司 将醇转化为羰基化合物的方法
DE10244633B3 (de) 2002-09-25 2004-02-26 Consortium für elektrochemische Industrie GmbH Verfahren zur Herstellung von Alkincarbonsäuren durch Oxidation von Alkinalkoholen
WO2004031150A1 (en) * 2002-10-07 2004-04-15 Ciba Specialty Chemicals Holding Inc. Oxoammonium salts of 1-oxy-2,2,6,6-tetramethyl-1-piperidine (tempo) and their use as oxidizing agents
WO2005084800A1 (en) * 2004-03-02 2005-09-15 Johnson Matthey Plc Oxidation catalysts
CN1300081C (zh) * 2004-12-30 2007-02-14 中国科学院大连化学物理研究所 一种催化空气氧化醇制备醛和酮的方法
US7658802B2 (en) * 2005-11-22 2010-02-09 Applied Materials, Inc. Apparatus and a method for cleaning a dielectric film
CN101774898B (zh) * 2009-01-14 2012-08-08 中国科学院大连化学物理研究所 一种丙酮醇的制备方法
CN105272954B (zh) * 2014-06-27 2017-10-13 上海弈柯莱生物医药科技有限公司 一种6‑取代甲基‑4‑羟基四氢吡喃‑2‑酮及其衍生物的制备方法
CN111646963B (zh) * 2020-06-29 2022-09-27 张明 一种δ-环戊内酯的制备方法
CN115819388B (zh) * 2021-09-17 2024-06-11 台州学院 一种δ-环戊内酯的制备方法
US20250170565A1 (en) * 2022-03-02 2025-05-29 Asymchem Life Science (Tianjin) Co. Ltd. Catalyst Loaded with TEMPO Compound, and Preparation Method and Use thereof
US20240199566A1 (en) * 2022-11-16 2024-06-20 Wisconsin Alumni Research Foundation Catalytic synthesis of delta-valerolactone (dvl) from furfural-derived 2-hydroxytetrahydropyran (hthp)
CN116751173A (zh) * 2023-05-05 2023-09-15 易简和成(江苏)医药科技有限公司 一种药物中间体的绿色合成方法

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01132635A (ja) * 1987-11-19 1989-05-25 Nippon Soda Co Ltd オルガノホスファゼンポリマーの製造法
JPH0832647B2 (ja) * 1989-01-27 1996-03-29 大阪有機化学工業株式会社 １級アルコールからアルデヒドの製造法
JP3039025B2 (ja) * 1991-07-19 2000-05-08 吉富製薬株式会社 置換アセトアルデヒドの製造方法
US5155280A (en) * 1991-09-30 1992-10-13 Shell Oil Company Process for the oxidation of alcohols to aldehydes
US5155278A (en) * 1991-09-30 1992-10-13 Shell Oil Company Process for the oxidation of alcohols to aldehydes
US5155279A (en) * 1991-10-18 1992-10-13 Shell Oil Company Process for the oxidation of alcohols to aldehydes
JPH05310632A (ja) * 1992-04-28 1993-11-22 Sumitomo Chem Co Ltd ｍ−フェノキシベンズアルデヒドの製造方法
WO1995016698A1 (en) * 1993-12-17 1995-06-22 The Upjohn Company Conversion of bisnoralcohol to bisnoraldehyde
US5856584A (en) * 1997-08-06 1999-01-05 The Nutrasweet Company Preparation of 3,3-dimethylbutyraldehyde by oxidation of 3, 3-dimethylbutanol
JP3775919B2 (ja) * 1998-03-13 2006-05-17 大塚化学ホールディングス株式会社 難燃性樹脂、その組成物及びその製造法
JP2000290214A (ja) * 1999-04-02 2000-10-17 Kuraray Co Ltd ベンジルオキシアセトアルデヒドの製造方法
JP2001011007A (ja) * 1999-07-01 2001-01-16 Sumika Fine Chemicals Co Ltd ベンジルオキシアセトアルデヒド化合物の製造法

Also Published As

Publication number Publication date
US6660860B2 (en) 2003-12-09
ATE240285T1 (de) 2003-05-15
JP2001199923A (ja) 2001-07-24
US20020161265A1 (en) 2002-10-31
SK17582000A3 (sk) 2001-06-11
CA2326304A1 (en) 2001-05-19
CN1304921A (zh) 2001-07-25
EP1103537B1 (de) 2003-05-14
SK284566B6 (sk) 2005-06-02
TWI266763B (en) 2006-11-21
KR20010051782A (ko) 2001-06-25
KR100707839B1 (ko) 2007-04-17
CZ20004299A3 (cs) 2002-05-15
DE50002160D1 (de) 2003-06-18
US6441243B1 (en) 2002-08-27
CN1173913C (zh) 2004-11-03
EP1103537A1 (de) 2001-05-30

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