JP4538327B2 - 親水化ブロックトポリイソシアネート - Google Patents

親水化ブロックトポリイソシアネート Download PDF

Info

Publication number
JP4538327B2
JP4538327B2 JP2004562697A JP2004562697A JP4538327B2 JP 4538327 B2 JP4538327 B2 JP 4538327B2 JP 2004562697 A JP2004562697 A JP 2004562697A JP 2004562697 A JP2004562697 A JP 2004562697A JP 4538327 B2 JP4538327 B2 JP 4538327B2
Authority
JP
Japan
Prior art keywords
weight
ester
polyisocyanate
group
polyisocyanates
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP2004562697A
Other languages
English (en)
Japanese (ja)
Other versions
JP2006510784A5 (enExample
JP2006510784A (ja
Inventor
トルステン・リーシェ
クリストフ・ギュルトラー
カリン・ナウヨクス
トーマス・フェラー
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Covestro Deutschland AG
Original Assignee
Bayer MaterialScience AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer MaterialScience AG filed Critical Bayer MaterialScience AG
Publication of JP2006510784A publication Critical patent/JP2006510784A/ja
Publication of JP2006510784A5 publication Critical patent/JP2006510784A5/ja
Application granted granted Critical
Publication of JP4538327B2 publication Critical patent/JP4538327B2/ja
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/80—Masked polyisocyanates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/80—Masked polyisocyanates
    • C08G18/8061—Masked polyisocyanates masked with compounds having only one group containing active hydrogen
    • C08G18/8093—Compounds containing active methylene groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
    • C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
    • C08G18/0823—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups containing carboxylate salt groups or groups forming them
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
    • C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
    • C08G18/0828—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups containing sulfonate groups or groups forming them
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/2805—Compounds having only one group containing active hydrogen
    • C08G18/2815—Monohydroxy compounds
    • C08G18/283—Compounds containing ether groups, e.g. oxyalkylated monohydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
    • C08G18/3819—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen
    • C08G18/3821—Carboxylic acids; Esters thereof with monohydroxyl compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
    • C08G18/3819—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen
    • C08G18/3823—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen containing -N-C=O groups
    • C08G18/3831—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen containing -N-C=O groups containing urethane groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/703—Isocyanates or isothiocyanates transformed in a latent form by physical means
    • C08G18/705—Dispersions of isocyanates or isothiocyanates in a liquid medium
    • C08G18/706—Dispersions of isocyanates or isothiocyanates in a liquid medium the liquid medium being water
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Paints Or Removers (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
JP2004562697A 2002-12-20 2003-12-06 親水化ブロックトポリイソシアネート Expired - Fee Related JP4538327B2 (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10260298A DE10260298A1 (de) 2002-12-20 2002-12-20 Hydrophilierte blockierte Polysocyanate
PCT/EP2003/013820 WO2004058847A1 (de) 2002-12-20 2003-12-06 Hydrophilierte blockierte polyisocyanate

Publications (3)

Publication Number Publication Date
JP2006510784A JP2006510784A (ja) 2006-03-30
JP2006510784A5 JP2006510784A5 (enExample) 2007-02-01
JP4538327B2 true JP4538327B2 (ja) 2010-09-08

Family

ID=32404131

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2004562697A Expired - Fee Related JP4538327B2 (ja) 2002-12-20 2003-12-06 親水化ブロックトポリイソシアネート

Country Status (14)

Country Link
US (1) US7220814B2 (enExample)
EP (1) EP1581576B1 (enExample)
JP (1) JP4538327B2 (enExample)
KR (1) KR101080442B1 (enExample)
CN (1) CN1326903C (enExample)
AT (1) ATE471347T1 (enExample)
AU (1) AU2003292202A1 (enExample)
BR (1) BR0317429A (enExample)
CA (1) CA2510554C (enExample)
DE (2) DE10260298A1 (enExample)
ES (1) ES2345883T3 (enExample)
MX (1) MXPA05006531A (enExample)
RU (1) RU2345097C2 (enExample)
WO (1) WO2004058847A1 (enExample)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10260269A1 (de) * 2002-12-20 2004-07-01 Bayer Ag Neue Dual Cure-Systeme
DE102005048823A1 (de) * 2005-10-10 2007-04-12 Bayer Materialscience Ag Reaktivsysteme, deren Herstellung und Verwendung
JP5399625B2 (ja) * 2007-11-13 2014-01-29 日東電工株式会社 複合フィルム
SI2218740T1 (sl) * 2009-02-13 2014-03-31 Bayer Materialscience Llc ÄŚistilni poliuretanski premazi na vodni osnovi
US8940853B2 (en) * 2011-03-16 2015-01-27 Asahi Kasei Chemicals Corporation Cationic blocked polyisocyanate and aqueous composition comprising the same
EP2971416A2 (en) 2013-03-15 2016-01-20 Spectrum Brands, Inc. Wireless lockset with integrated antenna, touch activation, and light communication method
CN105452320B (zh) * 2013-08-23 2019-02-26 三井化学株式会社 封端异氰酸酯、涂料组合物、粘接剂组合物和物品
CN104448232B (zh) * 2013-09-13 2017-12-15 万华化学集团股份有限公司 一种氨基磺酸改性的多异氰酸酯及其制备方法和用途
JP2015102636A (ja) * 2013-11-22 2015-06-04 富士フイルム株式会社 偏光子保護フィルム、偏光板及び画像表示装置
JP6226762B2 (ja) * 2014-01-31 2017-11-08 富士フイルム株式会社 光学用ポリエステルフィルム、偏光板、画像表示装置、光学用ポリエステルフィルムの製造方法、および易接着層用組成物
RU2713424C1 (ru) 2016-06-03 2020-02-05 ХАНТСМЭН ИНТЕРНЭШНЛ ЭлЭлСи Композиция блокированного изоцианата
CN108264622B (zh) * 2016-12-30 2020-06-19 比亚迪股份有限公司 水性聚氨酯及其制备中间体和制备方法
US10858474B2 (en) 2017-01-31 2020-12-08 Hewlett-Packard Development Company, L.P. Reactive polyurethane dispersions
WO2018143922A1 (en) 2017-01-31 2018-08-09 Hewlett-Packard Development Company, L.P. Reactive polyurethane dispersions
US10640599B2 (en) 2017-01-31 2020-05-05 Hewlett-Packard Development Company, L.P. Reactive polyurethane dispersions
EP3507318B1 (en) 2017-01-31 2022-11-09 Hewlett-Packard Development Company, L.P. Reactive polyurethane dispersions
CN106565928A (zh) * 2017-02-23 2017-04-19 北京理工大学 一种混合亲水聚异氰酸酯固化剂
CN107236114B (zh) * 2017-06-15 2021-01-29 盐城工学院 一种含纳米二氧化硅结构的水性封闭型聚异氰酸酯交联剂及其制备方法
EP3560975B2 (de) 2018-04-25 2023-12-06 Covestro Intellectual Property GmbH & Co. KG Ionisch hydrophilierte polyisocyanate und antioxidantien
ES2884214T3 (es) 2018-04-25 2021-12-10 Covestro Deutschland Ag Poliisocianatos hidrofilizados iónicamente y secuestradores de radicales y/o descomponedores de peróxidos
EP3560974A1 (de) * 2018-04-25 2019-10-30 Covestro Deutschland AG Ionisch hydrophilierte polyisocyanate, wassergehalt

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4108814A (en) 1974-09-28 1978-08-22 Bayer Aktiengesellschaft Aqueous polyurethane dispersions from solvent-free prepolymers using sulfonate diols
DE2456469C2 (de) 1974-11-29 1983-01-13 Bayer Ag, 5090 Leverkusen Verfahren zur Herstellung von in Wasser löslichen bzw. dispergierbaren blockierten Polyisocyanaten und ihre Verwendung als Beschichtungsmittel
DE2853937A1 (de) 1978-12-14 1980-07-03 Bayer Ag Verfahren zur herstellung von wasserdispergierbaren oder -loeslichen blockierten polyisocyanaten, die nach dem verfahren erhaeltlichen blockierten polyisocyanate, sowie diese blockierte polyisocyanate als isocyanatkomponente enthaltende lackbindemittel
DE4240480A1 (de) * 1992-12-02 1994-08-25 Bayer Ag Organische Polyisocyanate mit zumindest teilweise blockierten Isocyanatgruppen
GB2290793B (en) * 1994-06-20 1998-05-06 Cray Valley Ltd Powder coating compositions
JP3431285B2 (ja) * 1994-07-13 2003-07-28 旭化成株式会社 水性ブロックポリイソシアナート組成物及びそれを含む水性塗料組成物
US6025433A (en) * 1995-12-20 2000-02-15 Basf Coatings Ag Thermosetting paint composition
JP3947260B2 (ja) * 1997-02-19 2007-07-18 旭化成ケミカルズ株式会社 水性ブロックポリイソシアネート組成物
DE19750186A1 (de) 1997-11-13 1999-05-20 Bayer Ag Hydrophilierungsmittel, ein Verfahren zu dessen Herstellung sowie dessen Verwendung als Dispergator für wäßrige Polyurethan-Dispersionen
DE19813352A1 (de) 1998-03-26 1999-09-30 Bayer Ag Malonesterblockierte Polyisocyanate mit Formaldehyd gegen Thermovergilbung
RU2148061C1 (ru) * 1998-04-09 2000-04-27 Институт проблем химической физики РАН Блокированные полиизоцианаты, способ их получения, применение их в качестве компонента защитных и декоративных покрытий и магнитная регистрирующая среда на основе блокированных полиизоцианатов
DE10024624A1 (de) 2000-05-18 2001-11-22 Bayer Ag Modifizierte Polyisocyanate
JP3884277B2 (ja) * 2001-02-21 2007-02-21 関西ペイント株式会社 ブロックイソシアネート基含有樹脂組成物及びこれを含む熱硬化性組成物
DE10132016A1 (de) * 2001-07-03 2003-01-16 Bayer Ag Cyclische Ketone als Blockierungsmittel
NZ530396A (en) * 2001-07-03 2005-07-29 Bayer Ag Cyclic ketones as blocking agents
DE10226926A1 (de) * 2002-06-17 2004-02-05 Bayer Ag Blockierte Polyisocyanate
DE10260270A1 (de) * 2002-12-20 2004-07-01 Bayer Ag Hydrophile Polyurethan-Polyharnstoff-Dispersion
DE10260299A1 (de) * 2002-12-20 2004-07-01 Bayer Ag Reaktivsysteme, deren Herstellung und deren Verwendung

Also Published As

Publication number Publication date
RU2005122823A (ru) 2006-01-20
BR0317429A (pt) 2005-11-16
US7220814B2 (en) 2007-05-22
CN1326903C (zh) 2007-07-18
US20040138403A1 (en) 2004-07-15
CA2510554A1 (en) 2004-07-15
ATE471347T1 (de) 2010-07-15
EP1581576A1 (de) 2005-10-05
MXPA05006531A (es) 2005-08-26
EP1581576B1 (de) 2010-06-16
KR20050085792A (ko) 2005-08-29
JP2006510784A (ja) 2006-03-30
CN1729223A (zh) 2006-02-01
KR101080442B1 (ko) 2011-11-04
ES2345883T3 (es) 2010-10-05
CA2510554C (en) 2011-09-20
RU2345097C2 (ru) 2009-01-27
AU2003292202A1 (en) 2004-07-22
WO2004058847A1 (de) 2004-07-15
DE50312819D1 (en) 2010-07-29
DE10260298A1 (de) 2004-07-01
HK1088024A1 (en) 2006-10-27

Similar Documents

Publication Publication Date Title
JP4538327B2 (ja) 親水化ブロックトポリイソシアネート
US6767958B2 (en) Modified polyisocyanates
JP4705013B2 (ja) ４価バナジウム触媒を含む一成分ポリウレタン被覆系
JP4331822B2 (ja) 水分散性の向上した、ポリエーテル改質ポリイソシアネート混合物
US6777523B1 (en) Highly functional polyisocyanate mixtures which are dispersible in water
JP4733278B2 (ja) アシルウレア基含有ポリイソシアネート混合物
EP3887424B1 (en) Modified polyisocyanate
EP3529326B1 (de) Harte beschichtungen mit hoher chemischer und mechanischer beständigkeit
JP4417656B2 (ja) サイズ組成物
JP2005514501A (ja) 安定化した水性架橋剤分散系
US6509433B2 (en) Fluorine-containing blocked isocyanates
KR100730269B1 (ko) 개질된 폴리이소시아네이트
HK1088024B (en) Hydrophilized blocked polyisocyanates
US20240239944A1 (en) Production of a Blocked Curing Agent Based on a Partly Organic-Based Polyisocyanate and Use as a 1K PUR Baking Enamel
HK1090072B (zh) 亲水性聚氨酯-聚脲分散体
HK1090072A1 (zh) 亲水性聚氨酯-聚脲分散体

Legal Events

Date Code Title Description
A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20061205

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20061205

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20090908

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20090924

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20091222

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20100202

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20100428

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20100525

A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20100621

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20130625

Year of fee payment: 3

R150 Certificate of patent or registration of utility model

Free format text: JAPANESE INTERMEDIATE CODE: R150

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

LAPS Cancellation because of no payment of annual fees