JP4504453B2 - 線状カーボンナノチューブ構造体の製造方法 - Google Patents
線状カーボンナノチューブ構造体の製造方法 Download PDFInfo
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- JP4504453B2 JP4504453B2 JP2009008216A JP2009008216A JP4504453B2 JP 4504453 B2 JP4504453 B2 JP 4504453B2 JP 2009008216 A JP2009008216 A JP 2009008216A JP 2009008216 A JP2009008216 A JP 2009008216A JP 4504453 B2 JP4504453 B2 JP 4504453B2
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- carbon nanotube
- nanotube structure
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- linear
- conductive layer
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims description 155
- 238000004519 manufacturing process Methods 0.000 title claims description 19
- 239000002041 carbon nanotube Substances 0.000 claims description 89
- 229910021393 carbon nanotube Inorganic materials 0.000 claims description 89
- 239000002238 carbon nanotube film Substances 0.000 claims description 44
- 238000009834 vaporization Methods 0.000 claims description 25
- 230000008016 vaporization Effects 0.000 claims description 25
- 239000007769 metal material Substances 0.000 claims description 12
- 239000003963 antioxidant agent Substances 0.000 claims description 11
- 230000003078 antioxidant effect Effects 0.000 claims description 11
- 238000009736 wetting Methods 0.000 claims description 11
- 230000001052 transient effect Effects 0.000 claims description 10
- 230000003014 reinforcing effect Effects 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 4
- 229920000642 polymer Polymers 0.000 claims description 3
- 238000003754 machining Methods 0.000 claims 1
- 239000002131 composite material Substances 0.000 description 13
- 238000000034 method Methods 0.000 description 10
- 239000000758 substrate Substances 0.000 description 9
- 239000000463 material Substances 0.000 description 8
- 238000000151 deposition Methods 0.000 description 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
- 230000008021 deposition Effects 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 239000000956 alloy Substances 0.000 description 5
- 229910045601 alloy Inorganic materials 0.000 description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 4
- 229910052802 copper Inorganic materials 0.000 description 4
- 239000010949 copper Substances 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- 238000009987 spinning Methods 0.000 description 4
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 239000002079 double walled nanotube Substances 0.000 description 3
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 229910052709 silver Inorganic materials 0.000 description 3
- 239000004332 silver Substances 0.000 description 3
- 230000007704 transition Effects 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000005229 chemical vapour deposition Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 238000005240 physical vapour deposition Methods 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- -1 polyethylene Polymers 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 239000011118 polyvinyl acetate Substances 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 239000002109 single walled nanotube Substances 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 229910003481 amorphous carbon Inorganic materials 0.000 description 1
- 230000003064 anti-oxidating effect Effects 0.000 description 1
- 238000001241 arc-discharge method Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 230000002500 effect on skin Effects 0.000 description 1
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000005226 mechanical processes and functions Effects 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000002048 multi walled nanotube Substances 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 239000000523 sample Substances 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 238000001771 vacuum deposition Methods 0.000 description 1
- 238000007738 vacuum evaporation Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B13/00—Apparatus or processes specially adapted for manufacturing conductors or cables
- H01B13/0026—Apparatus for manufacturing conducting or semi-conducting layers, e.g. deposition of metal
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/04—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of carbon-silicon compounds, carbon or silicon
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/20—Conductive material dispersed in non-conductive organic material
- H01B1/24—Conductive material dispersed in non-conductive organic material the conductive material comprising carbon-silicon compounds, carbon or silicon
Description
112 濡れ層
113 過渡層
114 導電層
115 抗酸化層
116 強化層
210 真空装置
212 気化源
214 カーボンナノチューブフィルム
216 カーボンナノチューブアレイ
220 容器
222 線状カーボンナノチューブ構造体
260 ローラー
Claims (6)
- 複数のカーボンナノチューブを含むカーボンナノチューブ構造体を提供する第一ステップと、
前記カーボンナノチューブ構造体における各々のカーボンナノチューブの表面に、少なくとも一つの導電性層を設置する第二ステップと、
前記導電性層が被覆されたカーボンナノチューブ構造体をねじって、線状カーボンナノチューブ構造体を形成する第三ステップと、
を含み、
前記第一ステップが、
真空装置内においてカーボンナノチューブアレイを提供する第一サブステップと、
前記カーボンナノチューブアレイからカーボンナノチューブフィルムを引き出す第二サブステップと、
を含み、
前記第二ステップが、
少なくとも一つの気化源を前記真空装置内に提供する第一サブステップと、
前記少なくとも一つの気化源を加熱させて、前記カーボンナノチューブフィルムの表面に金属材料を堆積させる第二サブステップと、
を含み、
前記第一ステップにおいて、
前記カーボンナノチューブ構造体が、少なくとも一枚のカーボンナノチューブフィルムを含み、
前記複数のカーボンナノチューブが前記カーボンナノチューブ構造体の表面に平行に配列されることを特徴とする線状カーボンナノチューブ構造体の製造方法。 - 前記第二ステップにおいて、複数の前記気化源を前記真空装置の中に設置し、前記複数の気化源が対向して設置されていることを特徴とする、請求項1に記載の線状カーボンナノチューブ構造体の製造方法。
- 前記第二ステップの第二サブステップは、さらに前記カーボンナノチューブの表面に濡れ層を形成するステップと、前記濡れ層の表面に過渡層を形成するステップと、前記過渡層の表面に導電層を形成するステップと、前記導電層の表面に抗酸化層を形成するステップと、を含むことを特徴とする、請求項1又は2に記載の線状カーボンナノチューブ構造体の製造方法。
- 前記カーボンナノチューブ構造体における各々のカーボンナノチューブの表面に、少なくとも一つの導電性層を設置した後、ポリマー溶液に前記カーボンナノチューブ構造体を浸漬させて、前記カーボンナノチューブ構造体の表面に強化層を形成することを特徴とする、請求項1〜3のいずれか一項に記載の線状カーボンナノチューブ構造体の製造方法。
- 前記導電性層の厚さが、1nm〜20nmであることを特徴とする、請求項1から4のいずれか一項に記載の線状カーボンナノチューブ構造体の製造方法。
- 前記第三ステップにおいて、
前記導電性層が被覆されたカーボンナノチューブ構造体を機械加工することを特徴とする、請求項1から5のいずれか一項に記載の線状カーボンナノチューブ構造体の製造方法。
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN200810066043 | 2008-02-01 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2009184909A JP2009184909A (ja) | 2009-08-20 |
JP4504453B2 true JP4504453B2 (ja) | 2010-07-14 |
Family
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Family Applications (1)
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JP2009008216A Active JP4504453B2 (ja) | 2008-02-01 | 2009-01-16 | 線状カーボンナノチューブ構造体の製造方法 |
Country Status (3)
Country | Link |
---|---|
US (1) | US8158199B2 (ja) |
JP (1) | JP4504453B2 (ja) |
CN (1) | CN101499338B (ja) |
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KR101458846B1 (ko) | 2004-11-09 | 2014-11-07 | 더 보드 오브 리전츠 오브 더 유니버시티 오브 텍사스 시스템 | 나노섬유 리본과 시트 및 트위스팅 및 논-트위스팅 나노섬유 방적사의 제조 및 애플리케이션 |
CN101499337B (zh) * | 2008-02-01 | 2013-01-09 | 清华大学 | 线缆的制造方法 |
DE102008013518A1 (de) * | 2008-03-07 | 2009-09-17 | Siemens Aktiengesellschaft | Strangförmiger Materialverbund mit CNT-Garnen und Verfahren zu desssen Herstellung |
US8354593B2 (en) * | 2009-07-10 | 2013-01-15 | Nanocomp Technologies, Inc. | Hybrid conductors and method of making same |
CN101996706B (zh) * | 2009-08-25 | 2015-08-26 | 清华大学 | 一种耳机线及具有该耳机线的耳机 |
CN101998200A (zh) * | 2009-08-25 | 2011-03-30 | 鸿富锦精密工业(深圳)有限公司 | 一种耳机线及具有该耳机线的耳机 |
CN101880035A (zh) | 2010-06-29 | 2010-11-10 | 清华大学 | 碳纳米管结构 |
US9903350B2 (en) | 2012-08-01 | 2018-02-27 | The Board Of Regents, The University Of Texas System | Coiled and non-coiled twisted polymer fiber torsional and tensile actuators |
US8865604B2 (en) * | 2012-09-17 | 2014-10-21 | The Boeing Company | Bulk carbon nanotube and metallic composites and method of fabricating |
US20140127053A1 (en) * | 2012-11-06 | 2014-05-08 | Baker Hughes Incorporated | Electrical submersible pumping system having wire with enhanced insulation |
JP6138000B2 (ja) * | 2013-09-04 | 2017-05-31 | 長野県 | 被覆カーボンナノチューブの製造方法 |
DE102014005339B4 (de) * | 2014-01-28 | 2022-06-09 | Wolfgang B. Thörner | Verfahren zur Herstellung eines Kontaktelements |
US20160057544A1 (en) * | 2014-08-21 | 2016-02-25 | Plugged Inc. | Carbon Nanotube Copper Composite Wire for Acoustic Applications |
JP6398627B2 (ja) * | 2014-11-10 | 2018-10-03 | 富士通株式会社 | 放熱シート、放熱シートの製造方法、及び電子装置の製造方法 |
US10115492B2 (en) | 2017-02-24 | 2018-10-30 | Delphi Technologies, Inc. | Electrically conductive carbon nanotube wire having a metallic coating and methods of forming same |
CN107421567B (zh) * | 2017-06-06 | 2019-09-27 | 南京邮电大学 | 一种扭转型碳纳米管的实现方法及其在传感器上的应用 |
CN109913851B (zh) * | 2019-03-13 | 2021-02-23 | 肇庆市华师大光电产业研究院 | 一种采用后退火处理的共溅射制备mwcnt@xy的方法及mwcnt@xy |
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- 2009-01-22 US US12/321,551 patent/US8158199B2/en active Active
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Publication number | Publication date |
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CN101499338A (zh) | 2009-08-05 |
US20090196985A1 (en) | 2009-08-06 |
CN101499338B (zh) | 2011-07-27 |
JP2009184909A (ja) | 2009-08-20 |
US8158199B2 (en) | 2012-04-17 |
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