JP4499919B2 - （メタ）アクリレートモノマーのための重合防止剤としての１−オキシル−４−ヒドロキシ−または４−アミノ−２，２，６，６−テトラメチルピペリジンの誘導体 - Google Patents

（メタ）アクリレートモノマーのための重合防止剤としての１−オキシル−４−ヒドロキシ−または４−アミノ−２，２，６，６−テトラメチルピペリジンの誘導体 Download PDF

Info

Publication number
JP4499919B2
JP4499919B2 JP2000560075A JP2000560075A JP4499919B2 JP 4499919 B2 JP4499919 B2 JP 4499919B2 JP 2000560075 A JP2000560075 A JP 2000560075A JP 2000560075 A JP2000560075 A JP 2000560075A JP 4499919 B2 JP4499919 B2 JP 4499919B2
Authority
JP
Japan
Prior art keywords
oxyl
group
tetramethylpiperidin
unsaturated
formula
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP2000560075A
Other languages
English (en)
Japanese (ja)
Other versions
JP2002520379A5 (https=
JP2002520379A (ja
Inventor
グレン トーマス クンケル
マシュー エドワード グランデ
レイモンド セルツァー
トーマス フレンド トンプソン
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Schweiz AG
Original Assignee
Ciba Holding AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Holding AG filed Critical Ciba Holding AG
Publication of JP2002520379A publication Critical patent/JP2002520379A/ja
Publication of JP2002520379A5 publication Critical patent/JP2002520379A5/ja
Application granted granted Critical
Publication of JP4499919B2 publication Critical patent/JP4499919B2/ja
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C231/00—Preparation of carboxylic acid amides
    • C07C231/22—Separation; Purification; Stabilisation; Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B63/00—Purification; Separation; Stabilisation; Use of additives
    • C07B63/04—Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/32—Separation; Purification; Stabilisation; Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
    • C07C303/42—Separation; Purification; Stabilisation; Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C07C51/50—Use of additives, e.g. for stabilisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/48—Separation; Purification; Stabilisation; Use of additives
    • C07C67/62—Use of additives, e.g. for stabilisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/92—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with a hetero atom directly attached to the ring nitrogen atom
    • C07D211/94—Oxygen atom, e.g. piperidine N-oxide

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Hydrogenated Pyridines (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polymerisation Methods In General (AREA)
JP2000560075A 1998-07-14 1998-07-14 （メタ）アクリレートモノマーのための重合防止剤としての１−オキシル−４−ヒドロキシ−または４−アミノ−２，２，６，６−テトラメチルピペリジンの誘導体 Expired - Fee Related JP4499919B2 (ja)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/EP1998/004382 WO2000003965A1 (en) 1998-07-14 1998-07-14 Derivatives of 1-oxyl-4-hydroxy- or 4-amino-2,2,6,6-tetramethylpiperidine as polymerization inhibitors for (meth)acrylate monomers

Publications (3)

Publication Number Publication Date
JP2002520379A JP2002520379A (ja) 2002-07-09
JP2002520379A5 JP2002520379A5 (https=) 2006-01-05
JP4499919B2 true JP4499919B2 (ja) 2010-07-14

Family

ID=8167003

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2000560075A Expired - Fee Related JP4499919B2 (ja) 1998-07-14 1998-07-14 （メタ）アクリレートモノマーのための重合防止剤としての１−オキシル−４−ヒドロキシ−または４−アミノ−２，２，６，６−テトラメチルピペリジンの誘導体

Country Status (8)

Country Link
EP (2) EP2030963B1 (https=)
JP (1) JP4499919B2 (https=)
KR (1) KR20010106405A (https=)
AU (1) AU8542498A (https=)
CA (1) CA2337032C (https=)
DE (1) DE69840389D1 (https=)
ES (2) ES2364724T3 (https=)
WO (1) WO2000003965A1 (https=)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100417098B1 (ko) * 1998-07-27 2004-02-05 니폰 쇼쿠바이 컴파니 리미티드 비닐 화합물의 중합 억제 방법
JP3863694B2 (ja) * 1999-12-24 2006-12-27 株式会社日本触媒 ビニル化合物中のｎ−オキシル化合物の安定化方法
BR0110854B1 (pt) 2000-05-19 2017-10-24 Ciba Specialty Chemicals Holdings Inc Method for reducing the polypropylene molecular weight, propylene copolymers or polypropylene mixtures, as a compound
WO2005061556A1 (ja) * 2003-12-24 2005-07-07 Mitsubishi Chemical Corporation （メタ）アクリル酸混合物の重合性の評価方法
ES2317123T5 (es) 2005-09-27 2017-05-05 Nestec S.A. Módulo de extracción para un dispositivo de producción de bebidas a partir de cápsulas
JP4961176B2 (ja) * 2006-07-31 2012-06-27 三菱レイヨン株式会社 含酸素アルコール残基を有する（メタ）アクリル酸エステル用重合防止剤および該（メタ）アクリル酸エステルの混合物
JP5191702B2 (ja) * 2006-08-01 2013-05-08 三菱レイヨン株式会社 Ｎ−オキシル化合物、その製造方法および重合防止方法
KR100891954B1 (ko) * 2007-05-02 2009-04-07 전병준 비닐아세테이트 단량체 제조공정중의 중합방지방법
US9399622B2 (en) 2013-12-03 2016-07-26 Ecolab Usa Inc. Nitroxide hydroxylamine and phenylenediamine combinations as polymerization inhibitors for ethylenically unsaturated monomer processes
CN116410124A (zh) * 2023-03-01 2023-07-11 烟台新特路新材料科技有限公司 一种含不饱和烃和自由基的自修复高分子助剂及其合成方法

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1127127A (en) 1966-04-26 1968-09-11 Bp Chem Int Ltd Stabilization of acrylic acid
GB1124009A (en) 1966-04-26 1968-08-14 Bp Chem Int Ltd Polymerization of chloroprene
GB1346774A (en) 1970-10-05 1974-02-13 Bp Chem Int Ltd Stabilisation of acrylonitrile
US4472547A (en) 1983-06-30 1984-09-18 Ciba-Geigy Corporation N-Piperidyl lactam light stabilizers
JPS6036501A (ja) 1983-08-10 1985-02-25 Adeka Argus Chem Co Ltd ビニル重合禁止剤
ATE49588T1 (de) 1984-10-10 1990-02-15 Amoco Corp Verfahren zur reinigung von methacrylsaeure.
DE69108626T2 (de) * 1990-07-20 1995-08-24 Ciba Geigy Ag Stabilisierte Monomerenzusammensetzungen.
JP3227204B2 (ja) 1992-05-21 2001-11-12 株式会社クラレ （メタ）アクリル酸の重合防止方法
JP3197947B2 (ja) 1992-05-21 2001-08-13 株式会社クラレ （メタ）アクリル酸の重合防止法
US5254760A (en) 1992-07-29 1993-10-19 Ciba-Geigy Corporation Inhibiting polymerization of vinyl aromatic monomers
US5322960A (en) 1993-04-15 1994-06-21 Nippon Shokubai Co., Ltd. Method for inhibiting polymerization of (meth) acrylic acid and esters thereof
TW294658B (https=) 1994-06-02 1997-01-01 Nippon Catalytic Chem Ind
EP0697386B1 (de) 1994-08-19 1998-11-25 Hüls Aktiengesellschaft Inhibierung der Polymerisation von Styrol
US5545786C1 (en) 1994-11-28 2001-10-16 Ciba Geigy Corp Method for inhibiting premature polymerization of vinyl aromatic monomers
DE19510184A1 (de) 1995-03-21 1996-09-26 Basf Ag 4-Acylaminopiperidin-N-oxyle
EP0791573A1 (en) 1996-02-21 1997-08-27 Nalco/Exxon Chemicals Company L.P. Nitroxides as antipolymerants for vinyl acetate units
DE19609312A1 (de) 1996-03-09 1997-09-11 Basf Ag Stabilisierte Monomerenzusammensetzung
JPH09268138A (ja) 1996-04-02 1997-10-14 Hakuto Co Ltd スチレン類の重合抑制方法
DE69701590T2 (de) 1996-05-27 2000-09-07 Mitsubishi Chemical Corp., Tokio/Tokyo Verfahren zur Polymerisationsinhibierung von (Meth-)Acrylsäure und ihrer Ester
GB9614854D0 (en) * 1996-07-15 1996-09-04 Marks A H & Co Ltd Free radical scavengers
US5877344A (en) * 1997-06-13 1999-03-02 Ciba Specialty Chemicals Corporation Polymerization inhibition of acrylates using blends of nitroxides
RU2223985C2 (ru) * 1997-07-23 2004-02-20 Циба Спешиалти Кемикалз Холдинг Инк. Ингибирование пожелтения целлюлозы и бумаги с использованием нитроксидов и других совместно вводимых добавок
JP4137228B2 (ja) * 1998-04-27 2008-08-20 旭化成ケミカルズ株式会社 メタクリル酸シクロヘキシルの製造方法

Also Published As

Publication number Publication date
ES2364724T3 (es) 2011-09-13
ES2316167T3 (es) 2009-04-01
DE69840389D1 (en) 2009-02-05
AU8542498A (en) 2000-02-07
EP1095006B1 (en) 2008-12-24
EP2030963A2 (en) 2009-03-04
CA2337032A1 (en) 2000-01-27
WO2000003965A1 (en) 2000-01-27
JP2002520379A (ja) 2002-07-09
EP2030963A3 (en) 2009-05-20
EP2030963B1 (en) 2011-06-08
KR20010106405A (ko) 2001-11-29
CA2337032C (en) 2008-12-02
EP1095006A1 (en) 2001-05-02

Similar Documents

Publication Publication Date Title
US5932735A (en) Derivatives of 1-oxyl-4-hydroxy-2,2,6,6-tetramethylpiperidine as polymerization inhibitors for (meth)acrylate monomers
EP1527079B1 (fr) Alcoxyamines issues de nitroxydes beta-phosphores
US5750765A (en) 7-substituted quinone methides as inhibitors for unsaturated monomers
JP4499919B2 (ja) （メタ）アクリレートモノマーのための重合防止剤としての１−オキシル−４−ヒドロキシ−または４−アミノ−２，２，６，６−テトラメチルピペリジンの誘導体
US6218536B1 (en) 1,2-bis-adducts of stable nitroxides with substituted ethylenes and stabilized compositions
US20100168434A1 (en) Inhibition of polymerisation
JP4647793B2 (ja) ラジカル重合の急停止法
JPH05194614A (ja) アクリル酸およびエステルの重合抑制剤
EP1056711B1 (de) Verfahren zur stabilisierung von (meth)acrylsäureestern gegen unerwünschte radikalische polymerisation
KR20070090805A (ko) 올레핀계 불포화 단량체를 안정화시키기 위한 중합 억제제
US5928558A (en) Derivatives of 1-oxyl-4-amino-2,2,6,6-tetramethylpiperidine as polymerization inhibitors for (meth)acrylate monomers
JP2022512587A (ja) アミノアルキル（メタ）アクリレートの安定化
KR20010031537A (ko) 라디칼 중합 반응의 즉시 종결 방법
JP4131005B2 (ja) 蒸留による（メタ）アクリルモノマーの精製方法
JP6393288B2 (ja) 早期重合の防止方法
JP3422987B2 (ja) Ｎ−オキシル化合物、その製造方法ならびにそのｎ−オキシル化合物を用いるビニル型単量体の重合防止方法
JP2002516298A (ja) 不飽和有機化合物を重合から安定化する方法
MXPA01000415A (en) Derivatives of 1-oxyl-4-hydroxy- or 4-amino-2,2,6,6-tetramethylpiperidine as polymerization inhibitors for (meth)acrylate monomers
JP2758239B2 (ja) 酸モノマーの重合を禁止する方法
JP3595110B2 (ja) Ｃ−ｈ−酸化合物のニトロソ化方法
JP2000327658A (ja) 安定化された２，２，６，６−テトラメチル−４−ヒドロキシピペリジン−ｎ−オキシル組成物
JP4618853B2 (ja) 気相熱分解時の重合防止方法
JPH07309826A (ja) （メタ）アクリル酸及びそのエステルの重合を防止するための安定剤
JP2004300031A (ja) （メタ）アクリル酸エステル類の重合防止剤
JPH0434984B2 (https=)

Legal Events

Date Code Title Description
A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20050705

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20050705

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20080730

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20081027

A602 Written permission of extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A602

Effective date: 20081104

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20081224

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20090805

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20090929

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20100331

A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20100416

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20130423

Year of fee payment: 3

R150 Certificate of patent or registration of utility model

Free format text: JAPANESE INTERMEDIATE CODE: R150

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20140423

Year of fee payment: 4

LAPS Cancellation because of no payment of annual fees