JP4423485B2 - 安定なニトロキシドと置換されたエチレンとの１，２−ビス−付加物および安定化された組成物 - Google Patents

安定なニトロキシドと置換されたエチレンとの１，２−ビス−付加物および安定化された組成物 Download PDF

Info

Publication number
JP4423485B2
JP4423485B2 JP34715897A JP34715897A JP4423485B2 JP 4423485 B2 JP4423485 B2 JP 4423485B2 JP 34715897 A JP34715897 A JP 34715897A JP 34715897 A JP34715897 A JP 34715897A JP 4423485 B2 JP4423485 B2 JP 4423485B2
Authority
JP
Japan
Prior art keywords
bis
butyl
tert
styrene
tetramethyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP34715897A
Other languages
English (en)
Japanese (ja)
Other versions
JPH10182605A5 (https=
JPH10182605A (ja
Inventor
トーマス カンクル グレン
フレンド トムソン トーマス
ハートムット フォン アーン フォルカー
アーサー エドウィン ウインター ローランド
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Schweiz AG
Original Assignee
Ciba Holding AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Holding AG filed Critical Ciba Holding AG
Publication of JPH10182605A publication Critical patent/JPH10182605A/ja
Publication of JPH10182605A5 publication Critical patent/JPH10182605A5/ja
Application granted granted Critical
Publication of JP4423485B2 publication Critical patent/JP4423485B2/ja
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/04—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D211/06—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members
    • C07D211/08—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hydrocarbon or substituted hydrocarbon radicals directly attached to ring carbon atoms
    • C07D211/10—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hydrocarbon or substituted hydrocarbon radicals directly attached to ring carbon atoms with radicals containing only carbon and hydrogen atoms attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/22—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with hetero atoms directly attached to ring nitrogen atoms
    • C07D295/24—Oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/38—Separation; Purification; Stabilisation; Use of additives
    • C07C17/42—Use of additives, e.g. for stabilisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C239/00—Compounds containing nitrogen-to-halogen bonds; Hydroxylamino compounds or ethers or esters thereof
    • C07C239/08—Hydroxylamino compounds or their ethers or esters
    • C07C239/20—Hydroxylamino compounds or their ethers or esters having oxygen atoms of hydroxylamino groups etherified
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D207/04—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members
    • C07D207/06—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with radicals, containing only hydrogen and carbon atoms, attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/92—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with a hetero atom directly attached to the ring nitrogen atom
    • C07D211/94—Oxygen atom, e.g. piperidine N-oxide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D223/00—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom
    • C07D223/02—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom not condensed with other rings
    • C07D223/04—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom not condensed with other rings with only hydrogen atoms, halogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D403/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00
    • C07D403/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings
    • C07D403/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings linked by a chain containing hetero atoms as chain links
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
    • C08K5/3432—Six-membered rings
    • C08K5/3435—Piperidines

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Hydrogenated Pyridines (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polymerisation Methods In General (AREA)
  • Indole Compounds (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
JP34715897A 1996-12-02 1997-12-02 安定なニトロキシドと置換されたエチレンとの１，２−ビス−付加物および安定化された組成物 Expired - Lifetime JP4423485B2 (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/755,882 1996-12-02
US08/755,882 US5844025A (en) 1996-12-02 1996-12-02 1,2-Bis-adducts of stable nitroxides with substituted ethylenes and stabilized compositions

Related Child Applications (1)

Application Number Title Priority Date Filing Date
JP2009121997A Division JP2009242802A (ja) 1996-12-02 2009-05-20 早期重合に対して安定化された組成物

Publications (3)

Publication Number Publication Date
JPH10182605A JPH10182605A (ja) 1998-07-07
JPH10182605A5 JPH10182605A5 (https=) 2005-07-21
JP4423485B2 true JP4423485B2 (ja) 2010-03-03

Family

ID=25041071

Family Applications (2)

Application Number Title Priority Date Filing Date
JP34715897A Expired - Lifetime JP4423485B2 (ja) 1996-12-02 1997-12-02 安定なニトロキシドと置換されたエチレンとの１，２−ビス−付加物および安定化された組成物
JP2009121997A Pending JP2009242802A (ja) 1996-12-02 2009-05-20 早期重合に対して安定化された組成物

Family Applications After (1)

Application Number Title Priority Date Filing Date
JP2009121997A Pending JP2009242802A (ja) 1996-12-02 2009-05-20 早期重合に対して安定化された組成物

Country Status (11)

Country Link
US (2) US5844025A (https=)
EP (1) EP0845458B1 (https=)
JP (2) JP4423485B2 (https=)
KR (1) KR100471949B1 (https=)
CN (1) CN1174968C (https=)
BR (1) BR9706064A (https=)
CA (1) CA2223112C (https=)
DE (1) DE69708028T2 (https=)
ES (1) ES2165015T3 (https=)
RU (1) RU2187502C2 (https=)
TW (1) TW434287B (https=)

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19725519A1 (de) * 1997-06-17 1998-12-24 Basf Ag Stoffmischung, enthaltend vinylgruppenhaltige Verbindungen und Stabilisatoren
US6148379A (en) * 1997-09-19 2000-11-14 Silicon Graphics, Inc. System, method and computer program product for page sharing between fault-isolated cells in a distributed shared memory system
US6235819B1 (en) * 1997-12-31 2001-05-22 Bridgestone Corporation Process to scavenge amines in polymeric compounds by treatment with triazine derivatives and compositions therefrom
US6040488A (en) * 1998-06-02 2000-03-21 Ppg Industries Ohio, Inc. Stabilization of vinylidene chloride
US5910232A (en) * 1998-06-10 1999-06-08 Nalco/Exxon Energy Chemicals, L.P. Method for inhibiting polymer formation in styrene processing
AU760809B2 (en) * 1998-09-09 2003-05-22 Baker Hughes Incorporated Styrene monomer polymerization inhibition using substituted dihydroxyarenes and nitroxides
AU5817099A (en) * 1998-09-09 2000-03-27 Baker Hughes Incorporated Vinyl monomer polymerization inhibition using hindered hydroxylamines
US6271377B1 (en) 1999-02-25 2001-08-07 Ciba Specialty Chemicals Corporation Hydroxy-substituted N-alkoxy hindered amines and compositions stabilized therewith
US6392041B1 (en) 1999-02-25 2002-05-21 Ciba Specialty Chemicals Corporation Hydroxy-substituted N-alkoxy hindered amines and compositions stabilized therewith
GB0003326D0 (en) * 1999-02-25 2000-04-05 Ciba Sc Holding Ag Hydroxy-Substituted N-Alkoxy hindered amines
US6376584B1 (en) 1999-02-25 2002-04-23 Ciba Specialty Chemicals Corporation Hydroxy-substituted N-alkoxy hindered amines and compositions stabilized therewith
US6472486B2 (en) 1999-03-09 2002-10-29 Symyx Technologies, Inc. Controlled stable free radical emulsion polymerization processes
JP4829447B2 (ja) * 1999-07-02 2011-12-07 チバ ホールディング インコーポレーテッド 官能化されたマクロマーの製造のための１および多官能価アルコキシアミン
US6716948B1 (en) * 1999-07-31 2004-04-06 Symyx Technologies, Inc. Controlled-architecture polymers and use thereof as separation media
DE19938841A1 (de) * 1999-08-17 2001-02-22 Basf Ag Inhibitorkomposition zur Stabilisierung von radikalisch polymerisierbaren Substanzen
US6525146B1 (en) * 2000-04-03 2003-02-25 Baker Hughes Incorporated Inhibition of popcorn polymer growth
US20030041268A1 (en) * 2000-10-18 2003-02-27 Noriaki Hashimoto Method and system for preventing unauthorized access to the internet
DE10106543A1 (de) * 2001-02-13 2002-08-22 Basf Ag Beschichtungsmittelzusammensetzungen
US20040143051A1 (en) * 2003-01-22 2004-07-22 Jianfeng Lou Unsaturated polyester resin compositions with improved processing and storage stability
US7118689B2 (en) 2003-08-27 2006-10-10 Ppg Industries Ohio, Inc. Stabilized polychloroethylenes
RU2262959C1 (ru) * 2004-04-02 2005-10-27 Степанченко Алексей Васильевич Способ лечения больных с обострениями неврологических заболеваний
ATE465183T1 (de) * 2005-08-30 2010-05-15 Basf Se Aus nitroxylradikalpolymerisation gewonnene polymere
US20100143580A1 (en) * 2008-05-28 2010-06-10 American Air Liquide, Inc. Stabilization of Bicycloheptadiene
KR101892623B1 (ko) * 2011-04-29 2018-08-30 삼성디스플레이 주식회사 중성표면을 형성하기 위한 랜덤 공중합체 및 그 제조 및 사용 방법들
ES2986971T3 (es) 2018-12-03 2024-11-13 Trinseo Europe Gmbh Espumas y método de formación de espumas de ionómeros de copolímeros de monómero aromático de vinilideno y compuestos insaturados con grupos ácidos

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4547537A (en) * 1984-08-02 1985-10-15 Ciba-Geigy Corporation N-Piperidyl tetrahydro-1,4-oxazin-2-one light stabilizers
SU1583415A1 (ru) * 1985-04-16 1990-08-07 Предприятие П/Я А-7253 Способ получени 4-окси-2,2,6,6-тетраметилпиперидин-1-оксила
JPS62167734A (ja) * 1986-01-18 1987-07-24 Sumitomo Chem Co Ltd 重合体副生成物の生成を防止する方法
ES2065924T5 (es) * 1987-09-21 2002-12-16 Ciba Sc Holding Ag Estabilizadores a base de amidas bloqueadas n-substituidas.
SU1558888A1 (ru) * 1987-12-11 1990-04-23 Всесоюзный Научно-Исследовательский Институт Химических Реактивов И Особочистых Химических Веществ Способ ингибировани полимеризации стирола
DE69026747T2 (de) * 1989-03-21 1996-11-14 Ciba Geigy Ag Nichtwandernde 1-Hydrocarbyloxy-gehinderte Amineverbindungen als Polymerstabilisatoren
EP0467851A1 (en) * 1990-07-20 1992-01-22 Ciba-Geigy Ag Stabilized monomer compositions
IT1246779B (it) * 1991-04-12 1994-11-26 Ciba Geigy Spa Composti piperidinici atti all'impiego come stabilizzanti per materiali organici.
US5322960A (en) * 1993-04-15 1994-06-21 Nippon Shokubai Co., Ltd. Method for inhibiting polymerization of (meth) acrylic acid and esters thereof
DE19510184A1 (de) * 1995-03-21 1996-09-26 Basf Ag 4-Acylaminopiperidin-N-oxyle
DE69710163T2 (de) * 1996-12-02 2002-10-02 Ondeo Nalco Energy Services, L.P. Hemmung der Polymerisation von vinylaromatischen Monomeren

Also Published As

Publication number Publication date
ES2165015T3 (es) 2002-03-01
BR9706064A (pt) 2000-03-14
US5844025A (en) 1998-12-01
JP2009242802A (ja) 2009-10-22
EP0845458A1 (en) 1998-06-03
RU2187502C2 (ru) 2002-08-20
MX9709369A (es) 1998-07-31
DE69708028T2 (de) 2002-06-06
TW434287B (en) 2001-05-16
KR19980063593A (ko) 1998-10-07
CA2223112A1 (en) 1998-06-02
DE69708028D1 (de) 2001-12-13
US6218536B1 (en) 2001-04-17
KR100471949B1 (ko) 2006-04-28
EP0845458B1 (en) 2001-11-07
CN1184102A (zh) 1998-06-10
CN1174968C (zh) 2004-11-10
CA2223112C (en) 2007-11-06
JPH10182605A (ja) 1998-07-07

Similar Documents

Publication Publication Date Title
JP4423485B2 (ja) 安定なニトロキシドと置換されたエチレンとの１，２−ビス−付加物および安定化された組成物
DE69232614T2 (de) 5-thio-substituierte benzotriazole, uv-absorber und stabilisierte mischungen
DE60210751T2 (de) Sterisch gehinderte n-(hydroxy-alkoxy)-substituierte amine und damit stabilisierte zusammensetzungen
US5021478A (en) Compounds containing both UV-absorber and 1-hydrocarbyloxy hindered amine moieties and stabilized compositions
DE69012615T2 (de) Äthylenisch ungesättigte Verbindungen, die 1-Hydrocarbyloxy-2,2,6,6-tetramethylpiperidine-Teile enthalten, und Polymere, Copolymere und stabilisierte Zusammensetzungen.
EP0389427B1 (en) Compounds containing both uv-absorber and 1-hydrocarbyloxy hindered amine moieties and stabilized compositions
US5380828A (en) Azodicarboxylic acid derivatives containing hindered amine moieties as polymer stabilizers
JPH09110841A (ja) ベンゾトリアゾールまたはベンゾフェノン部分により置換されたハイブリッドｓ−トリアジン光安定剤およびそれにより安定化された組成物
JP2867060B2 (ja) リン部分により置換されたｎ―ハイドロカルビルオキシ―ヒンダードアミン系光安定剤
JP2973122B2 (ja) ２，２，６，６，―テトラメチルピペリジンの不飽和誘導体並びに光安定剤および架橋剤としてのそれらの用途
US5185448A (en) Substituted 1-oxy-4-acyloxypiperidine and 1-oxy-4-acylaminopiperidine stabilizers
JP2860588B2 (ja) ビス（１―ヒドロカルビルオキシ―２，２，６，６―テトラメチルピペリジン―４―イル）アミン誘導体および安定化組成物
US5204422A (en) Peroxide free radical initiators containing hindered amine moieties with low basicity
US5140081A (en) Peroxide free radical initiators containing hindered amine moieties with low basicity
DE69400410T2 (de) 2-(Benzotriazol-2-yl)-4-alkyl-6-(2-hydroxy-3-benzoyl-benzyl)-phenole und stabilisierte Zusammensetzungen
DE69008402T2 (de) Poly(1-hydrocarbyloxy-2,2,6,6-tetraalkylpiperidin)- Lichtstabilisatoren.
US5051511A (en) Peroxide free radical initiators containing hindered amine moieties with low basicity
JP2879160B2 (ja) ヒンダードアミン置換ｓ―トリアジンのＮ―ヒドロカルビルオキシ誘導体
DE69012618T2 (de) Derivate des Triazins und des Hexahydrotriazins mit gehinderter Aminfunktion.
US5134183A (en) Sterically hindered oxime color improvers for polyolefin processing
US5371125A (en) Substituted 1-hydroxy-2,6-diaryl-4-acyloxypiperidines or 1-hydroxy-2,6-diaryl-4-acylaminopiperidines and stabilized compositions
US5266726A (en) Sterically hindered oxime color improvers for polyolefin processing
DE69012616T2 (de) Stabilisatoren mit N-hydroxy-substituierter, gehinderter Aminogruppe und ihre Herstellung durch Michael-Addition.
US5180829A (en) Substituted 1-hydroxy-2,6-diaryl-4-acyloxypiperidines or 1-hydroxy-2,6-diaryl-4-acylaminopiperidines and stabilized compositions
EP0389423B1 (en) Peroxide compounds containing hindered amine moieties with low basicity

Legal Events

Date Code Title Description
A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20041202

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20041202

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20080806

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20080820

A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20081120

A02 Decision of refusal

Free format text: JAPANESE INTERMEDIATE CODE: A02

Effective date: 20090204

A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20090520

A911 Transfer to examiner for re-examination before appeal (zenchi)

Free format text: JAPANESE INTERMEDIATE CODE: A911

Effective date: 20090713

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20091111

A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20091124

R150 Certificate of patent or registration of utility model

Free format text: JAPANESE INTERMEDIATE CODE: R150

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20121218

Year of fee payment: 3

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20121218

Year of fee payment: 3

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20131218

Year of fee payment: 4

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

EXPY Cancellation because of completion of term