JP4405787B2 - ポリアミド結合を有する有体物の着色方法および該方法で着色された有体物 - Google Patents
ポリアミド結合を有する有体物の着色方法および該方法で着色された有体物 Download PDFInfo
- Publication number
- JP4405787B2 JP4405787B2 JP2003382358A JP2003382358A JP4405787B2 JP 4405787 B2 JP4405787 B2 JP 4405787B2 JP 2003382358 A JP2003382358 A JP 2003382358A JP 2003382358 A JP2003382358 A JP 2003382358A JP 4405787 B2 JP4405787 B2 JP 4405787B2
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- JP
- Japan
- Prior art keywords
- coloring
- polyamide
- manufactured
- tangible
- aqueous solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000004952 Polyamide Substances 0.000 title claims description 29
- 229920002647 polyamide Polymers 0.000 title claims description 29
- 238000004040 coloring Methods 0.000 title claims description 18
- 238000000034 method Methods 0.000 title claims description 17
- 239000000463 material Substances 0.000 title description 17
- 239000000126 substance Substances 0.000 claims description 47
- 239000007864 aqueous solution Substances 0.000 claims description 30
- 150000003839 salts Chemical class 0.000 claims description 28
- 229910052751 metal Inorganic materials 0.000 claims description 24
- 239000002184 metal Substances 0.000 claims description 24
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 21
- 239000004744 fabric Substances 0.000 claims description 18
- 239000010985 leather Substances 0.000 claims description 8
- 239000000835 fiber Substances 0.000 claims description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 4
- BRRSNXCXLSVPFC-UHFFFAOYSA-N 2,3,4-Trihydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C(O)=C1O BRRSNXCXLSVPFC-UHFFFAOYSA-N 0.000 claims description 2
- CRPNQSVBEWWHIJ-UHFFFAOYSA-N 2,3,4-trihydroxybenzaldehyde Chemical compound OC1=CC=C(C=O)C(O)=C1O CRPNQSVBEWWHIJ-UHFFFAOYSA-N 0.000 claims description 2
- IXWOUPGDGMCKGT-UHFFFAOYSA-N 2,3-dihydroxybenzaldehyde Chemical compound OC1=CC=CC(C=O)=C1O IXWOUPGDGMCKGT-UHFFFAOYSA-N 0.000 claims description 2
- WXTMDXOMEHJXQO-UHFFFAOYSA-N 2,5-dihydroxybenzoic acid Chemical compound OC(=O)C1=CC(O)=CC=C1O WXTMDXOMEHJXQO-UHFFFAOYSA-N 0.000 claims description 2
- 229920000742 Cotton Polymers 0.000 claims description 2
- 239000004745 nonwoven fabric Substances 0.000 claims description 2
- 239000002759 woven fabric Substances 0.000 claims description 2
- -1 yarn Substances 0.000 claims description 2
- 239000003205 fragrance Substances 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 22
- 238000004043 dyeing Methods 0.000 description 16
- 239000000243 solution Substances 0.000 description 15
- IBGBGRVKPALMCQ-UHFFFAOYSA-N 3,4-dihydroxybenzaldehyde Chemical compound OC1=CC=C(C=O)C=C1O IBGBGRVKPALMCQ-UHFFFAOYSA-N 0.000 description 14
- 229910021577 Iron(II) chloride Inorganic materials 0.000 description 12
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 description 12
- 125000003118 aryl group Chemical group 0.000 description 11
- 210000002268 wool Anatomy 0.000 description 10
- 239000003795 chemical substances by application Substances 0.000 description 8
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 8
- PCYGLFXKCBFGPC-UHFFFAOYSA-N 3,4-Dihydroxy hydroxymethyl benzene Natural products OCC1=CC=C(O)C(O)=C1 PCYGLFXKCBFGPC-UHFFFAOYSA-N 0.000 description 7
- IUNJCFABHJZSKB-UHFFFAOYSA-N 2,4-dihydroxybenzaldehyde Chemical compound OC1=CC=C(C=O)C(O)=C1 IUNJCFABHJZSKB-UHFFFAOYSA-N 0.000 description 6
- 210000004209 hair Anatomy 0.000 description 6
- IUTKPPDDLYYMBE-UHFFFAOYSA-N 3,4,5-trihydroxybenzoic acid;hydrate Chemical compound O.OC(=O)C1=CC(O)=C(O)C(O)=C1 IUTKPPDDLYYMBE-UHFFFAOYSA-N 0.000 description 5
- 239000000975 dye Substances 0.000 description 5
- 229940097942 gallic acid monohydrate Drugs 0.000 description 5
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 102000004169 proteins and genes Human genes 0.000 description 4
- 108090000623 proteins and genes Proteins 0.000 description 4
- KHMGIQHRSVLFQG-OZVSTBQFSA-M r044n53c06 Chemical compound COS([O-])(=O)=O.C1([C@@H](CO)C(=O)OC2C[C@@H]3[N+]([C@H](C2)[C@@H]2[C@H]3O2)(C)C)=CC=CC=C1 KHMGIQHRSVLFQG-OZVSTBQFSA-M 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- 239000004677 Nylon Substances 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 229920001778 nylon Polymers 0.000 description 3
- TUSDEZXZIZRFGC-UHFFFAOYSA-N 1-O-galloyl-3,6-(R)-HHDP-beta-D-glucose Natural products OC1C(O2)COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC1C(O)C2OC(=O)C1=CC(O)=C(O)C(O)=C1 TUSDEZXZIZRFGC-UHFFFAOYSA-N 0.000 description 2
- AKEUNCKRJATALU-UHFFFAOYSA-N 2,6-dihydroxybenzoic acid Chemical compound OC(=O)C1=C(O)C=CC=C1O AKEUNCKRJATALU-UHFFFAOYSA-N 0.000 description 2
- 239000001263 FEMA 3042 Substances 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- LRBQNJMCXXYXIU-PPKXGCFTSA-N Penta-digallate-beta-D-glucose Natural products OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-PPKXGCFTSA-N 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 2
- 239000000118 hair dye Substances 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 229930014626 natural product Natural products 0.000 description 2
- WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 235000015523 tannic acid Nutrition 0.000 description 2
- LRBQNJMCXXYXIU-NRMVVENXSA-N tannic acid Chemical compound OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-NRMVVENXSA-N 0.000 description 2
- 229940033123 tannic acid Drugs 0.000 description 2
- 229920002258 tannic acid Polymers 0.000 description 2
- HTQNYBBTZSBWKL-UHFFFAOYSA-N 2,3,4-trihydroxbenzophenone Chemical compound OC1=C(O)C(O)=CC=C1C(=O)C1=CC=CC=C1 HTQNYBBTZSBWKL-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- RGHHSNMVTDWUBI-UHFFFAOYSA-N 4-hydroxybenzaldehyde Chemical compound OC1=CC=C(C=O)C=C1 RGHHSNMVTDWUBI-UHFFFAOYSA-N 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N 4-hydroxybenzoic acid Chemical group OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 102000009027 Albumins Human genes 0.000 description 1
- 108010088751 Albumins Proteins 0.000 description 1
- AOMZHDJXSYHPKS-DROYEMJCSA-L Amido Black 10B Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC2=CC(S([O-])(=O)=O)=C(\N=N\C=3C=CC=CC=3)C(O)=C2C(N)=C1\N=N\C1=CC=C(N(=O)=O)C=C1 AOMZHDJXSYHPKS-DROYEMJCSA-L 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- HDYRYUINDGQKMC-UHFFFAOYSA-M acetyloxyaluminum;dihydrate Chemical compound O.O.CC(=O)O[Al] HDYRYUINDGQKMC-UHFFFAOYSA-M 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 229940009827 aluminum acetate Drugs 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000010014 continuous dyeing Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 150000001879 copper Chemical class 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000001962 electrophoresis Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 229940074391 gallic acid Drugs 0.000 description 1
- 235000004515 gallic acid Nutrition 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- UCNNJGDEJXIUCC-UHFFFAOYSA-L hydroxy(oxo)iron;iron Chemical compound [Fe].O[Fe]=O.O[Fe]=O UCNNJGDEJXIUCC-UHFFFAOYSA-L 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 150000008442 polyphenolic compounds Chemical class 0.000 description 1
- 235000013824 polyphenols Nutrition 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/653—Nitrogen-free carboxylic acids or their salts
- D06P1/6536—Aromatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/152—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen having a hydroxy group bound to a carbon atom of a six-membered aromatic ring
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
- D06M13/238—Tannins, e.g. gallotannic acids
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/34—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using natural dyestuffs
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/62—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds with sulfate, sulfonate, sulfenic or sulfinic groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/653—Nitrogen-free carboxylic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67333—Salts or hydroxides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
- D06P3/04—Material containing basic nitrogen containing amide groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
- D06P3/04—Material containing basic nitrogen containing amide groups
- D06P3/14—Wool
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
- D06P3/04—Material containing basic nitrogen containing amide groups
- D06P3/24—Polyamides; Polyurethanes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
- D06P3/04—Material containing basic nitrogen containing amide groups
- D06P3/32—Material containing basic nitrogen containing amide groups leather skins
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Coloring (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Description
濃色化できる。
連続処理での着色が可能である。
再現性が有り、耐光堅牢度に優れている。
実施例1
0.2wt% 3,4−ジヒドロキシベンズアルデヒド(和光純薬工業(株)製)、0.5wt%塩化鉄(II)(和光純薬工業(株)製)及び0.2wt%浸透剤(MAC-100S(共栄社化学(株)製))の溶液を調製し、そこへ未処理羊毛織物を入れ、98℃、1時間処理し、水洗、乾燥させた。
0.5wt% 3,4−ジヒドロキシベンズアルデヒド(和光純薬工業(株)製)、2.5wt%塩化鉄(II)(和光純薬工業(株)製)及び0.2wt%浸透剤(MAC-100S(共栄社化学(株)製))の溶液を調製し、そこへ未処理羊毛織物を入れ、98℃、1時間処理し、水洗、乾燥させた。
1wt%塩化鉄(III)(和光純薬工業(株)製)及び0.2wt%浸透剤(MAC-100S(共栄社化学(株)製))の溶液を調製し、そこへ未処理羊毛織物を入れ、98℃、1時間処理し、水洗した。次に、0.5wt%没食子酸(和光純薬工業(株)製)及び0.2wt%浸透剤(MAC-100S(共栄社化学(株)製))の溶液を調製し、先に処理した生地を入れ、98℃、1時間処理し、水洗、乾燥した。
0.2wt% 3,4−ジヒドロキシベンズアルデヒド(和光純薬工業(株)製)、0.4%酢酸アルミニウム(和光純薬工業(株)製)及び0.2wt%浸透剤(MAC-100S(共栄社化学(株)製))の溶液を調製し、そこへ未処理羊毛織物を入れ、50℃、1時間処理し、水洗、乾燥した。
0.2wt% 2,6−ジヒドロキシ安息香酸(和光純薬工業(株)製)、0.4wt%塩化鉄(II)(和光純薬工業(株)製)及び0.2wt%浸透剤(MAC-100S(共栄社化学(株)製))の溶液を調製し、そこへ未処理羊毛織物を入れ、50℃、1時間処理し、水洗、乾燥した。
0.1wt% 3,4−ジヒドロキシベンズアルデヒド(和光純薬工業(株)製)、0.1wt% 2,4-ジヒドロキシベンズアルデヒド(和光純薬工業(株)製)、0.2wt%塩化鉄(II)(和光純薬工業(株)製)及び0.2wt%浸透剤(MAC-100S(共栄社化学(株)製))の溶液を調製し、そこへ未処理羊毛織物を入れ、50℃、1時間処理し、水洗、乾燥した。
処理温度を30℃で行った以外は、実施例1と同様に未処理羊毛織物を処理した。
実施例7
牛皮革13.6gを没食子酸一水和物(和光純薬工業(株)製)0.27g、塩化鉄(III)(和光純薬工業(株)製)0.54gの水溶液20.4mlに加えて45℃、30分処理した。更に加脂剤(サンドリックスJAK(クラリアントジャパン(株)製))0.82gを反応液に投入し、45℃、30分間処理して黒に着色した。反応終了後、水洗を3回行い、室温にて乾燥させた。
牛皮革13.4gをAcid Black 1(東京化成工業(株)製)1.6gの水溶液20.1mlに加えて45℃、30分処理した。続いて加脂剤(サンドリックスJAK(クラリアントジャパン(株)製))0.8gを反応液に投入し、45℃、30分間処理し、更に0.8mlのギ酸を加えて45℃、20分間処理して濃紺に染色した。反応終了後、水洗を3回行い、室温にて乾燥させた。
牛皮革0.3gを3,4−ジヒドロキシベンズアルデヒド(東京化成工業(株))15mg、塩化鉄(II)(和光純薬工業(株)製)12mg、pHを6に調整するために炭酸水素ナトリウム(キシダ化学(株)製)6mgを加えた水溶液0.9mlに加えて45℃、30分間処理した。更に加脂剤(サンドリックスJAK(クラリアントジャパン(株)製))18mgを反応液に投入し、45℃、30分間処理して黒色に着色した。反応終了後、水洗を3回行い、室温にて乾燥させた。
牛皮革0.3gを2,4−ジヒドロキシベンズアルデヒド(東京化成工業(株)製)15mg、塩化鉄(II)(和光純薬工業(株)製)15mgの水溶液0.9mlに加えて45℃、30分間処理した。更に加脂剤(サンドリックスJAK(クラリアントジャパン(株)製)18mgを反応液に投入し、45℃、30分間処理して茶色に着色した。反応終了後、水洗を3回行い、室温にて乾燥させた。
実施例10
3,4−ジヒドロキシベンズアルデヒド(東京化成工業(株)製)0.2g、塩化鉄(III)(和光純薬工業(株)製)0.4g、ノニオン系浸透剤(MAC-100S(共栄社化学(株)製))0.05mlを含む水溶液100mlを調製し、この水溶液に絹添付白布2-2号(JIS L 0803)3.3gを加えて、70℃、60分処理した。反応終了後、水洗し、室温で乾燥させ、灰色サンプルを得た。
没食子酸一水和物(和光純薬工業(株)製)0.1g、塩化鉄(II)(和光純薬工業(株)製)0.1g、ノニオン系浸透剤(MAC-100S(共栄社化学(株)製))0.05mlを含む水溶液100mlを調製し、この水溶液に絹添付白布2-2号(JIS L 0803)3.3gを加えて、70℃、60分処理した。反応終了後、水洗し、室温で乾燥させ、紺色サンプルを得た。
2,4−ジヒドロキシベンズアルデヒド(東京化成工業(株)製)0.2g、塩化鉄(II)(和光純薬工業(株)製)0.4g、ノニオン系浸透剤(MAC-100S(共栄社化学(株)製))0.05mlを含む水溶液100mlを調製し、この水溶液に絹添付白布2-2号(JIS L 0803)3.3gを加えて、70℃、60分処理した。反応終了後、水洗し、室温で乾燥させ、赤茶色サンプルを得た。
実施例13
3,4−ジヒドロキシベンズアルデヒド(東京化成工業(株)製)0.2g、塩化鉄(II)(和光純薬工業(株)製)0.4g、ノニオン系浸透剤(MAC-100S(共栄社化学(株)製))0.05mlを含む水溶液100mlを調製し、この水溶液にナイロン添付白布7号(JIS L 0803)3.3gを加えて、95℃、60分処理した。反応終了後、水洗し、室温で乾燥させ、赤黒色サンプルを得た。
没食子酸一水和物(和光純薬工業(株)製)0.1g、塩化鉄(II)(和光純薬工業(株)製)0.1g、ノニオン系浸透剤(MAC-100S(共栄社化学(株)製))0.05mlを含む水溶液100mlを調製し、この水溶液にナイロン添付白布7号(JIS L 0803)3.3gを加えて、95℃、60分処理した。反応終了後、水洗し、室温で乾燥させ、灰色サンプルを得た。
2,3,4−トリヒドロキシベンゾフェノン(東京化成工業(株)製)0.2g、塩化鉄(II)(和光純薬工業(株)製)0.4g、ノニオン系浸透剤(MAC-100S(共栄社化学(株)製))0.05mlを含む水溶液100mlを調製し、この水溶液にナイロン添付白布7号(JIS L 0803)3.3gを加えて、95℃、60分処理した。反応終了後、水洗し、室温で乾燥させ、緑色サンプルを得た。
没食子酸一水和物(和光純薬工業(株)製)0.17g、塩化鉄(II)(和光純薬工業(株)製)0.17g、ノニオン系浸透剤(MAC-100S(共栄社化学(株)製))0.05mlを含む水溶液84mlを調製し、この水溶液に多織交織布の交織1号(JIS L 0803)2.8gを加えて、95℃、60分処理した。反応終了後、水洗し、室温で乾燥させた。各繊維の種類で得られたLabダイアグラムを表3に示す。表3よりポリアミド有体物以外の素材では着色されなかった。
Claims (3)
- ポリアミド結合を有する、皮、ワタ、糸、織物、編物、不織布または繊維から選ばれる有体物を、ジヒドロキシ安息香酸、ジヒドロキシベンズアルデヒド、トリヒドロキシ安息香酸、またはトリヒドロキシベンズアルデヒドから選ばれる水酸基を1ヶ以上含む芳香族誘導体及び金属塩を含有する水溶液にて、40℃以上の温度で同時に又は別個に処理する工程からなり、染料を使用しないで着色することを特徴とする、ポリアミド結合を有する有体物の着色方法。
- 金属塩が鉄塩であることを特徴とする請求項1に記載の有体物の着色方法。
- 請求項1〜2いずれかに記載の方法により着色されたポリアミド結合を有する有体物。
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JP2003382358A JP4405787B2 (ja) | 2003-11-12 | 2003-11-12 | ポリアミド結合を有する有体物の着色方法および該方法で着色された有体物 |
PCT/JP2004/016544 WO2005047591A1 (ja) | 2003-11-12 | 2004-11-08 | ポリアミド結合を有する有体物の着色方法および該方法で着色された有体物 |
AU2004289885A AU2004289885B2 (en) | 2003-11-12 | 2004-11-08 | Method for coloring corporeal substance having polyamide bond and corporeal substance colored by such method |
US10/568,950 US7476263B2 (en) | 2003-11-12 | 2004-11-08 | Coloring method of tangible matter having polyamide bond and tangible matter colored by such method |
CN2004800334011A CN101035948B (zh) | 2003-11-12 | 2004-11-08 | 具有聚酰胺键的有形物的着色方法及用该方法着色的有形物 |
EP04818463A EP1683910B1 (en) | 2003-11-12 | 2004-11-08 | Method for coloring corporeal substance having polyamide bond |
NZ545615A NZ545615A (en) | 2003-11-12 | 2004-11-08 | Method for coloring corporeal substance having polyamide bond and corporeal substance colored by such method |
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JP2007262001A (ja) * | 2006-03-29 | 2007-10-11 | Shiseido Co Ltd | 毛髪染毛用組成物およびそれを用いた染毛方法 |
CN101942761B (zh) * | 2010-08-21 | 2012-08-08 | 大连工业大学 | 一种蛋白质纤维的无染料显色方法 |
CN108642863A (zh) * | 2018-05-17 | 2018-10-12 | 江苏汇鸿国际集团中锦控股有限公司 | 一种可常温染色的尼龙面料的制备方法 |
CN110055772A (zh) * | 2018-12-07 | 2019-07-26 | 广州市佐力新材料科技有限公司 | 一种皮革泡泡爆裂染料及其制备方法 |
CN109652996A (zh) * | 2018-12-25 | 2019-04-19 | 广州市佐力新材料科技有限公司 | 一种雾化分散皮革染料及其制备方法 |
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GB219995A (en) | 1922-12-01 | 1924-10-03 | Standard Silk Dyeing Company | Improvements relating to dyeing silk black |
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JPS4324207Y1 (ja) * | 1964-10-21 | 1968-10-12 | ||
DE2356548A1 (de) * | 1973-11-13 | 1975-06-26 | Cassella Farbwerke Mainkur Ag | Verfahren zum faerben von polyamidfasern mit schwefelfarbstoffen |
JPS5845401B2 (ja) | 1977-04-16 | 1983-10-08 | 株式会社資生堂 | 染毛剤 |
FR2509841B1 (fr) * | 1981-07-17 | 1986-07-18 | Creusot Loire | Perfectionnement aux generateurs de vapeur du type sodium-eau |
US4620852A (en) * | 1984-06-19 | 1986-11-04 | Toray Industries, Inc. | Grained artificial leather having good color fastness and dyeing method of ultrafine polyamide fibers |
BG50051A3 (en) | 1991-04-02 | 1992-04-15 | Dimitar K Khristov | Method for colouring of materials |
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US5516338A (en) * | 1995-01-25 | 1996-05-14 | Pai; Panemangalore S. | Water-soluble titanium salt-tannin dyes and methods of use thereof |
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JP3705335B2 (ja) | 1999-08-12 | 2005-10-12 | 福岡県 | 繊維の着色方法 |
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