JP4358336B2 - フッ素化熱可塑性エラストマー - Google Patents
フッ素化熱可塑性エラストマー Download PDFInfo
- Publication number
- JP4358336B2 JP4358336B2 JP35459698A JP35459698A JP4358336B2 JP 4358336 B2 JP4358336 B2 JP 4358336B2 JP 35459698 A JP35459698 A JP 35459698A JP 35459698 A JP35459698 A JP 35459698A JP 4358336 B2 JP4358336 B2 JP 4358336B2
- Authority
- JP
- Japan
- Prior art keywords
- fluorinated
- per
- plastomer
- segment
- elastomer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229920002725 thermoplastic elastomer Polymers 0.000 title claims description 51
- 239000000203 mixture Substances 0.000 claims description 80
- 229920000034 Plastomer Polymers 0.000 claims description 62
- 229920001971 elastomer Polymers 0.000 claims description 50
- 239000000806 elastomer Substances 0.000 claims description 50
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims description 36
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 claims description 34
- 239000004816 latex Substances 0.000 claims description 31
- 229920000126 latex Polymers 0.000 claims description 31
- 150000001336 alkenes Chemical class 0.000 claims description 28
- 239000000178 monomer Substances 0.000 claims description 28
- 229920001577 copolymer Polymers 0.000 claims description 17
- -1 Polytetrafluoroethylene Polymers 0.000 claims description 16
- 239000002033 PVDF binder Substances 0.000 claims description 15
- 229920000642 polymer Polymers 0.000 claims description 15
- 229920002981 polyvinylidene fluoride Polymers 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 14
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 13
- 238000006116 polymerization reaction Methods 0.000 claims description 12
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical compound FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 claims description 10
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical group C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 claims description 8
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 claims description 8
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical group [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 7
- 239000003431 cross linking reagent Substances 0.000 claims description 7
- 230000005855 radiation Effects 0.000 claims description 7
- 229920001169 thermoplastic Polymers 0.000 claims description 7
- UUAGAQFQZIEFAH-UHFFFAOYSA-N chlorotrifluoroethylene Chemical compound FC(F)=C(F)Cl UUAGAQFQZIEFAH-UHFFFAOYSA-N 0.000 claims description 6
- 125000001033 ether group Chemical group 0.000 claims description 6
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 5
- 125000002947 alkylene group Chemical group 0.000 claims description 5
- 229910052801 chlorine Inorganic materials 0.000 claims description 5
- 239000000460 chlorine Substances 0.000 claims description 5
- 125000003709 fluoroalkyl group Chemical group 0.000 claims description 5
- 229910052739 hydrogen Inorganic materials 0.000 claims description 5
- 125000005702 oxyalkylene group Chemical group 0.000 claims description 5
- MIZLGWKEZAPEFJ-UHFFFAOYSA-N 1,1,2-trifluoroethene Chemical group FC=C(F)F MIZLGWKEZAPEFJ-UHFFFAOYSA-N 0.000 claims description 4
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 4
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 4
- 229910052794 bromium Inorganic materials 0.000 claims description 4
- 229910052740 iodine Inorganic materials 0.000 claims description 4
- QMIWYOZFFSLIAK-UHFFFAOYSA-N 3,3,3-trifluoro-2-(trifluoromethyl)prop-1-ene Chemical compound FC(F)(F)C(=C)C(F)(F)F QMIWYOZFFSLIAK-UHFFFAOYSA-N 0.000 claims description 3
- 238000000137 annealing Methods 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 125000002993 cycloalkylene group Chemical group 0.000 claims description 3
- 238000007720 emulsion polymerization reaction Methods 0.000 claims description 3
- 239000001257 hydrogen Substances 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 239000000155 melt Substances 0.000 claims description 3
- 238000002844 melting Methods 0.000 claims description 3
- 230000008018 melting Effects 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 125000006551 perfluoro alkylene group Chemical group 0.000 claims description 3
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 3
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 3
- ABADUMLIAZCWJD-UHFFFAOYSA-N 1,3-dioxole Chemical class C1OC=CO1 ABADUMLIAZCWJD-UHFFFAOYSA-N 0.000 claims description 2
- HFNSTEOEZJBXIF-UHFFFAOYSA-N 2,2,4,5-tetrafluoro-1,3-dioxole Chemical compound FC1=C(F)OC(F)(F)O1 HFNSTEOEZJBXIF-UHFFFAOYSA-N 0.000 claims description 2
- PDFSXHZXNZCKNF-UHFFFAOYSA-N 3,3,4,4,5,5,6,6,7,7,8,8-dodecafluorodeca-1,9-diene Chemical compound C=CC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C=C PDFSXHZXNZCKNF-UHFFFAOYSA-N 0.000 claims description 2
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims description 2
- 239000000839 emulsion Substances 0.000 claims description 2
- 238000012703 microemulsion polymerization Methods 0.000 claims description 2
- 125000001246 bromo group Chemical group Br* 0.000 claims 3
- 125000002346 iodo group Chemical group I* 0.000 claims 3
- 125000001309 chloro group Chemical group Cl* 0.000 claims 2
- 125000006832 (C1-C10) alkylene group Chemical group 0.000 claims 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 1
- 239000005977 Ethylene Substances 0.000 claims 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 1
- 239000007789 gas Substances 0.000 description 13
- 238000002360 preparation method Methods 0.000 description 13
- 239000000243 solution Substances 0.000 description 13
- BLTXWCKMNMYXEA-UHFFFAOYSA-N 1,1,2-trifluoro-2-(trifluoromethoxy)ethene Chemical compound FC(F)=C(F)OC(F)(F)F BLTXWCKMNMYXEA-UHFFFAOYSA-N 0.000 description 12
- 238000006243 chemical reaction Methods 0.000 description 11
- 238000005227 gel permeation chromatography Methods 0.000 description 7
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 6
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium peroxydisulfate Substances [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 6
- VAZSKTXWXKYQJF-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)OOS([O-])=O VAZSKTXWXKYQJF-UHFFFAOYSA-N 0.000 description 6
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 6
- 238000005259 measurement Methods 0.000 description 6
- 239000004530 micro-emulsion Substances 0.000 description 5
- 230000035484 reaction time Effects 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 238000001125 extrusion Methods 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 229920002959 polymer blend Polymers 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 238000007789 sealing Methods 0.000 description 4
- JOQDDLBOAIKFQX-UHFFFAOYSA-N 1,1,2,2,3,3,4,4,5,5,6,6-dodecafluoro-1,6-diiodohexane Chemical compound FC(F)(I)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)I JOQDDLBOAIKFQX-UHFFFAOYSA-N 0.000 description 3
- 239000012986 chain transfer agent Substances 0.000 description 3
- 230000001112 coagulating effect Effects 0.000 description 3
- 230000006835 compression Effects 0.000 description 3
- 238000007906 compression Methods 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- 239000004971 Cross linker Substances 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 230000002902 bimodal effect Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 239000003480 eluent Substances 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical compound FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- BZPCMSSQHRAJCC-UHFFFAOYSA-N 1,2,3,3,4,4,5,5,5-nonafluoro-1-(1,2,3,3,4,4,5,5,5-nonafluoropent-1-enoxy)pent-1-ene Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)=C(F)OC(F)=C(F)C(F)(F)C(F)(F)C(F)(F)F BZPCMSSQHRAJCC-UHFFFAOYSA-N 0.000 description 1
- AYCANDRGVPTASA-UHFFFAOYSA-N 1-bromo-1,2,2-trifluoroethene Chemical group FC(F)=C(F)Br AYCANDRGVPTASA-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- XBRDBODLCHKXHI-UHFFFAOYSA-N epolamine Chemical compound OCCN1CCCC1 XBRDBODLCHKXHI-UHFFFAOYSA-N 0.000 description 1
- 150000002222 fluorine compounds Chemical class 0.000 description 1
- 229920002313 fluoropolymer Polymers 0.000 description 1
- 239000004811 fluoropolymer Substances 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 125000005010 perfluoroalkyl group Chemical group 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
- C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT97MI002764A IT1296968B1 (it) | 1997-12-15 | 1997-12-15 | Elastomeri termoplastici fluorurati |
| IT97A002764 | 1997-12-15 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JPH11240997A JPH11240997A (ja) | 1999-09-07 |
| JPH11240997A5 JPH11240997A5 (enExample) | 2006-02-02 |
| JP4358336B2 true JP4358336B2 (ja) | 2009-11-04 |
Family
ID=11378365
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP35459698A Expired - Fee Related JP4358336B2 (ja) | 1997-12-15 | 1998-12-14 | フッ素化熱可塑性エラストマー |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US6207758B1 (enExample) |
| EP (1) | EP0924257B1 (enExample) |
| JP (1) | JP4358336B2 (enExample) |
| DE (1) | DE69819458T2 (enExample) |
| IT (1) | IT1296968B1 (enExample) |
Families Citing this family (48)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6277919B1 (en) * | 1999-05-13 | 2001-08-21 | Dyneon Llc | Polymer processing additive containing a multimodal fluoropolymer and melt processable thermoplastic polymer composition employing the same |
| EP1209176A4 (en) * | 1999-06-30 | 2002-09-18 | Daikin Ind Ltd | FLEXIBLE, HEAT-RESISTANT AND NON-STICKY FLUORCHEMICAL MATERIAL |
| EP1097957A1 (en) * | 1999-11-03 | 2001-05-09 | Daikin Industries, Limited | Fluorinated thermoplastic elastomers |
| IT1320359B1 (it) * | 2000-05-23 | 2003-11-26 | Dayco Europe Srl | Cinghia dentata. |
| FR2812294B1 (fr) * | 2000-07-31 | 2003-01-17 | Solvay | Polymeres du fluorure de vinylidene, procede pour les fabriquer et utilisation de ceux-ci |
| ATE356152T1 (de) * | 2001-07-16 | 2007-03-15 | Arkema France | Vinylidenfluoridpolymer mit nicht übertragenem kettenteil und verfahren zu seiner herstellung |
| DE50207999D1 (de) * | 2002-05-07 | 2006-10-12 | Ems Chemie Ag | Gewellter Mehrschicht-Polymer-Schlauch- oder Rohrleitung mit reduzierter Längenänderung |
| US6838512B2 (en) * | 2003-06-05 | 2005-01-04 | 3M Innovative Properties Company | Cold shrink fluoroelastomeric article |
| JP4586021B2 (ja) * | 2003-09-23 | 2010-11-24 | ザ ユニバーシティ オブ ノース カロライナ アット チャペル ヒル | マイクロ流体装置の新規な材料として使用するための光硬化性ペルフルオロポリエーテル |
| US7261946B2 (en) | 2003-11-14 | 2007-08-28 | Advanced Cardiovascular Systems, Inc. | Block copolymers of acrylates and methacrylates with fluoroalkenes |
| SG150506A1 (en) * | 2004-02-13 | 2009-03-30 | Univ North Carolina State | Functional materials and novel methods for the fabrication of microfluidic devices |
| WO2007021762A2 (en) | 2005-08-09 | 2007-02-22 | The University Of North Carolina At Chapel Hill | Methods and materials for fabricating microfluidic devices |
| US7135122B2 (en) * | 2004-03-31 | 2006-11-14 | Freudenberg-Nok General Partnership | Polytetrafluoroethylene composites |
| US7342072B2 (en) * | 2004-06-30 | 2008-03-11 | Freudenberg-Nok General Partnership | Bimodal compounds having an elastomeric moiety |
| US7521508B2 (en) | 2004-06-30 | 2009-04-21 | Freudenberg-Nok General Partnership | Electron beam inter-curing of plastic and elastomer blends |
| US7244329B2 (en) * | 2004-06-30 | 2007-07-17 | Freudenberg-Nok General Partnership | Electron beam curing in a composite having a flow resistant adhesive layer |
| US7230038B2 (en) * | 2004-06-30 | 2007-06-12 | Freudenberg-Nok General Partnership | Branched chain fluoropolymers |
| US7452577B2 (en) * | 2004-06-30 | 2008-11-18 | Freudenberg-Nok General Partnership | Electron beam curing of fabricated polymeric structures |
| US20060000801A1 (en) * | 2004-06-30 | 2006-01-05 | Park Edward H | Surface bonding in halogenated polymeric components |
| US7381765B2 (en) * | 2004-11-08 | 2008-06-03 | Freudenberg-Nok General Partnership | Electrostatically dissipative fluoropolymers |
| US20060099368A1 (en) * | 2004-11-08 | 2006-05-11 | Park Edward H | Fuel hose with a fluoropolymer inner layer |
| US20060100368A1 (en) * | 2004-11-08 | 2006-05-11 | Park Edward H | Elastomer gum polymer systems |
| EP1816161A4 (en) * | 2004-11-26 | 2009-05-27 | Daikin Ind Ltd | Thermoplastic Polyethylene Composition |
| US20070045967A1 (en) * | 2005-08-31 | 2007-03-01 | Freudenberg-Nok General Partnership | Assemblies sealed with multilayer composite torsion seals having a layer of dispersed fluoroelastomer in thermoplastic |
| US20070044906A1 (en) * | 2005-08-31 | 2007-03-01 | Freudenberg-Nok General Partnership | Multilayer polymeric composites having a layer of dispersed fluoroelastomer in thermoplastic |
| US20070048476A1 (en) * | 2005-08-31 | 2007-03-01 | Freudenberg-Nok General Partnership | Assemblies sealed with multilayer composite compression seals having a layer of dispersed fluoroelastomer in thermoplastic |
| JPWO2008050588A1 (ja) * | 2006-10-25 | 2010-02-25 | ユニマテック株式会社 | 燃料系部品成形用含フッ素エラストマーおよびその組成物 |
| US7863365B2 (en) | 2006-12-20 | 2011-01-04 | Freudenberg-Nok General Partnership | Robust magnetizable elastomeric thermoplastic blends |
| US7608216B2 (en) * | 2006-12-27 | 2009-10-27 | Freudenberg-Nok General Partnership | Methods for preparing articles from processable and dimensionally stable elastomer compositions |
| US20080194724A1 (en) * | 2007-02-12 | 2008-08-14 | Pankaj Singh Gautam | Method of forming a crosslinked poly(arylene ether) film, and film formed thereby |
| EP2185647B1 (en) * | 2007-08-29 | 2015-10-14 | Solvay Specialty Polymers Italy S.p.A. | (per)fluoroelastomeric compositions |
| JP2009256658A (ja) * | 2008-03-28 | 2009-11-05 | Daikin Ind Ltd | 燃料低透過性ブロック共重合体 |
| JP6712445B2 (ja) * | 2015-05-27 | 2020-06-24 | 株式会社バルカー | 熱可塑性フッ素樹脂組成物、及び架橋体の製造方法 |
| US10590224B2 (en) | 2015-07-13 | 2020-03-17 | 3M Innovative Properties Company | Fluorinated block copolymers |
| WO2018050688A1 (en) * | 2016-09-16 | 2018-03-22 | Solvay Specialty Polymers Italy S.P.A. | Fluorinated thermoplastic elastomer |
| JP2019533036A (ja) * | 2016-09-16 | 2019-11-14 | ソルベイ スペシャルティ ポリマーズ イタリー エス．ピー．エー． | フッ素化熱可塑性エラストマー |
| EP3571247A4 (en) * | 2017-01-18 | 2020-11-11 | 3M Innovative Properties Company | FLUORINE SEQUENCED COPOLYMERS |
| US11267922B2 (en) | 2017-01-18 | 2022-03-08 | 3M Innovative Properties Company | Fluorinated block copolymers derived from nitrile cure-site monomers |
| JP7088945B2 (ja) | 2017-02-16 | 2022-06-21 | ソルベイ スペシャルティ ポリマーズ イタリー エス．ピー．エー． | パーフッ素化熱可塑性エラストマー |
| CN110300768A (zh) | 2017-02-16 | 2019-10-01 | 索尔维特殊聚合物意大利有限公司 | 用于制造三维物体的方法 |
| EP3372623A1 (en) | 2017-03-08 | 2018-09-12 | Solvay Specialty Polymers Italy S.p.A. | Fluorinated thermoplastic elastomers |
| WO2018167091A1 (en) * | 2017-03-14 | 2018-09-20 | Solvay Specialty Polymers Italy S.P.A. | Composition comprising a semi-crystalline vdf polymer and a fluorinated thermoplastic elastomer block copolymer |
| US11180648B2 (en) | 2017-03-14 | 2021-11-23 | Solvay Specialty Polymers Italy S.P.A. | Composition comprising a semi-crystalline thermoplastic fluoropolymer and a fluorinated thermoplastic elastomer block copolymer |
| KR102711160B1 (ko) | 2017-04-18 | 2024-09-30 | 솔베이 스페셜티 폴리머스 이태리 에스.피.에이. | 플루오린화 열가소성 엘라스토머 |
| EP3649193B1 (en) * | 2017-07-05 | 2022-04-20 | Solvay Specialty Polymers Italy S.p.A. | Composition containing fluorinated thermoplastic elastomers and vulcanizates |
| JP2021524512A (ja) * | 2018-05-17 | 2021-09-13 | ソルベイ スペシャルティ ポリマーズ イタリー エス．ピー．エー． | 熱収縮物品 |
| US20220372185A1 (en) * | 2019-10-03 | 2022-11-24 | Arkema Inc. | Method to process fluorinated thermoplastic elastomers |
| CN114953296B (zh) * | 2022-05-26 | 2023-08-29 | 业成科技（成都）有限公司 | 多晶相聚偏氟乙烯薄膜的制作方法以及穿戴式装置 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3810874A (en) | 1969-03-10 | 1974-05-14 | Minnesota Mining & Mfg | Polymers prepared from poly(perfluoro-alkylene oxide) compounds |
| US3865845A (en) | 1971-02-24 | 1975-02-11 | Paul Raphael Resnick | Fluorinated dioxoles |
| US3978030A (en) | 1973-08-01 | 1976-08-31 | E. I. Du Pont De Nemours And Company | Polymers of fluorinated dioxoles |
| US4051003A (en) * | 1974-07-18 | 1977-09-27 | International Telephone And Telegraph Corporation | Curable compositions diallyl esters of dicarboxylic acids and fluoropolymers |
| JPS584728B2 (ja) | 1976-06-30 | 1983-01-27 | ダイキン工業株式会社 | 含フツ素系多元セグメント化ポリマ−の製法 |
| JPS5838707A (ja) | 1981-08-20 | 1983-03-07 | イ−・アイ・デユポン・デ・ニモアス・アンド・カンパニ− | パ−フルオロ−２，２−ジメチル−１，３−ジオキソ−ルの無定形共重合体 |
| US4429143A (en) | 1981-09-28 | 1984-01-31 | E. I. Du Pont De Nemours & Co. | Cyclic monomers derived from trifluoropyruvate esters |
| US4399264A (en) | 1981-11-19 | 1983-08-16 | E. I. Du Pont De Nemours & Co. | Perfluorodioxole and its polymers |
| EP0203457B1 (en) * | 1985-05-14 | 1990-08-01 | Sumitomo Electric Industries Limited | Fluoroelastomer composition and heat shrinkable articles comprising same |
| EP0524700A1 (en) * | 1987-03-11 | 1993-01-27 | Raychem Corporation | Polymeric blends |
| US5057345A (en) * | 1989-08-17 | 1991-10-15 | Raychem Corporation | Fluoroopolymer blends |
| CA2037234A1 (en) | 1990-03-01 | 1991-09-02 | Dana P. Carlson | Fluorinated thermoplastic elastomers with improved base stability |
| IT1265033B1 (it) | 1993-05-28 | 1996-10-28 | Ausimont Spa | Polivinilidenfluoruro ad elevate prestazioni meccaniche ed elevata stabilita' termochimica, e relativo processo di preparazione |
| IT1265223B1 (it) | 1993-11-25 | 1996-10-31 | Ausimont Spa | Processo per la preparazione di polimeri del vinilidenfluoruro |
| IT1265460B1 (it) * | 1993-12-29 | 1996-11-22 | Ausimont Spa | Elastomeri termoplastici fluorurati dotati di migliorate proprieta' meccaniche ed elastiche, e relativo processo di preparazione |
| IT1269513B (it) | 1994-05-18 | 1997-04-01 | Ausimont Spa | Elastomeri termoplastici fluorurati dotati di migliorate proprieta' meccaniche ed elastiche,e relativo processo di preparazione |
-
1997
- 1997-12-15 IT IT97MI002764A patent/IT1296968B1/it active IP Right Grant
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1998
- 1998-11-26 EP EP98122415A patent/EP0924257B1/en not_active Expired - Lifetime
- 1998-11-26 DE DE69819458T patent/DE69819458T2/de not_active Expired - Lifetime
- 1998-12-14 JP JP35459698A patent/JP4358336B2/ja not_active Expired - Fee Related
- 1998-12-14 US US09/210,394 patent/US6207758B1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| DE69819458D1 (de) | 2003-12-11 |
| ITMI972764A1 (it) | 1999-06-15 |
| US6207758B1 (en) | 2001-03-27 |
| EP0924257B1 (en) | 2003-11-05 |
| EP0924257A1 (en) | 1999-06-23 |
| IT1296968B1 (it) | 1999-08-03 |
| JPH11240997A (ja) | 1999-09-07 |
| DE69819458T2 (de) | 2004-09-09 |
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