JP4043520B2 - 酢酸ビニル製造用不均質バイメタルパラジウム―金触媒 - Google Patents

酢酸ビニル製造用不均質バイメタルパラジウム―金触媒 Download PDF

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Publication number
JP4043520B2
JP4043520B2 JP54263697A JP54263697A JP4043520B2 JP 4043520 B2 JP4043520 B2 JP 4043520B2 JP 54263697 A JP54263697 A JP 54263697A JP 54263697 A JP54263697 A JP 54263697A JP 4043520 B2 JP4043520 B2 JP 4043520B2
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Prior art keywords
catalyst
gold
palladium
vinyl acetate
compound
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Expired - Fee Related
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JP54263697A
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English (en)
Japanese (ja)
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JP2000511105A (ja
JP2000511105A5 (index.php
Inventor
ワン，タオ
ブロウサード，ジェリー・エイ
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セラニーズ・インターナショナル・コーポレーション
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0207—Pretreatment of the support
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/52—Gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/58—Platinum group metals with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0205—Impregnation in several steps
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
    • C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
    • C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
JP54263697A 1996-05-24 1997-05-15 酢酸ビニル製造用不均質バイメタルパラジウム―金触媒 Expired - Fee Related JP4043520B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US08/655,571 US5700753A (en) 1996-05-24 1996-05-24 Heterogeneous bimetallic palladium-gold catalyst for vinyl acetate production
US08/655,571 1996-05-24
PCT/US1997/008491 WO1997044130A1 (en) 1996-05-24 1997-05-15 Heterogeneous bimetallic palladium-gold catalyst for vinyl acetate production

Publications (3)

Publication Number Publication Date
JP2000511105A JP2000511105A (ja) 2000-08-29
JP2000511105A5 JP2000511105A5 (index.php) 2004-12-09
JP4043520B2 true JP4043520B2 (ja) 2008-02-06

Family

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Family Applications (1)

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JP54263697A Expired - Fee Related JP4043520B2 (ja) 1996-05-24 1997-05-15 酢酸ビニル製造用不均質バイメタルパラジウム―金触媒

Country Status (28)

Country Link
US (1) US5700753A (index.php)
EP (1) EP0906151B1 (index.php)
JP (1) JP4043520B2 (index.php)
CN (1) CN1093001C (index.php)
AR (2) AR007116A1 (index.php)
AT (1) ATE203187T1 (index.php)
AU (1) AU713368B2 (index.php)
BR (1) BR9709033A (index.php)
CA (1) CA2254912C (index.php)
CZ (1) CZ297144B6 (index.php)
DE (1) DE69705720T2 (index.php)
DK (1) DK0906151T3 (index.php)
ES (1) ES2159137T3 (index.php)
HU (1) HUP9904003A3 (index.php)
ID (1) ID16953A (index.php)
IN (1) IN191380B (index.php)
MY (1) MY114044A (index.php)
NO (1) NO316363B1 (index.php)
NZ (1) NZ332917A (index.php)
PL (1) PL189150B1 (index.php)
RU (1) RU2182516C2 (index.php)
SA (1) SA97180048B1 (index.php)
TR (1) TR199802415T2 (index.php)
TW (1) TW448074B (index.php)
UA (1) UA61073C2 (index.php)
WO (1) WO1997044130A1 (index.php)
YU (1) YU49149B (index.php)
ZA (1) ZA973748B (index.php)

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US6034030A (en) * 1994-02-22 2000-03-07 Celanese International Corporation Vinyl acetate catalyst preparation method
DE4443701C1 (de) * 1994-12-08 1996-08-29 Degussa Schalenkatalysator, Verfahren zu seiner Herstellung und seine Verwendung
US5968869A (en) * 1997-06-03 1999-10-19 Celanese International Corporation Vinyl acetate catalyst comprising palladium and gold deposited on a copper containing carrier
US5948724A (en) * 1997-10-28 1999-09-07 Celanese International Corporation Vinyl acetate catalyst comprising metallic palladium and gold and cupric acetate
CN1292726A (zh) * 1998-02-05 2001-04-25 恩格尔哈德公司 减缓pd－Au醋酸乙烯催化剂的老化
US6017847A (en) * 1998-06-02 2000-01-25 Celanese International Corporation Vinyl acetate catalyst prepared with potassium aurate and comprising metallic palladium and gold on a carrier precoated with copper
ID26891A (id) * 1998-06-02 2001-02-15 Celanese Internasional Corp Katalis vinil asetat yang terdiri dari palladium logam dan emas yang dibuat dengan potasium aurat
US6015769A (en) * 1998-06-02 2000-01-18 Celanese International Corporation Vinyl acetate catalyst comprising metallic palladium, gold and copper supported on a carrier and prepared with potassium aurate
JP2000070718A (ja) 1998-06-17 2000-03-07 Nippon Shokubai Co Ltd ベンジルエステルの製造方法
DE19914066A1 (de) * 1999-03-27 2000-10-05 Celanese Chem Europe Gmbh Katalysatoren für die Gasphasenoxidation von Ethylen und Essigsäure zu Vinylacetat, Verfahren zu ihrer Herstellung und ihre Verwendung
US6821923B1 (en) * 1999-04-08 2004-11-23 Dow Global Technologies Inc. Method of preparing a catalyst containing gold and titanium
EP1185495B1 (en) 1999-04-14 2005-06-15 Showa Denko K K Catalyst for production of acetic acid or acetic acid and ethyl acetate, process for its production and process for production of acetic acid or acetic acid and ethyl acetate using it
US6303537B1 (en) 1999-11-17 2001-10-16 Celanese International Corporation Vinyl acetate catalyst comprising metallic palladium and gold and prepared utilizing sonication
US6509292B1 (en) 2001-03-30 2003-01-21 Sud-Chemie Inc. Process for selective hydrogenation of acetylene in an ethylene purification process
US6936568B2 (en) * 2002-06-12 2005-08-30 Sud-Chemie Inc. Selective hydrogenation catalyst
FR2842125B1 (fr) * 2002-07-09 2006-03-31 Sicat Methode de preparation par impregnation biphasique de nouveaux catalyseurs pour catalyse heterogene, et utilisation desdits catalyseurs
US7655021B2 (en) * 2003-03-10 2010-02-02 Boston Scientific Scimed, Inc. Dilator with expandable member
NZ547073A (en) * 2003-12-19 2010-05-28 Celanese Int Corp Layered support material for catalysts
TW201236755A (en) * 2003-12-19 2012-09-16 Celanese Int Corp Halide free precursors for catalysts
WO2006068764A2 (en) 2004-12-20 2006-06-29 Celanese International Corporation Modified support materials for catalysts
US7507495B2 (en) * 2004-12-22 2009-03-24 Brookhaven Science Associates, Llc Hydrogen absorption induced metal deposition on palladium and palladium-alloy particles
JP4261502B2 (ja) * 2005-03-14 2009-04-30 富士通マイクロエレクトロニクス株式会社 検証支援装置、検証支援方法、検証支援プログラム、および記録媒体
US8227369B2 (en) 2005-05-25 2012-07-24 Celanese International Corp. Layered composition and processes for preparing and using the composition
US7704919B2 (en) * 2005-08-01 2010-04-27 Brookhaven Science Associates, Llc Electrocatalysts having gold monolayers on platinum nanoparticle cores, and uses thereof
KR100917495B1 (ko) * 2006-11-27 2009-09-16 나노스텔라 인코포레이티드 팔라듐-금을 포함하는 엔진 배기가스 촉매
US8258070B2 (en) * 2006-11-27 2012-09-04 WGCH Technology Limited Engine exhaust catalysts containing palladium-gold
US7534738B2 (en) 2006-11-27 2009-05-19 Nanostellar, Inc. Engine exhaust catalysts containing palladium-gold
US7709414B2 (en) * 2006-11-27 2010-05-04 Nanostellar, Inc. Engine exhaust catalysts containing palladium-gold
US7811968B2 (en) * 2007-05-11 2010-10-12 Lyondell Chemical Technology, L.P. Preparation of palladium-gold catalysts
DE102007025358A1 (de) * 2007-05-31 2009-01-08 Süd-Chemie AG Verfahren zur Herstellung eines mit Pd und/oder Au beladenen Schalenkatalysators
DE102007025362A1 (de) 2007-05-31 2008-12-11 Süd-Chemie AG Dotierter Pd/Au-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung
DE102007025223A1 (de) 2007-05-31 2008-12-04 Süd-Chemie AG Zirkoniumoxid-dotierter VAM-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung
DE102007025356A1 (de) * 2007-05-31 2009-01-08 Süd-Chemie AG Verfahren zur Herstellung eines Schalenkatalysators und Schalenkatalysator
DE102007025443A1 (de) 2007-05-31 2008-12-04 Süd-Chemie AG Pd/Au-Schalenkatalysator enthaltend HfO2, Verfahren zu dessen Herstellung sowie dessen Verwendung
DE102007025315A1 (de) * 2007-05-31 2008-12-11 Süd-Chemie AG Katalysator zur selektiven Hydrierung acetylenischer Kohlenwasserstoffe und Verfahren zu seiner Herstellung
DE102007025442B4 (de) 2007-05-31 2023-03-02 Clariant International Ltd. Verwendung einer Vorrichtung zur Herstellung eines Schalenkatalysators und Schalenkatalysator
DE102008059341A1 (de) 2008-11-30 2010-06-10 Süd-Chemie AG Katalysatorträger, Verfahren zu seiner Herstellung sowie Verwendung
US8071504B2 (en) * 2008-12-19 2011-12-06 Caterpillar Inc. Exhaust system having a gold-platinum group metal catalyst
GB201110850D0 (en) 2011-03-04 2011-08-10 Johnson Matthey Plc Catalyst and mehtod of preparation
JP6441454B2 (ja) * 2015-03-09 2018-12-19 国立研究開発法人産業技術総合研究所 金ヒドロキソ陰イオン錯体溶液

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CH534005A (de) * 1968-02-01 1973-02-28 Bayer Ag Verfahren zur Herstellung eines Palladium und Gold enthaltenden Katalysators
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Also Published As

Publication number Publication date
AU713368B2 (en) 1999-12-02
NO316363B1 (no) 2004-01-19
YU49149B (sh) 2004-03-12
ZA973748B (en) 1998-10-30
PL330065A1 (en) 1999-04-26
ID16953A (id) 1997-11-27
EP0906151B1 (en) 2001-07-18
US5700753A (en) 1997-12-23
NO985446L (no) 1998-11-23
DK0906151T3 (da) 2001-09-24
WO1997044130A1 (en) 1997-11-27
JP2000511105A (ja) 2000-08-29
UA61073C2 (en) 2003-11-17
AR007116A1 (es) 1999-10-13
ES2159137T3 (es) 2001-09-16
CN1219893A (zh) 1999-06-16
AR011995A2 (es) 2000-09-13
TW448074B (en) 2001-08-01
MY114044A (en) 2002-07-31
DE69705720T2 (de) 2002-06-13
DE69705720D1 (de) 2001-08-23
NO985446D0 (no) 1998-11-23
BR9709033A (pt) 1999-08-03
AU3072097A (en) 1997-12-09
PL189150B1 (pl) 2005-06-30
CZ382598A3 (cs) 1999-08-11
EP0906151A1 (en) 1999-04-07
CZ297144B6 (cs) 2006-09-13
RU2182516C2 (ru) 2002-05-20
CA2254912C (en) 2006-02-14
YU15897A (sh) 1999-06-15
SA97180048B1 (ar) 2005-12-21
IN191380B (index.php) 2003-11-29
CA2254912A1 (en) 1997-11-27
CN1093001C (zh) 2002-10-23
HUP9904003A1 (hu) 2000-03-28
TR199802415T2 (xx) 1999-02-22
ATE203187T1 (de) 2001-08-15
NZ332917A (en) 2000-03-27
HUP9904003A3 (en) 2000-09-28

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